JP4307244B2 - 改良されたアクセシビリティを有する触媒の製造方法 - Google Patents
改良されたアクセシビリティを有する触媒の製造方法 Download PDFInfo
- Publication number
- JP4307244B2 JP4307244B2 JP2003501595A JP2003501595A JP4307244B2 JP 4307244 B2 JP4307244 B2 JP 4307244B2 JP 2003501595 A JP2003501595 A JP 2003501595A JP 2003501595 A JP2003501595 A JP 2003501595A JP 4307244 B2 JP4307244 B2 JP 4307244B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- destabilization
- mixture
- reactor
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title claims description 82
- 238000000034 method Methods 0.000 title claims description 34
- 230000008569 process Effects 0.000 title claims description 16
- 239000000203 mixture Substances 0.000 claims description 64
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 26
- 229910052782 aluminium Inorganic materials 0.000 claims description 25
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 24
- 230000001687 destabilization Effects 0.000 claims description 21
- 239000012018 catalyst precursor Substances 0.000 claims description 20
- 238000001694 spray drying Methods 0.000 claims description 19
- 239000010457 zeolite Substances 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 13
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 13
- 229910021536 Zeolite Inorganic materials 0.000 claims description 12
- 239000004927 clay Substances 0.000 claims description 11
- 239000003002 pH adjusting agent Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 239000007921 spray Substances 0.000 claims description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 8
- 125000000129 anionic group Chemical group 0.000 claims description 8
- 229910017604 nitric acid Inorganic materials 0.000 claims description 8
- 239000002243 precursor Substances 0.000 claims description 8
- 229910001593 boehmite Inorganic materials 0.000 claims description 7
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 claims description 5
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000000908 ammonium hydroxide Substances 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 235000019353 potassium silicate Nutrition 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000004254 Ammonium phosphate Substances 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 3
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 3
- 239000012736 aqueous medium Substances 0.000 claims description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 239000005696 Diammonium phosphate Substances 0.000 claims description 2
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 2
- 150000003839 salts Chemical group 0.000 claims description 2
- 238000010335 hydrothermal treatment Methods 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 18
- 239000002002 slurry Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 11
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 10
- 239000005995 Aluminium silicate Substances 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 8
- 235000012211 aluminium silicate Nutrition 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 8
- 235000021317 phosphate Nutrition 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 7
- 229910001701 hydrotalcite Inorganic materials 0.000 description 7
- 229960001545 hydrotalcite Drugs 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- -1 cationic hydroxyaluminum complexes Chemical class 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000004231 fluid catalytic cracking Methods 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000368 destabilizing effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 239000002638 heterogeneous catalyst Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 238000001935 peptisation Methods 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- ZZBAGJPKGRJIJH-UHFFFAOYSA-N 7h-purine-2-carbaldehyde Chemical compound O=CC1=NC=C2NC=NC2=N1 ZZBAGJPKGRJIJH-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000000411 inducer Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/37—Acid treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01202146A EP1264635A1 (en) | 2001-06-05 | 2001-06-05 | Process for the production of catalysts with improved accessibility |
| PCT/EP2002/005826 WO2002098563A1 (en) | 2001-06-05 | 2002-05-28 | Process for the production of catalysts with improved accessibility |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004528180A JP2004528180A (ja) | 2004-09-16 |
| JP2004528180A5 JP2004528180A5 (enExample) | 2006-01-05 |
| JP4307244B2 true JP4307244B2 (ja) | 2009-08-05 |
Family
ID=8180423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003501595A Expired - Lifetime JP4307244B2 (ja) | 2001-06-05 | 2002-05-28 | 改良されたアクセシビリティを有する触媒の製造方法 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6930067B2 (enExample) |
| EP (2) | EP1264635A1 (enExample) |
| JP (1) | JP4307244B2 (enExample) |
| KR (1) | KR100931747B1 (enExample) |
| CN (1) | CN1268431C (enExample) |
| AT (1) | ATE300355T1 (enExample) |
| BR (1) | BR0210173A (enExample) |
| CA (1) | CA2449325C (enExample) |
| DE (1) | DE60205245T2 (enExample) |
| DK (1) | DK1392433T3 (enExample) |
| ES (1) | ES2247361T3 (enExample) |
| WO (1) | WO2002098563A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6887457B2 (en) | 2002-08-28 | 2005-05-03 | Akzo Nobel N.V. | Process for the preparation of catalysts comprising a pentasil-type zeolite |
| KR20050085754A (ko) * | 2002-12-18 | 2005-08-29 | 알베마를 네덜란드 비.브이. | 촉매 미소구체를 제조하는 방법 |
| EP1682633A1 (en) * | 2003-10-15 | 2006-07-26 | Albemarle Netherlands B.V. | Composition for reducing nox emissions in fcc regeneration process |
| EP1732679B1 (en) * | 2003-12-05 | 2012-03-07 | Intercat, Inc. | Method for reducing SOx, NOx, and CO emissions from a fluid stream |
| US8381738B2 (en) * | 2003-12-22 | 2013-02-26 | Philip Morris Usa Inc. | Composite materials and their use in smoking articles |
| JP2006142273A (ja) * | 2004-11-24 | 2006-06-08 | Catalysts & Chem Ind Co Ltd | 炭化水素流動接触分解用触媒組成物の製造方法 |
| CN101115560B (zh) * | 2004-12-21 | 2012-09-19 | 雅宝荷兰有限责任公司 | 耐磨催化剂及其制备方法和应用 |
| WO2006067154A1 (en) * | 2004-12-21 | 2006-06-29 | Albemarle Netherlands Bv | Fcc catalyst, its preparation and use |
| US20060277819A1 (en) * | 2005-06-13 | 2006-12-14 | Puri Suresh K | Synergistic deposit control additive composition for diesel fuel and process thereof |
| US8222180B2 (en) * | 2005-08-01 | 2012-07-17 | Indian Oil Corporation Limited | Adsorbent composition for removal of refractory sulphur compounds from refinery streams and process thereof |
| CA2618039C (en) * | 2005-10-07 | 2014-04-08 | Sk Energy Co., Ltd. | Hydrothermally stable microporous molecular sieve catalyst and preparation method thereof |
| US7517827B2 (en) * | 2006-02-27 | 2009-04-14 | Indian Oil Company Ltd | Process for preparation of liquefied petroleum gas selective cracking catalyst |
| CA2539231C (en) * | 2006-03-10 | 2013-08-13 | Baojian Shen | Catalyst composition for treating heavy feedstocks |
| WO2008021774A1 (en) * | 2006-08-07 | 2008-02-21 | Intercat Equipment, Inc. | Vacuum powered addition system |
| US7605333B2 (en) * | 2006-08-07 | 2009-10-20 | Intercat Equipment, Inc. | Vacuum powered addition system |
| US7560078B2 (en) * | 2006-08-07 | 2009-07-14 | Intercat Equipment, Inc. | Vacuum powered addition system |
| US7815867B2 (en) * | 2006-08-07 | 2010-10-19 | Intercat Equipment, Inc. | Smart addition system |
| CO5930068A1 (es) * | 2006-12-06 | 2008-06-27 | Ecopetrol Sa | Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso |
| JP4859766B2 (ja) * | 2007-06-22 | 2012-01-25 | 日揮触媒化成株式会社 | 流動接触分解触媒の製造方法 |
| US8097213B2 (en) * | 2007-10-24 | 2012-01-17 | Intercat Equipment, Inc. | Calibration system, material delivery system, and methods for such delivery and calibration |
| BRPI0820132A2 (pt) * | 2007-12-20 | 2015-05-12 | Grace W R & Co | Processo de preparação composições inorganicas resistente a altos atritos e composições preparadas do mesmo |
| US8084384B2 (en) * | 2008-10-03 | 2011-12-27 | Chevron U.S.A. Inc. | Magnesium aluminosilicate clays—synthesis and catalysis |
| US10005072B2 (en) | 2012-07-23 | 2018-06-26 | W. R. Grace & Co.-Conn | High matrix surface area catalytic cracking catalyst stabilized with magnesium and silica |
| US9993810B2 (en) | 2012-07-23 | 2018-06-12 | W. R. Grace & Co.-Conn | Silica sol bound catalytic cracking catalyst stabilized with magnesium |
| US10173206B2 (en) * | 2012-12-21 | 2019-01-08 | Albemarle Europe Sprl | Modified Y-zeolite/ZSM-5 catalyst for increased propylene production |
| RU2749420C2 (ru) | 2016-08-01 | 2021-06-09 | В.Р. Грейс Энд Ко.-Конн. | Способ пептизации оксида алюминия для псевдоожижаемых катализаторов |
| EP3493903A1 (en) | 2016-08-04 | 2019-06-12 | Albemarle Corporation | Fcc catalyst with more than one silica, its preparation and use |
| JP2021510623A (ja) * | 2018-01-12 | 2021-04-30 | アルベマール コーポレーション | 向上されたメソ多孔率を有するfcc触媒、その調製及び使用 |
| EP3737499A1 (en) | 2018-01-12 | 2020-11-18 | Albemarle Corporation | Fcc catalyst prepared by a process involving more than one silica material |
| US12024878B2 (en) | 2018-08-10 | 2024-07-02 | OceanLink USA, Inc. | Waterproofing membrane system and method |
| CN116406315A (zh) | 2020-10-30 | 2023-07-07 | 雅宝公司 | 具有增加的污染物耐受性的基本上不含粘土的fcc催化剂、其制备和用途 |
| CN114762832B (zh) * | 2021-01-12 | 2023-12-08 | 洛阳市科创石化科技开发有限公司 | 一种用于苯与碳四烯烃烷基化生产混合丙苯的催化剂的制备方法及应用 |
| JP2024526605A (ja) | 2021-06-30 | 2024-07-19 | アルベマール コーポレーション | 超安定ゼオライト及び遷移アルミナを有するfcc触媒及びその使用 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB489769A (en) | 1937-01-25 | 1938-08-03 | Ig Farbenindustrie Ag | Improvements in the manufacture and production of water-soluble basic aluminium compounds |
| US3939058A (en) | 1968-07-31 | 1976-02-17 | Mobil Oil Corporation | Method for fluid cracking with a composite catalyst |
| CA967136A (en) | 1969-07-28 | 1975-05-06 | Apparao T. Lengade | Hydrocarbon conversion catalyst |
| US3867308A (en) * | 1973-12-10 | 1975-02-18 | Grace W R & Co | Process for preparing a petroleum cracking catalyst |
| US3972835A (en) * | 1974-04-23 | 1976-08-03 | W. R. Grace & Co. | Fluid cracking catalyst based on silica sol matrix |
| US4176090A (en) | 1975-11-18 | 1979-11-27 | W. R. Grace & Co. | Pillared interlayered clay materials useful as catalysts and sorbents |
| US4126579A (en) * | 1977-03-22 | 1978-11-21 | W. R. Grace & Co. | Hydrocarbon conversion catalyst manufacture |
| US4332699A (en) * | 1980-07-10 | 1982-06-01 | W. R. Grace & Co. | Catalyst preparation |
| US4458023A (en) | 1981-08-10 | 1984-07-03 | W. R. Grace & Co. | Catalyst manufacture |
| US4843052A (en) * | 1982-05-21 | 1989-06-27 | W. R. Grace & Co.-Conn. | Acid-reacted metakaolin catalyst and catalyst support compositions |
| US4547487A (en) * | 1983-05-19 | 1985-10-15 | Gulf Research & Development Company | Process for preparing catalysts |
| JPS6034733A (ja) * | 1983-08-04 | 1985-02-22 | Nikki Universal Co Ltd | アルミナ触媒担体の製造法 |
| US4537866A (en) * | 1984-03-29 | 1985-08-27 | Uop Inc. | Method of preparing silicate composition |
| EP0358261B1 (en) * | 1988-09-06 | 1994-04-13 | Petroleo Brasileiro S.A. - Petrobras | Kaolin containing fluid cracking catalyst |
| GB8925979D0 (en) * | 1989-11-16 | 1990-01-04 | Shell Int Research | Process for the preparation of extrudates,extrudates,and use of the extrudates |
| US5081815A (en) * | 1990-07-16 | 1992-01-21 | Carnell Joe W | Mechanized shingle applying apparatus |
| US5366948A (en) * | 1991-03-12 | 1994-11-22 | Mobil Oil Corp. | Catalyst and catalytic conversion therewith |
| US5190902A (en) * | 1992-06-04 | 1993-03-02 | Demmel Edward J | Method for producing attrition-resistant catalyst binders |
| WO1996009890A1 (en) | 1994-09-26 | 1996-04-04 | Thiele Kaolin Company | Cracking catalyst and process for preparing same |
| US5521133A (en) * | 1994-11-29 | 1996-05-28 | Engelhard Corporation | Phosphorus bound porous microspheres |
| US6613710B2 (en) * | 2001-09-25 | 2003-09-02 | Indian Oil Corporation Limited | Process for preparation of bi-functional fluid catalytic cracking catalyst composition |
-
2001
- 2001-06-05 EP EP01202146A patent/EP1264635A1/en not_active Withdrawn
-
2002
- 2002-05-28 BR BR0210173-4A patent/BR0210173A/pt not_active IP Right Cessation
- 2002-05-28 ES ES02754593T patent/ES2247361T3/es not_active Expired - Lifetime
- 2002-05-28 DE DE60205245T patent/DE60205245T2/de not_active Expired - Lifetime
- 2002-05-28 KR KR1020037015878A patent/KR100931747B1/ko not_active Expired - Lifetime
- 2002-05-28 AT AT02754593T patent/ATE300355T1/de not_active IP Right Cessation
- 2002-05-28 JP JP2003501595A patent/JP4307244B2/ja not_active Expired - Lifetime
- 2002-05-28 CA CA2449325A patent/CA2449325C/en not_active Expired - Lifetime
- 2002-05-28 CN CNB028112628A patent/CN1268431C/zh not_active Expired - Lifetime
- 2002-05-28 WO PCT/EP2002/005826 patent/WO2002098563A1/en not_active Ceased
- 2002-05-28 DK DK02754593T patent/DK1392433T3/da active
- 2002-05-28 EP EP02754593A patent/EP1392433B1/en not_active Expired - Lifetime
- 2002-06-04 US US10/161,865 patent/US6930067B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DK1392433T3 (da) | 2005-10-24 |
| DE60205245D1 (de) | 2005-09-01 |
| JP2004528180A (ja) | 2004-09-16 |
| EP1392433B1 (en) | 2005-07-27 |
| CN1512914A (zh) | 2004-07-14 |
| KR20050022862A (ko) | 2005-03-08 |
| ATE300355T1 (de) | 2005-08-15 |
| EP1264635A1 (en) | 2002-12-11 |
| KR100931747B1 (ko) | 2009-12-14 |
| ES2247361T3 (es) | 2006-03-01 |
| DE60205245T2 (de) | 2006-05-24 |
| WO2002098563A1 (en) | 2002-12-12 |
| EP1392433A1 (en) | 2004-03-03 |
| BR0210173A (pt) | 2004-04-27 |
| CA2449325C (en) | 2011-02-08 |
| US6930067B2 (en) | 2005-08-16 |
| US20030027713A1 (en) | 2003-02-06 |
| CA2449325A1 (en) | 2002-12-12 |
| CN1268431C (zh) | 2006-08-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4307244B2 (ja) | 改良されたアクセシビリティを有する触媒の製造方法 | |
| US6673235B2 (en) | FCC catalysts for feeds containing nickel and vanadium | |
| US9381502B2 (en) | FCC catalyst, its preparation and use | |
| JP5255844B2 (ja) | 触媒、これらの製造方法およびこれらの使用 | |
| EP0108610A2 (en) | Method for preparing a zeolite-containing catalyst | |
| US11254878B2 (en) | FCC catalyst having alumina derived from crystalline boehmite | |
| KR20070001987A (ko) | 구조적으로 강화된 크래킹 촉매 | |
| JP2019141845A (ja) | 優れた耐摩耗性を有するメソポーラスfcc触媒 | |
| JP3949778B2 (ja) | 接触分解触媒 | |
| JP7080217B2 (ja) | 複数のシリカを有するfcc触媒、その調製及び使用 | |
| CN101238198A (zh) | 掺杂金属的混合金属氧化物、其制备方法及其作为催化剂组合物的应用 | |
| JP2005169215A (ja) | 炭化水素流動接触分解用触媒組成物の製造方法およびその製造装置 | |
| JP2021511200A (ja) | 1を超えるシリカ材料が関与するプロセスによって調製されるfcc触媒 | |
| JP4167123B2 (ja) | 炭化水素流動接触分解用触媒組成物およびそれを用いた重質炭化水素の流動接触分解法 | |
| RU2780317C2 (ru) | Fcc-катализатор, содержащий оксид алюминия, полученный из кристаллического боемита |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20050530 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20050602 |
|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20051228 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080523 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20080825 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20080901 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20080924 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20081001 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20081022 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20090403 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20090428 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4307244 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120515 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120515 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130515 Year of fee payment: 4 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140515 Year of fee payment: 5 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |