JP5026724B2 - Oil makeup cosmetics - Google Patents

Description

  The present invention relates to oil-based makeup cosmetics, and in particular, is excellent in feeling of use (lightness of spread and no stickiness), durability of gloss and glossiness of cosmetic film, secondary adhesion preventing effect, moisturizing effect (drying) The present invention relates to an oil-based makeup cosmetic with excellent feeling.

  Conventionally, oil-based makeup cosmetics have been required as a quality that has a long-lasting cosmetic effect and a moisturizing effect that can be moistened compared to powder-based makeup cosmetics, water-based, and emulsified makeup cosmetics. ing. In particular, in lip cosmetics, after applying lipstick to the lips, the lipstick does not adhere to clothes, etc., in addition to the so-called secondary adhesion preventing effect, and recently, the makeup effect is also excellent in the gloss of the coating film. Sustained gloss is required as an important quality.

  As a technique for realizing the gloss of the decorative film and the persistence of the gloss, a technique using a combination of a specific organic silicone resin, a low-polymerization silicone oil, and a hydrocarbon wax (see, for example, Patent Document 1), polybutene and dextrin Examples include a technique using a fatty acid ester and / or 12-hydroxystearic acid (for example, see Patent Document 2), and a technique of combining an acrylic-silicone graft copolymer, a solid oil having a specific melting point, and a branched ester oil. . (For example, see Patent Document 3)

On the other hand, as a technique for embodying the effect of preventing cosmetic breakage and preventing secondary adhesion, a technique for forming a water-repellent oily film on the skin by mixing with an oil component in which a water-insoluble salt of alginic acid coexists (for example, patent documents) 4) and a technique in which a water-repellent polymer such as a silicone resin such as trimethylsiloxysilicic acid exists on the coated surface due to volatilization of volatile oil (for example, Patent Document 5).
In addition, a polyoxyalkylene-modified organopolysiloxane is blended to increase the viscosity by moisture in the coating film (for example, Patent Document 6), polyoxyalkylene-modified organopolysiloxane, and a perfluoroalkyl group. Techniques (for example, Patent Documents 7 and 8) that improve the feeling of use in addition to long-lasting makeup by combining a liquid oil agent or a branched ester oil and a (semi) solid fat have been studied.

  Furthermore, by using polydimerlinoleic acid dimer dilinoleyl, which is a specific oil agent, a technique for giving gloss to a decorative film and improving adhesion and makeup durability (for example, Patent Document 9), dimer acid and An ester obtained by esterifying an oligomer ester with a divalent or higher alcohol with a monovalent alcohol or / and a monovalent carboxylic acid, or an oligomer ester with a dimer diol and a divalent or higher carboxylic acid is converted into a monovalent alcohol. Alternatively, there is a technique (for example, Patent Document 10) relating to an ester esterified with a monovalent carboxylic acid.

Japanese Patent No. 2577588 Japanese Patent Laid-Open No. 2002-3340 JP 2001-187712 A Japanese Patent No. 2519186 JP-A-7-267826 Japanese Patent No. 2754108 Japanese Patent No. 3200347 Japanese Patent No. 3138141 JP 2002-128629 A JP 2004-256515 A

  However, the recent market needs require a considerably higher quality with respect to the gloss and the sustainability of the gloss, and the technology described in Patent Document 1 that reduces stickiness and lightens the spread is applied. Although the gloss immediately after is obtained, the persistence of the gloss and the feeling of adhesion may be lacking. In addition, the technique described in Patent Document 2 is excellent in gloss and adhesion, but has a strong stickiness and good usability. Furthermore, in the technology described in Patent Document 3, the gloss and the durability of the gloss are excellent, but the level of the gloss is inferior to the level that has recently been required. Further, it was not excellent in terms of lightness of spread, no stickiness, and adhesion (adhesion).

On the other hand, with regard to the secondary adhesion preventing effect, it is difficult to obtain a glossy feeling immediately after coating with the technique described in Patent Document 4, and it takes a long time to obtain the secondary adhesion preventing effect. In the technique described in Patent Document 5, the effect of preventing secondary adhesion can be obtained over time, but the gloss of the decorative film is remarkably reduced, and there may be a problem that a feeling of dryness or a burden after application is felt.
Further, in the techniques described in Patent Documents 6 to 8, there is a problem in that although the reduction in gloss is small, it feels dry over time after application. That is, when the polyoxyalkylene-modified silicone is blended, the secondary adhesion prevention effect is caused by the mechanism that the component absorbs moisture to thicken the coating film and improve the adhesion of pigments and the like. However, since the uniformity of the coating film cannot be obtained, there is a feeling of dryness when the coating film is thin, and a burden may be caused when the coating film is thick.

  Furthermore, Patent Documents 9 and 10 describe techniques related to oligomeric esters of dimer acid, but there is no description regarding the effect of preventing secondary adhesion.

Thus, in the prior art, secondary adhesion prevention effect and gloss feeling, secondary adhesion prevention effect and moisturizing feeling (no dry feeling), lightness of the gloss feeling and no stickiness feel are contradictory phenomena. Met.
Therefore, oily makeup cosmetics with excellent feeling of use (lightness and no stickiness), durability of gloss and glossiness of the cosmetic film, secondary adhesion prevention effect, and moisturizing feeling (no dryness) Was demanded.

Under such circumstances, the present inventors have conducted extensive studies to solve the above problems, and as a result, esterified carboxyl groups at both ends of oligomeric esters of dimer acid and dimer diol, which are specific ester compounds, with isostearyl alcohol. By using a water-soluble polymer or a polyoxyalkylene group-containing silicone compound that is a specific secondary anti-adhesive agent, the coating feels light and has no stickiness, and has a uniform thickness. By making it into a film, the persistence of gloss and glossiness is improved, and a feeling of adhesion (adhesion) with the skin and lips can be obtained. As a result, the present invention was completed.
This is because the cosmetic film absorbs water over time after being applied to the skin and lips, and as a result, the cosmetic film thickens and the adhesion to the skin and lips is improved. It is the same as the mechanism of the secondary anti-adhesive agent, but not only the secondary anti-adhesive agent absorbs water, but also retains the ester compound, which is an oil agent, to increase the viscosity while maintaining a uniform cosmetic film, Adhesion with the lips increased, and the secondary adhesion prevention effect could be enhanced. In addition, when only the secondary anti-adhesive agent absorbs water, it is generally difficult to obtain a thickness, uniformity and transparency in the decorative film, so that the glossiness and moisturizing feeling could not be enhanced. In the invention, since the thickness, uniformity and transparency of the decorative film can be obtained, as a result, a decorative film having a glossy and moisturizing feeling can be obtained.

That is, the present invention comprises the following components (a) and (b):
(A) Compound R ³ OCO—R ¹ — (— COO—R ² —OCO— in which the carboxyl groups at both ends of the oligomeric ester of dimer acid and dimer diol represented by the following chemical formula (1) are esterified with isostearyl alcohol R ^1- ) _n -COOR ³ (1)
(In the formula, R ¹ represents a dimer acid residue, R ² represents a dimer diol residue, R ³ represents an isostearyl alcohol residue, and n represents a number of 4 to 6.)
(B) one or more secondary adhesion inhibitors selected from long-chain alkyl-containing polyoxyalkylene-modified organopolysiloxanes, polyoxyalkylene-modified organopolysiloxanes, carboxyvinyl polymers, alkyl-modified carboxyvinyl polymers, and agar An oil-based makeup cosmetic to be blended is provided.

  The oil-based makeup cosmetic composition of the present invention has an excellent feeling of use (lightness and no stickiness), durability of gloss and glossiness of the cosmetic film, secondary adhesion prevention effect, moisturizing feeling (no dryness) It is excellent.

Hereinafter, the present invention will be described in detail.
The compound obtained by esterifying the carboxyl groups at both ends of the oligomeric ester of the dimer acid and dimer diol of the component (a) used in the present invention with isostearyl alcohol (hereinafter sometimes simply referred to as “ester compound”), It can be represented by the following general formula (1).
R ³ OCO—R ¹ — (— COO—R ² —OCO—R ¹ —) _n —COOR ³ (1)
(In the formula, R ¹ represents a dimer acid residue, R ² represents a dimer diol residue, R ³ represents an isostearyl alcohol residue, and n represents a number of 4 to 6.)

The ester compound of component (a) used in the present invention is a compound obtained by esterifying carboxyl groups present at both ends of an oligomer ester obtained from dimer acid and dimer diol with isostearyl alcohol.
Dimer acid, which is a starting material, is obtained by an intermolecular polymerization reaction of unsaturated fatty acid, but is obtained by dimerizing unsaturated fatty acid having 11 to 22 carbon atoms, and mainly a dibasic acid having about 36 carbon atoms. It is an ingredient. The CAS number corresponds to 61788-89-4. Further, in the dimerization reaction, hydrogenated dimer acid obtained by hydrogenating double bonds is preferable. Examples of commercially available products include PRIPOL 1006, 1009, 1015, and 1025 (manufactured by Unikema).
The dimer diol is mainly composed of a diol having about 36 carbon atoms in which the dimer acid and / or lower alcohol ester thereof is hydrogenated in the presence of a catalyst and the carboxylic acid portion of the dimer acid is an alcohol. Examples of commercially available products include PRIPOL 2033 (manufactured by Unikema).
Isostearyl alcohol includes those obtained by reducing fatty acids obtained from dimer acid by-products, those obtained by garvet method, those obtained by aldol condensation method, etc. Can also be used. Examples of commercially available products include Speziol C18 ISOC (manufactured by Cognis).

Although the manufacturing method of the ester compound of a component (a) is not specifically limited, For example, after esterifying dimer acid and dimer diol and obtaining oligomer ester, it obtains by esterifying a carboxyl group with isostearyl alcohol further. Can do. It can also be obtained by esterifying dimer acid, dimer diol and isostearyl alcohol at once.
In the production of component (a), when an oligomer ester is obtained as an intermediate, the oligomer ester of dimer acid and dimer diol, which is an intermediate, can be obtained by changing the respective charging ratios, The average molecular weight can be adjusted. The range of the charging ratio is preferably 0.4 to 0.9 molar equivalent of dimer diol with respect to 1 molar equivalent of dimer acid. Furthermore, when esterifying with isostearyl alcohol, it is preferable that it is 0.8-1.5 mol with respect to the remaining carboxyl group.

  The conditions for the esterification reaction in obtaining the ester compound of component (a) are not particularly limited, and are carried out by a commonly used method. For example, paratoluenesulfonic acid, sulfuric acid, hydrochloric acid, methanesulfonic acid, boron trifluoride diethyl ether complex or the like is used as a catalyst, and heptane, hexane, cyclohexane, toluene, xylene or the like is used as a solvent at 50 to 260 ° C. be able to. Alternatively, esterification can be carried out at 100 to 260 ° C. even without solvent and without catalyst.

  The ester compound of component (a) preferably has a viscosity at 25 ° C. of 10,000 to 20,000 mPa · s. Examples of such ester compounds include LUSPLAN DA-DD-IS (manufactured by Nippon Seika Co., Ltd.). The viscosity was measured using a cone plate viscometer (ROTO visco1 manufactured by Haake Co.) under the conditions of a shear rate of 100 (1 / s), a cone diameter of 35 mm, and an angle of 2 °.

  The blending amount of the component (a) in the oily makeup cosmetic of the present invention is not particularly limited, but is preferably 1 to 40% by mass (hereinafter simply referred to as “%”), and more preferably 5 to 30%. . When it mix | blends in this range, a coating film will become uniform and it will become especially excellent in gloss and the sustainability of gloss.

The component (b) used in the present invention is one or two selected from long-chain alkyl-containing polyoxyalkylene-modified organopolysiloxane, polyoxyalkylene-modified organopolysiloxane, carboxyvinyl polymer, alkyl-modified carboxyvinyl polymer, and agar. It is a secondary adhesion inhibitor of seeds or more, and it can be made difficult to remove the decorative film by combining with component (a).
In the present invention, the secondary anti-adhesive agent is a compound having a water-absorbing ability, and in particular, after forming a decorative film, the decorative film absorbs water over time, and as a result, the decorative film thickens, Adhesive force is improved, and the effect of preventing secondary adhesion occurs.
As these commercial products, for example, ABIL EM90 (manufactured by Goldschmidt) as a long-chain alkyl-containing polyoxyalkylene-modified organopolysiloxane, and KF-6015, KF-6017, KF-6028 (Shin-Etsu Chemical) as polyoxyalkylene-modified organopolysiloxanes. Kogapol 940 (manufactured by Goodrich Chemical Co.) as carboxyvinyl polymer, Pemulene TR-1, TR-2 (manufactured by NOVEON), carbopol 1342 (manufactured by Goodrich Chemical) as carboxyvinyl polymer Etc. As the agar, generally known agar can be used, and examples thereof include low-strength agar obtained by cleaving the molecule by acid treatment disclosed in JP-A-5-317008.
Any of these components may be used alone or in combination of two or more as required.

  Although the compounding quantity of the component (b) in the oil-based makeup cosmetics of this invention is not specifically limited, 0.1 to 15% is preferable and 0.5 to 10% is especially more preferable. When it mix | blends in this range, the makeup lasting will be favorable and it will become excellent in gloss.

  Moreover, in this invention, hardness and the touch at the time of application | coating can be adjusted by mix | blending an oil agent other than component (a) and (b). The oil agent used here can be used without particular limitation as long as it is an oil component usually used in cosmetics. The origin of animal oil, vegetable oil, synthetic oil, etc., solid oil, semi-solid oil, liquid oil, volatile oil Hydrocarbons, fats and oils, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gelling agents, etc. Can be used. Specifically, liquid paraffin, heavy liquid isoparaffin, α-olefin oligomer, squalane, petrolatum, polyisobutylene, polybutene, ceresin wax, polyethylene wax, Fischer-Tropsch wax, paraffin wax, microcrystalline wax, ozokerite wax, ethylene Hydrocarbons such as propylene copolymers, oils and fats such as olive oil, castor oil, mink oil, macadamian nut oil, and mole, wax such as beeswax, carnauba wax, candelilla wax, gay wax, and montan wax, pentaerythrosyl phosphate Trit ester, dipentaerythritol fatty acid ester, cholesterol fatty acid ester, N-lauroyl-L-glutamate di (cholesteryl behenyl octyldodecyl), Esters such as isopropyl stannate, isopropyl palmitate, cetyl 2-ethylhexanoate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, polyglyceryl triisostearate, diisostearyl malate, neopentyl glycol dioctanoate, jojoba oil , Fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, low polymerization degree Dimethylpolysiloxane, high degree of polymerization dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethyl Silicones such as lucyclotetrasiloxane, alkoxy-modified polysiloxane, cross-linked organopolysiloxane, fluorine-modified polysiloxane, fluorine oils such as perfluorodecane, perfluorooctane, perfluoropolyether, lanolin, lanolin acetate, lanolin Examples include lanolin derivatives such as fatty acid isopropyl and lanolin alcohol, and oily gelling agents include 12-hydroxystearic acid, dextrin palmitate, dextrin palmitate / 2-ethylhexanoate, dextrin stearate, dextrin palmitate / dextrin stearate , Dextrin oleate, dextrin isopalmitate, dextrin fatty acid esters of dextrin isostearate, sucrose stearate, sucrose acetate stearate Scan sucrose fatty acid esters, aluminum isostearate, calcium stearate, and organic-modified clay minerals such as dimethyl distearyl ammonium hectorite, and the like.

  In the cosmetic of the present invention, various components other than the essential components, for example, a powder component, an aqueous component, an ultraviolet absorber, a surfactant, a water-soluble component, as necessary, within a range not impairing the effects of the present invention. Polymers, moisturizers, film forming agents, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, lame agents, fragrances, and the like can be appropriately blended to impart various effects.

  The powder is not particularly limited by the shape of a sphere, plate, needle, etc., the particle size of fumes, fine particles, pigment grade, etc., or the particle structure of porous, nonporous, etc. Bright powders, organic powders, pigment powders, metal powders, composite powders, and the like can be used. Specific powders include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, bitumen and ultramarine, talc and white cloud. Mother, phlogopite, phlogopite, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, smectite, aluminum oxide, magnesium oxide, zirconium oxide, antimony oxide, siliceous earth, silicic acid Aluminum, magnesium aluminum silicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, silicon dioxide, etc. White powder, titanium dioxide coated mica, titanium dioxide coated oxychloride Bismuth, iron oxide mica titanium, bitumen treated mica , Carmine-treated mica titanium, bismuth oxychloride, luster powder such as fish scale foil, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, styrene -Copolymer resin such as acrylic copolymer resin, organic polymer resin powder such as polypropylene resin, silicone resin and urethane resin, organic low molecular weight powder such as N-acyl lysine, starch, silk powder, cellulose powder, etc. Organic powder, red 201, red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404, yellow 401, etc., organic pigment powder, red 3, Red 104, red 106, orange 205, yellow 4, yellow 5, green 3, blue 1, etc. zirconium, burrs Organic pigment powder such as aluminum or aluminum lake or further metal powder such as aluminum powder, gold powder, silver powder, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide containing silicon dioxide, Examples thereof include composite powders such as zinc oxide-containing silicon dioxide. These powders can be used singly or in combination of two or more of them. These powders are one or two of fluorine compound, silicone compound, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbon, higher fatty acid, higher alcohol, ester, wax, wax, surfactant and the like. Surface treatment may be performed using seeds or more.

The surfactant can be used for the purpose of improving the dispersibility of the powder, and is not particularly limited as long as it is a surfactant generally used in cosmetics. Nonionic surfactants, anionic surfactants, cations An ionic surfactant, an amphoteric surfactant, and the like are used. Furthermore, examples of the ultraviolet absorber include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based ultraviolet absorbers, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone, and the like. Examples of the agent include protein, mucopolysaccharide, collagen, elastin, keratin and the like.
Furthermore, the aqueous component can be used for the purpose of imparting a moisture effect, and may be any component that is soluble in water and water. In addition to water, for example, propylene glycol, 1,3-butylene glycol, Examples include glycols such as dipropylene glycol and polyethylene glycol, glycerols such as glycerin, diglycerin, and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, and rose.
Furthermore, as antioxidants, for example, α-tocopherol, ascorbic acid, etc., as cosmetic ingredients, for example, vitamins, anti-inflammatory agents, herbal medicines, etc., as preservatives, for example, paraoxybenzoic acid ester, phenoxyethanol, etc., respectively. Can be mentioned.

  The oily makeup cosmetic of the present invention is not particularly limited, and examples thereof include solid, semi-solid, and liquid forms, and lipstick, lip gloss, lip base for base, lipstick overcoat, lip balm And eye color, face color, foundation and the like. Among them, lip cosmetics such as lipstick, lip gloss, lip base for base, lipstick overcoat, lip balm and the like are preferable because they can exhibit more effects.

  Next, the present invention will be described in more detail with reference to examples. The present invention is not limited at all by these.

(Synthesis Example 1)
(Synthesis Example 1)
"Dimer acid dimer diol oligomer ester isostearyl alcohol ester compound"
Hydrogenated dimer acid (PRIPOL 1006: manufactured by Unikema) 200 g (0.348 mol) and dimer diol (PRIPOL 2033: manufactured by Unikema) 132 g (0.243 mol) were charged into a reactor and heated to 210-220 ° C. in a nitrogen stream. Then, the esterification reaction was carried out for 5 hours while distilling off the generated water to obtain 323 g of an intermediate dimer acid dimer diol oligomer ester (dimer acid: dimer diol = 1: 0.7). Furthermore, 307 g of the oligomer ester and 59 g (0.217 mol) of isostearyl alcohol (Speziol C18 ISOC: manufactured by Cognis) were charged into a reactor, heated to 210 to 220 ° C. in a nitrogen stream, and the generated water was distilled off. Then, the esterification reaction was performed for 10 hours to obtain 351 g of the target ester compound. The obtained ester compound had a hue Gardner 2, an acid value of 5.2, a saponification value of 111, a viscosity of 15,000 mPa · s, and a refractive index of 1.48.

Examples 1 to 5 and Comparative Examples 1 to 4 Stick-shaped lipsticks Stick-shaped lipsticks were produced according to the formulation shown in Table 1 and the production method shown below. About each obtained stick-like lipstick, glossiness was evaluated by the measured value of the gloss meter. In addition, sensory evaluation evaluates the feeling of use (lightness and no stickiness), adhesion, uniformity of coating film, durability of glossiness, secondary adhesion prevention effect, moisturizing feeling (no dryness) did. The results are also shown in Table 1.

* 1: EP-700 (manufactured by New Phase Technology)
* 2: Ester compound of Synthesis Example 1 * 3: Polybutene 100R (manufactured by Idemitsu Kosan Co., Ltd.)
* 4: Pemulen TR-2 (Goodrich Chemical)
* 5: KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 6: AEROSIL R972 (Nippon Aerosil Co., Ltd.)
* 7: 5% perfluoroalkyl phosphate treatment with diethanolamine * 8: 3% (dimethicone / methicone) copolymer treatment (production method)
A: Components 1 to 12 are heated and dissolved at 110 to 120 ° C., then components 13 to 19 are added and mixed uniformly.
B: Components 20 to 23 are added to A and mixed uniformly.
C: Ingredient 24 is added to B, heated, defoamed, poured into a mold, filled, cooled and molded.

(Evaluation)
1. (D) Gloss Each stick-shaped lipstick is treated twice with three rollers to form a paste, and a film is formed on a glass plate with an applicator having a film thickness of 10 μm to obtain a measurement sample. The glossiness was measured with a gloss meter VG-1D (manufactured by Nippon Denshoku Industries Co., Ltd.). The measured value was judged on the basis of the following criteria, and judged in five stages from ◎ to xx.
(Glossiness): (Judgment)
45.0 or more: Very good: ◎
40.0 or more and less than 45.0: Good: ○
35.0 or more and less than 40.0: Somewhat good: Δ
30.0 or more and less than 35.0: Defect: ×
Less than 30.0: Very bad: XX

2. Sensory evaluation (i) Lightness and no stickiness of (b), (b) adhesion, (c) Uniformity of coating film, (e) Persistence of gloss, (f) Secondary adhesion prevention Regarding the lack of dryness of the effect (g), a 20-special panel use test was conducted, and each panel member gave a rating based on the following absolute evaluation, giving a score. The average value was calculated and judged according to the following four-stage criteria.
In addition, regarding the persistence of the gloss feeling of (e) and the lack of dry feeling of (g), each sample was applied to the lips, and the panel was allowed to have a normal life, and the gloss and dry feeling after 3 hours. The lack of was evaluated.
As for the secondary adhesion prevention effect of (f), each sample was applied to the lips, and after 1 hour, the tissue paper was applied to the lips, and the degree of transfer to the tissue paper was evaluated.
(Absolute evaluation)
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad (judgment criteria)
(Average score): (Judgment)
More than 5 points: Very good: ◎
3 points to 5 points or less: Good: ○
Over 2 points and under 3 points: Somewhat bad: △
2 points or less: Defect: ×

As is clear from Table 1, the stick-like lipstick of the present invention has a feeling of adhesion (adhesiveness) despite a feeling of lightness and no stickiness, and the coating film is thick and uniform. It was excellent in the sustainability of the skin, and was excellent in the effect of preventing secondary adhesion and lack of dryness by improving the feeling of close contact with the lips.
On the other hand, in Comparative Example 1 in which the component (a) was not blended, a good product was not obtained particularly in terms of adhesion, persistence of gloss and gloss, and lack of dryness. In Comparative Example 2 in which polybutene, which can be expected to improve gloss, was used in place of component (a), particularly, it was light and had no stickiness, and a good secondary adhesion preventing effect was not obtained. In Comparative Example 3 in which the component (b) was not blended, a product particularly good in terms of preventing secondary adhesion was not obtained. In Comparative Example 4 containing sodium alginate instead of component (b), no good product was obtained particularly in terms of durability of gloss and glossiness, secondary adhesion prevention effect, and lack of dryness.

(Example 6) Solid lipstick (component) (%)
1. Ceresin wax 6
2. Polyethylene wax * 9 2
3. 3. Glyceryl tri-2-ethylhexanoate Polyisobutylene 10
5. Liquid paraffin 15
6). Ester compound * 2 10
7). Polyoxyalkylene-modified organopolysiloxane * 10 5
8). Smoke-like silica * 11 3
9. Fluorine compound-treated mica titanium * 7 5
10. Red No. 202 0.1
11. Yellow No. 4 1.5
12 Titanium oxide 2
13. Black iron oxide 0.2
14 Red No. 104 aluminum lake 1.5
15. Vitamin E 0.5
16. Perfume appropriate amount * 9: Performaren 655 (manufactured by New Phase Technology)
* 10: KF-6015 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 11: AEROSIL 300 (Nippon Aerosil Co., Ltd.)
(Production method)
A: Components 1 to 7 are uniformly dissolved at 100 ° C.
B: Components 8 to 16 are added to A and dispersed uniformly.
C: B was poured into a metal pan and solidified by cooling to obtain a solid lipstick.
In Example 6, the feeling of use is light and there is no stickiness, and the coating film is thick and uniform, thereby improving the durability of the gloss and gloss, and obtaining a feeling of adhesion (adhesion) with the lips. Therefore, it was a solid lipstick with excellent secondary adhesion preventing effect and dry feeling.

(Example 7) Oily gel lipstick (component) (%)
1. Dextrin fatty acid ester * 12 6
2. Ester compound * 2 30
3. 3. Glyceryl tri-2-ethylhexanoate Polyisobutylene 10
5. Liquid paraffin 10
6). Heavy liquid isoparaffin 15
7). Long chain alkyl-containing polyoxyalkylene-modified organopolysiloxane * 13 10
8). Haze-like silica * 14 3
9. Fluorine compound-treated mica titanium * 7 5
10. Red No. 202 0.1
11. Yellow No. 4 0.6
12 Titanium oxide 0.5
13. Black iron oxide 0.1
14 Red No. 104 aluminum lake 0.5
15. Paramethoxycinnamate-2-ethylhexyl 1
16. Vitamin E 0.5
17. Perfume appropriate amount * 12: Leo Pearl KL (Chiba Flour Mills)
* 13: ABIL EM90 (Gold Schmidt)
* 14: AEROSIL 380S (Nippon Aerosil Co., Ltd.)
(Production method)
A: Components 1 to 7 are uniformly dissolved at 90 ° C.
B: Components 8 to 16 are added to A and dispersed uniformly.
C: The container was filled into an oily gel lipstick.
In Example 7, the feeling of use is light and there is no stickiness, and the coating film is thick and uniform, thereby improving the durability of the gloss and gloss, and obtaining a feeling of adhesion (adhesion) with the lips. Therefore, it was an oily gel lipstick with excellent secondary adhesion prevention effect and lack of dryness.

(Example 8) Stick-shaped lip balm (ingredient) (%)
1. Ethylene propylene copolymer * 1 7
2. Ceresin 7
3. Beeswax 5
4). Vaseline 10
5. Ester compound * 2 20
6). Polyoxyalkylene-modified organopolysiloxane * 5 5
7). Diglyceryl triisostearate Remaining 8.2 Cetyl 2-ethylhexanoate 20
9. Tocopherol acetate 0.5
10. N-lauroyl-glutamate di (octyldodecyl / phytosteryl / behenyl) * 15 10
11. Vitamin E 0.5
12 Perfume appropriate amount * 15: Erdu PS-304 (Ajinomoto Co., Inc.)
(Production method)
A: Components 1 to 10 are heated and dissolved at 110 to 120 ° C.
B: Components 11 to 12 are added to A and mixed uniformly.
C: B is defoamed, poured into a mold, filled, cooled and molded.
In Example 8, the feeling of use is light and has no stickiness, and the coating film is thick and uniform, thereby improving the durability of the gloss and gloss, and obtaining a feeling of adhesion (adhesion) with the lips. Therefore, it was a stick-like lip balm excellent in secondary adhesion preventing effect and dry feeling.

(Example 9) Oily foundation (component) (%)
1. Candelilla wax 5
2. Microcrystalline wax 10
3. Polyoxyalkylene-modified organopolysiloxane * 5 2
4). Polyethylene wax * 16 0.5
5. Polyglyceryl triisostearate 10
6). Ester compound * 2 5
7). Tri (capryl / capric acid) glyceride Smoke-like silica * 6 0.1
9. Fine particle titanium oxide 1
10. Fine zinc oxide 1
11. Titanium oxide 8
12 Barium sulfate 2
13. Sericite 15
14 Bengala 1
15. Yellow iron oxide 2
16. Black iron oxide 0.5
17. Carboxyvinyl polymer * 17 0.1
18.1,3-Butylene glycol 0.5
19. Aloe extract appropriate amount20. Perfume appropriate amount * 16: Permalinene 500 (manufactured by New Phase Technology)
* 17: Carbopol 940 (Goodrich Chemical)
(Production method)
A: 1-7 are uniformly dissolved at 100 ° C.
B: Add 8 to 20 to A and disperse uniformly.
C: B was poured into a metal pan and cooled and solidified to obtain an oily foundation.
In Example 9, the feeling of use is light and has no stickiness, the coating film is uniform, and the adhesion (adhesion) to the skin is obtained, so it is excellent in the effect of preventing secondary adhesion and the feeling of dryness. Oily foundation.

(Example 10) Oily eye color (component) (%)
1. Microcrystalline wax 5
2. Ceresin wax 10
3. Polyglyceryl triisostearate 4
4). α-olefin oligomer * 18 2
5. Long chain alkyl-containing polyoxyalkylene-modified organopolysiloxane * 13 10
6). Ester compound * 2 10
7). 7. Squalane remaining amount Propylene glycol dicaprate 15
9. Stearyl-modified acrylate silicone * 19 15
10. Sorbitan sesquioleate 0.5
11. Monooleic acid polyoxyethylene sorbitan (20E.O.) 0.8
12 Agar * 20 0.1
13. Spherical nylon powder 5
14 Silicone-treated talc * 8 10
15. Red No. 202 0.5
16. Blue No. 404 1
17. Silicone-treated titanium oxide * 8 2
18. Smoke-like silica * 12 1
19. Collagen aqueous solution appropriate amount 20. Perfume appropriate amount * 18: Nomucoat HPD-C (Nisshin Oilio Co., Ltd.)
* 19: KP-561 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 20: Ina Agar UP-37CS (manufactured by Ina Food Industry Co., Ltd.)
(Production method)
A: Components 1 to 11 are uniformly dissolved at 100 ° C.
B: Components 12 to 20 are added to A and mixed and dispersed uniformly.
C: B was poured into a metal pan and cooled and solidified to obtain an oily eye color.
In Example 10, the feeling of use is light and has no stickiness, and since the coating film becomes uniform, the durability of gloss and gloss is improved, and a feeling of adhesion (adhesion) with the skin is obtained. The oily eye color was excellent in preventing secondary adhesion and lacking dryness.

Claims (3)

The following components (a) and (b);
(A) Compound R ³ OCO—R ¹ — (— COO—R ² —OCO) obtained by esterifying carboxyl groups at both ends of the oligomeric ester of dimer acid and dimer diol represented by the following general formula (1) with isostearyl alcohol ^{-R 1 -) n-COOR 3} ··· (1)
(In the formula, R ¹ represents a dimer acid residue, R ² represents a dimer diol residue, R ³ represents an isostearyl alcohol residue, and n represents a number of 4 to 6.)
(B) An oily makeup cosmetic comprising one or two types of secondary anti-adhesive agents selected from carboxyvinyl polymers and alkyl-modified carboxyvinyl polymers.   2. The oily makeup cosmetic according to claim 1, wherein the amount of the component (b) is 0.1 to 15% by mass.   The oily makeup cosmetic according to claim 1 or 2, wherein the oily makeup cosmetic is a lip cosmetic.