JP4395315B2 - 排ガス中の水銀除去方法およびそのシステム - Google Patents

排ガス中の水銀除去方法およびそのシステム Download PDF

Info

Publication number
JP4395315B2
JP4395315B2 JP2003107482A JP2003107482A JP4395315B2 JP 4395315 B2 JP4395315 B2 JP 4395315B2 JP 2003107482 A JP2003107482 A JP 2003107482A JP 2003107482 A JP2003107482 A JP 2003107482A JP 4395315 B2 JP4395315 B2 JP 4395315B2
Authority
JP
Japan
Prior art keywords
mercury
exhaust gas
air
scrubber
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2003107482A
Other languages
English (en)
Japanese (ja)
Other versions
JP2004313833A5 (https=
JP2004313833A (ja
Inventor
新太郎 本城
徹 高品
耕三 飯田
進 沖野
康浩 竹内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP2003107482A priority Critical patent/JP4395315B2/ja
Priority to US10/815,419 priority patent/US7572420B2/en
Publication of JP2004313833A publication Critical patent/JP2004313833A/ja
Publication of JP2004313833A5 publication Critical patent/JP2004313833A5/ja
Priority to US12/459,023 priority patent/US8703080B2/en
Application granted granted Critical
Publication of JP4395315B2 publication Critical patent/JP4395315B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8665Removing heavy metals or compounds thereof, e.g. mercury
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/006Layout of treatment plant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/60Heavy metals or heavy metal compounds
    • B01D2257/602Mercury or mercury compounds
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/60Heavy metals; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/40Sorption with wet devices, e.g. scrubbers

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
JP2003107482A 2003-04-11 2003-04-11 排ガス中の水銀除去方法およびそのシステム Expired - Fee Related JP4395315B2 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2003107482A JP4395315B2 (ja) 2003-04-11 2003-04-11 排ガス中の水銀除去方法およびそのシステム
US10/815,419 US7572420B2 (en) 2003-04-11 2004-04-01 Method for removing mercury in exhaust gas and system therefor
US12/459,023 US8703080B2 (en) 2003-04-11 2009-06-25 Method for removing mercury in exhaust gas and system therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2003107482A JP4395315B2 (ja) 2003-04-11 2003-04-11 排ガス中の水銀除去方法およびそのシステム

Publications (3)

Publication Number Publication Date
JP2004313833A JP2004313833A (ja) 2004-11-11
JP2004313833A5 JP2004313833A5 (https=) 2005-06-09
JP4395315B2 true JP4395315B2 (ja) 2010-01-06

Family

ID=33127988

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2003107482A Expired - Fee Related JP4395315B2 (ja) 2003-04-11 2003-04-11 排ガス中の水銀除去方法およびそのシステム

Country Status (2)

Country Link
US (2) US7572420B2 (https=)
JP (1) JP4395315B2 (https=)

Families Citing this family (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004337781A (ja) * 2003-05-16 2004-12-02 Mitsubishi Heavy Ind Ltd 排ガス処理方法、排ガス処理システム及び触媒酸化装置
EP1649922B1 (en) 2003-07-10 2011-01-26 Taiheiyo Cement Corporation Device and method for processing combustion exhaust gas
US7771514B1 (en) * 2004-02-03 2010-08-10 Airgard, Inc. Apparatus and method for providing heated effluent gases to a scrubber
JP2006263700A (ja) * 2005-02-28 2006-10-05 Mitsubishi Heavy Ind Ltd 排ガス中の水銀除去システムおよび除去方法
US20060198774A1 (en) * 2005-03-03 2006-09-07 Cross Joseph B Mercury Removal sorbent
US7404939B2 (en) * 2005-03-03 2008-07-29 Conocophillips Company Mercury removal sorbent
JP2007007612A (ja) * 2005-07-01 2007-01-18 Mitsubishi Heavy Ind Ltd 排ガス処理装置及び方法
CN101247878B (zh) 2005-08-26 2013-05-08 太平洋水泥株式会社 溶解反应装置及方法
US20070092418A1 (en) * 2005-10-17 2007-04-26 Chemical Products Corporation Sorbents for Removal of Mercury from Flue Gas
EP1944278A4 (en) 2005-10-31 2013-12-25 Taiheiyo Cement Corp APPARATUS AND METHOD FOR ADDING MOISTURE AS WELL TO CEMENT
US7704920B2 (en) * 2005-11-30 2010-04-27 Basf Catalysts Llc Pollutant emission control sorbents and methods of manufacture
US7575629B2 (en) * 2005-11-30 2009-08-18 Basf Catalysts Llc Pollutant emission control sorbents and methods of manufacture
US7578869B2 (en) * 2005-11-30 2009-08-25 Basf Catalysts Llc Methods of manufacturing bentonite pollution control sorbents
JP4838579B2 (ja) * 2005-12-21 2011-12-14 三菱重工業株式会社 水銀除去システムおよび水銀除去方法
JP4928786B2 (ja) * 2006-01-11 2012-05-09 三菱重工業株式会社 水銀固定化方法およびこれを用いた石膏生産方法、並びに水銀固定化装置およびこれを用いた排煙脱硫システム
US7753992B2 (en) 2006-06-19 2010-07-13 Basf Corporation Methods of manufacturing mercury sorbents and removing mercury from a gas stream
US7572421B2 (en) * 2006-06-19 2009-08-11 Basf Catalysts Llc Mercury sorbents and methods of manufacture and use
US7611684B2 (en) * 2006-08-09 2009-11-03 Airgard, Inc. Effluent gas scrubber and method of scrubbing effluent gasses
EP2062989B1 (en) 2006-10-24 2015-10-14 Taiheiyo Cement Corporation Method for removing lead from cement kiln
CN101583578A (zh) 2006-12-05 2009-11-18 太平洋水泥株式会社 煤灰的处理方法及处理装置
JP5553966B2 (ja) 2008-03-19 2014-07-23 千代田化工建設株式会社 水銀吸着材およびその吸着材を用いた排煙処理方法
JP4388542B2 (ja) 2006-12-07 2009-12-24 三菱重工業株式会社 水銀除去方法及び水銀除去システム
EP2135664B1 (en) 2007-03-07 2014-03-05 Chiyoda Corporation Method of treating emission gas
JP4719171B2 (ja) * 2007-03-09 2011-07-06 三菱重工業株式会社 排ガス処理装置及び方法
US7524473B2 (en) * 2007-03-23 2009-04-28 Alstom Technology Ltd Method of mercury removal in a wet flue gas desulfurization system
US8685351B2 (en) * 2007-09-24 2014-04-01 Basf Corporation Pollutant emission control sorbents and methods of manufacture and use
US20090081092A1 (en) * 2007-09-24 2009-03-26 Xiaolin David Yang Pollutant Emission Control Sorbents and Methods of Manufacture and Use
US8906823B2 (en) 2007-09-24 2014-12-09 Basf Corporation Pollutant emission control sorbents and methods of manufacture and use
US7758829B2 (en) * 2007-12-05 2010-07-20 Alstom Technology Ltd Process for promoting mercury retention in wet flue gas desulfurization systems
US8632742B2 (en) 2007-12-07 2014-01-21 Nalco Company Methods of controlling mercury emission
CN201138790Y (zh) * 2008-01-03 2008-10-22 中山大洋电机股份有限公司 一种单相交流电机的电子启动电路
JP5215673B2 (ja) * 2008-01-11 2013-06-19 三菱重工業株式会社 塩化水素供給装置、排ガス処理システム及び塩化水素供給管理システム
JP2009166012A (ja) * 2008-01-21 2009-07-30 Mitsubishi Heavy Ind Ltd 石炭焚ボイラの排ガス処理システム及びその運転方法
JP4719228B2 (ja) * 2008-01-21 2011-07-06 三菱重工業株式会社 石炭焚ボイラの排ガス処理システム
JP2009166010A (ja) * 2008-01-21 2009-07-30 Mitsubishi Heavy Ind Ltd 石炭焚ボイラの排ガス処理システム及び方法
JP2009166011A (ja) 2008-01-21 2009-07-30 Mitsubishi Heavy Ind Ltd 石炭焚ボイラの排ガス処理システム及び方法
US20090252663A1 (en) * 2008-04-02 2009-10-08 Todd Marshall Wetherill Method and system for the removal of an elemental trace contaminant from a fluid stream
US7854792B2 (en) * 2008-09-17 2010-12-21 Airgard, Inc. Reactive gas control
CN101391178B (zh) * 2008-10-24 2012-07-25 中国科学院山西煤炭化学研究所 一种应用v2o5/炭材料催化剂脱除烟气中汞的方法
US8598073B2 (en) 2009-04-20 2013-12-03 Corning Incorporated Methods of making and using activated carbon-containing coated substrates and the products made therefrom
JP5417068B2 (ja) * 2009-07-14 2014-02-12 株式会社日立製作所 酸素燃焼ボイラ及び酸素燃焼ボイラの制御方法
US8092766B2 (en) * 2009-07-16 2012-01-10 Babcock & Wilcox Power Generation Group, Inc. Redox method for capture of total gaseous mercury by wet FGD
WO2011009217A1 (en) * 2009-07-24 2011-01-27 Dickson Graham C Apparatus and method for removing mercury from a gas
US8404026B2 (en) 2010-07-21 2013-03-26 Corning Incorporated Flow-through substrates and methods for making and using them
CA2808563C (en) * 2010-10-15 2015-06-16 Nobuyuki Ukai System for processing mercury in flue gas
JP2013006144A (ja) * 2011-06-23 2013-01-10 Mitsubishi Heavy Ind Ltd 排ガス処理装置及び排ガス処理装置のorp制御方法
JP2013006143A (ja) * 2011-06-23 2013-01-10 Mitsubishi Heavy Ind Ltd 排ガス処理装置及び排ガス処理装置のorp制御方法
JP2013039511A (ja) * 2011-08-12 2013-02-28 Babcock Hitachi Kk 湿式排煙脱硫装置およびそれを備えた火力発電プラント
US10018356B2 (en) * 2012-07-12 2018-07-10 The Babcock & Wilcox Company System and method for controlling one or more process parameters associated with a combustion process
US20140072483A1 (en) * 2012-09-10 2014-03-13 Mitsubishi Heavy Industries, Ltd. Desulfurization device and particulate collection system
JP2014057912A (ja) * 2012-09-14 2014-04-03 Mitsubishi Heavy Ind Ltd 排ガス中の水銀処理システム
US20140079615A1 (en) * 2012-09-14 2014-03-20 Mitsubishi Heavy Industries, Ltd. Exhaust gas treatment system and a method of treating exhaust gas
US8828341B1 (en) * 2013-07-18 2014-09-09 Alstom Technology Ltd Sulfite control to reduce mercury re-emission
CN103505999B (zh) * 2013-10-23 2016-01-06 中冶长天国际工程有限责任公司 一种湿法脱硫脱硝的系统和方法
CN107249717A (zh) * 2015-02-24 2017-10-13 日立造船株式会社 燃烧排气的处理装置
EP3275529B1 (en) 2015-03-27 2020-11-11 Mitsubishi Power, Ltd. Wet flue gas desulfurization device and method of operating wet flue gas desulfurization device
US20170326498A1 (en) * 2016-05-11 2017-11-16 General Electric Company Sulfite Preconditioning Systems And Methods To Reduce Mercury Concentrations In Waste Water
JP6879801B2 (ja) * 2017-03-31 2021-06-02 三菱パワー株式会社 石膏回収システム及び石膏回収方法
CN109187883B (zh) * 2018-10-08 2021-08-03 中国石油天然气股份有限公司 一种天然气脱汞剂评价装置
US20230398486A1 (en) * 2020-11-12 2023-12-14 W. L. Gore & Associates, Inc. Articles, systems, and methods including articles with halogen reservoirs
WO2022104040A1 (en) * 2020-11-12 2022-05-19 W. L. Gore & Associates, Inc. Articles, systems, and methods including articles with halogen reservoirs
KR102230332B1 (ko) * 2021-02-08 2021-03-22 (주)에스에스에코텍 가변 설정형 탈취기 및 탈취 방법
CN117192052A (zh) * 2023-07-17 2023-12-08 华能国际电力股份有限公司大连电厂 一种海水脱硫废水中重金属再释放检测方法与系统

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3725009A (en) * 1968-06-24 1973-04-03 J Lovelock Detection of trace gases utilizing an electron capture detector
US5009871A (en) * 1984-08-31 1991-04-23 Nippon Kokan Kabushiki Kaisha Method of removing mercury in exhaust gases from a waster incinerator
JPH02191526A (ja) 1988-10-11 1990-07-27 Nkk Corp 排ガス中の水銀濃度制御方法
JPH0356123A (ja) 1989-07-25 1991-03-11 Nkk Corp ガス中の水銀及びNOxの除去方法
JPH05220345A (ja) 1991-12-26 1993-08-31 Nkk Corp 排ガス中の水銀除去方法
JP3935547B2 (ja) * 1997-02-19 2007-06-27 三菱重工業株式会社 排ガス処理方法及び排ガス処理装置
JP3056123B2 (ja) 1997-05-27 2000-06-26 静岡日本電気株式会社 メッセージ表示機能付き無線選択呼出受信機
JP3546160B2 (ja) * 1999-12-10 2004-07-21 三菱重工業株式会社 水銀除去方法
JP5220345B2 (ja) 2007-05-23 2013-06-26 日本分光株式会社 回折格子設計プログラム

Also Published As

Publication number Publication date
US7572420B2 (en) 2009-08-11
US8703080B2 (en) 2014-04-22
US20040202596A1 (en) 2004-10-14
JP2004313833A (ja) 2004-11-11
US20090269241A1 (en) 2009-10-29

Similar Documents

Publication Publication Date Title
JP4395315B2 (ja) 排ガス中の水銀除去方法およびそのシステム
JP4175465B2 (ja) 排ガス中の水銀除去方法およびそのシステム
JP4831801B2 (ja) 排ガスの水銀除去方法及び装置
CN101932376B (zh) 废气的处理方法和装置
JP3935547B2 (ja) 排ガス処理方法及び排ガス処理装置
JP5198786B2 (ja) 排ガス浄化方法と装置
JP5180097B2 (ja) 排ガス処理方法と装置
JP4388542B2 (ja) 水銀除去方法及び水銀除去システム
CN102959386B (zh) 气体分析装置、汞除去系统、气体分析方法及废气中的汞除去方法
JP2001198434A (ja) 排ガス中の水銀処理方法および排ガスの処理システム
JPWO2008078722A1 (ja) 排ガス処理方法と装置
US10247414B2 (en) Coal-fired boiler exhaust gas treatment apparatus and coal-fired boiler exhaust gas treatment method
JP5035722B2 (ja) Nt−scr−触媒の再生
JP2009166010A (ja) 石炭焚ボイラの排ガス処理システム及び方法
JP2009208078A (ja) 排ガス中の水銀処理方法および排ガスの処理システム
CN103768918B (zh) 一种己内酰胺装置尾气净化方法和装置
CN111054201A (zh) 一种脱硫脱硝除尘一体化技术的研制
WO2003008072A1 (fr) Procede de traitement du mercure dans un gaz d'echappement et systeme de traitement de gaz d'echappement
JP2004255342A (ja) 排ガス処理システムおよび排ガス処理方法
CN103079692A (zh) 废气处理装置
CN106345250A (zh) 一种催化裂化烟气超低排放工艺
WO2010021237A1 (ja) 排ガス処理装置及び排ガス処理システム
JPH04300626A (ja) 排煙脱硫装置およびその運転方法

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20040907

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060315

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20070726

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20070731

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20071001

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20090522

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090821

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20090901

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20090925

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20091019

R151 Written notification of patent or utility model registration

Ref document number: 4395315

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R151

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121023

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121023

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20131023

Year of fee payment: 4

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313111

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees