JP4228124B2 - シロキサン系のためのｕｖ−安定化剤 - Google Patents
シロキサン系のためのｕｖ−安定化剤 Download PDFInfo
- Publication number
- JP4228124B2 JP4228124B2 JP50143499A JP50143499A JP4228124B2 JP 4228124 B2 JP4228124 B2 JP 4228124B2 JP 50143499 A JP50143499 A JP 50143499A JP 50143499 A JP50143499 A JP 50143499A JP 4228124 B2 JP4228124 B2 JP 4228124B2
- Authority
- JP
- Japan
- Prior art keywords
- coating material
- hydroxybenztriazole
- siloxane coating
- general formula
- stabilizer mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 title claims description 27
- 239000012963 UV stabilizer Substances 0.000 title claims description 9
- 238000000576 coating method Methods 0.000 claims description 39
- 239000011248 coating agent Substances 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 29
- 229920000515 polycarbonate Polymers 0.000 claims description 21
- 239000004417 polycarbonate Substances 0.000 claims description 21
- JMTMSDXUXJISAY-UHFFFAOYSA-N 2H-benzotriazol-4-ol Chemical compound OC1=CC=CC2=C1N=NN2 JMTMSDXUXJISAY-UHFFFAOYSA-N 0.000 claims description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 11
- 229910000077 silane Inorganic materials 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 9
- 229920001169 thermoplastic Polymers 0.000 claims description 8
- 239000004416 thermosoftening plastic Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 150000001247 metal acetylides Chemical class 0.000 claims description 2
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims 3
- 239000000376 reactant Substances 0.000 claims 1
- 239000004922 lacquer Substances 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- 150000002118 epoxides Chemical group 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 0 C*c1cc(*C(O)=O)cc(-[n]2nc(cccc3)c3n2)c1O Chemical compound C*c1cc(*C(O)=O)cc(-[n]2nc(cccc3)c3n2)c1O 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 230000003678 scratch resistant effect Effects 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 229910001593 boehmite Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- FBMPWJWZZAAOHP-UHFFFAOYSA-N 4-[3-(benzotriazol-2-yl)-5-cyclohexyl-4-hydroxyphenyl]butanoic acid Chemical compound OC=1C(N2N=C3C=CC=CC3=N2)=CC(CCCC(=O)O)=CC=1C1CCCCC1 FBMPWJWZZAAOHP-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- -1 Poly (Ester Carbonate Chemical class 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000005297 pyrex Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- MVRPPTGLVPEMPI-UHFFFAOYSA-N 2-cyclohexylphenol Chemical compound OC1=CC=CC=C1C1CCCCC1 MVRPPTGLVPEMPI-UHFFFAOYSA-N 0.000 description 1
- DPJCXCZTLWNFOH-UHFFFAOYSA-N 2-nitroaniline Chemical compound NC1=CC=CC=C1[N+]([O-])=O DPJCXCZTLWNFOH-UHFFFAOYSA-N 0.000 description 1
- OYGYNUPKLMDVHM-UHFFFAOYSA-N 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(N2N=C3C=CC=CC3=N2)=C1O OYGYNUPKLMDVHM-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- DQAJDDUCDILVLR-UHFFFAOYSA-N aluminum 2,2,2-tributoxyethanolate Chemical compound [Al+3].CCCCOC(C[O-])(OCCCC)OCCCC.CCCCOC(C[O-])(OCCCC)OCCCC.CCCCOC(C[O-])(OCCCC)OCCCC DQAJDDUCDILVLR-UHFFFAOYSA-N 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 125000005586 carbonic acid group Chemical group 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000006120 scratch resistant coating Substances 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 229920006352 transparent thermoplastic Polymers 0.000 description 1
- UTPQWRVOSYXUHO-UHFFFAOYSA-N trimethoxy-[1-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(C(C)[Si](OC)(OC)OC)CCC2OC21 UTPQWRVOSYXUHO-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19724397A DE19724397A1 (de) | 1997-06-10 | 1997-06-10 | UV-Stabilisatoren für Siloxan-Systeme |
| DE19724397.5 | 1997-06-10 | ||
| PCT/EP1998/003157 WO1998056853A1 (de) | 1997-06-10 | 1998-05-28 | Uv-stabilisatoren für siloxan-systeme |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002511894A JP2002511894A (ja) | 2002-04-16 |
| JP2002511894A5 JP2002511894A5 (enExample) | 2005-12-22 |
| JP4228124B2 true JP4228124B2 (ja) | 2009-02-25 |
Family
ID=7832017
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50143499A Expired - Fee Related JP4228124B2 (ja) | 1997-06-10 | 1998-05-28 | シロキサン系のためのｕｖ−安定化剤 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6306512B1 (enExample) |
| EP (1) | EP0988340B1 (enExample) |
| JP (1) | JP4228124B2 (enExample) |
| KR (1) | KR100541298B1 (enExample) |
| CN (1) | CN1124309C (enExample) |
| AU (1) | AU7916398A (enExample) |
| BR (1) | BR9810434A (enExample) |
| CA (1) | CA2293603C (enExample) |
| DE (2) | DE19724397A1 (enExample) |
| DK (1) | DK0988340T3 (enExample) |
| ES (1) | ES2167903T3 (enExample) |
| ID (1) | ID23428A (enExample) |
| IL (1) | IL132795A0 (enExample) |
| TW (1) | TW459011B (enExample) |
| WO (1) | WO1998056853A1 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19858998A1 (de) * | 1998-12-21 | 2000-06-29 | Bayer Ag | Cerdioxid enthaltende Beschichtungszusammensetzungen |
| JP2001079491A (ja) * | 1999-09-10 | 2001-03-27 | Koito Mfg Co Ltd | 塗膜形成方法及び該方法で形成された車両用灯具 |
| US6620509B1 (en) | 2002-04-22 | 2003-09-16 | Mitsubishi Gas Chemical Company, Inc. | Transparent resin laminate and molded article used the same |
| US7056916B2 (en) | 2002-11-15 | 2006-06-06 | Boehringer Ingelheim Pharma Gmbh & Co. Kg | Medicaments for the treatment of chronic obstructive pulmonary disease |
| US7220742B2 (en) | 2004-05-14 | 2007-05-22 | Boehringer Ingelheim International Gmbh | Enantiomerically pure beta agonists, process for the manufacture thereof and use thereof as medicaments |
| US7642303B2 (en) * | 2004-10-15 | 2010-01-05 | Shakely Thomas L | Thermoplastic articles for packaging UV sensitive materials, processes for the articles production and use and novel UV absorbers |
| EP1805255A1 (en) | 2004-10-25 | 2007-07-11 | Ciba Specialty Chemicals Holding Inc. | Functionalized nanoparticles |
| DE102006000040B4 (de) * | 2005-02-01 | 2008-04-03 | Kabushiki Kaisha Toyota Jidoshokki, Kariya | Beschichtetes Element |
| JP4730886B2 (ja) * | 2005-06-01 | 2011-07-20 | 信越化学工業株式会社 | 紫外線吸収性基含有オルガノポリシロキサン、該ポリシロキサンの製造方法、及び該ポリシロキサンを配合してなる処理剤 |
| US8089795B2 (en) * | 2006-02-09 | 2012-01-03 | Google Inc. | Memory module with memory stack and interface with enhanced capabilities |
| CN101208316B (zh) * | 2005-08-15 | 2012-05-09 | 贝林格尔·英格海姆国际有限公司 | 制备β-模拟物的方法 |
| WO2007099784A1 (ja) * | 2006-02-24 | 2007-09-07 | Idemitsu Kosan Co., Ltd. | コーティング組成物、硬化膜及び樹脂積層体 |
| WO2008022952A1 (en) | 2006-08-24 | 2008-02-28 | Ciba Holding Inc. | Uv-dosis indicators |
| CA2693892A1 (en) | 2007-07-18 | 2009-01-22 | Jonathan Campbell | Laser-sensitive coating formulation |
| RU2011120235A (ru) | 2008-10-23 | 2012-11-27 | Дейталейз Лимитед | Теплопоглощающие добавки |
| WO2010049282A1 (en) | 2008-10-27 | 2010-05-06 | Basf Se | Coating composition for marking substrates |
| BR112012000425A2 (pt) | 2009-07-07 | 2018-04-10 | Basf Se | particulas de solução sólida de bronze de potássio-césio-tungstênio, processo para a preparação de partículas de solução sólida de bronze de potássio-césio-tungstênio, potássio-césio-tungstênio. |
| PL3517541T3 (pl) | 2012-05-08 | 2020-12-28 | Nicox Ophthalmics, Inc. | Postać polimorficzna propionianu flutykazonu |
| CN104562660B (zh) * | 2013-10-11 | 2018-06-15 | 中国石油化工股份有限公司 | 基于苯并三唑类紫外线吸收剂的聚酯纤维及其制备方法 |
| CN104562302B (zh) * | 2013-10-11 | 2018-05-29 | 中国石油化工股份有限公司 | 一种抗紫外老化聚酯纤维及其制备方法 |
| CN105683313B (zh) | 2013-10-29 | 2019-09-17 | 巴斯夫欧洲公司 | 2-(2-羟苯基)苯并三唑化合物在涂料中作为uv吸收剂的用途 |
| CN105802238B (zh) * | 2014-12-31 | 2019-06-25 | 埃肯有机硅（上海）有限公司 | 可固化的聚硅氧烷组合物 |
| CN107345369A (zh) * | 2017-06-26 | 2017-11-14 | 苏州威尔德工贸有限公司 | 一种蚕丝织物用抗紫外线染色剂 |
| TW201942312A (zh) | 2018-04-04 | 2019-11-01 | 德商巴地斯顏料化工廠 | 紫外線輻射吸收聚合物組合物(uvrap)作為用於非生物及非角蛋白材料之塗料之uv吸收劑的用途 |
| CN108486899B (zh) * | 2018-04-21 | 2020-08-07 | 上海鑫妙纺织助剂有限公司 | 一种织物柔软整理剂及其制备方法 |
Family Cites Families (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2946701A (en) | 1957-11-12 | 1960-07-26 | Dow Corning | Method of treating glass with epoxysilanes and their epoxy-amine adducts, and the articles made thereby |
| NL149226B (nl) | 1971-06-30 | 1976-04-15 | Monsanto Co | Werkwijze voor de bereiding van chelaatvormende polycarbonzuren en werkwijze voor de bereiding van wasmiddelen die ze bevatten. |
| US3790527A (en) | 1972-07-21 | 1974-02-05 | Gen Electric | Flexible tack free silicone resins |
| US4051161A (en) | 1972-09-15 | 1977-09-27 | E. I. Du Pont De Nemours And Company | Ultraviolet screening agents and coating materials containing organosilane ester groups |
| US3887514A (en) | 1974-01-02 | 1975-06-03 | Gen Electric | Bodied organopolysiloxanes and process therefor |
| US4006271A (en) | 1976-01-28 | 1977-02-01 | Itek Corporation | Abrasion resistant coating for polycarbonate substrates |
| JPS53111336A (en) * | 1977-03-11 | 1978-09-28 | Toray Ind Inc | Coating composition |
| CA1192103A (en) | 1977-08-08 | 1985-08-20 | Nazir A. Memon | Process for applying a silicone or siloxane-based abrasion resistant coating to a polycarbonate substrate, and coated articles |
| US4243720A (en) | 1978-11-01 | 1981-01-06 | General Electric Company | Silicone coated abrasion resistant polycarbonate article |
| US4476281A (en) | 1978-11-30 | 1984-10-09 | General Electric Company | Silicone resin coating composition |
| US4299746A (en) | 1978-11-30 | 1981-11-10 | General Electric Company | Silicone resin coating composition |
| US4324712A (en) | 1978-11-30 | 1982-04-13 | General Electric Company | Silicone resin coating composition |
| US4413088A (en) | 1978-11-30 | 1983-11-01 | General Electric Co. | Silicone resin coating composition especially suited for primerless adhesion to cast acrylics |
| US4277287A (en) | 1978-11-30 | 1981-07-07 | General Electric Company | Silicone resin coating composition |
| JPS55110166A (en) | 1979-02-16 | 1980-08-25 | Ito Kogaku Kogyo Kk | Coating composition |
| DE2914427A1 (de) | 1979-04-10 | 1980-10-23 | Bayer Ag | Beschichtung fuer thermoplasten |
| GB2047721A (en) | 1979-04-16 | 1980-12-03 | Dow Corning | Coating composition |
| US4368235A (en) | 1980-01-18 | 1983-01-11 | General Electric Co. | Silicone resin coating composition |
| US4278804A (en) | 1980-05-30 | 1981-07-14 | General Electric Company | Ultraviolet light absorbing agents and compositions and articles containing same |
| US4374674A (en) | 1980-05-30 | 1983-02-22 | General Electric Co. | Ultraviolet light absorbing agents and compositions and articles containing same |
| US4419405A (en) | 1981-01-15 | 1983-12-06 | General Electric Company | Ultraviolet light absorbing agents and compositions and articles containing same |
| US4853471A (en) * | 1981-01-23 | 1989-08-01 | Ciba-Geigy Corporation | 2-(2-Hydroxyphenyl)-benztriazoles, their use as UV-absorbers and their preparation |
| DE3134777A1 (de) | 1981-09-02 | 1983-03-10 | Röhm GmbH, 6100 Darmstadt | Wasserhaltige beschichtungsmittel auf silikonharzbasis |
| DE3135241A1 (de) | 1981-09-05 | 1983-03-17 | Röhm GmbH, 6100 Darmstadt | Wasserhaltige beschichtungsmittel auf silikonharzbasis |
| DE3151350A1 (de) | 1981-12-24 | 1983-07-07 | Bayer Ag, 5090 Leverkusen | Mit einem 3-schichtueberzug ausgeruestete kunststofformkoerper und ein verfahren zur herstellung der ausruestung |
| US4525426A (en) | 1982-04-30 | 1985-06-25 | General Electric Company | Ultraviolet light absorbing agents, method for making, compositions, and articles containing same |
| US4495360A (en) | 1982-04-30 | 1985-01-22 | General Electric Company | Ultraviolet light absorbing agents, method for making, compositions and articles containing same |
| DE3407087C2 (de) | 1984-02-27 | 1994-07-07 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 8000 München | Verfahren und Lack zur Herstellung von kratzfesten Beschichtungen |
| US4587169A (en) * | 1984-08-17 | 1986-05-06 | Minnesota Mining And Manufacturing Company | Abrasion resistant coatings |
| US4624870A (en) | 1984-11-14 | 1986-11-25 | General Electric Company | Sodium free silicone resin coating compositions |
| US4680232A (en) * | 1986-01-02 | 1987-07-14 | General Electric Company | Abrasion and UV resistant coating compositions |
| DE3706714A1 (de) | 1987-03-02 | 1988-09-15 | Fraunhofer Ges Forschung | Anorganische polykondensate mit eingebauten organischen polymeren |
| US4957818A (en) * | 1987-08-14 | 1990-09-18 | Mitsubishi Kasei Vinyl Company | Molded synthetic resin product |
| US4859759A (en) * | 1988-04-14 | 1989-08-22 | Kimberly-Clark Corporation | Siloxane containing benzotriazolyl/tetraalkylpiperidyl substituent |
| DE3836815A1 (de) | 1988-10-28 | 1990-07-26 | Hofmann Klaus Dipl Chem | Verfahren und zusammensetzung zur herstellung von kratzfesten materialien, insbesondere beschichtungen mit verbesserter elastizitaet und haftung |
| DE3917535A1 (de) | 1989-05-30 | 1990-12-06 | Fraunhofer Ges Forschung | Verfahren zur herstellung kratzfester materialien und zusammensetzung hierfuer |
| DE4011045A1 (de) | 1990-04-05 | 1991-10-10 | Fraunhofer Ges Forschung | Verfahren zum beschichten von kunststoffsubstraten und lack zur verwendung in diesem verfahren |
| DE4020316B4 (de) | 1990-06-26 | 2004-07-08 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung eines Lacks und dessen Verwendung |
| US5371138A (en) * | 1990-07-24 | 1994-12-06 | Tru Vue, Inc. | Ultraviolet blocking polysiloxane resin and process for making the same |
| DE4122743C1 (enExample) | 1991-07-10 | 1992-11-26 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung Ev, 8000 Muenchen, De | |
| JP3560243B2 (ja) | 1992-02-03 | 2004-09-02 | ヘキスト・セラニーズ・コーポレーション | 紫外線安定剤，酸化防止剤および着色剤である４´−ヒドロキシアセトフェノン，４−ヒドロキシスチレン，１，１，１−トリス（４´−ヒドロキシフェニル）エタン，および１，３，５−トリス（４´−ヒドロキシフェニル）ベンゼンの誘導体 |
| DE4338361A1 (de) | 1993-11-10 | 1995-05-11 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung von Zusammensetzungen auf der Basis von Epoxidgruppen-haltigen Silanen |
| JP3524617B2 (ja) * | 1995-03-13 | 2004-05-10 | 新日本石油株式会社 | 紫外線吸収剤及びコーティング材料 |
| EP0913446B1 (en) * | 1996-06-27 | 2008-08-20 | Nippon Mitsubishi Oil Corporation | Ultraviolet absorbing material and ultraviolet absorbing plate |
| US6001163A (en) * | 1997-04-17 | 1999-12-14 | Sdc Coatings, Inc. | Composition for providing an abrasion resistant coating on a substrate |
-
1997
- 1997-06-10 DE DE19724397A patent/DE19724397A1/de not_active Ceased
-
1998
- 1998-05-15 TW TW087107508A patent/TW459011B/zh active
- 1998-05-28 CA CA002293603A patent/CA2293603C/en not_active Expired - Fee Related
- 1998-05-28 ES ES98929392T patent/ES2167903T3/es not_active Expired - Lifetime
- 1998-05-28 BR BR9810434-9A patent/BR9810434A/pt not_active IP Right Cessation
- 1998-05-28 DK DK98929392T patent/DK0988340T3/da active
- 1998-05-28 WO PCT/EP1998/003157 patent/WO1998056853A1/de not_active Ceased
- 1998-05-28 US US09/445,113 patent/US6306512B1/en not_active Expired - Fee Related
- 1998-05-28 CN CN98806105A patent/CN1124309C/zh not_active Expired - Fee Related
- 1998-05-28 ID IDW991375A patent/ID23428A/id unknown
- 1998-05-28 DE DE59802740T patent/DE59802740D1/de not_active Expired - Fee Related
- 1998-05-28 KR KR1019997011582A patent/KR100541298B1/ko not_active Expired - Fee Related
- 1998-05-28 JP JP50143499A patent/JP4228124B2/ja not_active Expired - Fee Related
- 1998-05-28 AU AU79163/98A patent/AU7916398A/en not_active Abandoned
- 1998-05-28 IL IL13279598A patent/IL132795A0/xx unknown
- 1998-05-28 EP EP98929392A patent/EP0988340B1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DK0988340T3 (da) | 2002-05-21 |
| CN1259973A (zh) | 2000-07-12 |
| CN1124309C (zh) | 2003-10-15 |
| EP0988340B1 (de) | 2001-11-21 |
| US20020002262A1 (en) | 2002-01-03 |
| JP2002511894A (ja) | 2002-04-16 |
| KR20010013575A (ko) | 2001-02-26 |
| EP0988340A1 (de) | 2000-03-29 |
| ID23428A (id) | 2000-04-20 |
| US6306512B1 (en) | 2001-10-23 |
| DE59802740D1 (de) | 2002-02-21 |
| TW459011B (en) | 2001-10-11 |
| BR9810434A (pt) | 2000-09-19 |
| ES2167903T3 (es) | 2002-05-16 |
| DE19724397A1 (de) | 1999-01-14 |
| IL132795A0 (en) | 2001-03-19 |
| CA2293603C (en) | 2007-07-31 |
| KR100541298B1 (ko) | 2006-01-12 |
| AU7916398A (en) | 1998-12-30 |
| CA2293603A1 (en) | 1998-12-17 |
| WO1998056853A1 (de) | 1998-12-17 |
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