JP2013194035A - Oily stick-like lipstick - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an oily stick-like lipstick which easily comes loose and expands lightly when applied to a lip, brings about a sticking feeling, and is easily recoatable, and of which the makeup keeps for a long time.SOLUTION: An oily stick-like lipstick is formed by combining a solid oil, a predetermined dimer dilinoleate derivative, a long chain acylamino acid sterol derivative, and nearly spherical powder having two or more projections on the surface with one another.

Description

  The present invention relates to an oily stick-like lipstick comprising a solid oil, a specific dimer linoleic acid derivative, a long-chain acylamino acid sterol derivative, and a substantially spherical powder having a plurality of protrusions on the surface. The present invention relates to an oily stick-like lipstick capable of producing a feeling of close contact, ease of overcoating, and good makeup.

Widely used for its portability and ease of use, stick-shaped lipsticks are required to have a variety of effects such as touch and good color in addition to the lipstick function of imparting color to the lips. . At the same time, it must also have shape retention functions such as folding and high temperature stability. In addition, when using a stick-shaped lipstick, the overlaying operation is usually performed about 2 to 4 times in order to obtain high color development and gloss, so that the ease of overlaying is one of the important qualities.
Stick-like lipsticks have been studied with regard to their constituent components, waxes, oils, and powders. For example, a specific amount of solid oil and polymethylsilsesquioxane particles having an uneven surface are blended, and a stick-like oily solid cosmetic (Patent Document 1) having a good shape retention, feeling of use, and good adhesion at the time of application, specific There are lipophilic lipsticks (Patent Document 2) having good physical stability, moisturizing and refreshing feeling, including polyglycerin fatty acid ester, N-long chain acyl acidic amino acid ester of sterol and dimer acid ester.

JP 2008-094790 A However, if the stick-shaped lipstick is to have shape retention and lightness of use at the time of application and good stretch spread, the surface of the cosmetic film becomes slippery due to lack of adhesion. However, there was a tendency that it was impossible to draw a lip line without blurring or blurring, it was difficult to apply overcoats, and makeup lasting life was poor.

  Therefore, this application can draw a smooth and clear lip line because the cosmetics are easily loosened and lightly stretched on the lips at the time of application, and it can be firmly stacked without slipping up even when overlapping, There is an oil-based stick-like lipstick with good makeup.

  As a result of intensive investigations, the present inventors have formulated a solid oil, a specific oil agent, and a substantially spherical powder having a plurality of protrusions on the surface in combination to form an oily stick that solves the above problem. The lipstick invention was completed.

That is, the present invention provides the following components (A) to (D);
(A) solid oil,
(B) dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) and / or dimer linoleic acid dimer linoleyl bis (behenyl / isostearyl / phytosteryl),
(C) a long-chain acylamino acid sterol derivative,
(D) a substantially spherical powder having a plurality of protrusions on the surface;
An oily stick-like lipstick characterized in that is formulated.

  The present invention provides an oily stick-like lipstick that is easy to loosen when applied to the lips, is lightly stretched, has a feeling of close contact, and is easy to apply repeatedly.

  Hereinafter, the present invention will be specifically described with a focus on preferred embodiments. In the present specification, “to” means a range including numerical values before and after.

The solid oil used for the oily stick-like lipstick of the present invention is not particularly limited as long as it is a solid oil such as animal oil, vegetable oil, synthetic oil or the like generally used in cosmetics, and one or more of these oils are used. Can be used. Examples of the wax include, but are not limited to, polyethylene wax, microcrystalline wax, ethylene / propylene copolymer, Fischer-Tropsch wax, candelilla wax, candelilla wax esters, carnauba wax, rice bran wax, ozokerite wax, paraffin wax and the like. It is done. Among them, it is preferable to add candelilla wax esters and Fischer-Tropsch wax in that they are easy to loosen and produce light elongation. Further, when Candelilla wax esters and Fischer-Tropsch wax are blended at a mass ratio of 1:10 to 5: 5, more satisfactory products are easily obtained. Candelilla wax esters (INCI name CANDELLILLA WAX Esters) are manufactured by refining crude candelilla wax, and commercially available products include refined candelilla wax FR-100 (manufactured by Nippon Natural Products). Examples of commercially available Fischer-Tropsch wax include SASOLWAX C80 / H1 (manufactured by SASOL), CIREBELLE108 / 109L / 303 (manufactured by CIREBELLE), and the like. Also, SMART WAX 7743S (manufactured by Nippon Natural Products Co., Ltd.) that is commercially available as a mixture of Candelilla wax esters and Fischer-Tropsch wax can be used.

  The blending amount of the component (A) in the present invention is not particularly limited, but it is 5-30% by mass (hereinafter simply abbreviated as “%”) and 6-20% in that it easily loosens and produces light elongation. preferable.

  The dimerlinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) and / or dimerlinoleic acid dimerlinoleyl bis (behenyl / isostearyl / phytosteryl) used in the present invention is mainly linole. An ester of a dimer acid obtained by polymerizing 2 to 3 molecules of acid and a mixed alcohol such as phytosterol, isostearyl alcohol, cetanol, stearyl alcohol, and behenyl alcohol. In the present invention, it is easily loosened and has a light elongation and good makeup. Is to produce. Examples of commercially available products include PLANDOOL-S, H, and G (manufactured by Nippon Seika Co., Ltd.).

  Although the compounding quantity of the component (B) in this invention is not restrict | limited in particular, 1 to 30%, Furthermore, 2 to 20% is preferable. If it is this range, it is easy to loosen and it is preferable at the point of the light elongation and the good makeup-holding.

  The component (C) long chain acylamino acid sterol derivative used in the present invention comprises a long chain acylamino acid such as lauroylglutamic acid, sterols such as cholesterol and phytosterol, and higher alcohols such as behenyl alcohol, octyldodecyl alcohol and isostearyl alcohol. It is a diester. In the present invention, it produces a feeling of close contact and good makeup. Such long chain acylamino acid sterol derivatives include dilauroyl glutamate (octyldodecyl / phytosteryl / behenyl), dilauroyl glutamate (phytosteryl / octyldodecyl), dilauroyl glutamate (cholesteryl / octyldodecyl), dilauroyl glutamate (cholesteryl / Behenyl / octyldodecyl) and the like. Commercially available products include L-Du PS-203, PS-304, PS-306, CL-202, CL-301 (above, manufactured by Ajinomoto Co., Inc.), PLANDOOL-LG1, LG2, LG3 (above, manufactured by Nippon Seika Co., Ltd.) Can be used.

  The blending amount of the component (C) in the present invention is not particularly limited, but is preferably 1 to 30%, and more preferably 2 to 20%, since a satisfactory one can be obtained in terms of adhesion and good makeup.

  In addition, in this invention, it is preferable to mix | blend a component (B) and a component (C) 5-30% in total, The mass ratio of a component (B) and a component (C) is the range of 1: 4-9: 1. If it is, it is preferable at the point of the light looseness which is easy to loosen at the time of application | coating.

The substantially spherical powder having a plurality of protrusions on the surface of the component (D) used in the present invention has a plurality of protrusions over the entire surface of the spherical particles, and is a powder having a shape like a so-called confetti. is there. An average particle size including protrusions on the surface of 1 to 30 [mu] m, more preferably 1 to 15 [mu] m can be suitably used in terms of feel. A plurality of protrusions on the surface are present on the entire surface of the particle, and the size is not particularly limited, but (the average diameter of the bottom surface of the protrusion) / (the average particle diameter of the spherical particles serving as the core) is 0.01 to 0. 3 and (average height of protrusions) / (average particle diameter of spherical particles as a core) is 0.01 to 0.3, the effect is sufficiently exerted. Here, the “average particle size of the component (D)” is a substantially spherical particle size including the top of the protrusions existing on the surface, and “the average particle size of the spherical particles serving as the core” The particle size of “” is the particle size of the spherical portion not including the protrusions. These values, values such as the average bottom diameter of the protrusions and the average height of the protrusions can be obtained from a particle size distribution measuring device or an electron micrograph.
The material is not particularly limited, but a resin powder such as silicone or polymethacrylate is preferable. Commercially available products include TOSPEARL 150KA (produced by Momentive Performance Materials), which is a polymethylsilsesquioxane, both of spherical core particles and protrusions, and inorganic particles in polymethylsilsesquioxane. MSP-AK06 (manufactured by Nikko Rika), Silcrusta MK03 (manufactured by Nikko Rica), in which the spherical particles as the core are methyl methacrylate crosspolymer and the protrusions are polymethylsilsesquioxane.

  The blending amount of the component (D) in the present invention is not particularly limited, but is preferably 1 to 30%, more preferably 1 to 10%, from the viewpoint of easy elongation and light elongation and ease of overcoating.

  In addition to the essential components (A) to (D) described above, the lip cosmetic of the present invention is generally used in cosmetics, oily components, powders, surfactants, fibers, aqueous components, and UV absorbers. Antifading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, fragrances and the like can be blended within a range that does not impede the effects of the present invention.

As oily components, hydrocarbons, fats and oils can be used as long as they are generally used in cosmetics other than components (A) to (C), regardless of properties such as semi-solid oil, liquid oil, and volatile oil. Waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, oily gelling agents and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, α-olefin oligomer, petrolatum, polyisobutylene, polybutene, oils such as olive oil, castor oil, mink oil, macadamian nut oil, jojoba oil, glyceryl trioctanoate , Polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribethenate, glyceryl trioctanoate, glyceryl triisostearate, polyglyceryl polyisostearate, cetyl 2-ethylhexanoate, isotridecyl isononanoate, isopropyl myristate, isopropyl palmitate, myristic acid Octyldodecyl, pentaerythrityl tetraisostearate, pentaerythrityl rosinate, neopentyl glycol dioctanoate, cholesterol fat Esters such as acid esters, phytosterol fatty acid esters, triglycerides, diisostearyl malate, tritridecyl trimerate, dialkyl carbonate, stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid and other fatty acids, stearyl Higher alcohols such as alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, trimethylsiloxysilicic acid, high polymerization Degree of methyl phenyl polysiloxane, cross-linked polyether modified methyl polysiloxane, oleyl modified organopolysiloxane, behenyl modified Silicones such as organopolysiloxane, high degree of polymerization dimethylpolysiloxane, alkoxy-modified organopolysiloxane, fluorine-modified organopolysiloxane, fluorine oils such as perfluorodecane, perfluorooctane, perfluoropolyether, lanolin, lanolin acetate Lanolin derivatives such as lanolin fatty acid isopropyl, lanolin alcohol, sucrose fatty acid ester, dextrin fatty acid ester, starch fatty acid ester, aluminum isostearate, 12-hydroxystearic acid and the like oily gelling agents, etc. Two or more kinds can be used.

  As a powder component, if it is a powder generally used for cosmetics other than the component (D), a spherical shape, a plate shape, a needle shape, a haze shape, a fine particle, a particle size such as a pigment class, a porous material, etc. There is no particular limitation depending on the particle structure such as non-porous, and examples thereof include inorganic powders, glittering powders, lame, organic powders, pigment powders, and composite powders. Specifically, synthetic phlogopite, mica, sericite, talc, kaolin, titanium oxide, black titanium oxide, conger, ultramarine, bengara, yellow iron oxide, black iron oxide, zinc oxide, aluminum oxide, silicic anhydride, silica Magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, silicon carbide, barium sulfate, bentonite, smectite, boron nitride, etc. Inorganic powders, bismuth oxychloride, titanium oxide coated bismuth oxychloride, titanium oxide coated mica, titanium oxide coated synthetic phlogopite, iron oxide coated mica, iron oxide coated mica titanium, anhydrous silicic acid coated mica titanium, bituminized mica titanium , Organic pigment coated mica titanium, iron oxide coated anhydrous Ionic acid, fish scale foil, titanium oxide coated glass powder, iron oxide titanium oxide coated glass powder, anhydrous titanium silicate oxide coated glass powder, aluminum powder and other glittering powders, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / Polymethylmethacrylate laminated film powder, lamellar agent of resin laminated powder such as polyethylene terephthalate / aluminum / epoxy laminated powder, nylon powder, polymethyl methacrylate powder, acrylonitrile-methacrylic acid copolymer powder, vinylidene chloride-methacrylic acid copolymer powder , Organic powders such as polyethylene powder, polystyrene powder, polyurethane powder, wool powder, silk powder, crystalline cellulose powder, red 201, red 202, red 20 No., Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401 and other organic pigment powders, Red No. 3, Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1 etc. zirconium, barium or aluminum lake and other organic pigment powders, aluminum powder, gold powder, silver powder and other metal powders, fine particle titanium oxide coated mica titanium, Examples thereof include composite powders such as fine particle zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicic acid anhydride, and zinc oxide-containing silicic acid anhydride, and these can be used alone or in combination. These powders may be used after surface treatment with a generally known treating agent such as a fluorine compound, silicone compound, metal soap, wax, surfactant, oil, fat, hydrocarbon, aqueous polymer or the like.

As the aqueous component, in addition to water, for example, alcohols such as ethyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol and polyethylene glycol, glycerol such as glycerin, diglycerin and polyglycerin , Plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose.
The surfactant is not particularly limited as long as it is usually used in cosmetics, and examples thereof include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. Examples of the UV absorber include UV absorbers such as benzophenone, PABA, cinnamic acid, and salicylic acid, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone, and the like. Examples include proteins, mucopolysaccharides, collagen, elastin, keratin, etc., antioxidants include, for example, α-tocopherol, ascorbic acid, etc., and cosmetic ingredients include, for example, vitamins, anti-inflammatory agents, herbal medicines, etc. Examples of the preservative include paraoxybenzoic acid ester, phenoxyethanol, and 1,2 pentanediol.

  The oily stick-like lipstick of the present invention contains oils such as wax as a main component, contains substantially 1% or less of water, and is a lipstick or lip that imparts color or gloss to the lips. Although it is suitable for gloss, it can also be applied to lip balms and lipstick bases used for lip care.

  Hereinafter, the present invention will be described in more detail with reference to examples. In addition, these do not limit this invention at all.

Examples 1 to 7 and Comparative Examples 1 to 4: Oily stick lipsticks Oily stick lipsticks having the formulations shown in Table 1 below were prepared by the following production methods and evaluated by the following evaluation methods. The results are also shown in Table 1.
* 1 SMART WAX 7743S (Candelilla wax esters: Fischer-Tropsch wax mass ratio 2.5: 7.5 mixture, manufactured by Nippon Natural Products)
* 2 PERFORMALENE 500 (manufactured by New Phase Technology)
* 3 TOWAX-3P3 (manufactured by Toa Kasei)
* 4 PLANDOOL-S (manufactured by Nippon Seika Co., Ltd.)
* 5 El Dew PS-306 (Ajinomoto Co., Inc.)
* 6 Pearl Dream 18 (manufactured by NOF Corporation)
* 7 TOSPEARL 150KA (polymethylsilsesquioxane, manufactured by Momentive Performance Materials)
* 8 Matsumoto Microsphere M101 (Matsumoto Yushi Seiyaku Co., Ltd.)
* 9 KSP-300 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 10 AEROSIL R-976S (Nippon Aerosil Co., Ltd.)
* 11 FLAMENCO SPARKLE GOLD 220J (BASF)

[Production method]
A. Ingredients (1) to (8) are heated to 100 ° C. and uniformly dissolved.
B. Components (9) to (19) are added to A and mixed and dispersed uniformly.
C. After defoaming B, it was heated to 100 ° C. and then poured directly into a stick-like lipstick container to obtain a lipstick after cooling.

[Evaluation method]
(Evaluation item)
A. Easy to loosen and light elongation b. A feeling of adhesion c. Ease of overcoating d. Goodness of makeup Each sample is subjected to a usage test by 20 specialist panels, and each panel member gives a score based on the absolute evaluation criteria for each evaluation item, and the average value of each sample from the total score of all the panel members Was calculated according to the following floor criteria. For (a), whether each sample is lightly spread and spread when applied, and a sharp lip line can be drawn, for (b) whether each sample forms a uniform cosmetic film with a close feeling, It was evaluated at the time of use whether or not a uniform decorative film was formed without twisting when it was applied three times. As for D, each sample was applied, and after having a normal life on the panel, the durability after 3 hours was evaluated.

(Absolute evaluation criteria)
Score: Evaluation 5: Very good 4: Good 3: Somewhat good 2: Normal 1: Somewhat bad 0: Bad (Criteria)
Judgment: Average score
◎ Very good: 4 points or more
○ Good: Less than 4 points 3 points or more
△ Slightly bad: Less than 3 points and more than 1 point
× Defect: 1 point or less

As is clear from the results in Table 1, the lipsticks of Examples 1 to 7 of the present invention are more easily loosened and lightly stretched, have a feeling of adhesion, ease of overcoating, and longer-lasting makeup than the lipsticks of Comparative Examples 1 to 4. It was excellent.
On the other hand, the comparative example 1 which does not mix | blend a component (B) was not able to be satisfied in the easy elongation and the light elongation and the long-lasting makeup. In Comparative Example 2 in which the component (C) was not blended, satisfactory results were not obtained in terms of adhesion and good makeup. In Comparative Examples 3 and 4 in which a spherical resin powder having a smooth surface was blended in place of the component (D), satisfactory results were not obtained in terms of adhesion and ease of overcoating.

Example 8: Stick-like lip gloss (component) (%)
1: Polyethylene wax * 2 15.0
2: Dimer linoleic acid (phytosteryl /
Isostearyl / cetyl / stearyl / behenyl) * 4 10.0
3: Lauroyl glutamate di (phytosteryl / octyldodecyl) * 12 5.0
4: Heavy liquid isoparaffin * 13 20.0
5: Acetic acid liquid lanolin 15.0
6: Diisostearyl malate 10.0
7: Isotridecyl isononanoate 10.0
8: Polyglyceryl triisostearate Remaining amount 9: Substantially spherical powder having a plurality of protrusions on the surface * 7 3.0
10: Silylated silica anhydride * 10 2.0
11: Calcium carbonate 0.1
12: 2,6-di-tert-butyl-paracresol 0.1
13: Phenoxyethanol 0.1
14: Sodium benzoate 0.1
15: Tocopherol acetate 0.1
16: Titanium oxide 1.5
17: Black iron oxide 0.1
18: Red 202 No. 0.5
19: Yellow No. 4 0.5
20: Titanium mica * 14 5.0
21: Fragrance 0.1
* 12 El Dew PS-203 (Ajinomoto Co., Inc.)
* 13 Pearl Dream 24 (manufactured by NOF Corporation)
* 14 Timilon Super Red (Merck) 5% methylpolysiloxane treatment

(Production method)
A: Components (1) to (8) are uniformly dissolved at 100 to 110 ° C.
B: Components (9) to (21) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated and poured into a lipstick mold made of rubber mold, cooled, removed from the mold, and loaded into a container to obtain a stick-shaped lip gloss.
The stick-shaped lip gloss of Example 8 was satisfactory in terms of easy loosening, light elongation, adhesion, ease of overcoating, and good makeup.

Example 9: Stick-shaped lip balm (ingredient) (%)
1: Candelilla wax * 15 6.0
2: Ethylene / propylene copolymer * 16 5.0
3: Dimer linoleic acid (phytosteryl /
Isostearyl / cetyl / stearyl / behenyl) * 4 10.0
4: Lauroyl glutamic acid
Di (octyldodecyl / phytosteryl / behenyl) * 5 10.0
5: Dilauroyl glutamate (phytosteryl / octyldodecyl) * 12 10.0
6: Glyceryl tri-2-ethylhexanoate 10.0
7: Diisostearyl malate 5.0
8: Cetyl ethylhexanoate 5.0
9: Methylphenylpolysiloxane 5.0
10: Jojoba oil 1.0
11: polyglyceryl triisostearate remaining amount 12: substantially spherical powder having a plurality of protrusions on the surface * 7 5.0
13: Silylated silica anhydride * 10 3.0
14: Calcium carbonate 0.1
15: 2,6-di-tert-butyl-paracresol 0.1
16: Phenoxyethanol 0.1
17: Sodium benzoate 0.1
18: Tocopherol acetate 0.1
19: Fragrance 0.1
* 15 Refined candelilla wax SR-3 (manufactured by Nippon Natural Products)
* 16 EP-700 (manufactured by Baker Petrolite)
(Production method)
A: Components (1) to (11) are uniformly dissolved at 100 to 110 ° C.
B: Components (12) to (19) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated and poured into a lipstick mold made of rubber mold. After cooling, it was taken out of the mold and loaded into a container to obtain a stick-shaped lip balm.
The stick-shaped lip balm of Example 9 was satisfactory in terms of easy loosening, light elongation, adhesion, ease of overcoating, and good makeup.

Example 10: Stick-shaped lipstick (ingredient) (%)
1: Candelilla wax esters * 17 1.5
2: Fischer-Tropsch wax * 18 5.0
3: Polyethylene wax * 19 5.0
4: Dimer linoleic acid (phytosteryl /
(Isostearyl / cetyl / stearyl / behenyl) * 4 2.0
5: Lauroyl glutamic acid
Di (octyldodecyl / phytosteryl / behenyl) * 5 2.0
6: Lauroyl glutamate di (phytosteryl / octyldodecyl) * 12 2.0
7: Glyceryl tri-2-ethylhexanoate 20.0
8: Dialkyl carbonate 10.0
9: Liquid paraffin * 20 10.0
10: Olive oil 1.0
11: Polyglyceryl triisostearate Remaining amount 12: Substantially spherical powder having protrusions on the surface * 21 5.0
13: Nylon powder * 22 5.0
14: Silylated silicic acid * 10 3.0
15: Calcium carbonate 0.1
16: 2,6-di-tert-butyl-paracresol 0.1
17: Phenoxyethanol 0.1
18: Sodium benzoate 0.1
19: Tocopherol acetate 0.1
20: Titanium oxide 1.5
21: Black iron oxide 0.1
22: Red 202 No. 0.5
23: Yellow No. 4 0.5
24: Titanium mica * 23 5.0
25: Bengala-coated mica titanium oxide * 24 5.0
26: Silicone-treated titanium oxide coated glass flakes * 25 2.0
27: Fragrance 0.1
* 17 High melting point candelilla wax FR100 (manufactured by Nippon Natural Products)
* 18 CIREBELLE108 (manufactured by CIREBELLE)
* 19 PERFORMALENE 655 (manufactured by New Phase Technology)
* 20 KLEAROL (manufactured by SONNEBORN)
* 21 Silcrusta MK03 (manufactured by Nikko Rica)
* 22 Olgasol 2002D (Aftona Japan)
* 23 TIMICA EXTRA BRIGHT 1500 (manufactured by BASF)
* 24 Cloisonol Rouge Flambe (BASF) 2% perfluoroalkyl phosphate diethanolamine salt treatment * 25 Metashine 1080RC-Y (Nihon Sheet Glass Co., Ltd.)
(Production method)
A: Components (1) to (11) are uniformly dissolved at 100 to 110 ° C.
B: Components (12) to (27) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated and poured into a resin capsule mold, cooled, removed from the mold, and loaded into a container to obtain a stick-shaped lipstick.
The stick-shaped lipstick of Example 10 was satisfactory in terms of easy loosening, light elongation, adhesion, ease of overcoating, and good makeup.

Example 11: Stick-shaped lipstick (ingredient) (%)
1: Ethylene / propylene copolymer * 16 7.0
2: Microcrystalline wax * 26 5.0
3: Carnauba wax * 27 3.0
4: Dimer linoleic acid (phytosteryl /
(Isostearyl / cetyl / stearyl / behenyl) * 4 5.0
5: Lauroyl glutamic acid
Di (octyldodecyl / phytosteryl / behenyl) * 5 20.0
7: Glyceryl tri-2-ethylhexanoate 10.0
8: Vaseline 10.0
9: Methyl polysiloxane 10.0
10: polyglyceryl triisostearate remaining amount 11: substantially spherical powder having a plurality of protrusions on the surface * 21 2.0
12: Serisite * 28 3.0
13: Silicic anhydride * 29 1.0
14: Calcium carbonate 0.1
15: 2,6-di-tert-butyl-paracresol 0.1
16: Phenoxyethanol 0.1
17: Sodium benzoate 0.1
18: Tocopherol acetate 0.1
19: Titanium oxide * 30 1.5
20: Black iron oxide * 31 0.1
21: Red No. 202 0.5
22: Yellow No. 4 0.5
23: Titanium mica * 23 5.0
24: Zinc oxide 1.0
25: Polyethylene terephthalate / aluminum / epoxy laminated powder * 32 3.0
26: Fragrance 0.1
* 26 Multi wax W-445 (manufactured by SONNEBORN)
* 27 Refined carnauba wax No. 1 (manufactured by Nippon Natural Products)
* 28 Treated with 3% perfluorooctyltriethoxysilane * 29 AEROSIL 380S (manufactured by Nippon Aerosil Co., Ltd.)
* 30 Treatment with 2% perfluoroalkyl phosphate diethanolamine salt * 31 Treatment with 5% dimethylpolysiloxane * 32 Aluminum flake silver 0.15mm
(Production method)
A: Components (1) to (10) are uniformly dissolved at 100 to 110 ° C.
B: Components (11) to (26) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated and poured into a lipstick mold, cooled, removed from the mold, and loaded into a container to obtain a stick-shaped lipstick.
The stick-shaped lipstick of Example 11 was satisfactory in terms of easy loosening, light elongation, adhesion, ease of overcoating, and good makeup.

Example 12: Stick-shaped lipstick base (component) (%)
1: Ethylene / propylene copolymer * 16 5.0
2: Polyethylene wax * 19 5.0
3: Microcrystalline wax * 26 3.0
4: Dimer linoleic acid (phytosteryl /
Isostearyl / cetyl / stearyl / behenyl) * 33 5.0
5: Dilauroyl glutamate (phytosteryl / octyldodecyl) * 12 5.0
7: Pentaerythrityl tetraisostearate 20.0
8: Di-2-ethylhexyl succinate 15.0
9: Diglyceryl adipate mixed fatty acid ester 10.0
10: polyglyceryl triisostearate remaining amount 11: substantially spherical powder having a plurality of protrusions on the surface * 7 15.0
12: Silylated silicic acid * 10 2.0
13: Silicic anhydride * 29 1.0
14: Calcium carbonate 0.1
15: 2,6-di-tert-butyl-paracresol 0.1
16: Phenoxyethanol 0.1
17: Sodium benzoate 0.1
18: Tocopherol acetate 0.1
19: Fragrance 0.1
* 33 PLANDOOL-H (Nippon Seika Co., Ltd.)
(Production method)
A: Components (1) to (10) are uniformly dissolved at 100 to 110 ° C.
B: Components (11) to (19) are added to A and mixed and dispersed uniformly.
C: After defoaming B, it was heated and poured directly into a lipstick container, and after cooling, a stick-like lipstick substrate was obtained.
The stick-shaped lipstick substrate of Example 12 was satisfactory in terms of easy loosening, light elongation, adhesion, ease of overcoating, and good makeup.

Claims (3)

An oily stick-like lipstick characterized by blending the following components (A) to (D).
(A) solid oil (B) dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) and / or dimer linoleic acid dimer linoleyl bis (behenyl / isostearyl / phytosteryl)
(C) Long-chain acylamino acid sterol derivative (D) A substantially spherical powder having a plurality of protrusions on the surface   The oily stick lipstick according to claim 1, wherein 5 to 30% by mass of the component (B) and the component (C) are blended in total.   The oily stick-like lipstick according to claim 1 or 2, wherein the component (A) contains candelilla wax esters and Fischer-Tropsch wax.