JP4982050B2 - 塗料組成物及び塗装方法 - Google Patents
塗料組成物及び塗装方法 Download PDFInfo
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- JP4982050B2 JP4982050B2 JP2005062061A JP2005062061A JP4982050B2 JP 4982050 B2 JP4982050 B2 JP 4982050B2 JP 2005062061 A JP2005062061 A JP 2005062061A JP 2005062061 A JP2005062061 A JP 2005062061A JP 4982050 B2 JP4982050 B2 JP 4982050B2
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- SGLXWMAOOWXVAM-UHFFFAOYSA-L manganese(2+);octanoate Chemical compound [Mn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O SGLXWMAOOWXVAM-UHFFFAOYSA-L 0.000 description 1
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Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Description
しかし、このような含窒素化合物は、塗料を着色してしまう場合があり、また形成塗膜における経時的な黄変を引き起こす場合もある。そのため、特に白色系の塗料においては使用しづらく、改善が求められている状況である。
本発明者は、このような目的を達成するため鋭意検討を行った結果、含窒素化合物として、特定のポリイソシアネートとアミン化合物との反応物を使用することに想到し、本発明の完成に至った。
1.酸化硬化形樹脂、金属ドライヤー、及び含窒素化合物を含み、全溶剤のうち50重量%以上が脂肪族炭化水素である塗料組成物であって、該含窒素化合物として、
(p)炭素数1〜12のモノアルコールとイソシアネート化合物との反応によって得られる、アロファネート構造を有するポリイソシアネートと、
(q)ベンジルアミン、エチルアミン、n−プロピルアミン、sec−プロピルアミン、n−ブチルアミン、sec−ブチルアミン、tert−ブチルアミン、n−ペンチルアミン、α‐メチルブチルアミン、α‐エチルプロピルアミン、β‐エチルブチルアミン、ヘキシルアミン、オクチルアミン、デシルアミン、ラウリルアミン、ステアリルアミン、シクロヘキシルアミン、アニリンから選ばれる一種以上のアミン化合物
との反応生成物を、酸化硬化形樹脂の固形分100重量部に対し0.1〜20重量部含むことを特徴とする塗料組成物。
2.基材に対し下塗材を塗装した後、上塗材として1.記載の塗料組成物を塗装することを特徴とする塗装方法。
3.前記下塗材がエポキシ樹脂下塗材である2.記載の塗装方法。
2)エポキシ基含有ビニル単量体と、この単量体と共重合可能な他のビニル単量体とを共重合させた後、前記エポキシ基含有ビニル単量体に不飽和脂肪酸を付加させて得られた樹脂。
3)酸化重合性基を有するビニル単量体と、この単量体と共重合可能な他のビニル単量体とをアルキド樹脂にグラフト重合させて得られた樹脂。
また、体質顔料としては、例えば重質炭酸カルシウム、クレー、カオリン、タルク、沈降性硫酸バリウム、炭酸バリウム、ホワイトカーボン、珪藻土等が挙げられる。このような体質顔料を適宜混合することにより、形成塗膜の光沢度、肉厚感等を調整することができる。
本発明の塗料組成物を塗装する際には、基材に直接塗装することもできるし、何らかの表面処理(シーラー、プライマー、サーフェーサ、フィラー、パテ等の下塗材による下地処理等)を施した上に塗装することも可能である。
エポキシ樹脂下塗材の形態は、1液型、2液型のいずれであってもよい。2液型の場合、硬化剤としてはアミン化合物等を含むものが使用できる。
酸化硬化形樹脂40重量部を容器に仕込み、これを攪拌羽根で攪拌しながらn−ブチルアミン0.3重量部を混合し、次いでポリイソシアネート0.4重量部を混合後5分間攪拌した。さらに、酸化チタン80重量部、酸化硬化形樹脂160重量部、増粘剤4重量部、消泡剤2重量部、金属ドライヤー8重量部を順次常法により混合して塗料1を製造した。この塗料1の全溶剤中における脂肪族炭化水素の比率は70重量%である。
上記方法にて得られた塗料1を、すきま125μmのフィルムアプリケータを用いて200×120mmの白色紙に塗付し、標準状態(温度23℃、相対湿度50%)で48時間乾燥養生した。このときの塗膜の色相を分光光度計(東京電色社製「TOPSCAN TC−1800」)にて測定し、CIE1976L*a*b*色空間におけるb*値を算出した。次いで、塗膜を標準状態にて7日間養生後、同様にb*値を算出し、さらに初期値との差(Δb*)を求めた。このb*値は塗膜の黄味の度合を表すものである(b*値が大である場合は黄味が強いことを表す)。結果を表1に示す。
上記方法にて得られた塗料1を、すきま125μmのフィルムアプリケータを用いて150×120mmのガラス板に塗付し、標準状態で所定時間(8時間、16時間)乾燥養生後、塗膜表面にキシレンをスポットし、塗膜溶出の状態を観察した。このとき溶出が認められなかったものを「○」、溶出が認められたものを「×」として評価を行った。結果を表1に示す。
200×150mmのブリキ板に対し、2液反応硬化型エポキシ樹脂下塗材(主剤成分:エポキシ当量1350g/eqのフェノールノボラック型エポキシ樹脂、硬化剤成分:活性水素当量360g/eqのポリアミドアミン)を塗付量0.1kg/m2で刷毛塗りし、標準状態で24時間乾燥養生した。次いで、上記方法にて得られた塗料1を塗付量0.12kg/m2で刷毛塗りし、所定時間(8時間、16時間、24時間、48時間)乾燥養生後、再度塗料1を塗付量0.12kg/m2で刷毛塗りした。このときの塗膜の表面状態を観察し、異常が認められなかったものを「○」、リフティング現象は認められなかったが溶解現象が認められたものを「△」、リフティング現象が認められたものを「×」として評価を行った。結果を表1に示す。
n−ブチルアミンに代えてオクチルアミンを使用した以外は、実施例1と同様にして塗料2を製造した。以上の方法で得られた塗料2について、実施例1と同様の試験を行った。結果を表1に示す。
酸化硬化形樹脂200重量部、1,10−フェナントロリン0.7重量部、酸化チタン80重量部、増粘剤4重量部、消泡剤2重量部、金属ドライヤー8重量部を常法により混合して塗料3を製造した。以上の方法で得られた塗料3について、実施例1と同様の試験を行った。結果を表1に示す。
酸化硬化形樹脂200重量部、2,2’−ビピリジル0.7重量部、酸化チタン80重量部、増粘剤4重量部、消泡剤2重量部、金属ドライヤー8重量部を常法により混合して塗料4を製造した。以上の方法で得られた塗料4について、実施例1と同様の試験を行った。結果を表1に示す。
酸化硬化形樹脂200重量部、酸化チタン80重量部、増粘剤4重量部、消泡剤2重量部、金属ドライヤー8重量部を常法により混合して塗料5を製造した。以上の方法で得られた塗料5について、実施例1と同様の試験を行った。結果を表1に示す。
Claims (3)
- 酸化硬化形樹脂、金属ドライヤー、及び含窒素化合物を含み、全溶剤のうち50重量%以上が脂肪族炭化水素である塗料組成物であって、該含窒素化合物として、
(p)炭素数1〜12のモノアルコールとイソシアネート化合物との反応によって得られる、アロファネート構造を有するポリイソシアネートと、
(q)ベンジルアミン、エチルアミン、n−プロピルアミン、sec−プロピルアミン、n−ブチルアミン、sec−ブチルアミン、tert−ブチルアミン、n−ペンチルアミン、α‐メチルブチルアミン、α‐エチルプロピルアミン、β‐エチルブチルアミン、ヘキシルアミン、オクチルアミン、デシルアミン、ラウリルアミン、ステアリルアミン、シクロヘキシルアミン、アニリンから選ばれる一種以上のアミン化合物
との反応生成物を、酸化硬化形樹脂の固形分100重量部に対し0.1〜20重量部含むことを特徴とする塗料組成物。 - 基材に対し下塗材を塗装した後、上塗材として請求項1記載の塗料組成物を塗装することを特徴とする塗装方法。
- 前記下塗材がエポキシ樹脂下塗材である請求項2記載の塗装方法。
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