JP4669223B2 - 絹の触感を有する塗工紙 - Google Patents
絹の触感を有する塗工紙 Download PDFInfo
- Publication number
- JP4669223B2 JP4669223B2 JP2003553068A JP2003553068A JP4669223B2 JP 4669223 B2 JP4669223 B2 JP 4669223B2 JP 2003553068 A JP2003553068 A JP 2003553068A JP 2003553068 A JP2003553068 A JP 2003553068A JP 4669223 B2 JP4669223 B2 JP 4669223B2
- Authority
- JP
- Japan
- Prior art keywords
- paper
- coating composition
- polyurethane
- coated
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920002635 polyurethane Polymers 0.000 claims abstract description 17
- 239000004814 polyurethane Substances 0.000 claims abstract description 17
- 239000011230 binding agent Substances 0.000 claims abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims description 14
- 239000008199 coating composition Substances 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 4
- 229920003043 Cellulose fiber Polymers 0.000 claims description 3
- 238000007645 offset printing Methods 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000011806 microball Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 13
- 238000007639 printing Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 8
- 239000002562 thickening agent Substances 0.000 description 3
- 239000003125 aqueous solvent Substances 0.000 description 2
- 230000035807 sensation Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/42—Coatings with pigments characterised by the pigments at least partly organic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
- D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/72—Coated paper characterised by the paper substrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/254—Polymeric or resinous material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
- Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
- Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
- Y10T428/277—Cellulosic substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
Description
・24.7部の水
・0.1部の湿潤剤
・33.3部のポリウレタンの水性エマルジョン Witcobond 290H
・20部のポリウレタンの超微粉
・0.5部のpH調節剤
・1部の粘稠剤
を含む。
・様々な部のポリウレタンの水性エマルジョン Rolflex PAD
・20部のポリウレタンの超微粉 Daiplacoat RHU 5070
・0.5部のpH調節剤
・1部の粘稠剤
を含む。
・ポリウレタンの超微粉層を有する面の触感を、手で評価する。
a)台の上に取り付けられ、布状の黒のフエルト(羊毛70%、ポリアミド30%の混紡)で覆われた、40mm×40mm、重量2kgのすべり片を、前記層を塗布した1枚または数枚の用紙の上に当てる、
b)全長6mを覆うように紙の上に1回だけ通す
c)すべり片のフエルトを取り去る
d)ELREPHOの装置を用いてフエルトの反射率を測定する(粗布で測定した値は約1.4)
a)幅48mm、長さ250mmの試験される紙の試験片を作成する
b)第1印刷台と第2印刷転写台を有するPRUFBAU試験機を用いる
c)第1台の圧力を1000Nに、第2台の圧力を400Nに調節する
d)機械の速度を0.5m/秒に調節する
e)HUBER408010タイプの青のインクで30秒間、第1台のインクローラーにインクを付ける
f)試験片を備えた運搬機を第1台の前に置く
g)インクの付いていないローラーを第2台の上に置く
h)第1台で試験片を印刷する
i)印刷直後にストップウオッチを始動する
j)第2台の新たなローラーの上に、同じ紙の試験片を接着テープを用いて付ける
k)ストップウオッチで120秒が経過したら、印刷された試験片を備えた運搬機をブランケットの部位まで差し込む
l)第2台の試験片をそのローラーから直ちに引き離す
m)新たな試験片に転写されたシアンの光学密度を、密度計XRITEを用いて測定する。
実施例1〜5の試験結果は表1に示されている。
2.8kgの水
0.03kgの湿潤剤TEXAPON Z95P
81kgのLAMBERTIが市販している結合剤ROLFLEX PAD
6.1kgのPROMECOMEが市販しているポリウレタンの超微粉DAIPLACOAT RHU5070
1kgのAQUALONが市販している2.5%の粘稠剤CMC BLANOSE 7M65
を片面あたり乾燥重量で5.4g/m2付着させて得られた。
Claims (6)
- 色素と結合剤を含むオフセット印刷されるための塗工紙用の塗工組成物において、前記塗工紙に絹の触感を与えるために、塗工色素が10マイクロメートル未満のサイズを有するポリウレタンの超微粉であり、用いられる結合剤が500%以上の伸長率を有するポリウレタンの水性エマルジョンであることを特徴とする、塗工組成物。
- 色素に対する結合剤の割合が、重量で200%以上であることを特徴とする、請求項1に記載の塗工組成物。
- 少なくとも片面に、請求項1に記載の塗工組成物が塗布された、絹の触感を有する紙。
- 200gのすべり片を用いて規格NF−Q−03−082に従って測定したとき、塗工したその表の面と同様に塗工したその別の裏面との間の動的摩擦係数が1.0以下であることを特徴とする、請求項3に記載の紙。
- 少なくとも一つの面に塗布した層の重量が、乾燥重量で2〜10g/m2の間に含まれることを特徴とする、請求項3に記載の紙。
- トレーシングペーパーを構成するセルロース繊維を高度に精製することによって得られたトレーシングペーパーであることを特徴とする、請求項3に記載の紙。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0116417A FR2833625B1 (fr) | 2001-12-18 | 2001-12-18 | Papier couche possedant un toucher soyeux |
PCT/FR2002/004378 WO2003052203A2 (fr) | 2001-12-18 | 2002-12-17 | Papier couche possedant un toucher soyeux |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005513282A JP2005513282A (ja) | 2005-05-12 |
JP4669223B2 true JP4669223B2 (ja) | 2011-04-13 |
Family
ID=8870662
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003553068A Expired - Fee Related JP4669223B2 (ja) | 2001-12-18 | 2002-12-17 | 絹の触感を有する塗工紙 |
Country Status (20)
Country | Link |
---|---|
US (1) | US20050031851A1 (ja) |
EP (1) | EP1458930B1 (ja) |
JP (1) | JP4669223B2 (ja) |
KR (2) | KR100956864B1 (ja) |
CN (1) | CN100347375C (ja) |
AT (1) | ATE526455T1 (ja) |
AU (1) | AU2002364844B2 (ja) |
BR (1) | BR0207323B1 (ja) |
CA (1) | CA2469016C (ja) |
ES (1) | ES2372815T3 (ja) |
FR (1) | FR2833625B1 (ja) |
HK (1) | HK1076133A1 (ja) |
HU (1) | HUP0600861A2 (ja) |
MX (1) | MXPA04005869A (ja) |
NO (1) | NO20033545L (ja) |
NZ (1) | NZ533961A (ja) |
PT (1) | PT1458930E (ja) |
RU (1) | RU2294998C2 (ja) |
WO (1) | WO2003052203A2 (ja) |
ZA (1) | ZA200306262B (ja) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6866906B2 (en) | 2000-01-26 | 2005-03-15 | International Paper Company | Cut resistant paper and paper articles and method for making same |
ES2347993T3 (es) | 2002-09-13 | 2010-11-26 | International Paper Company | Papel con rigidez y cuerpo mejorados y método para fabricarlo campo de aplicación de la invención. |
KR101329927B1 (ko) * | 2005-03-11 | 2013-11-20 | 인터내셔널 페이퍼 컴퍼니 | 팽창성 미소구체 및 이온성 화합물을 함유하는 조성물, 및 이의 제조 및 사용 방법 |
KR100845602B1 (ko) * | 2007-01-31 | 2008-07-10 | 주식회사 케이에프텍 | 인조피혁지 |
CN101821454B (zh) * | 2007-10-12 | 2012-09-12 | 花王株式会社 | 涂布纸的制造方法 |
US8382945B2 (en) | 2008-08-28 | 2013-02-26 | International Paper Company | Expandable microspheres and methods of making and using the same |
FR2942169B1 (fr) * | 2009-02-13 | 2011-04-01 | Arjo Wiggins Fine Papers Ltd | Feuille imprimable multicouche a toucher doux ou soyeux et son procede de fabrication |
FR2960889B1 (fr) * | 2010-06-03 | 2012-07-27 | Arjo Wiggins Fine Papers Ltd | Papier fin couche a toucher doux |
CN104674596B (zh) * | 2015-02-05 | 2016-12-07 | 骏源新材料(上海)有限公司 | 一种触感纸的制备方法 |
JP6971442B2 (ja) * | 2018-03-13 | 2021-11-24 | ダイニック株式会社 | スエード調塗工紙 |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02277899A (ja) * | 1989-04-12 | 1990-11-14 | Ricoh Co Ltd | 透明原紙及びそれを用いた静電記録体 |
JPH0450857A (ja) * | 1990-06-15 | 1992-02-19 | Ricoh Co Ltd | 第二原図用静電記録紙 |
JPH0482736A (ja) * | 1990-07-25 | 1992-03-16 | Achilles Corp | スエード調シートおよびその製造方法 |
JPH04144743A (ja) * | 1990-10-05 | 1992-05-19 | Dainippon Printing Co Ltd | スエード調包装用紙の製造方法 |
JPH0631873A (ja) * | 1992-07-13 | 1994-02-08 | Dainippon Printing Co Ltd | クロス調化粧材 |
JPH0679831A (ja) * | 1992-09-02 | 1994-03-22 | Dainippon Printing Co Ltd | 艶消し化粧材及びその製造方法 |
JPH09143876A (ja) * | 1995-11-27 | 1997-06-03 | Kanebo Ltd | 繊維ウェッブ |
JPH1095062A (ja) * | 1996-07-19 | 1998-04-14 | Inoac Corp | スエード調の外観を有する装飾材及びその製造方法 |
JPH1124205A (ja) * | 1997-04-28 | 1999-01-29 | Eastman Kodak Co | 架橋した弾性艶消ビーズを含む画像形成要素用の裏打ち層 |
JPH1150397A (ja) * | 1997-06-03 | 1999-02-23 | Hakusan Sangyo Kk | 肌当て紙及びその製造方法 |
JPH11315492A (ja) * | 1998-02-25 | 1999-11-16 | Rengo Co Ltd | 無機多孔結晶―親水性高分子複合体を含有する織物、不織布または紙 |
JP2000234294A (ja) * | 1999-02-12 | 2000-08-29 | Oji Paper Co Ltd | 強光沢印刷用シート |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4756950A (en) * | 1985-03-23 | 1988-07-12 | Mitsubishi Paper Mills, Ltd. | Gradation recording heat-transfer sheet |
ID27891A (id) * | 1998-06-24 | 2001-05-03 | Akzo Nobel Nv | Ionik poliuretan |
FR2791368B1 (fr) * | 1999-03-26 | 2001-06-01 | Arjo Wiggins Sa | Feuille avec un toucher "peau" imprimable a des cadences elevees et son procede de fabrication et emballage la comportant |
US6517674B1 (en) | 2000-02-02 | 2003-02-11 | The Mead Corporation | Process for manufacturing wear resistant paper |
JP4670496B2 (ja) * | 2005-06-14 | 2011-04-13 | 住友電気工業株式会社 | 光受信器 |
-
2001
- 2001-12-18 FR FR0116417A patent/FR2833625B1/fr not_active Expired - Fee Related
-
2002
- 2002-12-17 WO PCT/FR2002/004378 patent/WO2003052203A2/fr active Application Filing
- 2002-12-17 BR BRPI0207323-4A patent/BR0207323B1/pt not_active IP Right Cessation
- 2002-12-17 ES ES02801137T patent/ES2372815T3/es not_active Expired - Lifetime
- 2002-12-17 EP EP02801137A patent/EP1458930B1/fr not_active Expired - Lifetime
- 2002-12-17 CA CA2469016A patent/CA2469016C/fr not_active Expired - Fee Related
- 2002-12-17 AT AT02801137T patent/ATE526455T1/de not_active IP Right Cessation
- 2002-12-17 RU RU2004121956/12A patent/RU2294998C2/ru not_active IP Right Cessation
- 2002-12-17 JP JP2003553068A patent/JP4669223B2/ja not_active Expired - Fee Related
- 2002-12-17 NZ NZ533961A patent/NZ533961A/en not_active IP Right Cessation
- 2002-12-17 AU AU2002364844A patent/AU2002364844B2/en not_active Ceased
- 2002-12-17 KR KR1020047009271A patent/KR100956864B1/ko not_active IP Right Cessation
- 2002-12-17 US US10/498,066 patent/US20050031851A1/en not_active Abandoned
- 2002-12-17 HU HU0600861A patent/HUP0600861A2/hu unknown
- 2002-12-17 MX MXPA04005869A patent/MXPA04005869A/es active IP Right Grant
- 2002-12-17 PT PT02801137T patent/PT1458930E/pt unknown
- 2002-12-17 KR KR1020087026912A patent/KR20080107481A/ko not_active Application Discontinuation
- 2002-12-17 CN CNB028253558A patent/CN100347375C/zh not_active Expired - Fee Related
-
2003
- 2003-08-11 NO NO20033545A patent/NO20033545L/no not_active Application Discontinuation
- 2003-08-13 ZA ZA2003/06262A patent/ZA200306262B/en unknown
-
2005
- 2005-09-20 HK HK05108237A patent/HK1076133A1/xx not_active IP Right Cessation
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02277899A (ja) * | 1989-04-12 | 1990-11-14 | Ricoh Co Ltd | 透明原紙及びそれを用いた静電記録体 |
JPH0450857A (ja) * | 1990-06-15 | 1992-02-19 | Ricoh Co Ltd | 第二原図用静電記録紙 |
JPH0482736A (ja) * | 1990-07-25 | 1992-03-16 | Achilles Corp | スエード調シートおよびその製造方法 |
JPH04144743A (ja) * | 1990-10-05 | 1992-05-19 | Dainippon Printing Co Ltd | スエード調包装用紙の製造方法 |
JPH0631873A (ja) * | 1992-07-13 | 1994-02-08 | Dainippon Printing Co Ltd | クロス調化粧材 |
JPH0679831A (ja) * | 1992-09-02 | 1994-03-22 | Dainippon Printing Co Ltd | 艶消し化粧材及びその製造方法 |
JPH09143876A (ja) * | 1995-11-27 | 1997-06-03 | Kanebo Ltd | 繊維ウェッブ |
JPH1095062A (ja) * | 1996-07-19 | 1998-04-14 | Inoac Corp | スエード調の外観を有する装飾材及びその製造方法 |
JPH1124205A (ja) * | 1997-04-28 | 1999-01-29 | Eastman Kodak Co | 架橋した弾性艶消ビーズを含む画像形成要素用の裏打ち層 |
JPH1150397A (ja) * | 1997-06-03 | 1999-02-23 | Hakusan Sangyo Kk | 肌当て紙及びその製造方法 |
JPH11315492A (ja) * | 1998-02-25 | 1999-11-16 | Rengo Co Ltd | 無機多孔結晶―親水性高分子複合体を含有する織物、不織布または紙 |
JP2000234294A (ja) * | 1999-02-12 | 2000-08-29 | Oji Paper Co Ltd | 強光沢印刷用シート |
Also Published As
Publication number | Publication date |
---|---|
RU2004121956A (ru) | 2005-03-27 |
PT1458930E (pt) | 2011-12-15 |
HK1076133A1 (en) | 2006-01-06 |
EP1458930A2 (fr) | 2004-09-22 |
MXPA04005869A (es) | 2005-03-31 |
BR0207323A (pt) | 2004-02-10 |
CA2469016C (fr) | 2010-10-19 |
ES2372815T3 (es) | 2012-01-26 |
FR2833625A1 (fr) | 2003-06-20 |
KR20040066905A (ko) | 2004-07-27 |
NZ533961A (en) | 2007-08-31 |
AU2002364844A1 (en) | 2003-06-30 |
NO20033545D0 (no) | 2003-08-11 |
FR2833625B1 (fr) | 2004-03-05 |
RU2294998C2 (ru) | 2007-03-10 |
HUP0600861A2 (en) | 2007-05-02 |
JP2005513282A (ja) | 2005-05-12 |
ATE526455T1 (de) | 2011-10-15 |
KR100956864B1 (ko) | 2010-05-11 |
CA2469016A1 (fr) | 2003-06-26 |
WO2003052203A3 (fr) | 2003-12-11 |
CN100347375C (zh) | 2007-11-07 |
AU2002364844B2 (en) | 2008-04-24 |
EP1458930B1 (fr) | 2011-09-28 |
CN1604980A (zh) | 2005-04-06 |
ZA200306262B (en) | 2005-04-26 |
KR20080107481A (ko) | 2008-12-10 |
US20050031851A1 (en) | 2005-02-10 |
NO20033545L (no) | 2003-08-11 |
WO2003052203A2 (fr) | 2003-06-26 |
BR0207323B1 (pt) | 2013-01-22 |
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