JP4395315B2 - 排ガス中の水銀除去方法およびそのシステム - Google Patents
排ガス中の水銀除去方法およびそのシステム Download PDFInfo
- Publication number
- JP4395315B2 JP4395315B2 JP2003107482A JP2003107482A JP4395315B2 JP 4395315 B2 JP4395315 B2 JP 4395315B2 JP 2003107482 A JP2003107482 A JP 2003107482A JP 2003107482 A JP2003107482 A JP 2003107482A JP 4395315 B2 JP4395315 B2 JP 4395315B2
- Authority
- JP
- Japan
- Prior art keywords
- mercury
- exhaust gas
- air
- scrubber
- oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims description 166
- 229910052753 mercury Inorganic materials 0.000 title claims description 145
- 238000000034 method Methods 0.000 title claims description 34
- 239000007788 liquid Substances 0.000 claims description 85
- 239000003054 catalyst Substances 0.000 claims description 71
- 238000004140 cleaning Methods 0.000 claims description 44
- 230000003647 oxidation Effects 0.000 claims description 39
- 238000007254 oxidation reaction Methods 0.000 claims description 39
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 claims description 38
- 238000002485 combustion reaction Methods 0.000 claims description 27
- 230000033116 oxidation-reduction process Effects 0.000 claims description 25
- 239000002250 absorbent Substances 0.000 claims description 17
- 230000002745 absorbent Effects 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 17
- 238000009423 ventilation Methods 0.000 claims description 17
- 239000003595 mist Substances 0.000 claims description 10
- 238000013022 venting Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 96
- 238000010521 absorption reaction Methods 0.000 description 75
- 238000006477 desulfuration reaction Methods 0.000 description 64
- 230000023556 desulfurization Effects 0.000 description 64
- 238000001816 cooling Methods 0.000 description 45
- 229940008718 metallic mercury Drugs 0.000 description 20
- 239000007800 oxidant agent Substances 0.000 description 17
- 238000012360 testing method Methods 0.000 description 16
- 239000000243 solution Substances 0.000 description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 13
- 239000000428 dust Substances 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 11
- 239000012320 chlorinating reagent Substances 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 11
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 11
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 11
- 230000007246 mechanism Effects 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 230000001590 oxidative effect Effects 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000011144 upstream manufacturing Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000009471 action Effects 0.000 description 5
- 238000005273 aeration Methods 0.000 description 5
- 229910052681 coesite Inorganic materials 0.000 description 5
- 230000001276 controlling effect Effects 0.000 description 5
- 229910052906 cristobalite Inorganic materials 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910052682 stishovite Inorganic materials 0.000 description 5
- 229910052905 tridymite Inorganic materials 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000010440 gypsum Substances 0.000 description 4
- 229910052602 gypsum Inorganic materials 0.000 description 4
- 229910052741 iridium Inorganic materials 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000003303 reheating Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 229910052815 sulfur oxide Inorganic materials 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 241000772991 Aira Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002730 mercury Chemical class 0.000 description 2
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 2
- 239000010742 number 1 fuel oil Substances 0.000 description 2
- -1 on the support Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8665—Removing heavy metals or compounds thereof, e.g. mercury
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/006—Layout of treatment plant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2215/00—Preventing emissions
- F23J2215/60—Heavy metals; Compounds thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/40—Sorption with wet devices, e.g. scrubbers
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Treating Waste Gases (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003107482A JP4395315B2 (ja) | 2003-04-11 | 2003-04-11 | 排ガス中の水銀除去方法およびそのシステム |
| US10/815,419 US7572420B2 (en) | 2003-04-11 | 2004-04-01 | Method for removing mercury in exhaust gas and system therefor |
| US12/459,023 US8703080B2 (en) | 2003-04-11 | 2009-06-25 | Method for removing mercury in exhaust gas and system therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003107482A JP4395315B2 (ja) | 2003-04-11 | 2003-04-11 | 排ガス中の水銀除去方法およびそのシステム |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004313833A JP2004313833A (ja) | 2004-11-11 |
| JP2004313833A5 JP2004313833A5 (https=) | 2005-06-09 |
| JP4395315B2 true JP4395315B2 (ja) | 2010-01-06 |
Family
ID=33127988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003107482A Expired - Fee Related JP4395315B2 (ja) | 2003-04-11 | 2003-04-11 | 排ガス中の水銀除去方法およびそのシステム |
Country Status (2)
| Country | Link |
|---|---|
| US (2) | US7572420B2 (https=) |
| JP (1) | JP4395315B2 (https=) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004337781A (ja) * | 2003-05-16 | 2004-12-02 | Mitsubishi Heavy Ind Ltd | 排ガス処理方法、排ガス処理システム及び触媒酸化装置 |
| EP1649922B1 (en) | 2003-07-10 | 2011-01-26 | Taiheiyo Cement Corporation | Device and method for processing combustion exhaust gas |
| US7771514B1 (en) * | 2004-02-03 | 2010-08-10 | Airgard, Inc. | Apparatus and method for providing heated effluent gases to a scrubber |
| JP2006263700A (ja) * | 2005-02-28 | 2006-10-05 | Mitsubishi Heavy Ind Ltd | 排ガス中の水銀除去システムおよび除去方法 |
| US20060198774A1 (en) * | 2005-03-03 | 2006-09-07 | Cross Joseph B | Mercury Removal sorbent |
| US7404939B2 (en) * | 2005-03-03 | 2008-07-29 | Conocophillips Company | Mercury removal sorbent |
| JP2007007612A (ja) * | 2005-07-01 | 2007-01-18 | Mitsubishi Heavy Ind Ltd | 排ガス処理装置及び方法 |
| CN101247878B (zh) | 2005-08-26 | 2013-05-08 | 太平洋水泥株式会社 | 溶解反应装置及方法 |
| US20070092418A1 (en) * | 2005-10-17 | 2007-04-26 | Chemical Products Corporation | Sorbents for Removal of Mercury from Flue Gas |
| EP1944278A4 (en) | 2005-10-31 | 2013-12-25 | Taiheiyo Cement Corp | APPARATUS AND METHOD FOR ADDING MOISTURE AS WELL TO CEMENT |
| US7704920B2 (en) * | 2005-11-30 | 2010-04-27 | Basf Catalysts Llc | Pollutant emission control sorbents and methods of manufacture |
| US7575629B2 (en) * | 2005-11-30 | 2009-08-18 | Basf Catalysts Llc | Pollutant emission control sorbents and methods of manufacture |
| US7578869B2 (en) * | 2005-11-30 | 2009-08-25 | Basf Catalysts Llc | Methods of manufacturing bentonite pollution control sorbents |
| JP4838579B2 (ja) * | 2005-12-21 | 2011-12-14 | 三菱重工業株式会社 | 水銀除去システムおよび水銀除去方法 |
| JP4928786B2 (ja) * | 2006-01-11 | 2012-05-09 | 三菱重工業株式会社 | 水銀固定化方法およびこれを用いた石膏生産方法、並びに水銀固定化装置およびこれを用いた排煙脱硫システム |
| US7753992B2 (en) | 2006-06-19 | 2010-07-13 | Basf Corporation | Methods of manufacturing mercury sorbents and removing mercury from a gas stream |
| US7572421B2 (en) * | 2006-06-19 | 2009-08-11 | Basf Catalysts Llc | Mercury sorbents and methods of manufacture and use |
| US7611684B2 (en) * | 2006-08-09 | 2009-11-03 | Airgard, Inc. | Effluent gas scrubber and method of scrubbing effluent gasses |
| EP2062989B1 (en) | 2006-10-24 | 2015-10-14 | Taiheiyo Cement Corporation | Method for removing lead from cement kiln |
| CN101583578A (zh) | 2006-12-05 | 2009-11-18 | 太平洋水泥株式会社 | 煤灰的处理方法及处理装置 |
| JP5553966B2 (ja) | 2008-03-19 | 2014-07-23 | 千代田化工建設株式会社 | 水銀吸着材およびその吸着材を用いた排煙処理方法 |
| JP4388542B2 (ja) | 2006-12-07 | 2009-12-24 | 三菱重工業株式会社 | 水銀除去方法及び水銀除去システム |
| EP2135664B1 (en) | 2007-03-07 | 2014-03-05 | Chiyoda Corporation | Method of treating emission gas |
| JP4719171B2 (ja) * | 2007-03-09 | 2011-07-06 | 三菱重工業株式会社 | 排ガス処理装置及び方法 |
| US7524473B2 (en) * | 2007-03-23 | 2009-04-28 | Alstom Technology Ltd | Method of mercury removal in a wet flue gas desulfurization system |
| US8685351B2 (en) * | 2007-09-24 | 2014-04-01 | Basf Corporation | Pollutant emission control sorbents and methods of manufacture and use |
| US20090081092A1 (en) * | 2007-09-24 | 2009-03-26 | Xiaolin David Yang | Pollutant Emission Control Sorbents and Methods of Manufacture and Use |
| US8906823B2 (en) | 2007-09-24 | 2014-12-09 | Basf Corporation | Pollutant emission control sorbents and methods of manufacture and use |
| US7758829B2 (en) * | 2007-12-05 | 2010-07-20 | Alstom Technology Ltd | Process for promoting mercury retention in wet flue gas desulfurization systems |
| US8632742B2 (en) | 2007-12-07 | 2014-01-21 | Nalco Company | Methods of controlling mercury emission |
| CN201138790Y (zh) * | 2008-01-03 | 2008-10-22 | 中山大洋电机股份有限公司 | 一种单相交流电机的电子启动电路 |
| JP5215673B2 (ja) * | 2008-01-11 | 2013-06-19 | 三菱重工業株式会社 | 塩化水素供給装置、排ガス処理システム及び塩化水素供給管理システム |
| JP2009166012A (ja) * | 2008-01-21 | 2009-07-30 | Mitsubishi Heavy Ind Ltd | 石炭焚ボイラの排ガス処理システム及びその運転方法 |
| JP4719228B2 (ja) * | 2008-01-21 | 2011-07-06 | 三菱重工業株式会社 | 石炭焚ボイラの排ガス処理システム |
| JP2009166010A (ja) * | 2008-01-21 | 2009-07-30 | Mitsubishi Heavy Ind Ltd | 石炭焚ボイラの排ガス処理システム及び方法 |
| JP2009166011A (ja) | 2008-01-21 | 2009-07-30 | Mitsubishi Heavy Ind Ltd | 石炭焚ボイラの排ガス処理システム及び方法 |
| US20090252663A1 (en) * | 2008-04-02 | 2009-10-08 | Todd Marshall Wetherill | Method and system for the removal of an elemental trace contaminant from a fluid stream |
| US7854792B2 (en) * | 2008-09-17 | 2010-12-21 | Airgard, Inc. | Reactive gas control |
| CN101391178B (zh) * | 2008-10-24 | 2012-07-25 | 中国科学院山西煤炭化学研究所 | 一种应用v2o5/炭材料催化剂脱除烟气中汞的方法 |
| US8598073B2 (en) | 2009-04-20 | 2013-12-03 | Corning Incorporated | Methods of making and using activated carbon-containing coated substrates and the products made therefrom |
| JP5417068B2 (ja) * | 2009-07-14 | 2014-02-12 | 株式会社日立製作所 | 酸素燃焼ボイラ及び酸素燃焼ボイラの制御方法 |
| US8092766B2 (en) * | 2009-07-16 | 2012-01-10 | Babcock & Wilcox Power Generation Group, Inc. | Redox method for capture of total gaseous mercury by wet FGD |
| WO2011009217A1 (en) * | 2009-07-24 | 2011-01-27 | Dickson Graham C | Apparatus and method for removing mercury from a gas |
| US8404026B2 (en) | 2010-07-21 | 2013-03-26 | Corning Incorporated | Flow-through substrates and methods for making and using them |
| CA2808563C (en) * | 2010-10-15 | 2015-06-16 | Nobuyuki Ukai | System for processing mercury in flue gas |
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| CN109187883B (zh) * | 2018-10-08 | 2021-08-03 | 中国石油天然气股份有限公司 | 一种天然气脱汞剂评价装置 |
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| WO2022104040A1 (en) * | 2020-11-12 | 2022-05-19 | W. L. Gore & Associates, Inc. | Articles, systems, and methods including articles with halogen reservoirs |
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| US3725009A (en) * | 1968-06-24 | 1973-04-03 | J Lovelock | Detection of trace gases utilizing an electron capture detector |
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| JPH0356123A (ja) | 1989-07-25 | 1991-03-11 | Nkk Corp | ガス中の水銀及びNOxの除去方法 |
| JPH05220345A (ja) | 1991-12-26 | 1993-08-31 | Nkk Corp | 排ガス中の水銀除去方法 |
| JP3935547B2 (ja) * | 1997-02-19 | 2007-06-27 | 三菱重工業株式会社 | 排ガス処理方法及び排ガス処理装置 |
| JP3056123B2 (ja) | 1997-05-27 | 2000-06-26 | 静岡日本電気株式会社 | メッセージ表示機能付き無線選択呼出受信機 |
| JP3546160B2 (ja) * | 1999-12-10 | 2004-07-21 | 三菱重工業株式会社 | 水銀除去方法 |
| JP5220345B2 (ja) | 2007-05-23 | 2013-06-26 | 日本分光株式会社 | 回折格子設計プログラム |
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| US8703080B2 (en) | 2014-04-22 |
| US20040202596A1 (en) | 2004-10-14 |
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| US20090269241A1 (en) | 2009-10-29 |
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