JP4569417B2 - 熱可塑性樹脂の射出発泡成形方法 - Google Patents
熱可塑性樹脂の射出発泡成形方法 Download PDFInfo
- Publication number
- JP4569417B2 JP4569417B2 JP2005240731A JP2005240731A JP4569417B2 JP 4569417 B2 JP4569417 B2 JP 4569417B2 JP 2005240731 A JP2005240731 A JP 2005240731A JP 2005240731 A JP2005240731 A JP 2005240731A JP 4569417 B2 JP4569417 B2 JP 4569417B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- mold
- foaming agent
- injection
- foaming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007924 injection Substances 0.000 title claims description 84
- 238000002347 injection Methods 0.000 title claims description 84
- 229920005992 thermoplastic resin Polymers 0.000 title claims description 37
- 238000010097 foam moulding Methods 0.000 title claims description 29
- 229920005989 resin Polymers 0.000 claims description 111
- 239000011347 resin Substances 0.000 claims description 111
- 239000004088 foaming agent Substances 0.000 claims description 84
- 238000005187 foaming Methods 0.000 claims description 58
- 238000000034 method Methods 0.000 claims description 48
- 239000006260 foam Substances 0.000 claims description 27
- 238000001816 cooling Methods 0.000 claims description 10
- 239000000088 plastic resin Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 71
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 42
- 210000004027 cell Anatomy 0.000 description 26
- 229910002092 carbon dioxide Inorganic materials 0.000 description 21
- 239000001569 carbon dioxide Substances 0.000 description 21
- 239000002667 nucleating agent Substances 0.000 description 20
- 238000001746 injection moulding Methods 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 239000000126 substance Substances 0.000 description 15
- 238000000465 moulding Methods 0.000 description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 8
- 239000012778 molding material Substances 0.000 description 8
- 210000004940 nucleus Anatomy 0.000 description 8
- -1 polyethylene Polymers 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000012530 fluid Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- 239000000378 calcium silicate Substances 0.000 description 4
- 229910052918 calcium silicate Inorganic materials 0.000 description 4
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 4
- 210000003855 cell nucleus Anatomy 0.000 description 4
- 235000019359 magnesium stearate Nutrition 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- XLJMAIOERFSOGZ-UHFFFAOYSA-N cyanic acid Chemical compound OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 210000000497 foam cell Anatomy 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002832 nitroso derivatives Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229920002397 thermoplastic olefin Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/58—Moulds
- B29C44/586—Moulds with a cavity increasing in size during foaming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005240731A JP4569417B2 (ja) | 2005-08-23 | 2005-08-23 | 熱可塑性樹脂の射出発泡成形方法 |
US11/990,782 US7740776B2 (en) | 2005-08-23 | 2006-08-23 | Method for foam injection molding of thermoplastic resin |
PCT/JP2006/316507 WO2007023859A1 (ja) | 2005-08-23 | 2006-08-23 | 熱可塑性樹脂の射出発泡成形方法 |
CA2618845A CA2618845C (en) | 2005-08-23 | 2006-08-23 | Method for foam injection molding of thermoplastic resin |
KR1020087005909A KR101212125B1 (ko) | 2005-08-23 | 2006-08-23 | 열가소성 수지의 사출발포 성형방법 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005240731A JP4569417B2 (ja) | 2005-08-23 | 2005-08-23 | 熱可塑性樹脂の射出発泡成形方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007054993A JP2007054993A (ja) | 2007-03-08 |
JP4569417B2 true JP4569417B2 (ja) | 2010-10-27 |
Family
ID=37771602
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2005240731A Active JP4569417B2 (ja) | 2005-08-23 | 2005-08-23 | 熱可塑性樹脂の射出発泡成形方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US7740776B2 (ko) |
JP (1) | JP4569417B2 (ko) |
KR (1) | KR101212125B1 (ko) |
CA (1) | CA2618845C (ko) |
WO (1) | WO2007023859A1 (ko) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5370823B2 (ja) * | 2009-04-10 | 2013-12-18 | 宇部興産機械株式会社 | 射出発泡成形方法 |
US8529808B2 (en) * | 2010-05-21 | 2013-09-10 | Basf Se | Nanoporous polymer foams |
US20150321403A1 (en) * | 2013-01-24 | 2015-11-12 | Toyota Motor Europe Nv/Sa | Systems and methods for molding |
KR102204791B1 (ko) | 2014-04-16 | 2021-01-20 | 사빅 글로벌 테크놀러지스 비.브이. | 긴 유리 섬유 충전재에서의 발포 기술 |
JP5872668B1 (ja) | 2014-11-20 | 2016-03-01 | 東芝機械株式会社 | 開閉装置、成形装置および成形方法 |
JP6137368B1 (ja) * | 2016-03-24 | 2017-05-31 | 宇部興産機械株式会社 | トグル式型締機構を有する射出成形機の型締制御方法 |
JP6654971B2 (ja) * | 2016-06-17 | 2020-02-26 | 本田技研工業株式会社 | 樹脂成形部材の成形方法及び成形システム |
CN111590809B (zh) * | 2020-05-23 | 2022-11-08 | 芜湖达锦新材料科技有限公司 | 一种可调节式多功能发泡模具装置 |
KR102255180B1 (ko) | 2020-11-06 | 2021-05-24 | 주식회사 디엠씨 | 물리적 발포를 이용한 자동차 현가장치용 자운스범퍼의 제조방법 |
USD1022420S1 (en) | 2020-12-03 | 2024-04-16 | Puma SE | Shoe |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002240731A (ja) * | 2001-02-20 | 2002-08-28 | Koyo Seiko Co Ltd | パワーステアリング装置 |
JP2004009518A (ja) * | 2002-06-06 | 2004-01-15 | Kasai Kogyo Co Ltd | 発泡樹脂成形体の成形方法 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS439913Y1 (ko) | 1965-05-29 | 1968-04-30 | ||
JPS446080Y1 (ko) | 1966-08-18 | 1969-03-05 | ||
US3883629A (en) * | 1968-12-31 | 1975-05-13 | Ici Ltd | Injection molding of laminar articles having a foam core and an integral skin |
US3801686A (en) * | 1972-01-24 | 1974-04-02 | Usm Corp | Method of injection molding articles of foam material |
US4133858A (en) * | 1977-12-14 | 1979-01-09 | Usm Corporation | Injection foam molding process |
US4783292A (en) * | 1987-06-15 | 1988-11-08 | Rogers Roy K | Method of injection molding a foamed plastic article using a relatively light gas as a blowing agent |
JPH086332Y2 (ja) | 1989-12-28 | 1996-02-21 | 株式会社小糸製作所 | 車両用投光器 |
US5158986A (en) | 1991-04-05 | 1992-10-27 | Massachusetts Institute Of Technology | Microcellular thermoplastic foamed with supercritical fluid |
JP3091611B2 (ja) * | 1993-09-20 | 2000-09-25 | 株式会社神戸製鋼所 | 発泡射出成形方法 |
WO1997029896A1 (fr) * | 1996-02-16 | 1997-08-21 | Idemitsu Petrochemical Co., Ltd. | Procede de fabrication d'un article leger en resine thermoplastique renforcee de fibres, et article leger moule |
ES2192697T3 (es) * | 1996-10-11 | 2003-10-16 | Coraltech Ltd | Metodo de moldeo por inyeccion de un articulo espumado. |
TW438658B (en) | 1997-05-07 | 2001-06-07 | Idemitsu Petrochemical Co | Method of obtaining a gas-introduced fiber-reinforced resin injection molding and molding obtained by the same |
MY118653A (en) * | 1998-07-16 | 2004-12-31 | Mitsui Chemicals Inc | Addition method of supercritical carbon dioxide, and production process of expanded thermoplastic resin product by making use of the addition method. |
WO2000003859A1 (fr) * | 1998-07-16 | 2000-01-27 | Idemitsu Petrochemical Co., Ltd. | Produit en resine moulee, de faible poids, et son procede de fabrication |
EP1621312A3 (en) * | 2000-06-22 | 2009-09-30 | Mitsui Chemicals, Inc. | Thermoplastic resin foam product |
JP4233240B2 (ja) | 2000-06-22 | 2009-03-04 | 三井化学株式会社 | 射出発泡成形方法、並びにそれに適した射出成形機および樹脂組成物 |
JP2002283423A (ja) * | 2001-03-26 | 2002-10-03 | Toyota Auto Body Co Ltd | 発泡射出成形方法 |
JP3802774B2 (ja) * | 2001-04-09 | 2006-07-26 | 日泉化学株式会社 | 発泡成形品の製造方法 |
CN100537184C (zh) | 2002-02-28 | 2009-09-09 | 宇部兴产机械株式会社 | 发泡注射成形方法 |
JP4735541B2 (ja) * | 2004-07-26 | 2011-07-27 | 宇部興産機械株式会社 | 熱可塑性樹脂の射出発泡成形方法 |
WO2006051794A1 (ja) * | 2004-11-09 | 2006-05-18 | Prime Polymer Co., Ltd. | 射出発泡成形方法および射出発泡成形用金型 |
AT9383U1 (de) * | 2006-05-16 | 2007-09-15 | Engel Austria Gmbh | Verfahren zur herstellung geschäumter kunststoffkörper |
-
2005
- 2005-08-23 JP JP2005240731A patent/JP4569417B2/ja active Active
-
2006
- 2006-08-23 WO PCT/JP2006/316507 patent/WO2007023859A1/ja active Application Filing
- 2006-08-23 US US11/990,782 patent/US7740776B2/en active Active
- 2006-08-23 KR KR1020087005909A patent/KR101212125B1/ko active IP Right Grant
- 2006-08-23 CA CA2618845A patent/CA2618845C/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002240731A (ja) * | 2001-02-20 | 2002-08-28 | Koyo Seiko Co Ltd | パワーステアリング装置 |
JP2004009518A (ja) * | 2002-06-06 | 2004-01-15 | Kasai Kogyo Co Ltd | 発泡樹脂成形体の成形方法 |
Also Published As
Publication number | Publication date |
---|---|
KR101212125B1 (ko) | 2012-12-13 |
JP2007054993A (ja) | 2007-03-08 |
US7740776B2 (en) | 2010-06-22 |
CA2618845C (en) | 2010-12-21 |
CA2618845A1 (en) | 2007-03-01 |
KR20080046182A (ko) | 2008-05-26 |
US20090134541A1 (en) | 2009-05-28 |
WO2007023859A1 (ja) | 2007-03-01 |
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