JP4783893B2 - エネルギー貯蔵型色素増感太陽電池 - Google Patents
エネルギー貯蔵型色素増感太陽電池 Download PDFInfo
- Publication number
- JP4783893B2 JP4783893B2 JP2004360270A JP2004360270A JP4783893B2 JP 4783893 B2 JP4783893 B2 JP 4783893B2 JP 2004360270 A JP2004360270 A JP 2004360270A JP 2004360270 A JP2004360270 A JP 2004360270A JP 4783893 B2 JP4783893 B2 JP 4783893B2
- Authority
- JP
- Japan
- Prior art keywords
- charge storage
- electrode
- dye
- electrolyte solution
- sensitized solar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004146 energy storage Methods 0.000 title claims description 25
- 238000003860 storage Methods 0.000 claims description 84
- 239000008151 electrolyte solution Substances 0.000 claims description 59
- 239000012528 membrane Substances 0.000 claims description 42
- 238000005341 cation exchange Methods 0.000 claims description 32
- 239000004065 semiconductor Substances 0.000 claims description 29
- 229920001940 conductive polymer Polymers 0.000 claims description 28
- 150000001768 cations Chemical class 0.000 claims description 16
- 229920000128 polypyrrole Polymers 0.000 claims description 12
- -1 polyphenylene Polymers 0.000 claims description 9
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 4
- 229920003026 Acene Polymers 0.000 claims description 3
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims description 3
- 229920000265 Polyparaphenylene Polymers 0.000 claims description 3
- 239000002041 carbon nanotube Substances 0.000 claims description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 3
- 229910003472 fullerene Inorganic materials 0.000 claims description 3
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 claims description 3
- 229920000834 poly(ferrocenylene) polymer Polymers 0.000 claims description 3
- 229920000553 poly(phenylenevinylene) Polymers 0.000 claims description 3
- 229920001197 polyacetylene Polymers 0.000 claims description 3
- 229920000768 polyamine Polymers 0.000 claims description 3
- 229920000767 polyaniline Polymers 0.000 claims description 3
- 229920000123 polythiophene Polymers 0.000 claims description 3
- 239000010408 film Substances 0.000 description 38
- 239000000975 dye Substances 0.000 description 29
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 20
- 239000000243 solution Substances 0.000 description 19
- 150000001450 anions Chemical class 0.000 description 14
- 239000003638 chemical reducing agent Substances 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 12
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 10
- 239000007800 oxidant agent Substances 0.000 description 10
- 230000001590 oxidative effect Effects 0.000 description 10
- 229910052697 platinum Inorganic materials 0.000 description 10
- 229920002379 silicone rubber Polymers 0.000 description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
- 230000005611 electricity Effects 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 229920000557 Nafion® Polymers 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 230000007246 mechanism Effects 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000007599 discharging Methods 0.000 description 5
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 229910020366 ClO 4 Inorganic materials 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 229910003437 indium oxide Inorganic materials 0.000 description 4
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 4
- 229910052707 ruthenium Inorganic materials 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000005284 excitation Effects 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 3
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- FXPLCAKVOYHAJA-UHFFFAOYSA-N 2-(4-carboxypyridin-2-yl)pyridine-4-carboxylic acid Chemical compound OC(=O)C1=CC=NC(C=2N=CC=C(C=2)C(O)=O)=C1 FXPLCAKVOYHAJA-UHFFFAOYSA-N 0.000 description 2
- VMISXESAJBVFNH-UHFFFAOYSA-N 2-(4-carboxypyridin-2-yl)pyridine-4-carboxylic acid;ruthenium(2+);diisothiocyanate Chemical compound [Ru+2].[N-]=C=S.[N-]=C=S.OC(=O)C1=CC=NC(C=2N=CC=C(C=2)C(O)=O)=C1.OC(=O)C1=CC=NC(C=2N=CC=C(C=2)C(O)=O)=C1 VMISXESAJBVFNH-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910000484 niobium oxide Inorganic materials 0.000 description 2
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 2
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 2
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 229910001936 tantalum oxide Inorganic materials 0.000 description 2
- 229910001930 tungsten oxide Inorganic materials 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000000999 acridine dye Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- SQFDQLBYJKFDDO-UHFFFAOYSA-K merbromin Chemical compound [Na+].[Na+].C=12C=C(Br)C(=O)C=C2OC=2C([Hg]O)=C([O-])C(Br)=CC=2C=1C1=CC=CC=C1C([O-])=O SQFDQLBYJKFDDO-UHFFFAOYSA-K 0.000 description 1
- 229940008716 mercurochrome Drugs 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 239000001022 rhodamine dye Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/053—Energy storage means directly associated or integrated with the PV cell, e.g. a capacitor integrated with a PV cell
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
Landscapes
- Photovoltaic Devices (AREA)
- Hybrid Cells (AREA)
Description
所定の電解質溶液中に色素担持半導体を有する光電極と該光電極に対向する対向電極とを配置したセル部分と、
カチオン交換膜で前記セル部分の前記電解質溶液から隔離された区画内に、少なくとも導電性高分子を有し複数の貫通孔が設けられた電荷蓄積電極を配置すると共に前記区画内と前記電解質溶液との間を前記カチオン交換膜を介して前記電解質溶液のカチオン種が行き来可能に構成されたバッテリ部分と、
を備えたものである。
次に、本発明を実施するための最良の形態を図面を用いて以下に説明する。図1は第1実施形態のエネルギー貯蔵型色素増感太陽電池10の概略構成を表す説明図であり、(a)は充電時の様子を表し、(b)は放電時の様子を表す。図2は電荷蓄積電極18の製造手順を示す説明図である。
図3は第2実施形態のES−DSSC60の概略構成を表す説明図であり、(a)は充電時の様子を表し、(b)は放電時の様子を表す。図4は膜一体型電荷蓄積電極68の製造手順を示す説明図である。
実施例1は、第1実施形態のES−DSSC10を実際に作製した一例である。ここでは、図5に示すように、光電極12と、この光電極12と略同じ大きさの第1シリコンゴム40の略中央の角窓40aに挿入された対向電極14と、第1シリコンゴム40と略同じ大きさのカチオン交換膜46と、中央に角窓40aを有する第2シリコンゴム42と、この角窓42aと略同じ大きさの電荷蓄積電極18とを、この順に重ねて図示しないコックで挟み込み、第1シリコンゴム40の角窓40aには第1電解質溶液20を注入し、第2シリコンゴム42の角窓42aには第2電解質溶液22を注入することにより、ES−DSSC10を作製した。
実施例2は、第2実施形態のES−DSSC60を実際に作製した一例である。ここでは、図8に示すように、光電極12と、この光電極12と略同じ大きさのシリコンゴム40の略中央の角窓40aに挿入された膜一体型電荷蓄積電極68と、その上に配置された白金蒸着透明電極板である対向電極64とを、この順に重ねて図示しないコックで挟み込み、シリコンゴム40の角窓40aに第1電解質溶液70を注入することにより、ES−DSSC60を作製した。
Claims (7)
- 所定の電解質溶液中に色素担持半導体を有する光電極と該光電極に対向する対向電極とを配置したセル部分と、
カチオン交換膜で前記セル部分の前記電解質溶液から隔離された区画内に、少なくとも導電性高分子を有し複数の貫通孔が設けられた電荷蓄積電極を配置すると共に前記区画内と前記電解質溶液との間を前記カチオン交換膜を介して前記電解質溶液のカチオン種が行き来可能に構成されたバッテリ部分と、
を備えたエネルギー貯蔵型色素増感太陽電池。 - 前記導電性高分子は、ポリピロール、ポリアニリン、ポリチオフェン、ポリアセチレン、ポリフェニレン、ポリフェニレンビニレン、ポリアセン、ポリビニルカルバゾール、ポリビオロゲン、ポリポルフィリン、ポリフタロシアニン、ポリフェロセン、ポリアミン及びそれらのポリマーの誘導体、カーボンナノチューブ、フラーレン、並びにキノリン含有ポリマーからなる群より選ばれた1種以上である、請求項1に記載のエネルギー貯蔵型色素増感太陽電池。
- 前記電荷蓄積電極は、格子電極である、請求項1又は2に記載のエネルギー貯蔵型色素増感太陽電池。
- 前記格子電極は、導電性のある格子部材に導電性高分子が付着したものである、
請求項3に記載のエネルギー貯蔵型色素増感太陽電池。 - 前記格子部材は、線径0.01mm〜1mmで10〜500メッシュである、
請求項4に記載のエネルギー貯蔵型色素増感太陽電池。 - 前記セル部分と前記バッテリ部分は、前記カチオン交換膜により仕切られた異なる2つの隔室にそれぞれ配置されている、
請求項1〜5のいずれかに記載のエネルギー貯蔵型色素増感太陽電池。 - 前記バッテリ部分は、前記電荷蓄積電極を前記カチオン交換膜で被覆した膜一体型電荷蓄積電極を有し、該膜一体型電荷蓄積電極は、前記セル部分の前記電解質溶液中に配置されている、
請求項1〜5のいずれかに記載のエネルギー貯蔵型色素増感太陽電池。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004360270A JP4783893B2 (ja) | 2004-12-13 | 2004-12-13 | エネルギー貯蔵型色素増感太陽電池 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004360270A JP4783893B2 (ja) | 2004-12-13 | 2004-12-13 | エネルギー貯蔵型色素増感太陽電池 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006172758A JP2006172758A (ja) | 2006-06-29 |
JP4783893B2 true JP4783893B2 (ja) | 2011-09-28 |
Family
ID=36673291
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004360270A Active JP4783893B2 (ja) | 2004-12-13 | 2004-12-13 | エネルギー貯蔵型色素増感太陽電池 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4783893B2 (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4201035B2 (ja) | 2006-09-05 | 2008-12-24 | セイコーエプソン株式会社 | 電池素子および電子機器 |
JP5288368B2 (ja) * | 2007-11-30 | 2013-09-11 | 独立行政法人物質・材料研究機構 | 太陽電池 |
US8674215B2 (en) | 2008-08-28 | 2014-03-18 | Panasonic Corporation | Photoelectric device |
TW201034276A (en) * | 2009-02-09 | 2010-09-16 | Applied Materials Inc | Mesoporous carbon material for energy storage |
TWI480229B (zh) * | 2012-03-26 | 2015-04-11 | Toshiba Kk | A battery electrode material, a battery electrode paste, a method for manufacturing an electrode material for a battery, a dye-sensitized solar cell, and a battery |
WO2014148016A1 (ja) | 2013-03-22 | 2014-09-25 | パナソニック株式会社 | 光電変換素子 |
US20160276110A1 (en) * | 2013-11-08 | 2016-09-22 | Panasonic Corporation | Electrochemical device |
JP6222634B2 (ja) * | 2013-11-21 | 2017-11-01 | 国立大学法人 東京大学 | エネルギー貯蔵型色素増感太陽電池 |
WO2015174131A1 (ja) * | 2014-05-15 | 2015-11-19 | 株式会社村田製作所 | 光二次電池 |
JP6459582B2 (ja) * | 2015-02-09 | 2019-01-30 | 株式会社デンソー | 光エネルギー変換貯蔵システム |
WO2016132750A1 (ja) * | 2015-02-18 | 2016-08-25 | 株式会社村田製作所 | 光二次電池、及び光二次電池用電極の製造方法 |
WO2016132749A1 (ja) * | 2015-02-18 | 2016-08-25 | 株式会社村田製作所 | 光二次電池 |
CN111739738B (zh) * | 2020-06-19 | 2021-07-30 | 信阳师范学院 | 一体化两电极光充电电容器 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4037029A (en) * | 1975-07-06 | 1977-07-19 | John Harland Anderson | Photoelectrogenerative cell |
JPS5693270A (en) * | 1979-12-26 | 1981-07-28 | Fuji Photo Film Co Ltd | Reversible photo-charging photochemical cell |
JPH0614469B2 (ja) * | 1982-01-08 | 1994-02-23 | 株式会社半導体エネルギー研究所 | 光レドックス反応装置 |
JP3346449B2 (ja) * | 1996-03-18 | 2002-11-18 | 日本電信電話株式会社 | 光水素化空気二次電池 |
JP4757433B2 (ja) * | 2003-03-24 | 2011-08-24 | 独立行政法人科学技術振興機構 | 太陽電池 |
-
2004
- 2004-12-13 JP JP2004360270A patent/JP4783893B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
JP2006172758A (ja) | 2006-06-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Kato et al. | Light-assisted rechargeable lithium batteries: organic molecules for simultaneous energy harvesting and storage | |
Swierk et al. | Rutile TiO2 as an anode material for water-splitting dye-sensitized photoelectrochemical cells | |
Ileperuma et al. | Dye-sensitised photoelectrochemical solar cells with polyacrylonitrile based solid polymer electrolytes | |
JP4783893B2 (ja) | エネルギー貯蔵型色素増感太陽電池 | |
JP3690681B2 (ja) | 発電方法および電池 | |
Stalder et al. | Panchromatic donor–acceptor–donor conjugated oligomers for dye-sensitized solar cell applications | |
US8841550B2 (en) | Photoelectric element | |
JP2009081046A (ja) | 三極二層型光二次電池 | |
KR20070056581A (ko) | 태양전지용 전극, 그의 제조방법 및 그를 포함하는태양전지 | |
Abate et al. | An organic “donor-free” dye with enhanced open-circuit voltage in solid-state sensitized solar cells | |
Yang et al. | New approach for preparation of efficient solid-state dye-sensitized solar cells by photoelectrochemical polymerization in aqueous micellar solution | |
Park et al. | The application of camphorsulfonic acid doped polyaniline films prepared on TCO-free glass for counter electrode of bifacial dye-sensitized solar cells | |
Keothongkham et al. | Electrochemically deposited polypyrrole for dye-sensitized solar cell counter electrodes | |
JP2002222971A (ja) | 光電変換素子 | |
JP4757433B2 (ja) | 太陽電池 | |
US10147554B2 (en) | Energy storage dye-sensitized solar cell | |
Oyaizu et al. | BODIPY-sensitized photocharging of anthraquinone-populated polymer layers for organic photorechargeable air battery | |
Yu et al. | Electron transfer kinetics of a series of bilayer triphenylamine–oligothiophene–perylenemonoimide sensitizers for dye-sensitized NiO | |
Amao et al. | Near-IR light-sensitized voltaic conversion system using nanocrystalline TiO2 film by Zn chlorophyll derivative aggregate | |
Athanassov et al. | Sensitized electroluminescence on mesoporous oxide semiconductor films | |
JP4561073B2 (ja) | 光電変換素子および電子装置 | |
KR102286239B1 (ko) | 색소 증감 태양 전지의 대향 전극 활물질의 재활성화 방법, 및 그 방법을 응용한 색소 증감 태양 전지의 재생 방법, 색소 증감 태양 전지용의 촉매층, 대향 전극, 전해액 및 색소 증감 태양 전지 | |
JP4843904B2 (ja) | 光電変換素子及びその製造方法 | |
Morawski et al. | Titanyl phthalocyanine as a water photooxidation agent | |
Zhao et al. | All-in-one, solid-state, solar-powered electrochemical cell |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20071107 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110419 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110525 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110614 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
R150 | Certificate of patent (=grant) or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |