JP4990624B2 - アルキルオキシシラングラフト化熱可塑性ポリマーに基づくハイブリッド無機−有機ポリマー電解質膜(pem) - Google Patents

アルキルオキシシラングラフト化熱可塑性ポリマーに基づくハイブリッド無機−有機ポリマー電解質膜(pem) Download PDF

Info

Publication number
JP4990624B2
JP4990624B2 JP2006533486A JP2006533486A JP4990624B2 JP 4990624 B2 JP4990624 B2 JP 4990624B2 JP 2006533486 A JP2006533486 A JP 2006533486A JP 2006533486 A JP2006533486 A JP 2006533486A JP 4990624 B2 JP4990624 B2 JP 4990624B2
Authority
JP
Japan
Prior art keywords
polymer
groups
group
electrolyte membrane
pvdf
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2006533486A
Other languages
English (en)
Japanese (ja)
Other versions
JP2007500280A5 (enExample
JP2007500280A (ja
Inventor
シーウェン リー
メイリン ルイ
クンフイ スン
ウェン リー
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Georgia Tech Research Corp
Original Assignee
Georgia Tech Research Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Georgia Tech Research Corp filed Critical Georgia Tech Research Corp
Publication of JP2007500280A publication Critical patent/JP2007500280A/ja
Publication of JP2007500280A5 publication Critical patent/JP2007500280A5/ja
Application granted granted Critical
Publication of JP4990624B2 publication Critical patent/JP4990624B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F259/00Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
    • C08F259/08Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F287/00Macromolecular compounds obtained by polymerising monomers on to block polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/08Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
    • C08F290/12Polymers provided for in subclasses C08C or C08F
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/06Oxidation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/42Introducing metal atoms or metal-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42Block-or graft-polymers containing polysiloxane sequences
    • C08G77/442Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Conductive Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Fuel Cell (AREA)
JP2006533486A 2003-05-28 2004-05-28 アルキルオキシシラングラフト化熱可塑性ポリマーに基づくハイブリッド無機−有機ポリマー電解質膜(pem) Expired - Fee Related JP4990624B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US47381203P 2003-05-28 2003-05-28
US60/473,812 2003-05-28
PCT/US2004/016896 WO2005001037A2 (en) 2003-05-28 2004-05-28 Electrolyte membranes based on alkyloxysilane grafted thermoplastic polymers

Publications (3)

Publication Number Publication Date
JP2007500280A JP2007500280A (ja) 2007-01-11
JP2007500280A5 JP2007500280A5 (enExample) 2007-07-12
JP4990624B2 true JP4990624B2 (ja) 2012-08-01

Family

ID=33551464

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006533486A Expired - Fee Related JP4990624B2 (ja) 2003-05-28 2004-05-28 アルキルオキシシラングラフト化熱可塑性ポリマーに基づくハイブリッド無機−有機ポリマー電解質膜(pem)

Country Status (3)

Country Link
US (1) US7935735B2 (enExample)
JP (1) JP4990624B2 (enExample)
WO (1) WO2005001037A2 (enExample)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005005046A (ja) * 2003-06-10 2005-01-06 Canon Inc シロキサン高分子電解質膜及びそれを用いた固体高分子型燃料電池
US7576165B2 (en) 2004-01-27 2009-08-18 Georgia Institute Of Technology Heterocycle grafted monomers and related polymers and hybrid inorganic-organic polymer membranes
US7259230B2 (en) * 2004-06-07 2007-08-21 Battelle Energy Alliance, Llc Polybenzimidazole compounds, polymeric media, and methods of post-polymerization modifications
JP4825446B2 (ja) * 2005-05-06 2011-11-30 信越化学工業株式会社 固体高分子電解質膜及びその製造方法、並びに燃料電池
US8021676B2 (en) 2005-07-08 2011-09-20 Advanced Cardiovascular Systems, Inc. Functionalized chemically inert polymers for coatings
JP2007329062A (ja) * 2006-06-09 2007-12-20 Shin Etsu Chem Co Ltd ダイレクトメタノール型燃料電池用膜電極接合体及び燃料電池
JP5093440B2 (ja) * 2006-06-09 2012-12-12 信越化学工業株式会社 ダイレクトメタノール型燃料電池用電解質膜・電極接合体
JP2007329067A (ja) * 2006-06-09 2007-12-20 Shin Etsu Chem Co Ltd 電解質膜・電極接合体及びそれを用いた固体高分子型燃料電池
JP5131419B2 (ja) * 2006-06-09 2013-01-30 信越化学工業株式会社 ダイレクトメタノール型燃料電池用電解質膜・電極接合体
JP2007329069A (ja) * 2006-06-09 2007-12-20 Shin Etsu Chem Co Ltd 固体高分子電解質膜及び燃料電池
JP5137174B2 (ja) 2006-10-06 2013-02-06 独立行政法人日本原子力研究開発機構 シラン架橋構造を付与した燃料電池用高分子電解質膜の製造方法
US8603698B2 (en) * 2007-04-02 2013-12-10 Shin-Etsu Chemical Co., Ltd. Electrolyte for fuel cell, electrolyte membrane for fuel cell, binder for fuel cell, membrane electrode assembly for fuel cell, and fuel cell
FR2928920B1 (fr) * 2008-03-19 2012-09-14 Centre Nat Rech Scient Precurseur hybride sulfone, son procede de synthese et ses utilisations.
US7790803B2 (en) * 2008-06-02 2010-09-07 Uop Llc Crosslinked organic-inorganic hybrid membranes and their use in gas separation
GB0812185D0 (en) 2008-07-03 2008-08-13 Dow Corning Polymers modified by silanes
GB0812186D0 (en) 2008-07-03 2008-08-13 Dow Corning Modified polyolefins
US7947410B2 (en) 2008-08-22 2011-05-24 Toyota Motor Engineering & Manufacturing North America, Inc. Fuel cell electrodes with triazole modified polymers and membrane electrode assemblies incorporating same
KR20120023724A (ko) * 2009-04-30 2012-03-13 다우 코닝 코포레이션 실란에 의해 개질된 엘라스토머 조성물
GB201000117D0 (en) 2010-01-06 2010-02-17 Dow Corning Organopolysiloxanes containing an unsaturated group
GB201000121D0 (en) 2010-01-06 2010-02-17 Dow Corning Modified polyolefins
GB201000120D0 (en) 2010-01-06 2010-02-17 Dow Corning Process for forming crosslinked and branched polymers
RU2451540C1 (ru) * 2010-12-07 2012-05-27 Государственное образовательное учреждение высшего профессионального образования "Кубанский государственный университет" (ГОУ ВПО КубГУ) Способ получения модифицированной катионообменной мембраны
US10950849B2 (en) 2011-06-30 2021-03-16 Cornell University Hybrid materials and nanocomposite materials, methods of making same, and uses thereof
JP2013093260A (ja) 2011-10-27 2013-05-16 Samsung Electronics Co Ltd 燃料電池用電解質膜とその製造方法、膜電極接合体、及び燃料電池
JP5435094B2 (ja) * 2012-09-07 2014-03-05 信越化学工業株式会社 ダイレクトメタノール型燃料電池用電解質膜・電極接合体
FR3002859A1 (fr) * 2013-03-07 2014-09-12 Commissariat Energie Atomique Utilisation d'un reseau polysiloxane fonctionnalise pour stabiliser chimiquement un polymere, membrane ainsi stabilisee, son procede de preparation et ses utilisations
KR102543248B1 (ko) 2019-08-08 2023-06-14 주식회사 엘지에너지솔루션 겔 고분자 전해질용 고분자, 이를 포함하는 겔 고분자 전해질 및 리튬 이차전지

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2681319A (en) * 1951-01-10 1954-06-15 Rohm & Haas Permselective films of anionexchange resins
US3716391A (en) * 1968-09-14 1973-02-13 Furukawa Electric Co Ltd Process for graft polymerization onto organic macromolecular materials
JPS5512141A (en) * 1978-07-13 1980-01-28 Mitsubishi Petrochem Co Ltd Manufacturing of ion exchange membrane
US4491650A (en) 1982-05-05 1985-01-01 Essex Specialty Products, Inc. Acrylic resin having pendant silane groups thereon, and methods of making and using the same
US4567107A (en) * 1982-05-05 1986-01-28 Essex Specialty Products, Inc. Acrylic resin having pendant silane groups thereon, and methods of making and using the same
US4604443A (en) * 1985-04-30 1986-08-05 Ppg Industries, Inc. Partial hydrolyzates containing hydrolyzable moieties from organosilane compounds
US4753993A (en) * 1985-08-21 1988-06-28 Union Carbide Corporation Compositions based on thermoplastic polymers and metal carboxylate silanol condensation catalysts
JPH02115234A (ja) * 1988-10-26 1990-04-27 Tdk Corp 架橋ポリフッ化ビニリデンの製造方法
JPH02291603A (ja) 1989-01-07 1990-12-03 Hitachi Maxell Ltd イオン伝導性ポリマー電解質およびこれを用いた電池
US4978481A (en) * 1989-01-13 1990-12-18 Ciba-Geigy Corporation Process for the encapsulation of preformed substrates by graft copolymerization
IT1244483B (it) * 1990-12-21 1994-07-15 Eniricerche Spa Elettrolita polimerico solido a base di poliviniletere reticolato
JPH0720730A (ja) * 1993-06-30 1995-01-24 Fujitsu Ltd 画像形成装置
IT1264697B1 (it) * 1993-07-09 1996-10-04 Eniricerche Spa Elettrolita polimerico solido costituito da un polietere reticolato inglobante un composto ionico ed un plastificante liquido
JP3234721B2 (ja) * 1993-09-18 2001-12-04 等 金澤 高分子材料の表面改質方法
AU723265B2 (en) * 1996-01-22 2000-08-24 Usf Filtration And Separations Group Inc. Highly porous polyvinylidene difluoride membranes
JP3422627B2 (ja) * 1996-05-16 2003-06-30 旭化成株式会社 架橋高分子固体電解質および電池
JPH1112330A (ja) * 1997-06-23 1999-01-19 Nippon Kasei Chem Co Ltd グラフト化含フッ素ポリマーおよび架橋含フッ素ポリマー
JP4017741B2 (ja) * 1998-05-11 2007-12-05 旭化成エレクトロニクス株式会社 架橋高分子複合電解質および電池
ATE277121T1 (de) * 1998-06-22 2004-10-15 Gen Electric Silanvulkanisierte thermoplastische elastomeren
FR2811323B1 (fr) * 2000-07-07 2006-10-06 Fuma Tech Gmbh Materiau hybride, utilisation dudit materiau hybride et procede de sa fabrication
WO2002006384A1 (en) * 2000-07-14 2002-01-24 Mimotopes Pty Ltd Activated modular grafted polymeric surfaces
JP4858741B2 (ja) * 2000-07-26 2012-01-18 日立化成工業株式会社 高分子電解質ワニス、これを用いた高分子電解質、複合電極、高分子電解質エレメント又は電気化学的デバイス
JP2002114887A (ja) * 2000-10-06 2002-04-16 Sumitomo Bakelite Co Ltd シラン架橋ポリオレフィン樹脂組成物
JP3924675B2 (ja) * 2001-01-09 2007-06-06 独立行政法人産業技術総合研究所 プロトン伝導性膜、その製造方法及びそれを用いた燃料電池

Also Published As

Publication number Publication date
US20070100078A1 (en) 2007-05-03
WO2005001037A2 (en) 2005-01-06
WO2005001037A3 (en) 2005-03-03
JP2007500280A (ja) 2007-01-11
US7935735B2 (en) 2011-05-03

Similar Documents

Publication Publication Date Title
US7935735B2 (en) Hybrid inorganic-organic polymer electrolyte membranes (PEMs) based on alkyloxysilane grafted thermoplastic polymers
US7183370B2 (en) Phosphonic-acid grafted hybrid inorganic-organic proton electrolyte membranes (PEMs)
US8465857B2 (en) Proton exchange membranes (PEM) based on hybrid inorganic-organic copolymers with grafted phosphoric acid groups and implanted metal cations
CN100511489C (zh) 聚合物固体电解质用组合物、聚合物固体电解质、聚合物固体电解质电池和共聚物
JP2007504637A (ja) イミダゾール環末端可撓性分岐をグラフトしたハイブリッド無機−有機ポリマーを基剤とするポリマー電解質膜(pem)
JP2008311226A (ja) 複合高分子電解質膜、膜−電極接合体および燃料電池
JP4582740B2 (ja) プロトン導電性物質
US9227187B2 (en) Method for preparing proton-conducting inorganic particles
JP2001302721A (ja) 高プロトン伝導性電解質
Enomoto et al. Synthesis of copolymer grafts containing sulfoalkyl and hydrophilic groups in polymer electrolyte membranes
US20090047563A1 (en) Vinyl polymer of sulfonated monomer, production method thereof, polymer electrolyte, polymer electrolyte membrane and fuel cell
JP4992708B2 (ja) グラフト共重合体及びその製造方法
JP3111817B2 (ja) プロトン導電性高分子固体電解質
US7993767B2 (en) Solid-state polymer electrolyte membrane, method for manufacture thereof and solid-state polymer electrolyte fuel cell therewith
JP3922162B2 (ja) プロトン伝導材料
JP2007258003A (ja) 高分子電解質膜、膜−電極接合体及び固体高分子型燃料電池
US20130092873A1 (en) Method for preparing a composite material comprising a polymeric matrix and a filler consisting in ion exchange inorganic particles
KR20190026133A (ko) 아민화된 폴리스티렌에틸렌부틸렌스틸렌 공중합체를 포함하는 연료전지용 음이온교환막 및 이의 제조방법
JP4099699B2 (ja) プロトン伝導材料
Bingöl et al. Proton conducting phosphonated polymers and membranes for fuel cells
JP2004161873A (ja) 多分岐高分子、その製造方法、固体電解質及び電気化学素子並びに分離膜
ES2783831T3 (es) Método de preparación de partículas inorgánicas funcionalizadas con polímeros bifuncionales conductores de protones
JP4305186B2 (ja) 高耐久固体高分子電解質及び燃料電池

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060313

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20070528

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20070528

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20100826

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20101213

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110314

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110509

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20110809

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20110816

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20111109

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20120305

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20120402

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20120502

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150511

Year of fee payment: 3

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313117

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150511

Year of fee payment: 3

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees