JP4542738B2 - 吸着ヒートポンプ、吸着ヒートポンプ用吸着材及び車両用空調装置 - Google Patents
吸着ヒートポンプ、吸着ヒートポンプ用吸着材及び車両用空調装置 Download PDFInfo
- Publication number
- JP4542738B2 JP4542738B2 JP2002042476A JP2002042476A JP4542738B2 JP 4542738 B2 JP4542738 B2 JP 4542738B2 JP 2002042476 A JP2002042476 A JP 2002042476A JP 2002042476 A JP2002042476 A JP 2002042476A JP 4542738 B2 JP4542738 B2 JP 4542738B2
- Authority
- JP
- Japan
- Prior art keywords
- adsorption
- adsorbent
- heat pump
- vapor pressure
- zeolite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000001179 sorption measurement Methods 0.000 title claims description 169
- 239000000463 material Substances 0.000 title claims description 8
- 239000003463 adsorbent Substances 0.000 claims description 87
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 68
- 239000002156 adsorbate Substances 0.000 claims description 50
- 239000010457 zeolite Substances 0.000 claims description 45
- 229910021536 Zeolite Inorganic materials 0.000 claims description 42
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 41
- 229910052782 aluminium Inorganic materials 0.000 claims description 26
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 26
- 125000005842 heteroatom Chemical group 0.000 claims description 25
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 21
- 229910052698 phosphorus Inorganic materials 0.000 claims description 21
- 239000011574 phosphorus Substances 0.000 claims description 21
- 238000002336 sorption--desorption measurement Methods 0.000 claims description 15
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 239000010703 silicon Substances 0.000 claims description 10
- 238000001704 evaporation Methods 0.000 claims description 9
- 125000004429 atom Chemical group 0.000 claims description 7
- 230000008020 evaporation Effects 0.000 claims description 7
- 238000004378 air conditioning Methods 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000000498 cooling water Substances 0.000 description 18
- 238000001816 cooling Methods 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 238000003795 desorption Methods 0.000 description 8
- 239000000741 silica gel Substances 0.000 description 8
- 229910002027 silica gel Inorganic materials 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 230000008929 regeneration Effects 0.000 description 7
- 238000011069 regeneration method Methods 0.000 description 7
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 7
- 239000002808 molecular sieve Substances 0.000 description 6
- 239000000446 fuel Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- -1 EAB Chemical compound 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 1
- 241000269350 Anura Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
Landscapes
- Sorption Type Refrigeration Machines (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002042476A JP4542738B2 (ja) | 2001-02-21 | 2002-02-20 | 吸着ヒートポンプ、吸着ヒートポンプ用吸着材及び車両用空調装置 |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001045677 | 2001-02-21 | ||
| JP2001-45677 | 2001-02-21 | ||
| JP2001111902 | 2001-04-10 | ||
| JP2001-111902 | 2001-04-10 | ||
| JP2002042476A JP4542738B2 (ja) | 2001-02-21 | 2002-02-20 | 吸着ヒートポンプ、吸着ヒートポンプ用吸着材及び車両用空調装置 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008135924A Division JP2008267802A (ja) | 2001-02-21 | 2008-05-23 | 吸着ヒートポンプ、車両用空調装置、吸着ヒートポンプの運転方法、吸着ヒートポンプ用吸着材、及び吸着材の使用方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002372332A JP2002372332A (ja) | 2002-12-26 |
| JP2002372332A5 JP2002372332A5 (enExample) | 2005-06-23 |
| JP4542738B2 true JP4542738B2 (ja) | 2010-09-15 |
Family
ID=27346058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002042476A Expired - Lifetime JP4542738B2 (ja) | 2001-02-21 | 2002-02-20 | 吸着ヒートポンプ、吸着ヒートポンプ用吸着材及び車両用空調装置 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4542738B2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008267802A (ja) * | 2001-02-21 | 2008-11-06 | Mitsubishi Chemicals Corp | 吸着ヒートポンプ、車両用空調装置、吸着ヒートポンプの運転方法、吸着ヒートポンプ用吸着材、及び吸着材の使用方法 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4661772B2 (ja) * | 2002-08-20 | 2011-03-30 | 三菱化学株式会社 | 調湿空調用吸着材、調湿空調装置及びその運転方法 |
| WO2004090458A1 (ja) * | 2003-04-01 | 2004-10-21 | Mitsubishi Chemical Corporation | 吸着ヒートポンプ用吸着材、調湿空調装置用吸着材、吸着ヒートポンプ及び調湿空調装置 |
| JP4565539B2 (ja) * | 2003-05-08 | 2010-10-20 | 中部電力株式会社 | 吸着冷凍機の運転方法 |
| EP1652817A4 (en) * | 2003-06-20 | 2014-01-08 | Mitsubishi Plastics Inc | ZEOLITH, MANUFACTURING METHOD, ZEOLITE ADSORPTION AGENT, HEAT USE SYSTEM, ADSORPTION HEAT PUMP, HEATING AND COOLING MEMORY SYSTEM AND MOISTURE REGULATING AIR CONDITIONER |
| JP4654580B2 (ja) * | 2004-01-23 | 2011-03-23 | 三菱化学株式会社 | 吸着ヒートポンプの運転方法 |
| JP4654582B2 (ja) * | 2004-02-20 | 2011-03-23 | 三菱化学株式会社 | 吸着ヒートポンプの運転方法、吸着ヒートポンプ、調湿空調装置の運転方法、および調湿空調装置 |
| JP2007051112A (ja) * | 2005-08-19 | 2007-03-01 | Mitsubishi Chemicals Corp | 多孔性配位高分子およびその利用 |
| JP5061581B2 (ja) * | 2005-11-04 | 2012-10-31 | 三菱化学株式会社 | 吸着素子およびそれを用いた調湿用空調装置 |
| JP5231076B2 (ja) * | 2008-04-18 | 2013-07-10 | 株式会社豊田中央研究所 | 化学蓄熱システム |
| JP6200911B2 (ja) | 2015-03-03 | 2017-09-20 | 株式会社豊田中央研究所 | ヒートポンプ及び冷熱生成方法 |
| JP7747997B2 (ja) * | 2024-02-13 | 2025-10-02 | ダイキン工業株式会社 | 吸着式冷凍機 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4416765A (en) * | 1981-09-14 | 1983-11-22 | Mobil Oil Corporation | Catalytic cracking |
| US4440871A (en) * | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
| US5340563A (en) * | 1992-06-30 | 1994-08-23 | Chevron Research And Technology Company | Preparation of zeolites using low silica/alumina zeolites as a source of aluminum |
| JP3440250B2 (ja) * | 1992-08-05 | 2003-08-25 | 富士シリシア化学株式会社 | 熱交換用金属管及び吸着式ヒートポンプ |
| JPH06180159A (ja) * | 1992-12-09 | 1994-06-28 | Tokyo Gas Co Ltd | 吸着冷凍機 |
| JP3610665B2 (ja) * | 1996-02-28 | 2005-01-19 | 株式会社豊田中央研究所 | 高密度多孔体及びその製造方法 |
| JPH1163720A (ja) * | 1997-08-08 | 1999-03-05 | Yazaki Corp | 冷媒・吸着剤ペア及びこれを用いた吸着式冷熱発生装置 |
| JPH11223411A (ja) * | 1998-02-03 | 1999-08-17 | Toyota Central Res & Dev Lab Inc | 吸着式ヒートポンプ |
| JPH11223417A (ja) * | 1998-02-04 | 1999-08-17 | Sumitomo Metal Ind Ltd | 製鉄プロセスから発生する低温排熱の回収方法 |
| JP2000140625A (ja) * | 1998-09-07 | 2000-05-23 | Denso Corp | 吸着剤及びこの吸着剤を用いた車両用空調装置 |
| JP3974738B2 (ja) * | 2000-03-01 | 2007-09-12 | 有限会社山口ティー・エル・オー | ヒートポンプ用吸着剤並びにこれを用いたヒートポンプ |
-
2002
- 2002-02-20 JP JP2002042476A patent/JP4542738B2/ja not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008267802A (ja) * | 2001-02-21 | 2008-11-06 | Mitsubishi Chemicals Corp | 吸着ヒートポンプ、車両用空調装置、吸着ヒートポンプの運転方法、吸着ヒートポンプ用吸着材、及び吸着材の使用方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002372332A (ja) | 2002-12-26 |
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