JP4647443B2 - 液体消臭剤 - Google Patents
液体消臭剤 Download PDFInfo
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- JP4647443B2 JP4647443B2 JP2005267930A JP2005267930A JP4647443B2 JP 4647443 B2 JP4647443 B2 JP 4647443B2 JP 2005267930 A JP2005267930 A JP 2005267930A JP 2005267930 A JP2005267930 A JP 2005267930A JP 4647443 B2 JP4647443 B2 JP 4647443B2
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- liquid deodorant
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- 239000002781 deodorant agent Substances 0.000 title claims description 34
- 239000007788 liquid Substances 0.000 title claims description 32
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000004753 textile Substances 0.000 claims description 9
- 244000269722 Thea sinensis Species 0.000 claims description 8
- 235000009569 green tea Nutrition 0.000 claims description 8
- 238000000197 pyrolysis Methods 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 7
- 230000003139 buffering effect Effects 0.000 claims description 7
- 239000000284 extract Substances 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 7
- 125000003342 alkenyl group Chemical group 0.000 claims description 6
- 150000001735 carboxylic acids Chemical class 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 241000255925 Diptera Species 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 235000019645 odor Nutrition 0.000 description 25
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 230000001877 deodorizing effect Effects 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 239000004744 fabric Substances 0.000 description 9
- -1 alkali metal salts Chemical class 0.000 description 8
- 235000013372 meat Nutrition 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 235000011007 phosphoric acid Nutrition 0.000 description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 241000208125 Nicotiana Species 0.000 description 4
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 235000019504 cigarettes Nutrition 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000003016 phosphoric acids Chemical class 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 2
- 239000002526 disodium citrate Substances 0.000 description 2
- 235000019262 disodium citrate Nutrition 0.000 description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 2
- 235000019796 monopotassium phosphate Nutrition 0.000 description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 2
- 235000019799 monosodium phosphate Nutrition 0.000 description 2
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 229940038773 trisodium citrate Drugs 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- QSHKDIHEZKCYDU-UHFFFAOYSA-N 1,5-dimethylcyclohexa-2,4-diene-1-sulfonic acid Chemical compound C1(CC(=CC=C1)C)(C)S(=O)(=O)O QSHKDIHEZKCYDU-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 208000035985 Body Odor Diseases 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 206010040904 Skin odour abnormal Diseases 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明の(a)成分は緑茶の乾留による抽出物である。緑茶の乾留による抽出物とは、緑茶の乾燥した葉を減圧条件下、加熱することにより気化した成分を乾留物として抽出したものである。減圧下で加熱する工程の条件としては、圧力は消臭性能を有する化合物の性能を損なうことなく効率的に抽出出来る観点から、0.67〜13kPa(5〜100mmHg)が好ましく、1.3〜11kPa(10〜80mmHg)がより好ましく、2〜6.7kPa(15〜50mmHg)が特に好ましい。加熱温度は100〜250℃が好ましく、120〜220℃がより好ましく、140〜200℃が更に好ましい。具体的な抽出方法としては、繊維工学,Vol.40,No.3(1987)のP132〜140に記載されている方法を参考に出来る。乾留物として抽出した成分を用いることで対象物の着色を抑制することもできる。
本発明の(b)成分はリン酸類及びカルボン酸類から選ばれる少なくとも1種のpH緩衝効果を有する化合物であり、カルボン酸類から選ばれる少なくとも1種のpH緩衝効果を有する化合物が好ましい。ここでpH緩衝効果を有する化合物とは、pHが6.0〜8.0の範囲外に変動するのを抑制する性能を有する化合物である。
(b)成分は、1種又は2種以上を混合して用いることができる。
本発明の(c)成分は、分子中に4級アンモニウム基又はアミンオキサイド基を少なくとも1個、炭素数8〜22のアルキル基又はアルケニル基を1〜2個有する化合物であり、4級アンモニウム塩等の陽イオン界面活性剤、スルホベタイン、カルボベタイン、アミンオキシド等の両性界面活性剤を挙げることができる。これらの中でも好ましくは炭素数8〜22、特に炭素数8〜18のアルキル基もしくはアルケニル基を1つ有する4級アンモニウム塩又はアミンオキシド型界面活性剤、より好ましくは下記一般式(I)で表される4級アンモニウム塩及び一般式(II)又は(III)で表されるアミンオキシドであり、最も好ましくは一般式(II)又は(III)で表されるアミンオキシドである。
一般式(I)〜(III)において、R1としては、炭素数8〜18のアルキル基又はアルケニル基が好ましい。R2、R3及びR4としては、メチル基又はエチル基が好ましい。R5としては、炭素数1〜3のアルキレン基が好ましい。Yとしては、−CONH−、−COO−が好ましい。X-としては、ハロゲンイオン、炭素数1〜14の脂肪酸イオン、炭素数1〜3のアルキル硫酸イオンが好ましい。
(c)成分は、1種又は2種以上を混合して用いることができる。
本発明の液体消臭剤中の(a)成分の含有量は、消臭性能の観点から、0.001〜2.0重量%であり、0.01〜1.0重量%が好ましい。本発明の液体消臭剤中の(b)成分の含有量は、pHが本発明の範囲外に変動するのを抑制する観点から、0.1〜2.0重量%であり、0.1〜1.0重量%が好ましく、0.1〜0.5重量%がより好ましい。また、本発明の消臭剤が(c)成分を含有する場合、消臭剤中の(c)成分の含有量は、消臭持続性と繊維の風合い付与の観点から、0.1〜2.0重量%が好ましく、0.2〜1.5重量%が更に好ましい。
表1に示す各成分を用い、表1に示す組成の液体消臭剤を調製した。なお、液体消臭剤は、1/10規定NaOH又は1/10規定HClにより25℃でのpHを7に調整した。得られた液体消臭剤について、下記方法で消臭性能を評価した。結果を表1に示す。
下記方法で消臭対象布を調製し、市販の手動式スプレー容器(花王(株)製アイロン用スムーザー400mlの中身を抜いた手動式スプレー容器を匂いが無くなるまで洗浄し、自然乾燥させたもの)に、液体消臭剤を400ml充填し、消臭対象布の全体が一通り均一に湿るように噴霧を行った。その後、温度30℃で湿度が60%RHの調湿された室内で対象布を1時間放置したものについて下記方法で消臭性能を評価した。
・たばこ、焼き肉混在臭繊維製品の調製
5m×5mの密閉された喫煙室の1方の壁に、1m×1mの木綿金布2003#を床から布の上辺までの高さが3mになるように床に対して垂直に吊るした。この喫煙室で、2時間の間、10人の男性が各人3本づつのたばこを喫煙した。その後、IHクッキングヒーターを用いてタレをつけた牛肉を50gフライパン上で5分間焼くことで、たばこ臭と焼き肉臭が混在する布を調製した。上記布を20cm×20cmの試験片として実験に供した。
・消臭性能の評価
30歳代の男性及び女性10人(各5人ずつ)に消臭対象布のたばこと焼き肉の臭いを嗅ぎ分けてもらい、下記の六段階臭気強度表示法で評価し、平均点を求めた。平均点0以上1未満を◎、平均点1以上2未満を○、2以上3未満を△、3以上5以下を×とした。
1:何の臭いか分からないが、ややかすかに何かを感じる強さ(検知閾値のレベル)
2:何の臭いか分かる、容易に感じる弱い臭い(認知閾値のレベル)
3:明らかに感じる臭い
4:強い臭い
5:耐えられないほど強い臭い
Claims (2)
- (a)緑茶の乾留による抽出物0.01〜1.0重量%、(b)カルボン酸類から選ばれる少なくとも1種のpH緩衝効果を有する化合物0.1〜2.0重量%、(c)下記一般式(II)又は(III)で表されるアミンオキシド0.1〜2.0質量%を含有し、水分量が80〜99重量%であり(但し、アルキルグリコシドを含有する場合を除く)、且つ25℃でのpHが6.0〜7.5の繊維製品用の液体消臭剤。
- 請求項1に記載の液体消臭剤を手動式噴霧装置付き容器に充填した液体消臭剤物品。
Priority Applications (1)
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JP2000325454A (ja) * | 1999-03-16 | 2000-11-28 | Kao Corp | 液体消臭剤 |
JP2001095906A (ja) * | 1999-09-30 | 2001-04-10 | Kao Corp | スプレー用消臭剤 |
JP2002336337A (ja) * | 2001-05-14 | 2002-11-26 | Lion Corp | 消臭防汚剤 |
JP2003164515A (ja) * | 2001-11-30 | 2003-06-10 | Shiseido Co Ltd | マイナスイオン発生消臭剤 |
JP2006102477A (ja) * | 2004-09-08 | 2006-04-20 | Kao Corp | 消臭剤 |
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JP2753489B2 (ja) * | 1987-08-27 | 1998-05-20 | 白井松新薬 株式会社 | 耐久性消臭繊維材料およびその製造法 |
JPH0841780A (ja) * | 1994-07-26 | 1996-02-13 | Nikka Chem Co Ltd | 洗濯用濯ぎ助剤組成物 |
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JP2000325454A (ja) * | 1999-03-16 | 2000-11-28 | Kao Corp | 液体消臭剤 |
JP2001095906A (ja) * | 1999-09-30 | 2001-04-10 | Kao Corp | スプレー用消臭剤 |
JP2002336337A (ja) * | 2001-05-14 | 2002-11-26 | Lion Corp | 消臭防汚剤 |
JP2003164515A (ja) * | 2001-11-30 | 2003-06-10 | Shiseido Co Ltd | マイナスイオン発生消臭剤 |
JP2006102477A (ja) * | 2004-09-08 | 2006-04-20 | Kao Corp | 消臭剤 |
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