JP4817352B2 - 鉄、コバルトまたはニッケルを含む三成分錫亜鉛合金、ガルバーニ溶液およびそれらを生成するガルバーニ法 - Google Patents
鉄、コバルトまたはニッケルを含む三成分錫亜鉛合金、ガルバーニ溶液およびそれらを生成するガルバーニ法 Download PDFInfo
- Publication number
- JP4817352B2 JP4817352B2 JP2002527347A JP2002527347A JP4817352B2 JP 4817352 B2 JP4817352 B2 JP 4817352B2 JP 2002527347 A JP2002527347 A JP 2002527347A JP 2002527347 A JP2002527347 A JP 2002527347A JP 4817352 B2 JP4817352 B2 JP 4817352B2
- Authority
- JP
- Japan
- Prior art keywords
- alloy
- coating
- cobalt
- zinc
- tin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 41
- 229910052742 iron Inorganic materials 0.000 title claims description 20
- 239000010941 cobalt Substances 0.000 title claims description 19
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims description 19
- 229910017052 cobalt Inorganic materials 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title description 27
- 229910001297 Zn alloy Inorganic materials 0.000 title description 17
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 title description 16
- 229910052759 nickel Inorganic materials 0.000 title description 12
- 229910045601 alloy Inorganic materials 0.000 claims description 48
- 239000000956 alloy Substances 0.000 claims description 48
- 238000000576 coating method Methods 0.000 claims description 46
- 239000011248 coating agent Substances 0.000 claims description 37
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 21
- 239000011701 zinc Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 17
- 229910052725 zinc Inorganic materials 0.000 claims description 17
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 238000005260 corrosion Methods 0.000 claims description 11
- 230000007797 corrosion Effects 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000008139 complexing agent Substances 0.000 claims description 8
- 239000008151 electrolyte solution Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 229910000531 Co alloy Inorganic materials 0.000 claims description 7
- 239000000080 wetting agent Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- SDRDGBIYJHUXJX-UHFFFAOYSA-N [Co].[Zn].[Sn] Chemical compound [Co].[Zn].[Sn] SDRDGBIYJHUXJX-UHFFFAOYSA-N 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- 229940079864 sodium stannate Drugs 0.000 claims description 6
- IOUCSUBTZWXKTA-UHFFFAOYSA-N dipotassium;dioxido(oxo)tin Chemical compound [K+].[K+].[O-][Sn]([O-])=O IOUCSUBTZWXKTA-UHFFFAOYSA-N 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- TVQLLNFANZSCGY-UHFFFAOYSA-N disodium;dioxido(oxo)tin Chemical compound [Na+].[Na+].[O-][Sn]([O-])=O TVQLLNFANZSCGY-UHFFFAOYSA-N 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 150000007524 organic acids Chemical group 0.000 claims description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 3
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- FATUQANACHZLRT-KMRXSBRUSA-L calcium glucoheptonate Chemical compound [Ca+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O FATUQANACHZLRT-KMRXSBRUSA-L 0.000 claims description 2
- 238000004070 electrodeposition Methods 0.000 claims description 2
- 229940050410 gluconate Drugs 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 2
- WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 claims description 2
- 239000011253 protective coating Substances 0.000 claims 2
- 239000003792 electrolyte Substances 0.000 description 19
- 238000000151 deposition Methods 0.000 description 11
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 230000002378 acidificating effect Effects 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- 229940021013 electrolyte solution Drugs 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- 239000004327 boric acid Substances 0.000 description 4
- 239000008199 coating composition Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000000337 buffer salt Substances 0.000 description 3
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000001509 sodium citrate Substances 0.000 description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 3
- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 description 3
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 2
- 229910005728 SnZn Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 2
- 229940044175 cobalt sulfate Drugs 0.000 description 2
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 241001163841 Albugo ipomoeae-panduratae Species 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000288113 Gallirallus australis Species 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- JSCCXVCIUHYQIU-UHFFFAOYSA-N [Fe][Sn][Zn] Chemical compound [Fe][Sn][Zn] JSCCXVCIUHYQIU-UHFFFAOYSA-N 0.000 description 1
- OQDDOQFECBFUPY-UHFFFAOYSA-N [Ni].[Sn].[Zn] Chemical compound [Ni].[Sn].[Zn] OQDDOQFECBFUPY-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910002065 alloy metal Inorganic materials 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000002659 electrodeposit Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical group O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C13/00—Alloys based on tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/60—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of tin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10045991A DE10045991A1 (de) | 2000-09-16 | 2000-09-16 | Ternäre Zinn-Zink-Legierungen, galvanische Bäder und galvanisches Verfahren zur Erzeugung von ternären Zinn-Zink-Legierungsschichten |
| DE10045991.9 | 2000-09-16 | ||
| PCT/EP2001/009452 WO2002022913A2 (de) | 2000-09-16 | 2001-08-16 | Ternäre zinn-zink legierungen enthaltend eisen, kobalt oder nickel, galvanische bäder und galvanisches verfahren zu ihrer erzeugung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004509229A JP2004509229A (ja) | 2004-03-25 |
| JP2004509229A5 JP2004509229A5 (enExample) | 2008-10-02 |
| JP4817352B2 true JP4817352B2 (ja) | 2011-11-16 |
Family
ID=7656548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002527347A Expired - Fee Related JP4817352B2 (ja) | 2000-09-16 | 2001-08-16 | 鉄、コバルトまたはニッケルを含む三成分錫亜鉛合金、ガルバーニ溶液およびそれらを生成するガルバーニ法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20040091385A1 (enExample) |
| EP (1) | EP1319093B1 (enExample) |
| JP (1) | JP4817352B2 (enExample) |
| CN (1) | CN1239751C (enExample) |
| DE (2) | DE10045991A1 (enExample) |
| WO (1) | WO2002022913A2 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3878978B2 (ja) | 2002-10-24 | 2007-02-07 | コーア株式会社 | 鉛非含有はんだ、および鉛非含有の継手 |
| JP2005026188A (ja) | 2003-07-03 | 2005-01-27 | Koa Corp | 電流ヒューズ及び電流ヒューズの製造方法 |
| JP4901120B2 (ja) * | 2005-03-29 | 2012-03-21 | 兵庫県 | 亜鉛を含むめっき皮膜 |
| CN100554528C (zh) * | 2006-03-29 | 2009-10-28 | 哈尔滨工业大学 | 具有良好耐化学性及粘结力的电解铜箔镀层表面处理方法 |
| EP2085502A1 (en) * | 2008-01-29 | 2009-08-05 | Enthone, Incorporated | Electrolyte composition and method for the deposition of a tin-zinc alloy |
| KR20110028010A (ko) * | 2009-09-11 | 2011-03-17 | 삼성전기주식회사 | 미립 주석 분말 및 그 제조 방법 |
| CN102791902B (zh) * | 2010-02-01 | 2015-04-08 | 科卢斯博知识产权有限公司 | 镍基热喷涂粉末和涂层及其制备方法 |
| CN102212809B (zh) * | 2011-05-12 | 2012-07-18 | 北京化工大学 | 一种镍基合金加热管的防腐蚀方法 |
| US20130098691A1 (en) | 2011-10-25 | 2013-04-25 | Longyear Tm, Inc. | High-strength, high-hardness binders and drilling tools formed using the same |
| CN102690975B (zh) * | 2012-06-11 | 2014-12-03 | 东莞市闻誉实业有限公司 | 一种三元锡-锌合金及其电镀方法 |
| CN103849912A (zh) * | 2012-11-29 | 2014-06-11 | 沈阳工业大学 | 一种电镀光亮锡锌镍合金工艺 |
| RU2654030C2 (ru) | 2012-12-18 | 2018-05-15 | Лэнксесс Бутил Пте. Лтд. | Электронные устройства, содержащие бутилкаучук |
| CN103436825A (zh) * | 2013-08-23 | 2013-12-11 | 哈尔滨理工大学 | 纳米氧化锡涂覆陶瓷相增强体/铝基复合材料的制备方法 |
| CN106521580A (zh) * | 2016-11-02 | 2017-03-22 | 苏州市汉宜化学有限公司 | 四价锡Sn‑Co‑Zn三元合金代铬电镀液及电镀方法 |
| CN112779576B (zh) * | 2020-12-25 | 2022-06-21 | 南通正海磁材有限公司 | 一种钕铁硼磁体复合镀层及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51131427A (en) * | 1975-05-05 | 1976-11-15 | Whyco Chromium Co | Ternary alloy |
| JPS57161080A (en) * | 1981-02-25 | 1982-10-04 | Hooker Chemicals Plastics Corp | Metal plating composition and method |
| JPS5848694A (ja) * | 1981-09-16 | 1983-03-22 | Nippon Steel Corp | アルコ−ルを含有もしくはアルコ−ル系燃料容器用Ｓｎ−Ｚｎ系合金電気メツキ鋼板 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH103474A (fr) * | 1923-04-13 | 1924-02-16 | Enrico Scala Giuseppe | Soudure pour aluminium et procédé de fabrication de celle-ci. |
| US3791801A (en) * | 1971-07-23 | 1974-02-12 | Toyo Kohan Co Ltd | Electroplated steel sheet |
| US3881919A (en) * | 1974-01-07 | 1975-05-06 | Whyco Chromium Co | Ternary alloys |
| SU670638A1 (ru) * | 1977-02-14 | 1979-06-30 | Ярославский политехнический институт | Электролит дл нанесени покрытий из сплавов на основе олова |
| JPS58153796A (ja) * | 1982-03-05 | 1983-09-12 | Sumitomo Metal Ind Ltd | 電気メツキ鋼板 |
| JPS59170289A (ja) * | 1983-03-15 | 1984-09-26 | Sumitomo Metal Ind Ltd | 鉄系電気メツキ法 |
| US4488942A (en) * | 1983-08-05 | 1984-12-18 | Omi International Corporation | Zinc and zinc alloy electroplating bath and process |
| JPS63186860A (ja) * | 1987-01-27 | 1988-08-02 | Nippon Steel Corp | 耐錆性、溶接性に優れた表面処理鋼板の製造方法 |
| JPH01172593A (ja) * | 1987-12-25 | 1989-07-07 | Kawasaki Steel Corp | 塗装後密着性が優れたＺｎ−Ｎｉ−Ｓｎ合金めっき鋼板の製造方法 |
| US5429882A (en) * | 1993-04-05 | 1995-07-04 | The Louis Berkman Company | Building material coating |
| DE19644235C1 (de) * | 1996-10-24 | 1998-02-12 | Grillo Werke Ag | Schrot für Munitionszwecke |
-
2000
- 2000-09-16 DE DE10045991A patent/DE10045991A1/de not_active Ceased
-
2001
- 2001-08-16 US US10/380,212 patent/US20040091385A1/en not_active Abandoned
- 2001-08-16 DE DE50114623T patent/DE50114623D1/de not_active Expired - Lifetime
- 2001-08-16 CN CN01816986.4A patent/CN1239751C/zh not_active Expired - Fee Related
- 2001-08-16 WO PCT/EP2001/009452 patent/WO2002022913A2/de not_active Ceased
- 2001-08-16 JP JP2002527347A patent/JP4817352B2/ja not_active Expired - Fee Related
- 2001-08-16 EP EP01969597A patent/EP1319093B1/de not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51131427A (en) * | 1975-05-05 | 1976-11-15 | Whyco Chromium Co | Ternary alloy |
| JPS57161080A (en) * | 1981-02-25 | 1982-10-04 | Hooker Chemicals Plastics Corp | Metal plating composition and method |
| JPS5848694A (ja) * | 1981-09-16 | 1983-03-22 | Nippon Steel Corp | アルコ−ルを含有もしくはアルコ−ル系燃料容器用Ｓｎ−Ｚｎ系合金電気メツキ鋼板 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE50114623D1 (de) | 2009-02-12 |
| WO2002022913A3 (de) | 2002-07-25 |
| CN1239751C (zh) | 2006-02-01 |
| CN1468327A (zh) | 2004-01-14 |
| HK1054576A1 (zh) | 2003-12-05 |
| JP2004509229A (ja) | 2004-03-25 |
| US20040091385A1 (en) | 2004-05-13 |
| DE10045991A1 (de) | 2002-04-04 |
| EP1319093B1 (de) | 2008-12-31 |
| WO2002022913A2 (de) | 2002-03-21 |
| EP1319093A2 (de) | 2003-06-18 |
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