JP4763258B2 - Oily solid cosmetic - Google Patents
Oily solid cosmetic Download PDFInfo
- Publication number
- JP4763258B2 JP4763258B2 JP2004253466A JP2004253466A JP4763258B2 JP 4763258 B2 JP4763258 B2 JP 4763258B2 JP 2004253466 A JP2004253466 A JP 2004253466A JP 2004253466 A JP2004253466 A JP 2004253466A JP 4763258 B2 JP4763258 B2 JP 4763258B2
- Authority
- JP
- Japan
- Prior art keywords
- component
- formula
- acid
- oily solid
- solid cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007787 solid Substances 0.000 title claims description 22
- 239000002537 cosmetic Substances 0.000 title claims description 20
- -1 Triester compound Chemical class 0.000 claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
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- 229920001577 copolymer Polymers 0.000 claims description 7
- 229940105990 diglycerin Drugs 0.000 claims description 7
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 7
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- 229930006000 Sucrose Natural products 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
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- OWRMXHRUFYLLQP-UHFFFAOYSA-N [3-[2,3-bis(16-methylheptadecanoyloxy)propoxy]-2-hydroxypropyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)COCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C OWRMXHRUFYLLQP-UHFFFAOYSA-N 0.000 description 6
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
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- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 2
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- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、油性固形化粧料に関し、詳しくは化粧持ちが良好で、ツヤおよび使用感に優れ、形状保持、安定性が良好である油性固形化粧料に関する。 The present invention relates to an oily solid cosmetic, and particularly relates to an oily solid cosmetic having a good makeup, excellent gloss and feeling of use, and good shape retention and stability.
従来、油性固形化粧料は、固形の形状を保つため、固形油、半固形油、液体油等の配合成分の選択や、配合量を変えることについて検討がなされてきた。(例えば、特許文献1、特許文献2参照)また、形状を保持し、更に液体油が表面に染み出てくる発汗現象等の経時的な変化を抑制するため、ゲル化剤を用いる技術も検討されてきた。(例えば、特許文献3、特許文献4参照)。
このように形状の安定性を検討する一方、油性化粧料の特徴である、光沢感、使用感という外観や化粧効果を充分に活かすために、粉体や油剤を検討することがなされてきている。(例えば、特許文献5、特許文献6参照)
さらには、従来の油の構造を限定することにより、膜感、コク等の使用感を向上させる技術(例えば、特許文献7参照)が検討されてきた。
Conventionally, oily solid cosmetics have been studied for selection of blending components such as solid oil, semi-solid oil, and liquid oil, and changing the blending amount in order to maintain a solid shape. (For example, see Patent Document 1 and Patent Document 2) In addition, in order to maintain the shape and further suppress the change over time such as the sweating phenomenon that liquid oil oozes out on the surface, a technique using a gelling agent is also examined. It has been. (For example, refer to Patent Document 3 and Patent Document 4).
While examining the stability of the shape in this way, in order to make full use of the appearance and cosmetic effects such as glossiness and feeling of use, which are the characteristics of oily cosmetics, powders and oil agents have been studied. . (For example, see Patent Document 5 and Patent Document 6)
Furthermore, the technique (for example, refer patent document 7) which improves the usability | use_conditions, such as film | membrane feeling and richness, by limiting the structure of the conventional oil has been examined.
しかしながら、前記の固形の形状安定性のために用いるゲル化剤はツヤを低下させる傾向にあり、特に塗布後の経時においてツヤが顕著に減少することがあった。特にツヤに関しては、以前に比べかなり高いものが要求されるようになってきた。
加えて、使用感に対しても、従来の固形状化粧料の特徴である、芯がありつるつるとした使用感ではなく、しっかり付着した密着感を持ちながら、ゲル状のものを塗布するような、柔らかくて、滑らかな使用感が要求されるようになってきた。しかし、従来の技術では、固形でこのような使用感を得ることはできなかった。
そこで、化粧持ち、ツヤ及びその持続性、しっかり付着した密着感を持ちながら、ゲル状のものを塗布するような、柔らかくて、滑らかな使用感に優れ、形状保持性、経時安定性が良好である油性固形化粧料の開発が望まれていた。
However, the above-mentioned gelling agent used for solid shape stability tends to lower the gloss, and the gloss may be remarkably reduced particularly with the passage of time after application. In particular, the gloss has been required to be considerably higher than before.
In addition, for the feeling of use, it is not a characteristic of the conventional solid cosmetics, which has a core and a smooth feeling of use, but a gel-like one is applied while having a tight adhesion. Therefore, a soft and smooth feeling of use has been demanded. However, the conventional technique cannot obtain such a feeling of use in solid form.
Therefore, it has a soft and smooth feeling of use, such as applying a gel, while having a makeup hold, luster and its durability, a tight adhesion, and good shape retention and stability over time. The development of some oily solid cosmetics has been desired.
かかる実情において、本発明者らは上記課題を解決すべく鋭意研究を重ねた結果、特定固化剤、油剤、ゲル化剤を用いることにより、従来のゲル化構造とは異なり固形状でありながらゲル状の使用感を持ち、ツヤも優れた油性固形化粧料が得られ、化粧持ち、形状保持性、経時安定性も良好であることを見出し、本発明を完成するに至った。
すなわち本発明は、次の成分(a)〜(c);
(a)エチレンプロピレンコポリマー
(b)下記化学式(1)に示すイソステアリン酸とグリセリンおよび/またはジグリセリンとのエステル化合物
In such a situation, the present inventors have conducted extensive research to solve the above problems, and as a result, by using a specific solidifying agent, oil agent, and gelling agent, the gel is different from the conventional gelation structure while being in a solid state. As a result, the present inventors have found that an oily solid cosmetic material having a good feeling of use and excellent gloss is obtained, and that it has good makeup, shape retention, and stability over time, and has completed the present invention.
That is, the present invention provides the following components (a) to (c);
(A) ethylene propylene copolymer (b) ester compound of isostearic acid and glycerin and / or diglycerin represented by the following chemical formula (1)
(c)煙霧状シリカ
を含有する油性固形化粧料を提供するものである。
(C) An oil-based solid cosmetic containing fumed silica is provided.
本発明の油性固形化粧料は、しっかり付着した密着感を持ちながら、ゲル状のものを塗布するような、柔らかくて、滑らかな伸びのある使用感が得られるとともに、ツヤ、化粧持ちが良好で、形状保持性、安定性に優れるものである。 The oily solid cosmetic composition of the present invention has a soft and smooth use feeling such as applying a gel-like material while having a tight adhesion, and has a good gloss and a long-lasting makeup. It is excellent in shape retention and stability.
本発明に用いられる、成分(a)のエチレンプロピレンコポリマーは、主炭素数として35付近を有し、直鎖以外に分岐しているものも含まれる合成炭化水素ワックスであり、また、その中でも分子量が500〜700の範囲にあるものが好ましい。また、その融点は、特に80℃〜110℃のものが形状保持性の観点より好ましい。市販品として、EP−700、EP−1100(いずれもニューフェーズテクノロジー社製)、TRILENE CP−40、TRILENE CP−80(いずれもユニロイヤルケミカル社製)、EPSワックス(日本ナチュラルプロダクツ社製)等が例示できる。
成分(a)の含有量は、特に限定されないが、1〜40質量%(以下、単に「%」と略す。)が好ましく、特に、3〜30%がより好ましい。この範囲で含有させると、使用性が良好で、ツヤに優れるとともに、形状保持性がより向上するものとなる。
The ethylene propylene copolymer of component (a) used in the present invention is a synthetic hydrocarbon wax having a main carbon number of around 35 and includes those branched in addition to a straight chain, and among these, molecular weight Is preferably in the range of 500-700. Further, the melting point is particularly preferably from 80 ° C. to 110 ° C. from the viewpoint of shape retention. Commercially available products such as EP-700, EP-1100 (all manufactured by New Phase Technology), TRILENE CP-40, TRILENE CP-80 (all manufactured by Uniroyal Chemical), EPS wax (manufactured by Nippon Natural Products), etc. Can be illustrated.
The content of the component (a) is not particularly limited, but is preferably 1 to 40% by mass (hereinafter simply referred to as “%”), and more preferably 3 to 30%. When contained in this range, the usability is good, the gloss is excellent, and the shape retainability is further improved.
本発明に用いられる、成分(b)は、下記化学式(1)に示すイソステアリン酸とグリセリンおよび/またはジグリセリンとのエステル化合物である。下記化学式(1)に示すイソステアリン酸は側鎖を有するα−オレフィンを出発物質とするアルドール縮合反応で合成されるものであるが、(1)に示される構造を有するものであれば合成方法は限定されるものではない。
例えば、無触媒または触媒存在化、常圧溶剤還流もしくは減圧下において脱水反応することによりエステル化反応を行い、エステル化反応終了後、必要に応じて、反応混合物を脱色剤により脱色、脱臭精製するか、真空蒸留による精製を行うことによって得ることができる。
Component (b) used in the present invention is an ester compound of isostearic acid and glycerin and / or diglycerin represented by the following chemical formula (1). The isostearic acid represented by the following chemical formula (1) is synthesized by an aldol condensation reaction using an α-olefin having a side chain as a starting material, but if it has the structure represented by (1), the synthesis method is as follows. It is not limited.
For example, the esterification reaction is carried out by dehydration under no catalyst or in the presence of a catalyst, refluxing at atmospheric pressure or under reduced pressure, and after completion of the esterification reaction, the reaction mixture is decolorized and deodorized with a decoloring agent as necessary. Alternatively, it can be obtained by purification by vacuum distillation.
エステル化の度合いは特に限定されないが、トリエステルである、トリイソステアリン酸グリセリル、トリイソステアリン酸ジグリセリルが、使用感の点で特に好ましい。
市販品としては、前記化学式(1)に示すイソステアリン酸とグリセリンのトリエステルであるコスモール3318、前記化学式(1)に示すイソステアリン酸とジグリセリンのトリエステルであるコスモール43N(ともに日清オイリオグループ社製)等が挙げられる。
成分(b)の含有量は、特に限定されないが、5〜90%が好ましく、特に、10〜70%がより好ましい。この範囲で含有させると、化粧持ちが良好で、ツヤに優れるものとなる。
The degree of esterification is not particularly limited, but triesters such as glyceryl triisostearate and diglyceryl triisostearate are particularly preferable in terms of feeling in use.
Commercially available products include Cosmol 3318, which is a triester of isostearic acid and glycerin represented by the chemical formula (1), and Cosmol 43N, which is a triester of isostearic acid and diglycerin represented by the chemical formula (1) (both Nisshin Oillio Group, Inc.). Manufactured) and the like.
Although content of a component (b) is not specifically limited, 5-90% is preferable and especially 10-70% is more preferable. When contained in this range, the makeup lasting is good and the gloss is excellent.
本発明に用いられる、成分(c)の煙霧状シリカは、例えば、四塩化ケイ素を水素と酸素炎中で加水分解して得られる煙霧状無水ケイ酸が挙げられ、その市販品の例としては、AEROSIL50、AEROSIL130、AEROSIL200、AEROSIL200V、AEROSIL200CF、AEROSIL200FAD、AEROSIL300、AEROSIL300CF、AEROSIL380(日本アエロジル社製)等が挙げられる。これら無水ケイ酸は必要に応じて1種又は2種以上を使用することができる。また、これらの煙霧状無水ケイ酸の一次粒径は50nm以下が好ましく、20nm以下が特に好ましい。
なお、上記煙霧状無水ケイ酸として、前記煙霧状無水ケイ酸を疎水化処理した疎水化煙霧状無水ケイ酸を利用しても良く、その疎水化処理の方法としては、トリメチルシリルクロライドやヘキサメチルジシラザンによるトリメチルシロキシ処理、オクチルシラン化処理、メチルハイドロジェンポリシロキサンを用いたコーティング焼き付け処理、金属石鹸によるコーティング等が挙げられる。市販品の疎水化煙霧状無水ケイ酸の例としては、AEROSILR−972、AEROSILR−972V、AEROSILR−972CF、AEROSILR974、AEROSILRX200、AEROSILRY200、AEROSILR202、AEROSILR805、AEROSILR812、AEROSILRA200H(ともに日本アエロジル社製)、タラノックス500(タルコ社製)、キャボジルTS―530(キャボット社製)等が挙げられる。
これら成分は、何れも必要に応じて1種又は2種以上を用いることができる。
成分(c)の煙霧状シリカの含有量は、特に限定されるものでないが、0.1〜10%が好ましく、特に、0.5〜5%が好ましい。この範囲であれば、形状保持性、安定性、使用性に優れながら、ツヤ、化粧持ちが良好なものが得られる。
The fumed silica of the component (c) used in the present invention includes, for example, fumed silicic acid obtained by hydrolyzing silicon tetrachloride in hydrogen and an oxygen flame, and examples of commercially available products thereof AEROSIL50, AEROSIL130, AEROSIL200, AEROSIL200V, AEROSIL200CF, AEROSIL200FAD, AEROSIL300, AEROSIL300CF, AEROSIL380 (made by Nippon Aerosil Co., Ltd.), etc. are mentioned. These silicic anhydrides can be used alone or in combination of two or more as required. Further, the primary particle size of these fumed silicic anhydride is preferably 50 nm or less, particularly preferably 20 nm or less.
As the fumed silicic anhydride, hydrophobized fumed silicic acid obtained by hydrophobizing the fumed silicic acid may be used, and as a method of the hydrophobizing treatment, trimethylsilyl chloride or hexamethyldisulfide is used. Examples thereof include trimethylsiloxy treatment with silazane, octyl silanization treatment, coating baking treatment using methyl hydrogen polysiloxane, and coating with metal soap. Examples of commercially available hydrophobized fumed silicic acid are AEROSILR-972, AEROSILR-972V, AEROSILR-972CF, AEROSILR974, AEROSILRX200, AEROSILRY200, AEROSILR202, AEROSILR805, AEROSILR 812, AEROSILR 812, AEROSILR 812 (Manufactured by Talco), Cabosil TS-530 (manufactured by Cabot), and the like.
Any of these components may be used alone or in combination of two or more as required.
Although content of the fumed silica of a component (c) is not specifically limited, 0.1 to 10% is preferable and 0.5 to 5% is especially preferable. If it is this range, while being excellent in shape retainability, stability, and usability, a product with good gloss and longevity can be obtained.
本発明の油性固形化粧料には、上記必須成分以外に、本発明の効果を損なわない範囲で、油性ゲル化剤を適宜配合できる。例えば、12−ヒドロキシステアリン酸、デキストリン脂肪酸エステル、ショ糖脂肪酸エステル、金属石鹸、および有機変性粘土鉱物等が挙げられる。
デキストリン脂肪酸エステルは、油溶性のもので炭素数8〜24(好ましくは14〜18)の直鎖または分枝鎖の飽和または不飽和脂肪酸と平均重合度10〜50(好ましくは20〜30)のデキストリンとのエステル化合物である。具体例としてはパルミチン酸デキストリン、パルミチン酸/2-エチルヘキサン酸デキストリン、ステアリン酸デキストリン、パルミチン酸/ステアリン酸デキストリン、オレイン酸デキストリン、イソパルミチン酸デキストリン、イソステアリン酸デキストリン等が挙げられ、これらの1種または2種以上を用いることができる。市販品としてはパルミチン酸デキストリン(レオパールKL、レオパールTL)やパルミチン酸/2-エチルヘキサン酸デキストリン(レオパールTT)(いずれも千葉製粉(株)製)等が挙げられる。
また、ショ糖脂肪酸エステルとしては、ステアリン酸スクロースや酢酸ステアリン酸スクロース等があり、具体的には、シュガーワックスS−10E、DKエステルS−160、シュガーワックスA−10E(共に「第一工業製薬社製」)等が挙げられる。
さらに、金属石鹸としてはイソステアリン酸アルミニウム、ステアリン酸カルシウムなどが挙げられ、有機変性粘土鉱物としては、水膨潤性粘土鉱物を四級アルキルアンモニウム塩で処理したもの等が挙げられ、市販品の例としては、「ベントン38」、「ベントン27」(共に「NLインダストリー」社製)などが挙げられる。
In the oily solid cosmetic of the present invention, an oily gelling agent can be appropriately blended in addition to the above essential components within a range not impairing the effects of the present invention. Examples thereof include 12-hydroxystearic acid, dextrin fatty acid ester, sucrose fatty acid ester, metal soap, and organically modified clay mineral.
The dextrin fatty acid ester is oil-soluble and has an average polymerization degree of 10 to 50 (preferably 20 to 30) with a linear or branched saturated or unsaturated fatty acid having 8 to 24 carbon atoms (preferably 14 to 18 carbon atoms). It is an ester compound with dextrin. Specific examples include dextrin palmitate, dextrin palmitate / 2-ethylhexanoate, dextrin stearate, dextrin palmitate / dextrin stearate, dextrin oleate, dextrin isopalmitate, dextrin isostearate, etc. Or 2 or more types can be used. Examples of commercially available products include dextrin palmitate (Leopard KL, Leopard TL) and dextrin palmitate / 2-ethylhexanoate (Leopard TT) (both manufactured by Chiba Flour Milling Co., Ltd.).
Examples of sucrose fatty acid esters include sucrose stearate and sucrose acetate stearate. Specifically, sugar wax S-10E, DK ester S-160, sugar wax A-10E (both “Daiichi Kogyo Seiyaku” "Made by company").
Furthermore, examples of the metal soap include aluminum isostearate and calcium stearate, and examples of the organically modified clay mineral include those obtained by treating a water-swellable clay mineral with a quaternary alkyl ammonium salt. , “Benton 38”, “Benton 27” (both manufactured by “NL Industry”), and the like.
また、本発明において、更に油剤を配合することにより、硬さや塗布時の感触を調整できる。ここで用いる油剤としては、通常化粧料に用いられる油分であれば特に制約なく使用することができ、動物油、植物油、合成油等の起源や、成分(a)以外の固形油、半固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、ロウ類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類、ラノリン誘導体類等を利用することができる。具体的には、流動パラフィン、重質流動イソパラフィン、α−オレフィンオリゴマー、スクワラン、ワセリン、ポリイソブチレン、ポリブテン、セレシンワックス、ポリエチレンワックス、フィッシャートロプシュワックス、パラフィンワックス、マイクロクリスタリンワックス、オゾケライトワックス等の炭化水素類、オリーブ油、ヒマシ油、ミンク油、マカデミアンナッツ油、モクロウ等の油脂類、ミツロウ、カルナウバワックス、キャンデリラワックス、ゲイロウ、モンタンワックス等のロウ類、イソオクタン酸セチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、ジオクタン酸ネオペンチルグリコール、コレステロール脂肪酸エステル、ホホバ油等のエステル類、ステアリン酸、ラウリン酸、ミリスチン酸、ベヘニン酸、イソステアリン酸、オレイン酸等の脂肪酸類、ステアリルアルコール、セチルアルコール、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、ベヘニルアルコール等の高級アルコール類、低重合度ジメチルポリシロキサン、高重合度ジメチルポリシロキサン、メチルフェニルポリシロキサン、デカメチルシクロペンタシロキサン、オクタメチルシクロテトラシロキサン、ポリエーテル変性ポリシロキサン、ポリオキシアルキレン・アルキルメチルポリシロキサン・メチルポリシロキサン共重合体、アルコキシ変性ポリシロキサン、架橋型オルガノポリシロキサン、フッ素変性ポリシロキサン等のシリコーン類、パーフルオロデカン、パーフルオロオクタン、パーフルオロポリエーテル等のフッ素系油剤類、ラノリン、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ラノリンアルコール等のラノリン誘導体等が挙げられる。 Moreover, in this invention, hardness and the feel at the time of application | coating can be adjusted by mix | blending an oil agent further. As the oil agent used here, it can be used without particular limitation as long as it is an oil component usually used in cosmetics, origin of animal oil, vegetable oil, synthetic oil, etc., solid oil other than component (a), semi-solid oil, Regardless of the nature of liquid oil, volatile oil, etc., hydrocarbons, fats and oils, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, lanolin derivatives Etc. can be used. Specifically, liquid paraffin, heavy liquid isoparaffin, α-olefin oligomer, squalane, petrolatum, polyisobutylene, polybutene, ceresin wax, polyethylene wax, Fischer-Tropsch wax, paraffin wax, microcrystalline wax, ozokerite wax, etc. Oils such as hydrocarbons, olive oil, castor oil, mink oil, macadamian nut oil, molasses, wax such as beeswax, carnauba wax, candelilla wax, gay wax, montan wax, cetyl isooctanoate, isopropyl myristate, Isopropyl palmitate, octyldodecyl myristate, neopentyl glycol dioctanoate, esters of cholesterol fatty acid esters, jojoba oil, stearic acid, lauric Fatty acids such as acid, myristic acid, behenic acid, isostearic acid and oleic acid, higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, and behenyl alcohol, low polymerization dimethylpolysiloxane, high polymerization Dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, polyether-modified polysiloxane, polyoxyalkylene-alkylmethylpolysiloxane-methylpolysiloxane copolymer, alkoxy-modified polysiloxane, cross-linking Type organopolysiloxane, silicones such as fluorine-modified polysiloxane, perfluorodecane, perfluorooctane, perfluoropolyether, etc. And lanolin derivatives such as lanolin, lanolin acetate, lanolin fatty acid isopropyl, and lanolin alcohol.
本発明の油性固形化粧料の製造方法は特に限定されず、例えば、上記成分(a)、(b)を均一に加熱溶解したのち(c)を加えて均一に分散する方法が挙げられるが、更に必要に応じて、本発明の効果を損なわない範囲で、前記必須成分以外の各種成分、例えば、粉体、紫外線吸収剤、保湿剤、皮膜形成剤、褪色防止剤、酸化防止剤、消泡剤、美容成分、防腐剤、ラメ剤、香料などを各種の効果を付与するために適宜配合することができる。 The production method of the oily solid cosmetic of the present invention is not particularly limited, and examples thereof include a method in which the above components (a) and (b) are uniformly heated and dissolved, and then (c) is added and uniformly dispersed. Furthermore, various components other than the essential components, for example, powders, ultraviolet absorbers, moisturizers, film forming agents, anti-fading agents, antioxidants, antifoams, as long as they do not impair the effects of the present invention. Agents, cosmetic ingredients, preservatives, lame agents, fragrances, and the like can be appropriately blended in order to impart various effects.
粉体としては、球状、板状、針状等の形状や煙霧状、微粒子、顔料級等の粒子径、あるいは多孔質、無孔質等の粒子構造等により特に限定されず、無機粉体類、光輝性粉体類、有機粉体類、色素粉体類、金属粉体類、複合粉体類等を使用することがでる。具体的な粉体としては、酸化チタン、酸化亜鉛、酸化セリウム、硫酸バリウム等の白色無機顔料、酸化鉄、カーボンブラック、酸化クロム、水酸化クロム、紺青、群青等の有色無機顔料、タルク、白雲母、金雲母、紅雲母、黒雲母、合成雲母、絹雲母(セリサイト)、合成セリサイト、カオリン、炭化珪素、スメクタイト、酸化アルミニウム、酸化マグネシウム、酸化ジルコニウム、酸化アンチモン、珪ソウ土、ケイ酸アルミニウム、メタケイ酸アルミニウムマグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸マグネシウム、炭酸カルシウム、炭酸マグネシウム、ヒドロキシアパタイト、窒化ホウ素等の白色体質粉体、二酸化チタン被覆雲母、二酸化チタン被覆オキシ塩化ビスマス、酸化鉄雲母チタン、紺青処理雲母チタン、カルミン処理雲母チタン、オキシ塩化ビスマス、魚鱗箔等の光輝性粉体、ポリアミド系樹脂、ポリエチレン系樹脂、ポリアクリル系樹脂、ポリエステル系樹脂、フッ素系樹脂、セルロース系樹脂、ポリスチレン系樹脂、スチレン−アクリル共重合樹脂等のコポリマー樹脂、ポリプロピレン系樹脂、シリコーン樹脂、ウレタン樹脂等の有機高分子樹脂粉体、N−アシルリジン等の有機低分子性粉体、澱粉、シルク粉末、セルロース粉末等の天然有機粉体、赤色201号、赤色202号、赤色205号、赤色226号、赤色228号、橙色203号、橙色204号、青色404号、黄色401号等の有機顔料粉体、赤色3号、赤色104号、赤色106号、橙色205号、黄色4号、黄色5号、緑色3号、青色1号等のジルコニウム、バリウム又はアルミニウムレーキ等の有機顔料粉体あるいは更にアルミニウム粉、金粉、銀粉等の金属粉体、微粒子酸化チタン被覆雲母チタン、微粒子酸化亜鉛被覆雲母チタン、硫酸バリウム被覆雲母チタン、酸化チタン含有二酸化珪素、酸化亜鉛含有二酸化珪素等の複合粉体等を例示することができる。これら粉体はその1種又は2種以上を用いることができ、更に複合化したものを用いても良い。なお、これら粉体は、フッ素系化合物、シリコーン系化合物、金属石鹸、レシチン、水素添加レシチン、コラーゲン、炭化水素、高級脂肪酸、高級アルコール、エステル、ワックス、ロウ、界面活性剤等の1種又は2種以上を用いて表面処理を施してあっても良い。 The powder is not particularly limited by the shape of a sphere, plate, needle, etc., the particle size of fumes, fine particles, pigment grade, etc., or the particle structure of porous, nonporous, etc. Bright powders, organic powders, pigment powders, metal powders, composite powders, and the like can be used. Specific powders include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, bitumen and ultramarine, talc and white cloud. Mother, phlogopite, phlogopite, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, smectite, aluminum oxide, magnesium oxide, zirconium oxide, antimony oxide, siliceous earth, silicic acid Aluminum, magnesium metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, etc., white powder, titanium dioxide coated mica, titanium dioxide coated bismuth oxychloride, oxidation Iron mica titanium, bitumen treated mica titanium, karmi Bright powder such as treated mica titanium, bismuth oxychloride, fish scale foil, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, styrene-acrylic co Copolymer resin such as polymer resin, organic polymer resin powder such as polypropylene resin, silicone resin and urethane resin, organic low molecular weight powder such as N-acyl lysine, natural organic powder such as starch, silk powder and cellulose powder Red 201, Red 202, Red 205, Red 226, Red 228, Orange 203, Orange 204, Blue 404, Yellow 401, etc. Organic pigment powder, Red 3 and Red 104 , Red 106, orange 205, yellow 4, yellow 5, green 3, blue 1, etc. zirconium, barium or al Organic pigment powder such as lime lake or metal powder such as aluminum powder, gold powder, silver powder, fine titanium oxide coated mica titanium, fine zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide containing silicon dioxide, zinc oxide contained Examples thereof include composite powders such as silicon dioxide. These powders can be used singly or in combination of two or more of them. These powders are one or two of fluorine compound, silicone compound, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbon, higher fatty acid, higher alcohol, ester, wax, wax, surfactant and the like. Surface treatment may be performed using seeds or more.
また、界面活性剤は粉体の分散性向上の目的で用いることができ、化粧品一般に用いられている界面活性剤であれば特に制約はなく、非イオン界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等が使用される。更に、紫外線吸収剤としては、例えばベンゾフェノン系、PABA系、ケイ皮酸系、サリチル酸系等の紫外線吸収剤や、4−tert−ブチル−4'−メトキシジベンゾイルメタン、オキシベンゾン等が挙げられ、保湿剤としては、例えばタンパク質、ムコ多糖、コラーゲン、エラスチン、ケラチン等が挙げられる。
更にまた、水性成分はモイスチャー効果を付与する目的で用いることができ、水及び水に可溶な成分であれば何れでもよく、水の他に、例えば、プロピレングリコール、1,3−ブチレングリコール、ジプロピレングリコール、ポリエチレングリコール等のグリコール類、グリセリン、ジグリセリン、ポリグリセリン等のグリセロール類、アロエベラ、ウイッチヘーゼル、ハマメリス、キュウリ、レモン、ラベンダー、ローズ等の植物抽出液が挙げられる。
また更に、酸化防止剤としては、例えばα−トコフェロール、アスコルビン酸等が、美容成分としては、例えばビタミン類、消炎剤、生薬等が、防腐剤としては、例えばパラオキシ安息香酸エステル、フェノキシエタノール等がそれぞれ挙げられる。
The surfactant can be used for the purpose of improving the dispersibility of the powder, and is not particularly limited as long as it is a surfactant generally used in cosmetics. Nonionic surfactants, anionic surfactants, cations An ionic surfactant, an amphoteric surfactant, and the like are used. Furthermore, examples of the ultraviolet absorber include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based ultraviolet absorbers, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone, and the like. Examples of the agent include protein, mucopolysaccharide, collagen, elastin, keratin and the like.
Furthermore, the aqueous component can be used for the purpose of imparting a moisture effect, and may be any component that is soluble in water and water. In addition to water, for example, propylene glycol, 1,3-butylene glycol, Examples include glycols such as dipropylene glycol and polyethylene glycol, glycerols such as glycerin, diglycerin, and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, and rose.
Furthermore, as antioxidants, for example, α-tocopherol, ascorbic acid, etc., as cosmetic ingredients, for example, vitamins, anti-inflammatory agents, herbal medicines, etc., as preservatives, for example, paraoxybenzoic acid ester, phenoxyethanol, etc., respectively. Can be mentioned.
本発明の油性固形化粧料は、メイクアップ化粧料、スキンケア化粧料、毛髪化粧料等特に限定されず、具体的には、アイクリーム、口紅、リップグロス、リップクリーム、ファンデーション、頬紅、アイシャドウ等が挙げられ、その形状はスティック状、皿状等が挙げられる。 The oily solid cosmetic of the present invention is not particularly limited to makeup cosmetics, skin care cosmetics, hair cosmetics, and the like. Specifically, eye cream, lipstick, lip gloss, lip balm, foundation, blusher, eye shadow, etc. Examples of the shape include a stick shape and a dish shape.
次に実施例をもって本発明をより詳細に説明する。本発明はこれらにより、何ら限定されるものではない。 Next, the present invention will be described in more detail with reference to examples. The present invention is not limited at all by these.
(製造例1)
トリイソステアリン酸グリセリルの調製
前記化学式(1)で示すイソステアリン酸とグリセリンとを攪拌機、温度計、窒素ガス吹込管、水分離管を備えた4つ口フラスコに仕込み、触媒として塩化スズを、還流剤としてキシレンを一緒に加え、200〜250℃で15時間、反応させた。反応終了後、活性白土を用いて脱色し、常法にて脱臭を行い、トリイソステアリン酸グリセリルを分取した。
(Production Example 1)
Preparation of glyceryl triisostearate The isostearic acid and glycerin represented by the chemical formula (1) were charged into a four-necked flask equipped with a stirrer, a thermometer, a nitrogen gas blowing tube, and a water separation tube, and tin chloride as a catalyst was used as a reflux agent. Was added together and reacted at 200-250 ° C. for 15 hours. After completion of the reaction, it was decolorized using activated clay, deodorized by a conventional method, and glyceryl triisostearate was collected.
(製造例2)
トリイソステアリン酸ジグリセリルの調製
製造例1で用いたイソステアリン酸とジグリセリンを製造例1と同様にエステル化反応し、トリイソステアリン酸ジグリセリルを分取した。
(Production Example 2)
Preparation of diglyceryl triisostearate The isostearic acid and diglycerin used in Production Example 1 were esterified in the same manner as in Production Example 1 to fractionate diglyceryl triisostearate.
(実施例1〜5及び比較例1〜5)
スティック状口紅の調製
表1に示す処方のスティック状口紅を下記の製造方法にて製造し、得られた各スティック状口紅について、折れ荷重値の応力値より形状保持性を評価し、官能評価により、使用感、ツヤ及びツヤの持続性、化粧持ちを評価し、さらに高温下における安定性評価を実施した評価し、その結果を表1にあわせて示す。
(Examples 1-5 and Comparative Examples 1-5)
Preparation of stick-shaped lipsticks Stick-shaped lipsticks with the formulation shown in Table 1 were manufactured by the following manufacturing method, and for each of the obtained stick-shaped lipsticks, the shape retention was evaluated from the stress value of the bending load value, and by sensory evaluation Evaluation was made by evaluating the feeling of use, gloss and durability of the gloss, longevity of the makeup, and further evaluating the stability under high temperature. The results are also shown in Table 1.
*1:トリイソステアリン酸ジグリセリル
下記化学式(2)に示すイソステアリン酸とジグリセリンとのエステル化合物
* 1: Diglyceryl triisostearate ester compound of isostearic acid and diglycerin represented by the following chemical formula (2)
*2:シュガーワックスA−10E(第一工業製薬社製)
*3:AEROJILR−976S(日本アエロジール社製)
*4:パーフルオロアルキルリン酸5%処理(大東化成工業社製)
*5:ジメチコン3%処理(三好化成社製)
(製造方法)
A.成分(1)〜(14)を110〜120℃にて加熱溶解後、成分(15)〜(21)を加えて、均一混合する。
B.Aに成分(22)〜(25)を加えて均一に混合する。
C.Bに成分(26)を加えて加熱し、脱泡後、型に流し込み充填し、0℃に冷却して成型する。
* 2: Sugar wax A-10E (Daiichi Kogyo Seiyaku Co., Ltd.)
* 3: AEROJILR-976S (manufactured by Nippon Aerology Co., Ltd.)
* 4: 5% perfluoroalkyl phosphoric acid treatment (manufactured by Daito Kasei Kogyo Co., Ltd.)
* 5: Dimethicone 3% treatment (manufactured by Miyoshi Kasei)
(Production method)
A. After components (1) to (14) are heated and dissolved at 110 to 120 ° C., components (15) to (21) are added and mixed uniformly.
B. Add components (22) to (25) to A and mix uniformly.
C. Ingredient (26) is added to B, heated, defoamed, poured into a mold, filled, cooled to 0 ° C. and molded.
(評価)
1.折れ強度
サンプルを35℃の恒温槽に1時間セットし、レオメーターNRM―2002J(レオテック社製)にて、歯型押し棒により、応力値を測定する。その測定値を下記の基準により判断し、充分な形状保持を有するものから困難なものまで、◎〜××の5段階にて評価し、(ニ)形状保持性とした。
250g以上 ;非常に良好;◎
200g以上250g未満;良好 ;○
150g以上200g未満;やや良好 ;△
100g以上150g未満;不良 ;×
100g未満 ;非常に不良;××
(Evaluation)
1. Bending strength The sample is set in a thermostatic bath at 35 ° C. for 1 hour, and the stress value is measured with a tooth pressing bar using a rheometer NRM-2002J (manufactured by Rheotech). The measured values were judged according to the following criteria, and evaluated from five grades of ◎ to xx, from those having sufficient shape retention to those having difficulty in shape, as (d) shape retention.
250 g or more; very good;
200 g or more and less than 250 g; good;
150 g or more and less than 200 g; somewhat good;
100 g or more and less than 150 g; poor; x
<100 g; very poor; XX
2.官能評価
(イ)の使用感、(ロ)のツヤ及びその持続、(ハ)の化粧持ちについて、専門パネル20名による使用テストを行い、パネル各人が下記絶対評価にて7段階に評価し評点を付け、各試料毎にパネル全員の評点合計から、その平均値を算出し、下記4段階判定基準により判定した。
なお、(イ)の使用感については、芯がなく、柔らかく崩れ、密着性に優れるといった観点から評価した。(ロ)のツヤ及びツヤの持続性、(ハ)の化粧持ちについては、各試料を唇に塗布し、パネルに通常の生活をしてもらい、3時間後のツヤと化粧効果について評価した。
(絶対評価)
(評点):(評価)
6:非常に良い
5:良い
4:やや良い
3:普通
2:やや悪い
1:悪い
0:非常に悪い
(判定基準)
(評点平均値) :(判定)
5点を超える :非常に良好:◎
3点を超えて5点以下 :良好 :○
1点を超えて3点以下 :やや不良 :△
1点以下 :不良 :×
2. Sensory evaluation The use feeling of (i), gloss of (b) and its persistence, and (c) make-up test are conducted by 20 professional panelists, and each panel member evaluates to 7 levels according to the following absolute evaluation. A score was assigned, and the average value was calculated from the total score of all the panels for each sample, and judged according to the following four-step criteria.
In addition, about the usability | use_condition of (I), it evaluated from a viewpoint that there is no core, it collapses softly and it is excellent in adhesiveness. Regarding the gloss of (b) and the persistence of the gloss and (c), the samples were applied to the lips, and a normal life was given to the panel, and the gloss and makeup effect after 3 hours were evaluated.
(Absolute evaluation)
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad (judgment criteria)
(Average score): (Judgment)
More than 5 points: Very good: ◎
3 points to 5 points or less: Good: ○
More than 1 point and 3 points or less: Somewhat bad: △
1 point or less: Defect: ×
3.安定性評価
50℃の恒温槽に1ヶ月間、放置し、外観を目視観察し、異常のないもの(発汗していないもの)から、著しく発汗しているものまで、◎〜××の5段階で評価し、(ホ)経時安定性とした。
(評価) :(判定)
全く変化なし :◎
わずかに発汗しているが使用に支障なし :○
やや発汗しているため :△
発汗している :×
著しい発汗が見られる :××
3. Stability evaluation From a constant temperature bath at 50 ° C. for 1 month and visually observing the external appearance, from those with no abnormalities (no sweating) to those with significant sweating, ◎ to xx Evaluation was made in five stages, and (e) stability over time was set.
(Evaluation): (Judgment)
No change: ◎
Slightly sweating but no problem in use: ○
Slightly sweating: △
Sweating : ×
Remarkable sweating : ××
表1から明らかなごとく、本発明のスティック状口紅は、折れ強度が高く、形状保持性、安定性に優れ、さらには、塗布時の使用感、ツヤ及びその持続性、化粧持ちが良好であった。これに対して成分(a)が含有されていない比較例1では使用感および形状保持の点で、また、成分(b)が含有されていない比較例2ではツヤと化粧持ちの点で、さらに、成分(c)が含有されていない比較例3では安定性と化粧持ちの点で、成分(a)、(b)および(c)が含有されていない比較例4では、全ての点で、満足いくものが得られなかった。また、成分(b)の替わりに脂肪酸構造の異なるトリイソステアリン酸ジグリセリルを含有させた比較例5では、ツヤおよび化粧持ちの点で満足いくものが得られなかった。 As is apparent from Table 1, the stick-shaped lipstick of the present invention has high folding strength, excellent shape retention and stability, and also has a good feeling during use, gloss and its durability, and long-lasting makeup. It was. On the other hand, Comparative Example 1 containing no component (a) has a feeling of use and shape retention, and Comparative Example 2 containing no component (b) has a gloss and a longevity. In Comparative Example 3 in which component (c) is not contained, in terms of stability and longevity, in Comparative Example 4 in which components (a), (b) and (c) are not contained, in all respects, I couldn't get a satisfactory one. Further, in Comparative Example 5 in which diglyceryl triisostearate having a different fatty acid structure was contained instead of the component (b), a satisfactory product was not obtained in terms of gloss and longevity.
(実施例6)
皿状口紅
(成分) (%)
1.エチレンプロピレンコポリマー 3
2.パラフィンワックス 3
3.ミツロウ 3
4.デキストリン脂肪酸エステル*6 3
5.煙霧状シリカ*7 2
6.ワセリン 10
7.トリイソステアリン酸グリセリル(製造例1) 15
8.重質流動イソパラフィン 15
9.ジカプリン酸プロピレングリコール 10
10.テトライソステアリン酸ジグリセリル 10
11.紫外線吸収剤(パラメトキシケイ皮酸2−エチルヘキシル) 0.1
12.酸化防止剤(天然ビタミンE) 0.1
13.リンゴ酸ジイソステアリル 残量
14.酸化チタン被覆ガラス末*8 1
*6:レオパールKL(千葉製粉社製)
*7:AEROSIL300(日本アエロジール社製)
*8:メタシャイン1080RC−R
(製造方法)
A.成分(1)〜(13)を110〜120℃に加熱し均一に混合した後、成分(14)を加え、均一に混合する。
B.Aを脱泡後、皿に流し込み室温まで冷却して製品とする。
本実施例で得られた皿状口紅は、滑らかな使用感であるとともに、ツヤ及びその持続性、化粧持ちに優れ、発汗等もなく、経時安定性が良好なものであった。一方、成分7のトリイソステアリン酸グリセリルに替えて、トリオクタン酸グリセリルを用いたところ、ツヤおよび化粧持ちの点で良くないものであった。
(Example 6)
Dish lipstick (ingredient) (%)
1. Ethylene propylene copolymer 3
2. Paraffin wax 3
3. Beeswax 3
4). Dextrin fatty acid ester * 6 3
5. Haze-like silica * 7 2
6). Vaseline 10
7). Glyceryl triisostearate (Production Example 1) 15
8). Heavy liquid isoparaffin 15
9. Propylene glycol dicaprate 10
10. Diglyceryl tetraisostearate 10
11. UV absorber (2-ethylhexyl paramethoxycinnamate) 0.1
12 Antioxidant (natural vitamin E) 0.1
13. 14. Diisostearyl malate remaining 14 Titanium oxide coated glass powder * 8 1
* 6: Leopard KL (Chiba Flour Mills)
* 7: AEROSIL300 (manufactured by Nippon Aerology Co., Ltd.)
* 8: Metashine 1080RC-R
(Production method)
A. Components (1) to (13) are heated to 110 to 120 ° C. and mixed uniformly, and then component (14) is added and mixed uniformly.
B. After defoaming A, pour into a dish and cool to room temperature to make a product.
The dish-shaped lipstick obtained in this example had a smooth feeling of use, was excellent in gloss and its durability, long-lasting makeup, did not sweat, and had good stability over time. On the other hand, when glyceryl trioctanoate was used instead of component 7 glyceryl triisostearate, it was not good in terms of gloss and longevity.
(実施例7)
皿状アイシャドウ
(成分) (%)
1.エチレンプロピレンコポリマー 5
2.12−ヒドロキシステアリン酸*9 2
3.有機変性ベントナイト*10 2
4.煙霧状シリカ*11 5
5.ジメチルポリシロキサン 10
6.トリイソステアリン酸ジグリセリル(製造例2) 20
7.ポリブテン 10
8.紫外線吸収剤(オキシベンゾン) 0.1
9.酸化防止剤
(2,6−ジ−ターシャリーブチル−パラクレゾール) 0.1
10.トリオクタン酸グリセリル 10
11.マイカ 残量
12.赤色酸化鉄 0.5
13.酸化チタン 1
14.雲母チタン 10
*9:12−ヒドロキシステアリン酸(伊藤製油社製)
*10:ベントン27(NLインダストリー社製)
*11:キャボジルTS―530(キャボット社製)
(製造方法)
A.成分(1)〜(10)を110〜120℃に加熱し均一に混合する。
B.Aに成分(11)〜(14)を加え、均一に分散する。
C.Bを脱泡後、皿に流し込み室温まで冷却して製品とする。
本実施例で得られた皿状アイシャドウは、滑らかな使用感であるとともに、ツヤ及びその持続性、化粧持ちに優れ、発汗等もなく、経時安定性が良好なものであった。
(Example 7)
Dish eye shadow (ingredient) (%)
1. Ethylene propylene copolymer 5
2.12-hydroxystearic acid * 9 2
3. Organically modified bentonite * 10 2
4). Smoke-like silica * 11 5
5. Dimethylpolysiloxane 10
6). Diglyceryl triisostearate (Production Example 2) 20
7). Polybutene 10
8). UV absorber (oxybenzone) 0.1
9. Antioxidant (2,6-di-tert-butyl-paracresol) 0.1
10. Glyceryl trioctanoate 10
11. Mica remaining amount 12. Red iron oxide 0.5
13. Titanium oxide 1
14 Mica titanium 10
* 9: 12-hydroxystearic acid (Ito Oil Co., Ltd.)
* 10: Benton 27 (manufactured by NL Industry)
* 11: Cabosil TS-530 (Cabot)
(Production method)
A. Components (1) to (10) are heated to 110 to 120 ° C. and mixed uniformly.
B. Add components (11) to (14) to A and disperse uniformly.
C. After defoaming B, pour into a dish and cool to room temperature to make a product.
The dish-shaped eye shadow obtained in this example had a smooth feeling of use, was excellent in gloss and its durability, long-lasting makeup, did not sweat, and had good stability over time.
(実施例8)
スティック状ファンデーション
(成分) (%)
1.エチレンプロピレンコポリマー 5
2.オゾケライトワックス 3
3.ポリエチレンワックス 3
4.キャンデリラワックス 3
5.カルナウバワックス 3
6.トリイソステアリン酸グリセリル(製造例1) 10
7.トリイソステアリン酸ジグリセリル(製造例2) 10
8.ワセリン 5
9.煙霧状シリカ*12 2
10.紫外線吸収剤
(4−ターシャリーブチル−4‘−メトキシジベンゾイルメタン) 0.1
11.酸化防止剤(酢酸トコフェロール) 0.1
12.イソオクタン酸セチル 20
13.酸化チタン 10
14.マイカ 20
15.タルク 残量
16.赤色酸化鉄 0.5
17.黄色酸化鉄 2.5
18.黒色酸化鉄 0.1
*12:タラノックス500(タルコ社製)
(製造方法)
A.成分(1)〜(12)を110〜120℃に加熱し均一に混合する。
B.Aに成分(13)〜(18)を加え、均一に分散する。
C.Bを脱泡後、容器に充填し、室温に冷却して製品とする。
本実施例で得られたスティック状ファンデーションは、滑らかな使用感であるとともに、化粧持ちに優れ、発汗等もなく、経時安定性が良好なものであった。
(Example 8)
Stick-like foundation (ingredient) (%)
1. Ethylene propylene copolymer 5
2. Ozokerite wax 3
3. Polyethylene wax 3
4). Candelilla wax 3
5. Carnauba wax 3
6). Glyceryl triisostearate (Production Example 1) 10
7). Diglyceryl triisostearate (Production Example 2) 10
8). Vaseline 5
9. Smoke-like silica * 12 2
10. UV absorber (4-tertiarybutyl-4′-methoxydibenzoylmethane) 0.1
11. Antioxidant (tocopherol acetate) 0.1
12 Cetyl isooctanoate 20
13. Titanium oxide 10
14 Mica 20
15. Talc remaining 16. Red iron oxide 0.5
17. Yellow iron oxide 2.5
18. Black iron oxide 0.1
* 12: Taranox 500 (made by Tarco)
(Production method)
A. Components (1) to (12) are heated to 110 to 120 ° C. and mixed uniformly.
B. Add components (13) to (18) to A and disperse uniformly.
C. After defoaming B, the container is filled and cooled to room temperature to obtain a product.
The stick-like foundation obtained in this example had a smooth feeling of use, excellent makeup, no sweating, and good temporal stability.
Claims (2)
(a)エチレンプロピレンコポリマー
(b)下記化学式(1)に示すイソステアリン酸とグリセリンおよび/またはジグリセリ
ンとのトリエステル化合物
を含有することを特徴とする油性固形化粧料(但し、少なくとも、ショ糖脂肪酸エステル、スフィンゴシンおよび/またはその誘導体並びに水性成分を構成成分とするベシクル分散物、ジイソステアリン酸ポリグリセリル、下記式(I)
で表されるポリダイマージリノール酸ダイマージリノレイル、又は下記式(II)
で表されるフッ素変性環状シリコーンを含有するものを除く)。 The following components (a) to (c);
(A) Ethylene propylene copolymer (b) Triester compound of isostearic acid and glycerin and / or diglycerin represented by the following chemical formula (1)
A polydimerlinoleic acid dimer linoleyl represented by the following formula (II)
Except those containing a fluorine-modified cyclic silicone represented by:
分(c)の含有量が、0.1〜10質量%含有されていることを特徴とする請求項1記載
の油性固形化粧料。
The content of the component (a) is 3 to 30% by mass, the content of the component (b) is 3 to 70% by mass, and the content of the component (c) is 0.1 to 10% by mass. The oily solid cosmetic according to claim 1.
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JP5148909B2 (en) * | 2007-03-30 | 2013-02-20 | 株式会社コーセー | Lip cosmetics |
US9056053B2 (en) * | 2008-01-08 | 2015-06-16 | Avon Products, Inc | Nanoparticle compositions providing enhanced color for cosmetic formulations |
JP5661304B2 (en) * | 2010-03-11 | 2015-01-28 | 株式会社コーセー | Cosmetics for lips |
JP6960810B2 (en) * | 2017-09-12 | 2021-11-05 | ポーラ化成工業株式会社 | Oil-based solid cosmetics |
JP6758663B2 (en) * | 2018-08-18 | 2020-09-23 | ジェイオーコスメティックス株式会社 | Oily solid cleansing cosmetics |
CN109745243B (en) * | 2019-01-29 | 2021-07-16 | 上海欧润化妆品有限公司 | Lipstick and preparation process thereof |
JP6897993B2 (en) * | 2019-05-10 | 2021-07-07 | 東色ピグメント株式会社 | Stick-like oil-based solid cosmetics |
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JPS6178708A (en) * | 1984-09-26 | 1986-04-22 | Taiyo Kagaku Kk | Cosmetic |
JP3634977B2 (en) * | 1999-04-19 | 2005-03-30 | 株式会社コーセー | Oily cosmetics |
JP2001072537A (en) * | 1999-09-03 | 2001-03-21 | Kose Corp | Oily solid cosmetic |
JP2001328918A (en) * | 2000-03-15 | 2001-11-27 | Kose Corp | Oily solid cosmetic |
JP4414082B2 (en) * | 2000-10-23 | 2010-02-10 | 株式会社コーセー | Oily cosmetics |
JP2003026529A (en) * | 2001-07-12 | 2003-01-29 | Kose Corp | Oily cosmetic |
JP2003104841A (en) * | 2001-09-28 | 2003-04-09 | Kose Corp | Oily solid cosmetic |
JP3316499B1 (en) * | 2001-10-04 | 2002-08-19 | 株式会社ノエビア | Cosmetic and skin composition |
AU2002367142A1 (en) * | 2001-12-27 | 2003-07-15 | The Nisshin Oillio, Ltd. | Ester-containing oils and external preparations for skin and cosmetics containing the oils |
TW200413020A (en) * | 2002-07-05 | 2004-08-01 | Kose Corp | Vesicle dispersion and cosmetic containing the same |
JP3942540B2 (en) * | 2002-12-27 | 2007-07-11 | 株式会社コーセー | Oily gel cosmetic |
JP2004210720A (en) * | 2002-12-27 | 2004-07-29 | Kose Corp | Oily cosmetic |
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