JP4589533B2 - 多孔性で高度にフッ素化された酸性ポリマー触媒およびその調製のための方法 - Google Patents

多孔性で高度にフッ素化された酸性ポリマー触媒およびその調製のための方法 Download PDF

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JP4589533B2
JP4589533B2 JP2000595785A JP2000595785A JP4589533B2 JP 4589533 B2 JP4589533 B2 JP 4589533B2 JP 2000595785 A JP2000595785 A JP 2000595785A JP 2000595785 A JP2000595785 A JP 2000595785A JP 4589533 B2 JP4589533 B2 JP 4589533B2
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polymer
catalyst
precursor
fluid
porous
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JP2002535137A (ja
JP2002535137A5 (enExample
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バーチャード ロイド ラルフ
ジー．ハワード エドワード
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/032—Impregnation of a formed object with a gas
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2000595785A 1999-01-29 2000-01-28 多孔性で高度にフッ素化された酸性ポリマー触媒およびその調製のための方法 Expired - Fee Related JP4589533B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11769999P 1999-01-29 1999-01-29
US60/117,699 1999-01-29
PCT/US2000/002102 WO2000044495A1 (en) 1999-01-29 2000-01-28 Porous highly fluorinated acidic polymer catalyst and process for its preparation

Publications (3)

Publication Number Publication Date
JP2002535137A JP2002535137A (ja) 2002-10-22
JP2002535137A5 JP2002535137A5 (enExample) 2007-02-08
JP4589533B2 true JP4589533B2 (ja) 2010-12-01

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ID=22374336

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JP2000595785A Expired - Fee Related JP4589533B2 (ja) 1999-01-29 2000-01-28 多孔性で高度にフッ素化された酸性ポリマー触媒およびその調製のための方法

Country Status (6)

Country Link
US (1) US6200924B1 (enExample)
EP (1) EP1152830B1 (enExample)
JP (1) JP4589533B2 (enExample)
CN (1) CN1198687C (enExample)
DE (1) DE60041436D1 (enExample)
WO (1) WO2000044495A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19956568A1 (de) 1999-01-30 2000-08-17 Roland Kreutzer Verfahren und Medikament zur Hemmung der Expression eines vorgegebenen Gens
DE10100586C1 (de) 2001-01-09 2002-04-11 Ribopharma Ag Verfahren zur Hemmung der Expression eines Ziegens
US7193113B2 (en) 2000-12-15 2007-03-20 Japan Science And Technology Corporation Arylbis(perfluoroalkylsulfonyl) methane and metallic salt thereof, and methods for producing the same
US7423142B2 (en) 2001-01-09 2008-09-09 Alnylam Pharmaceuticals, Inc. Compositions and methods for inhibiting expression of anti-apoptotic genes
US7767802B2 (en) 2001-01-09 2010-08-03 Alnylam Pharmaceuticals, Inc. Compositions and methods for inhibiting expression of anti-apoptotic genes
JP3773824B2 (ja) * 2001-03-12 2006-05-10 独立行政法人科学技術振興機構 高分子担持型アリールビス（パーフルオロアルキルスルホニル）メタン
JP4712223B2 (ja) * 2001-05-22 2011-06-29 オルガノ株式会社 固体酸触媒
US6677269B2 (en) 2001-05-17 2004-01-13 George A Olah Environmentally safe alkylation of aliphatic and aromatic hydrocarbons with olefins using solid HF-equivalent catalysts
US6924407B2 (en) * 2001-08-27 2005-08-02 The University Of Kansas Pressure-tuned solid catalyzed heterogeneous chemical reactions
EP1857547B2 (en) 2002-08-05 2020-12-02 Silence Therapeutics GmbH Further novel forms of interfering RNA molecules
CN100360239C (zh) * 2005-07-14 2008-01-09 上海交通大学 大孔交联聚苯乙烯混合酸离子交换树脂及其制备方法
CN102228841B (zh) * 2011-05-11 2013-04-10 凯瑞化工股份有限公司 一种耐高温含氟树脂催化剂及其制备方法
JP2014515415A (ja) * 2011-05-23 2014-06-30 エキソノマー ピーティーワイ リミテッド 発泡アイオノマーおよびそれらの使用
KR101358940B1 (ko) 2012-06-01 2014-02-06 한국과학기술연구원 다공성 표면층을 가지는 나피온 막 및 그 제조 방법
KR101719293B1 (ko) 2015-01-13 2017-03-23 한국과학기술연구원 다공성 나피온 막 및 그 제조 방법
CN112808310B (zh) * 2019-11-18 2022-09-06 六盘水师范学院 一种两亲性有机多孔聚合物固体酸催化剂及其制备方法和应用
CN113999337A (zh) * 2020-07-27 2022-02-01 上海漫关越水处理有限公司 一种超大孔含氟超强酸催化树脂及其合成方法
CN112436167B (zh) * 2020-11-17 2021-10-12 中国科学院兰州化学物理研究所 一种直接式多醚类化合物燃料电池及系统

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
JPS52154862A (en) * 1976-06-17 1977-12-22 Sumitomo Electric Industries Method of producing porous material
US4180695A (en) * 1976-03-04 1979-12-25 Shell Oil Company Isoparaffin alkylation process using an unsupported perfluorinated polymer catalyst
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US5094995A (en) 1989-08-02 1992-03-10 E. I. Du Pont De Nemours And Company Supported perfluorinated ion-exchange polymers
EP0647250B1 (en) * 1992-06-25 2001-04-11 E.I. Du Pont De Nemours And Company Porous polytetrafluoroethylene and preparation
WO1994028059A1 (en) * 1993-05-21 1994-12-08 E.I. Du Pont De Nemours And Company Porous polytetrafluoroethylene and preparation
US5824622A (en) 1994-01-12 1998-10-20 E. I. Du Pont De Nemours And Company Porous microcomposite of perfluorinated ion-exchange polymer and metal oxide, a network of silica, or a network of metal oxide and silica derived via a sol-gel process
US5830923A (en) * 1996-05-22 1998-11-03 E. I. Du Pont De Nemours And Company Foamed fluoropolymer
JP3667005B2 (ja) * 1996-06-13 2005-07-06 旭化成エレクトロニクス株式会社 ゲル系電解質および電気化学素子の製造方法

Also Published As

Publication number Publication date
CN1198687C (zh) 2005-04-27
WO2000044495A1 (en) 2000-08-03
DE60041436D1 (de) 2009-03-12
US6200924B1 (en) 2001-03-13
EP1152830A1 (en) 2001-11-14
EP1152830B1 (en) 2009-01-21
JP2002535137A (ja) 2002-10-22
CN1337891A (zh) 2002-02-27

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