JP4490638B2 - ジルコニウムからハフニウムを分離する方法 - Google Patents

ジルコニウムからハフニウムを分離する方法 Download PDF

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Publication number
JP4490638B2
JP4490638B2 JP2003020032A JP2003020032A JP4490638B2 JP 4490638 B2 JP4490638 B2 JP 4490638B2 JP 2003020032 A JP2003020032 A JP 2003020032A JP 2003020032 A JP2003020032 A JP 2003020032A JP 4490638 B2 JP4490638 B2 JP 4490638B2
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feed mixture
aqueous
ratio
organic
hafnium
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JP2003306728A5 (enExample
JP2003306728A (ja
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ジェイムス・エイ・ソマーズ
ジェフ・ジー・ペリーネ
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エイティーアイ・プロパティーズ・インコーポレーテッド
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00—Obtaining refractory metals
    • C22B34/10—Obtaining titanium, zirconium or hafnium
    • C22B34/14—Obtaining zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/33—Cyanic acids, derivatives thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Extraction Or Liquid Replacement (AREA)
JP2003020032A 2002-01-29 2003-01-29 ジルコニウムからハフニウムを分離する方法 Expired - Lifetime JP4490638B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/059680 2002-01-29
US10/059,680 US6737030B2 (en) 2002-01-29 2002-01-29 Method for separating hafnium from zirconium

Publications (3)

Publication Number Publication Date
JP2003306728A JP2003306728A (ja) 2003-10-31
JP2003306728A5 JP2003306728A5 (enExample) 2005-11-04
JP4490638B2 true JP4490638B2 (ja) 2010-06-30

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JP2003020032A Expired - Lifetime JP4490638B2 (ja) 2002-01-29 2003-01-29 ジルコニウムからハフニウムを分離する方法

Country Status (6)

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US (1) US6737030B2 (enExample)
JP (1) JP4490638B2 (enExample)
CN (1) CN100355916C (enExample)
AU (1) AU2003200243C1 (enExample)
FR (1) FR2835260B1 (enExample)
RU (1) RU2296172C2 (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005010220A1 (ja) * 2003-07-25 2005-02-03 Nikko Materials Co., Ltd. 高純度ハフニウム材料、同材料からなるターゲット及び薄膜並びに高純度ハフニウムの製造方法
WO2005049882A1 (ja) * 2003-11-19 2005-06-02 Nikko Materials Co., Ltd. 高純度ハフニウム、同高純度ハフニウムからなるターゲット及び薄膜並びに高純度ハフニウムの製造方法
DE602006019454D1 (de) * 2005-07-07 2011-02-17 Nippon Mining Co Hochreines hafnium, target und hochreines hafnium umfassender dünner film und verfahren zur herstellung von hochreinem hafnium
JP2010013668A (ja) * 2008-06-30 2010-01-21 Toshiba Corp 金属ジルコニウムの製造方法
CN101813932B (zh) * 2009-02-03 2012-07-04 东北大学 湿法冶金萃取过程组分含量预测与优化操作方法
CN102021335B (zh) * 2009-09-16 2012-06-20 北京有色金属研究总院 一种萃淋法分离锆铪的方法
CN101691243B (zh) * 2009-10-28 2011-05-18 江西晶安高科技股份有限公司 一种制备高纯氧氯化锆的工艺
FR2963339B1 (fr) * 2010-08-02 2012-09-14 Centre Nat Rech Scient Procede de separation des tetrachlorures de zirconium et d'hafnium de leurs melanges
CN102389642A (zh) * 2011-10-24 2012-03-28 江西晶安高科技股份有限公司 Mibk萃取分离锆铪的萃余液中mibk脱除装置
KR101343426B1 (ko) 2012-08-09 2013-12-20 한국과학기술연구원 산성 추출제를 사용한 지르코늄과 하프늄의 분리방법
KR101521016B1 (ko) 2013-06-19 2015-05-15 목포대학교산학협력단 하프늄과 지르코늄의 분리방법
CN104199285A (zh) * 2014-06-12 2014-12-10 东北大学 一种湿法冶金金氰化浸出过程浸出率预测方法
US10047414B2 (en) * 2016-02-11 2018-08-14 Bloom Energy Corporation Method of refining of scandium oxide from concentrates using solvent extraction
CN108220597A (zh) * 2018-01-03 2018-06-29 中南民族大学 硝酸介质中萃取分离锆和铪的方法
CN109468460A (zh) * 2018-11-05 2019-03-15 中核二七二铀业有限责任公司 一种用于tbp萃取分离锆与铪的高选择性萃取原液制备方法
CN114317959B (zh) * 2021-12-31 2024-01-12 中核二七二铀业有限责任公司 一种锆铪分离萃余水沉淀滤渣回收锆铪的方法
CN115094250B (zh) * 2022-06-30 2023-03-14 深圳中铪科技有限公司 一种从含铪废渣中回收铪及其他金属的方法

Family Cites Families (32)

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US2938769A (en) 1952-07-31 1960-05-31 Lyle G Overholser Separation of hafnium from zirconium
US3006719A (en) 1957-07-17 1961-10-31 Nat Distillers Chem Corp Solvent extraction process for separating hafnium from zirconium
US3032388A (en) 1957-10-10 1962-05-01 Andrew T Mccord Method of purifying zirconium chlorides
US2952513A (en) 1958-01-14 1960-09-13 Du Pont Production of zirconium and silicon chlorides
US3069232A (en) 1959-07-14 1962-12-18 Nat Distillers Chem Corp Recovery of hafnium values
US4065544A (en) 1970-05-11 1977-12-27 Union Carbide Corporation Finely divided metal oxides and sintered objects therefrom
US4202862A (en) 1978-08-28 1980-05-13 Teledyne Industries, Inc. Removal of 3-mercapto-4-methyl-2-pentanone from zirconium/hafnium separation processes
DE2854200C2 (de) 1978-12-15 1981-02-05 Th. Goldschmidt Ag, 4300 Essen Verfahren zur Herstellung von Zirkonoxid aus technischem Calciumzirkonat
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US4749448A (en) 1986-12-18 1988-06-07 Westinghouse Electric Corp. Zirconium and hafnium tetrachloride separation by extractive distillation with molten zinc chloride calcium and/or magnesium chloride solvent
US4737244A (en) 1986-12-18 1988-04-12 Westinghouse Electric Corp. Zirconium and hafnium tetrachloride separation by extractive distillation with molten zinc chloride lead chloride solvent
US4876232A (en) 1987-09-28 1989-10-24 Pedro B. Macedo Supported heteropolycyclic compounds in the separation and removal of late transition metals
US5004711A (en) 1987-12-09 1991-04-02 Harshaw/Filtrol Partnership Process of producing colloidal zirconia sols and powders using an ion exchange resin
US4865695A (en) 1988-09-12 1989-09-12 Westinghouse Electric Corp. Preparation of complexes of zirconium and hafnium tetrachlorides with phosphorus oxychloride
US4874475A (en) 1988-09-12 1989-10-17 Westinghouse Electric Corp. Molten salt extractive distillation process for zirconium-hafnium separation
US4865693A (en) 1988-09-12 1989-09-12 Westinghouse Electric Corp. Preparation of complexes of zirconium and hafnium tetrachlorides with phosphorus oxychloride
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US5160482A (en) 1989-03-02 1992-11-03 Teledyne Industries, Inc. Zirconium-hafnium separation and purification process
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US5098678A (en) 1990-04-27 1992-03-24 Westinghouse Electric Corp. Chromatographic separation of zirconium isotopes
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US5132016A (en) * 1990-10-31 1992-07-21 Westinghouse Electric Corp. Solvent prestripping in a zr/hf separation liquid-liquid extraction (llx) circuit
CN1033279C (zh) * 1990-11-14 1996-11-13 北京有色金属研究总院 用三辛胺分馏萃取分离锆铪的工艺
US5133865A (en) 1991-05-10 1992-07-28 Westinghouse Electric Corp. Process for producing a hafnium extraction scrub solvent
US5312016A (en) * 1992-11-04 1994-05-17 Johnstone Pump Company Mastic applicator system
US5470550A (en) 1993-12-30 1995-11-28 Westinghouse Electric Corporation Zirconium sulfate precipitation
US5618502A (en) 1995-07-17 1997-04-08 Westinghouse Electric Corporation Zirconium and hafnium separation in sulfate solutions using continuous ion exchange chromatography
JPH11509632A (ja) 1995-07-17 1999-08-24 ウエスチングハウス・エレクトリック・コーポレイション 連続式イオン交換クロマトグラフィーによる塩化物溶液中のジルコニウムとハフニウムの分離

Also Published As

Publication number Publication date
FR2835260A1 (fr) 2003-08-01
AU2003200243C1 (en) 2008-09-04
FR2835260B1 (fr) 2006-09-29
JP2003306728A (ja) 2003-10-31
RU2296172C2 (ru) 2007-03-27
CN1438335A (zh) 2003-08-27
AU2003200243B2 (en) 2008-01-24
AU2003200243A2 (en) 2003-08-14
CN100355916C (zh) 2007-12-19
US20030143138A1 (en) 2003-07-31
US6737030B2 (en) 2004-05-18
AU2003200243A1 (en) 2003-08-14
AU2003200243A8 (en) 2003-08-14

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