JP4873831B2 - ポリウレタン組成物及びウレタン樹脂フィルム - Google Patents
ポリウレタン組成物及びウレタン樹脂フィルム Download PDFInfo
- Publication number
- JP4873831B2 JP4873831B2 JP2003372625A JP2003372625A JP4873831B2 JP 4873831 B2 JP4873831 B2 JP 4873831B2 JP 2003372625 A JP2003372625 A JP 2003372625A JP 2003372625 A JP2003372625 A JP 2003372625A JP 4873831 B2 JP4873831 B2 JP 4873831B2
- Authority
- JP
- Japan
- Prior art keywords
- urethane resin
- resin film
- trifunctional
- film
- polyurethane composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002803 thermoplastic polyurethane Polymers 0.000 title claims description 47
- 239000000203 mixture Substances 0.000 title claims description 43
- 229920002635 polyurethane Polymers 0.000 title claims description 39
- 239000004814 polyurethane Substances 0.000 title claims description 39
- 229920005862 polyol Polymers 0.000 claims description 36
- -1 caprolactone polyol Chemical class 0.000 claims description 26
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 23
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 23
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000005056 polyisocyanate Substances 0.000 claims description 17
- 229920001228 polyisocyanate Polymers 0.000 claims description 17
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 15
- 150000003077 polyols Chemical class 0.000 claims description 14
- 239000012790 adhesive layer Substances 0.000 claims description 6
- 230000001681 protective effect Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 description 23
- 238000000576 coating method Methods 0.000 description 15
- 238000011109 contamination Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 239000000126 substance Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 239000000976 ink Substances 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 8
- 239000010410 layer Substances 0.000 description 7
- 229920005749 polyurethane resin Polymers 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000011527 polyurethane coating Substances 0.000 description 5
- 239000011342 resin composition Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 230000001588 bifunctional effect Effects 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 238000003916 acid precipitation Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- YXRKNIZYMIXSAD-UHFFFAOYSA-N 1,6-diisocyanatohexane Chemical compound O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O YXRKNIZYMIXSAD-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 229920005906 polyester polyol Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003372625A JP4873831B2 (ja) | 2003-10-31 | 2003-10-31 | ポリウレタン組成物及びウレタン樹脂フィルム |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003372625A JP4873831B2 (ja) | 2003-10-31 | 2003-10-31 | ポリウレタン組成物及びウレタン樹脂フィルム |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005133013A JP2005133013A (ja) | 2005-05-26 |
| JP2005133013A5 JP2005133013A5 (enExample) | 2006-12-14 |
| JP4873831B2 true JP4873831B2 (ja) | 2012-02-08 |
Family
ID=34648956
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003372625A Expired - Lifetime JP4873831B2 (ja) | 2003-10-31 | 2003-10-31 | ポリウレタン組成物及びウレタン樹脂フィルム |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4873831B2 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101321837B (zh) * | 2005-10-18 | 2012-04-11 | 佩什托普特殊化学股份公司 | 双固化组合物 |
| WO2009120547A2 (en) | 2008-03-25 | 2009-10-01 | 3M Innovative Properties Company | Paint film composites and methods of making and using the same |
| CN102007000B (zh) | 2008-03-25 | 2014-07-16 | 3M创新有限公司 | 多层制品及其制造和使用方法 |
| DE102009047214B4 (de) | 2008-12-02 | 2023-10-05 | Basf Se | Verfahren zur Herstellung von kompakten transparenten Polyurethanen |
| WO2013160226A1 (de) | 2012-04-23 | 2013-10-31 | Bayer Materialscience Ag | Lichtechte polyurethanzusammensetzung |
| JP2015524359A (ja) * | 2012-06-27 | 2015-08-24 | バイエル・マテリアルサイエンス・アクチェンゲゼルシャフトBayer MaterialScience AG | 誘電性ポリウレタンフィルム |
| EP2774937A1 (de) | 2013-03-04 | 2014-09-10 | Basf Se | Glasklare Polyurethane |
| KR101969800B1 (ko) * | 2017-06-23 | 2019-04-19 | (주)이앤코리아 | 탄소소재를 이용한 자동차 충격보호용 복합소재 필름 제조방법 |
| JP7247646B2 (ja) * | 2019-02-25 | 2023-03-29 | 凸版印刷株式会社 | 保護フィルム |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05155976A (ja) * | 1991-11-27 | 1993-06-22 | Minnesota Mining & Mfg Co <3M> | 高温での伸び物性に優れたポリウレタン樹脂 |
| JPH07117202A (ja) * | 1993-10-21 | 1995-05-09 | Asahi Glass Co Ltd | 透明積層体及びその製造方法 |
| JPH07126342A (ja) * | 1993-10-21 | 1995-05-16 | Saint Gobain Vitrage | ポリウレタンの製造方法 |
| JP3419596B2 (ja) * | 1995-06-16 | 2003-06-23 | 日本ポリウレタン工業株式会社 | ポリイソシアネート硬化剤およびこれを用いた塗料組成物 |
| JP3493648B2 (ja) * | 1996-08-19 | 2004-02-03 | 日本ポリウレタン工業株式会社 | 2液注型用ポリウレタンエラストマー組成物、及びポリウレタンエラストマーの製造方法 |
| JP3161593B2 (ja) * | 1997-03-19 | 2001-04-25 | エスケー化研株式会社 | 耐久性に優れる弾性非汚染塗料組成物 |
| JP3946836B2 (ja) * | 1997-10-01 | 2007-07-18 | サンスター技研株式会社 | 二液型発泡性ウレタン材料の注入工法 |
| JP3504565B2 (ja) * | 1997-12-22 | 2004-03-08 | 三洋化成工業株式会社 | 二液型ドライラミネート用接着剤 |
-
2003
- 2003-10-31 JP JP2003372625A patent/JP4873831B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005133013A (ja) | 2005-05-26 |
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