JP4732674B2 - 特に化粧品用途の、水溶性単位とlcstを有する単位とを含むポリマーを含む起泡性エマルション及び起泡性組成物 - Google Patents
特に化粧品用途の、水溶性単位とlcstを有する単位とを含むポリマーを含む起泡性エマルション及び起泡性組成物 Download PDFInfo
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- JP4732674B2 JP4732674B2 JP2002556664A JP2002556664A JP4732674B2 JP 4732674 B2 JP4732674 B2 JP 4732674B2 JP 2002556664 A JP2002556664 A JP 2002556664A JP 2002556664 A JP2002556664 A JP 2002556664A JP 4732674 B2 JP4732674 B2 JP 4732674B2
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- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 description 1
- COXJMKGEQAWXNP-UHFFFAOYSA-N tris(14-methylpentadecyl) 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CC(C)CCCCCCCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCCCCCCCC(C)C)CC(=O)OCCCCCCCCCCCCCC(C)C COXJMKGEQAWXNP-UHFFFAOYSA-N 0.000 description 1
- 239000010679 vetiver oil Substances 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/91—Graft copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Detergent Compositions (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
D. Hourdetら、Polymer, 1994, Vol.35, No.12,p.2624-2630 [1] F. L'Alloretら、Coll. Polym. Sci., 1995, Vol.273, No.12, p.1163-1173 [2] F. L'Alloretら、Revue de l'Institut Francais du Petrole, 1997, Vol.52, No.2, p.117-128 [3]
−界面活性剤、その低分子質量(2000g/モル)で特徴付けられるもの、
−ミクロゲルタイプの両親媒性ゲル化剤、例えばPemulen TR1(Goodrich)、及び
−シリコーン油の存在下で用いられるジメチコーンコポリオール誘導体。
−界面活性剤は、皮膚に対して、比較的刺激性である;
−ミクロゲルタイプの両親媒性ゲル化剤は、数が限定されており、全てが、同じタイプのゲル化のきめをもたらす
−ジメチコーンコポリオール誘導体は、シリコーン油に特異的である。
−特に広い温度範囲(5−80℃)にわたって、化粧品エマルション及びフォームを安定化することが可能である
−皮膚に対して、ほとんど刺激性がない、及び
−広い範囲の、きめ、流動性または増粘化/ゲル化を付与することができる、
の利用可能な剤を有することが有利である。
これらの水溶性単位は、LCSTタイプの熱誘導化偏析温度を有さない。
− (メタ)アクリル酸;
− 以下の式(I)のビニルモノマー:
− RはH、−CH3、−C2H5、または−C3H7から選択され;及び
− Xは以下のものから選択される:
− −OR’タイプのアルキルオキシドであって、R’は少なくとも一つのハロゲン原子(ヨウ素、臭素、塩素、またはフッ素);スルホン酸(−SO3 −)、スルファート(−SO4 −)、ホスファート(−PO4H2);ヒドロキシル(−OH);第一級アミン(−NH2);第二級アミン(−NHR1)、第三級アミン(−NR1R2)、または第四級アミン(−N+R1R2R3)基{ここで、R1、R2及びR3は互いに独立に、1から6の炭素原子を含む直鎖状または分枝状の飽和または不飽和の炭化水素基(ここでR’+R1+R2+R3の炭素原子の合計が7を超えないことを条件とする)である}で任意に置換された、1から6の炭素原子を含む直鎖状または分枝状の飽和または不飽和の炭化水素基である;及び
− −NH2、−NHR4、及び−NR4R5基であって、R4及びR5は互いに独立に、1から6の炭素原子を含む直鎖状または分枝状の飽和または不飽和の炭化水素基(ここでR4+R5の炭素原子の合計が7を超えないことを条件とする)であって、前記R4及びR5はハロゲン原子(ヨウ素、臭素、塩素、またはフッ素);ヒドロキシル(−OH);スルホン酸(−SO3 −)、スルファート(−SO4 −);ホスファート(−PO4H2);第一級アミン(−NH2);第二級アミン(−NHR1)、第三級アミン(−NR1R2)、及び/または第四級アミン(−N+R1R2R3)基{ここで、R1、R2及びR3は互いに独立に、1から6の炭素原子を含む直鎖状または分枝状の飽和または不飽和の炭化水素基(ここでR4+R5+R1+R2+R3の炭素原子の合計が7を超えないことを条件とする)である}で任意に置換される]
− マレイン酸無水物;
− イタコン酸;
− 式CH2=CHOHのビニルアルコール;
− 式CH2=CH−OCOCH3のビニルアセタート;
− N−ビニルラクタム、例えばN−ビニルピロリドン、N−ビニルカプロラクタム、及びN−ブチロラクタム;
− 式CH2=CHOR6のビニルエーテルであって、R6は1から6の炭素を含む直鎖状または分枝状の、飽和または不飽和の炭化水素基である;
− 水溶性スチレン誘導体、特にスチレンスルホナート;
− ジメチルジアリルアンモニウムクロリド;並びに
− ビニルアセタミド。
− 水溶性ポリウレタン;
− キサンタンゴム、特にKelco社によりKeltrol T及びKeltrol SFの名称で;またはRhodia社によりRhodigel SM及びRhodigel 200の名称で市販されている製品;
− アルギナート(Monsanto社製のKelcosol)、及びその誘導体、例えばプロピレングリコールアルギナート(Kelco社製のKelcoloid LVF);
− セルロース誘導体、特にカルボキシメチルセルロース(Aquasorb A500, Hercules)、ヒドロキシプロピルセルロース、ヒドロキシエチルセルロース、及び第四級化ヒドロキシエチルセルロース;
− ガラクトマンナン及びその誘導体、例えばコンニャクゴム、グアルゴム、ヒドロキシプロピルグアル、ナトリウムメチルカルボキシラート基で変性されたヒドロキシプロピルグアル(Jaguar XC97-1, Rhodia)、ヒドロキシプロピルトリメチルアンモニウムグアルクロリド。
− ポリエーテル、例えばポリエチレンオキシド(PEO)、ポリプロピレンオキシド(PPO)、またはエチレンオキシド(EO)とプロピレンオキシド(PO)とのランダムコポリマー;
− ポリビニルメチルエーテル;
− ポリ−N−イソプロピルアクリルアミド及びポリ−N−エチルアクリルアミド;並びに
− ポリビニルカプロラクタム。
(EO)m(PO)n
[式中、mは1から40、好ましくは2から20の範囲の整数であり、nは10から60、好ましくは20から50の範囲の整数である]。
N−アルキルアミドベタイン及びその誘導体の例としては、Sanyo社によりLebon 2000 HGの名称で、またはAlbright & Wilson社によりEmpigen BBの名称で市販されているココアミドプロピルベタイン、及びWitco社によりRewoteric AMB12Pの名称で市販されているラウラミドプロピルベタインが挙げられる。
− 動物起源の炭化水素ベースの油、例えばパーヒドロスクアレン;
− 植物起源の炭化水素ベースの油、例えば4から10の炭素原子の脂肪酸の液体トリグリセリド、例えばヘプタン酸またはオクタン酸トリグリセリド、または別法として、例えばヒマワリ油、コーン油、ダイズ油、インゲンマメ油、グレープシード油、ゴマ油、ヘーゼルナッツ油、アンズ油、マカダミア油、アララ油、ヒマシ油、アボカド油、カプリル酸/カプリン酸トリグリセリド、例えばStearineries Dubois社により市販されているもの、またはDynamit Nobel社によりMyglyol 810、812及び818の名称で市販されているもの、ホホバ油、またはカリテバター;
− 特に脂肪酸の合成エステル及びエーテル、例えば式R1COOR2及びR1OR2の油、でR1が8から29の炭素原子を含む脂肪酸残基を表し、R2が3から30の炭素原子を含む分枝状または非分枝状炭化水素ベースの鎖を表すもの、例えばパーセリン油、イソノニルイソノナノアート、イソプロピルミリスタート、2−エチルヘキシルパルミタート、2−オクチルドデシルステアラート、2−オクチルドデシルエルカート、またはイソステアリルイソステアラート;ヒドロキシル化エステル、例えばイソステアリルラクタート、オクチルヒドロキシステアラート、オクチルドデシルヒドロキシステアラート、ジイソステアリルマラート、トリイソセチルシトラート、及び脂肪アルコールヘプタノアート、オクタノアート、及びデカノアート;ポリオールエステル、例えばプロピレングリコールジオクタノアート、ネオペンチルグリコールジヘプタノアート、及びジエチレングリコールジイソノナノアート;及びペンタエリスリトールエステル、例えばペンタエリスリチルテトライソステアラート;
− 鉱物または合成起源の直鎖状または分枝状炭化水素、例えば揮発性または不揮発性流動パラフィン及びその誘導体、ワセリン、ポリデセンまたは水素化ポリイソブテン、例えばパーリーム油;
− 天然または合成精油、例えばユーカリ油、ハイブリッドラベンダー油、ラベンダー油、ベチベルソウ油、リッツアキュベバ油、レモン油、ビャクダン油、ローズマリー油、カモミール油、ハッカ油、ナツメグ油、シナモン油、ヒソップ油、キャラウェイ油、オレンジ油、ゲラニトール油、カデ油、及びベルガモ油;
− 8から26の炭素原子を含む脂肪アルコール、例えばセチルアルコール、ステアリルアルコール、及びそれらの混合物(セチルステアリルアルコール)、オクチルドデカノール、2−ブチルオクタノール、2−ヘキシルデカノール、2−ウンデシルペンタデカノール、オレイルアルコール、またはリノレイルアルコール;
− 部分的に炭化水素ベースの及び/またはシリコーンベースのフルオロ油、例えば文献JP-A-2-295912に記載されているもの;
− シリコーン油、例えば室温で液状またはペースト状である、直鎖状または環状シリコーン鎖を含む、揮発性または不揮発性のポリジメチルシロキサン(PDMS)、特にシクロポリジメチルシロキサン(シクロメチコーン)、例えばシクロヘキサシロキサン;2から24の炭素原子を含むアルキル、アルコキシ、またはフェニル基をシリコーン鎖にペンダント状にまたは末端に含むポリジメチルシロキサン;フェニルシリコーン、例えばフェニルトリメチコーン、フェニルジメチコーン、フェニルトリメチルシロキシジフェニルシロキサン、ジフェニルジメチコーン、ジフェニルメチルジフェニルトリシロキサン、2−フェニルエチルトリメチルシロキシシリカート、及びポリメチルフェニルシロキサン;
− これらの混合物。
存在する場合には、油性相の量は、組成物の全重量に対して、例えば0.01から50重量%、好ましくは0.1から30重量%の範囲であって良い。
エマルションの場合、組成物のきめを調節するために、または乳液からクリームの広範囲のきめに近づけるために、特に、そこにゲル化剤を添加してもよい。
・第一の使用は、手にゲルを広げる工程、顔または身体にそれを適用する工程、次いで水の存在下でそれをマッサージして、顔または身体で直接気泡を形成させる工程からなる。
・他の考え得るこのタイプの製品の使用は、顔または身体にそれを適用する前に、手の平で気泡を形成される工程からなる。
顔の皮膚及び/または身体の皮膚、粘膜(唇)、頭皮及び/またはケラチン繊維(毛髪または睫毛)を、トリートメントするために、及び/またはUV光線から皮膚を保護するために用いることができる。
使用されるポリマーの特徴は、表1に示されている。
450000g/molの平均モル質量を有する3グラムのポリアクリル酸(Aldrich)を、60℃で12時間攪拌しながら、凝縮器を備えた500ml反応器中の220mlのN−メチルピロリドンに溶解する。
ポリ−N−イソプロピルアクリルアミド(pNIPAM)グラフトを含むポリマー2を、二段階法によって調製する:
8グラムのN−イソプロピルアクリルミド及び80mlのジメチルスルホキシドを、凝縮器と窒素流入口を備えた250mlの三口丸底フラスコ内に導入する。ウォーターバスを使用して攪拌しながらこの混合物を29℃に加熱し、窒素下に配置する。45分後、4mlのジメチルスルホキシドに事前に溶解した0.161グラムのアミノエタンチオールヒドロクロリドを反応媒体に加える。5分後、8mlのジメチルスルホキシドに溶解した0.191グラムの過硫酸カリウムを反応媒体に加える。この反応媒体を、29℃で3時間窒素雰囲気下で攪拌する。
550000g/molのモル質量を有する3グラムのポリアクリル酸を、60℃で12時間攪拌しながら、凝縮器を備えた250ml三口丸底フラスコ中の100mlの1−メチル−2−ピロリドンに溶解する。25mlの1−メチル−2−ピロリドンに事前に溶解した3.757グラムのpNIPAMオリゴマーを、攪拌しながら反応媒体内に滴下して導入する。15分後、25mlの1−メチル−2−ピロリドン中に事前に溶解した0.776グラムのジシクロヘキシルカルボジイミドを、激しく攪拌しながら反応媒体中に滴下して導入する。反応媒体を、攪拌しながら60℃で12時間維持する。
10.2グラムの固体を回収し、2リットルの脱イオン水に溶解する。10000ダルトンにセットされたカットオフ値を有する膜を含むMillipore限外濾過システムを使用して、この溶液を限外濾過する。かくして精製された溶液を凍結乾燥し、固体形態のポリマーを集める。
750000g/molの平均モル質量を有する1.51グラムのポリアクリル酸(Aldrich)を、20℃で12時間攪拌しながら、凝縮器を備えた1l反応器中の350mlの脱イオン水に溶解する。ついで、反応媒体のpHを、1Mの水酸化ナトリウム溶液で8に調整する。1.60グラムのモノアミノランダム(EO)6(PO)39コポリマー(Huntsman社製のJeffamine M-2005)を、5℃で30分間攪拌しながら、100mlの脱イオン水に溶解する。得られた溶液を、激しく攪拌しながら、反応媒体に滴下して加える。
−15℃、0.05と0.1%の濃度でのLCSTを有するグラフト(ポリマー1及び2)の混合温度未満の値。
−38℃、0.05と0.1%の濃度でのLCSTを有するグラフト(ポリマー1及び2)の偏析温度を超えた値。
− 15℃での粘度(10s−1):0.007Pa.s
− 38℃での粘度(10s−1):0.005Pa.s
水/パーリーム油の界面で、2つの温度で、測定を行なった。
− 15℃、LCSTを有するグラフト(ポリマー1と2)の混合温度未満の値。
− 38℃、LCSTを有するグラフト(ポリマー1と2)の偏析温度を超えた値。
−15℃での粘度(10s−1):0.12Pa.s
−38℃での粘度(10s−1):0.12Pa.s
グリセリン 5重量%
ポリマー3 0.3重量%
防腐剤 0.4重量%
ナトリウム=エチレンジアミンテトラアセタート 0.2重量%
脱イオン水 94.1重量%
この乳液は、下記の組成を有する油性相と水性相を含む。
パーリーム油 乳液の9重量%
シクロジメチルシロキサン 乳液の6重量%
水性相
ポリマー3 乳液の0.3重量%
防腐剤 乳液の0.2重量%
脱イオン水 乳液の84.5重量%
Claims (3)
- 水溶性単位及びLCSTを有する単位を含み、このLCSTを有する単位の水中における偏析温度が、水中に1質量%の濃度において5から40℃であるポリマーであって、前記ポリマーのLCSTを有する単位の質量割合が、前記ポリマーに対して5から70%であ
り、骨格に前記水溶性単位としてポリアクリル酸を有し、側鎖に前記LCSTを有する単位としてエチレンオキシド(EO)とプロピレンオキシド(PO)とのランダムコポリマーまたはポリ−N−イソプロピルアクリルアミド(pNIPAM)オリゴマーを有するグラフトポリマーであるポリマーを使用する、水の表面張力または界面張力を低下させるための方法。 - 水の表面張力または界面張力の低下が、5から80℃の範囲の温度、ポリマーが0.1質量%の濃度において、少なくとも15mN/mである、請求項1記載の方法。
- 水の表面張力または界面張力の低下が、ポリマーが0.1質量%の濃度で、温度がこの濃度におけるLCSTを有する単位の偏析温度よりも高い時に、少なくとも20mN/mである、請求項1記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0100480A FR2819429B1 (fr) | 2001-01-15 | 2001-01-15 | Emulsions et compositions moussantes contenant un polymere comprenant des unites hydrosolubles et des unites a lcst, notamment pour des applications cosmetiques |
FR01/00480 | 2001-01-15 | ||
PCT/FR2002/000100 WO2002055606A1 (fr) | 2001-01-15 | 2002-01-11 | Emulsions et compositions moussantes contenant un polymere comprenant des unites hydrosolubles et des unites lcst, notamment pour des applications cosmetiques |
Publications (2)
Publication Number | Publication Date |
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JP2004525886A JP2004525886A (ja) | 2004-08-26 |
JP4732674B2 true JP4732674B2 (ja) | 2011-07-27 |
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JP2002556664A Expired - Fee Related JP4732674B2 (ja) | 2001-01-15 | 2002-01-11 | 特に化粧品用途の、水溶性単位とlcstを有する単位とを含むポリマーを含む起泡性エマルション及び起泡性組成物 |
Country Status (7)
Country | Link |
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US (1) | US7655702B2 (ja) |
EP (1) | EP1355989B1 (ja) |
JP (1) | JP4732674B2 (ja) |
DE (1) | DE60234677D1 (ja) |
ES (1) | ES2336653T3 (ja) |
FR (1) | FR2819429B1 (ja) |
WO (1) | WO2002055606A1 (ja) |
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FR2838345A1 (fr) * | 2002-04-12 | 2003-10-17 | Oreal | Utilisation de polymeres hydrosolubles ou hydrodispersibles a unites a lcst comme agent tenseur dans des compositions cosmetiques, notamment antirides |
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-
2001
- 2001-01-15 FR FR0100480A patent/FR2819429B1/fr not_active Expired - Fee Related
-
2002
- 2002-01-11 EP EP02710976A patent/EP1355989B1/fr not_active Expired - Lifetime
- 2002-01-11 WO PCT/FR2002/000100 patent/WO2002055606A1/fr active Application Filing
- 2002-01-11 ES ES02710976T patent/ES2336653T3/es not_active Expired - Lifetime
- 2002-01-11 US US10/069,983 patent/US7655702B2/en not_active Expired - Fee Related
- 2002-01-11 DE DE60234677T patent/DE60234677D1/de not_active Expired - Lifetime
- 2002-01-11 JP JP2002556664A patent/JP4732674B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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WO2002055606A1 (fr) | 2002-07-18 |
US20030158330A1 (en) | 2003-08-21 |
JP2004525886A (ja) | 2004-08-26 |
EP1355989B1 (fr) | 2009-12-09 |
FR2819429A1 (fr) | 2002-07-19 |
ES2336653T3 (es) | 2010-04-15 |
EP1355989A1 (fr) | 2003-10-29 |
DE60234677D1 (de) | 2010-01-21 |
FR2819429B1 (fr) | 2003-03-07 |
US7655702B2 (en) | 2010-02-02 |
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