JP4197054B2 - 酸化マンガンリチウムスピネルを処理する方法 - Google Patents
酸化マンガンリチウムスピネルを処理する方法 Download PDFInfo
- Publication number
- JP4197054B2 JP4197054B2 JP50608798A JP50608798A JP4197054B2 JP 4197054 B2 JP4197054 B2 JP 4197054B2 JP 50608798 A JP50608798 A JP 50608798A JP 50608798 A JP50608798 A JP 50608798A JP 4197054 B2 JP4197054 B2 JP 4197054B2
- Authority
- JP
- Japan
- Prior art keywords
- spinel
- hydroxide
- manganese oxide
- lithium
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910052596 spinel Inorganic materials 0.000 title claims description 263
- 239000011029 spinel Substances 0.000 title claims description 263
- 238000000034 method Methods 0.000 title claims description 28
- QEXMICRJPVUPSN-UHFFFAOYSA-N lithium manganese(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Li+] QEXMICRJPVUPSN-UHFFFAOYSA-N 0.000 title description 9
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical group [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 186
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 158
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 82
- 239000001569 carbon dioxide Substances 0.000 claims description 79
- 239000002245 particle Substances 0.000 claims description 74
- 239000000843 powder Substances 0.000 claims description 70
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 69
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 27
- 239000011572 manganese Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 21
- 229910002102 lithium manganese oxide Inorganic materials 0.000 claims description 21
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 claims description 19
- 229910001416 lithium ion Inorganic materials 0.000 claims description 18
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 16
- -1 alkaline earth metal carbonate Chemical class 0.000 claims description 14
- 229910052744 lithium Inorganic materials 0.000 claims description 14
- 229910052723 transition metal Inorganic materials 0.000 claims description 13
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 9
- 150000008044 alkali metal hydroxides Chemical group 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 150000003624 transition metals Chemical class 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 150000004679 hydroxides Chemical class 0.000 claims description 7
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 claims description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical group [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims 2
- 150000008041 alkali metal carbonates Chemical class 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 229910000299 transition metal carbonate Inorganic materials 0.000 claims 2
- 229910052788 barium Inorganic materials 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 1
- 229910052701 rubidium Inorganic materials 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- 239000000523 sample Substances 0.000 description 50
- 239000000243 solution Substances 0.000 description 47
- 238000011282 treatment Methods 0.000 description 42
- 239000007789 gas Substances 0.000 description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 30
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- 150000003839 salts Chemical class 0.000 description 17
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 14
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 13
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 12
- 229940011182 cobalt acetate Drugs 0.000 description 12
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 150000007942 carboxylates Chemical class 0.000 description 8
- 230000002427 irreversible effect Effects 0.000 description 8
- 229910052566 spinel group Inorganic materials 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 7
- 235000011054 acetic acid Nutrition 0.000 description 7
- 229910052786 argon Inorganic materials 0.000 description 7
- 230000001351 cycling effect Effects 0.000 description 7
- 238000005562 fading Methods 0.000 description 7
- 229910052734 helium Inorganic materials 0.000 description 7
- 239000001307 helium Substances 0.000 description 7
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 7
- 229910052748 manganese Inorganic materials 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical class OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000011261 inert gas Substances 0.000 description 6
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 238000010405 reoxidation reaction Methods 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 5
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 5
- 239000003792 electrolyte Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 229910013872 LiPF Inorganic materials 0.000 description 4
- 101150058243 Lipf gene Proteins 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical class CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 239000007774 positive electrode material Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
- 239000005711 Benzoic acid Chemical class 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000001879 copper Chemical class 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000004310 lactic acid Chemical class 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 229910052808 lithium carbonate Inorganic materials 0.000 description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 2
- 229910001947 lithium oxide Inorganic materials 0.000 description 2
- 229940071125 manganese acetate Drugs 0.000 description 2
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Chemical class OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical class COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- 229910017205 LixMn2 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ISSGCAMUHKKFRI-UHFFFAOYSA-N [Mn].[Li].[Mn] Chemical compound [Mn].[Li].[Mn] ISSGCAMUHKKFRI-UHFFFAOYSA-N 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- HFDWIMBEIXDNQS-UHFFFAOYSA-L copper;diformate Chemical compound [Cu+2].[O-]C=O.[O-]C=O HFDWIMBEIXDNQS-UHFFFAOYSA-L 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(II) oxide Inorganic materials [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
- C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/30—Three-dimensional structures
- C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/679,497 US5733685A (en) | 1996-07-12 | 1996-07-12 | Method of treating lithium manganese oxide spinel |
| US08/757,055 US5783328A (en) | 1996-07-12 | 1996-11-26 | Method of treating lithium manganese oxide spinel |
| US08/757,055 | 1996-11-26 | ||
| US08/679,497 | 1996-11-26 | ||
| PCT/US1997/011816 WO1998002930A1 (en) | 1996-07-12 | 1997-07-08 | Method of treating lithium manganese oxide spinel |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2001527686A JP2001527686A (ja) | 2001-12-25 |
| JP2001527686A5 JP2001527686A5 (enExample) | 2005-03-10 |
| JP4197054B2 true JP4197054B2 (ja) | 2008-12-17 |
Family
ID=27102255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50608798A Expired - Fee Related JP4197054B2 (ja) | 1996-07-12 | 1997-07-08 | 酸化マンガンリチウムスピネルを処理する方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5783328A (enExample) |
| EP (1) | EP0910873B1 (enExample) |
| JP (1) | JP4197054B2 (enExample) |
| CN (1) | CN1195334C (enExample) |
| AR (1) | AR007848A1 (enExample) |
| AT (1) | ATE371959T1 (enExample) |
| AU (1) | AU3596097A (enExample) |
| CA (1) | CA2259574A1 (enExample) |
| DE (1) | DE69738068T2 (enExample) |
| TW (1) | TW360988B (enExample) |
| WO (1) | WO1998002930A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101517733B1 (ko) | 2013-07-26 | 2015-05-04 | 주식회사 엘지화학 | 양극 활물질 및 이의 제조방법 |
| US9905850B2 (en) | 2013-07-26 | 2018-02-27 | Lg Chem, Ltd. | Polycrystalline lithium manganese oxide particles, preparation method thereof, and cathode active material including the same |
| US9905851B2 (en) | 2013-07-26 | 2018-02-27 | Lg Chem, Ltd. | Cathode active material and method of preparing the same |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU4706597A (en) * | 1996-10-10 | 1998-05-05 | Merck Patent Gmbh | Modified electrode material and its use |
| US6869547B2 (en) * | 1996-12-09 | 2005-03-22 | Valence Technology, Inc. | Stabilized electrochemical cell active material |
| US6183718B1 (en) * | 1996-12-09 | 2001-02-06 | Valence Technology, Inc. | Method of making stabilized electrochemical cell active material of lithium manganese oxide |
| CN1246203A (zh) | 1997-01-31 | 2000-03-01 | 默克专利股份有限公司 | 新型二氧化锰电极、其制备方法和用途 |
| JP4185191B2 (ja) * | 1998-07-31 | 2008-11-26 | 松下電器産業株式会社 | スピネル型マンガン酸リチウムの製造方法 |
| US6322744B1 (en) | 1999-02-17 | 2001-11-27 | Valence Technology, Inc. | Lithium manganese oxide-based active material |
| KR100307160B1 (ko) * | 1999-03-06 | 2001-09-26 | 김순택 | 리튬 이차 전지용 양극 활물질 및 그 제조 방법 |
| US6506518B1 (en) * | 1999-04-27 | 2003-01-14 | Shin-Kobe Electric Machinery Co., Ltd. | Lithium secondary battery |
| US6468695B1 (en) * | 1999-08-18 | 2002-10-22 | Valence Technology Inc. | Active material having extended cycle life |
| US6455200B1 (en) | 1999-09-02 | 2002-09-24 | Illinois Institute Of Technology | Flame-retardant additive for li-ion batteries |
| US6730435B1 (en) * | 1999-10-26 | 2004-05-04 | Sumitomo Chemical Company, Limited | Active material for non-aqueous secondary battery, and non-aqueous secondary battery using the same |
| DE10014884A1 (de) | 2000-03-24 | 2001-09-27 | Merck Patent Gmbh | Beschichtete Lithium-Mischoxid-Partikel und ein Verfahren zu deren Herstellung |
| DE10016024A1 (de) | 2000-03-31 | 2001-10-04 | Merck Patent Gmbh | Aktives Anodenmaterial in elektrochemischen Zellen und Verfahren zu deren Herstellung |
| CN1263182C (zh) | 2000-09-25 | 2006-07-05 | 三星Sdi株式会社 | 用于可充电锂电池的正电极活性材料及其制备方法 |
| CN1269240C (zh) * | 2000-09-25 | 2006-08-09 | 三星Sdi株式会社 | 制备可充电锂电池的正极活性材料的方法 |
| US6984469B2 (en) * | 2000-09-25 | 2006-01-10 | Samsung Sdi Co., Ltd. | Positive active material for rechargeable lithium batteries and method of preparing same |
| US7138209B2 (en) * | 2000-10-09 | 2006-11-21 | Samsung Sdi Co., Ltd. | Positive active material for rechargeable lithium battery and method of preparing same |
| KR100428616B1 (ko) | 2001-01-19 | 2004-04-27 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 양극 활물질 및 그의 제조 방법 |
| US6558844B2 (en) | 2001-01-31 | 2003-05-06 | Wilmont F. Howard, Jr. | Stabilized spinel battery cathode material and methods |
| KR100728108B1 (ko) * | 2001-04-02 | 2007-06-13 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 양극 및 그의 제조 방법 |
| KR100420034B1 (ko) * | 2001-10-17 | 2004-02-25 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 양극 활물질의 제조방법 |
| JP5135664B2 (ja) * | 2003-12-05 | 2013-02-06 | 日産自動車株式会社 | 非水電解質リチウムイオン電池用正極材料およびこれを用いた電池 |
| CN1315217C (zh) * | 2004-04-22 | 2007-05-09 | 天津大学 | 针管式锂锰电池及其制造方法 |
| US7709149B2 (en) * | 2004-09-24 | 2010-05-04 | Lg Chem, Ltd. | Composite precursor for aluminum-containing lithium transition metal oxide and process for preparation of the same |
| CN1855587B (zh) * | 2005-04-28 | 2010-05-05 | 比亚迪股份有限公司 | 一种电池正极的制备方法和采用该正极的锂离子电池的制备方法 |
| JP2010177030A (ja) * | 2009-01-29 | 2010-08-12 | Nippon Chem Ind Co Ltd | リチウム系複合酸化物の表面処理剤、リチウム系複合酸化物の表面処理液、リチウムイオン二次電池用電解液、表面処理リチウムイオン二次電池用正極活物質及びその製造方法、表面処理リチウムイオン二次電池用負極活物質及びその製造方法、並びにリチウムイオン二次電池及びその製造方法 |
| US8999009B2 (en) | 2012-03-07 | 2015-04-07 | A123 Systems Llc | Surface modification of battery materials and method for making a battery |
| CN105050960A (zh) | 2013-02-01 | 2015-11-11 | 特罗诺克斯有限公司 | 改善的锂锰氧化物组合物 |
| CN105830260B (zh) * | 2013-11-29 | 2018-10-26 | 汉阳大学校产学协力团 | 用于全固态锂二次电池的活性材料，其制造方法和包含其的全固态锂二次电池 |
| CN105838895B (zh) * | 2016-05-16 | 2017-11-17 | 长沙矿冶研究院有限责任公司 | 一种从含锂富锰渣中提取锂和锰的方法 |
| CN110148712B (zh) * | 2018-02-11 | 2021-05-25 | 湖南杉杉能源科技股份有限公司 | 一种复合包覆改性的富锂锰正极材料及其制备方法 |
| US11621412B2 (en) * | 2021-03-08 | 2023-04-04 | Sk On Co., Ltd. | Cathode active material for lithium secondary battery and lithium secondary battery including the same |
| CN113321244B (zh) * | 2021-05-19 | 2022-09-20 | 上海大学 | 一种表面改性的层状氧化物正极材料的制备方法及应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2196785B (en) * | 1986-10-29 | 1990-05-23 | Sony Corp | Organic electrolyte secondary cell |
| JP3028582B2 (ja) * | 1990-10-09 | 2000-04-04 | ソニー株式会社 | 非水電解質二次電池 |
| US5266299A (en) * | 1991-01-28 | 1993-11-30 | Bell Communications Research, Inc. | Method of preparing LI1+XMN204 for use as secondary battery electrode |
| US5135732A (en) * | 1991-04-23 | 1992-08-04 | Bell Communications Research, Inc. | Method for preparation of LiMn2 O4 intercalation compounds and use thereof in secondary lithium batteries |
| JP3238954B2 (ja) * | 1992-09-25 | 2001-12-17 | 三洋電機株式会社 | 非水系二次電池 |
| GB9305440D0 (en) * | 1993-03-17 | 1993-05-05 | Dowty Electronic Components | Lithiated manganese oxide |
| GB9305457D0 (en) * | 1993-03-17 | 1993-05-05 | Dowty Electronic Components | Lithiated manganese oxide |
| US5425932A (en) * | 1993-05-19 | 1995-06-20 | Bell Communications Research, Inc. | Method for synthesis of high capacity Lix Mn2 O4 secondary battery electrode compounds |
| CA2114493C (en) * | 1994-01-28 | 1999-01-12 | Jeffrey Raymond Dahn | Method for increasing the reversible capacity of lithium transition metal oxide cathodes |
| US5820790A (en) * | 1994-11-11 | 1998-10-13 | Japan Storage Battery Co., Ltd. | Positive electrode for non-aqueous cell |
| US5597664A (en) * | 1995-09-07 | 1997-01-28 | Kerr-Mcgee Corporation | Lithium manganese oxide compound and method of preparation |
-
1996
- 1996-11-26 US US08/757,055 patent/US5783328A/en not_active Expired - Lifetime
-
1997
- 1997-07-08 WO PCT/US1997/011816 patent/WO1998002930A1/en not_active Ceased
- 1997-07-08 EP EP97932523A patent/EP0910873B1/en not_active Expired - Lifetime
- 1997-07-08 DE DE69738068T patent/DE69738068T2/de not_active Expired - Fee Related
- 1997-07-08 JP JP50608798A patent/JP4197054B2/ja not_active Expired - Fee Related
- 1997-07-08 AU AU35960/97A patent/AU3596097A/en not_active Abandoned
- 1997-07-08 CA CA002259574A patent/CA2259574A1/en not_active Abandoned
- 1997-07-08 CN CNB971970491A patent/CN1195334C/zh not_active Expired - Fee Related
- 1997-07-08 AT AT97932523T patent/ATE371959T1/de not_active IP Right Cessation
- 1997-07-11 AR ARP970103089A patent/AR007848A1/es unknown
- 1997-07-12 TW TW086109862A patent/TW360988B/zh active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101517733B1 (ko) | 2013-07-26 | 2015-05-04 | 주식회사 엘지화학 | 양극 활물질 및 이의 제조방법 |
| JP2015529958A (ja) * | 2013-07-26 | 2015-10-08 | エルジー・ケム・リミテッド | 正極活物質及びこの製造方法 |
| US9905850B2 (en) | 2013-07-26 | 2018-02-27 | Lg Chem, Ltd. | Polycrystalline lithium manganese oxide particles, preparation method thereof, and cathode active material including the same |
| US9905851B2 (en) | 2013-07-26 | 2018-02-27 | Lg Chem, Ltd. | Cathode active material and method of preparing the same |
| US9905840B2 (en) | 2013-07-26 | 2018-02-27 | Lg Chem, Ltd. | Cathode active material and method of preparing the same |
| US10236499B2 (en) | 2013-07-26 | 2019-03-19 | Lg Chem, Ltd. | Polycrystalline lithium manganese oxide particles, preparation method thereof, and cathode active material including the same |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2259574A1 (en) | 1998-01-22 |
| CN1195334C (zh) | 2005-03-30 |
| EP0910873A1 (en) | 1999-04-28 |
| ATE371959T1 (de) | 2007-09-15 |
| WO1998002930A1 (en) | 1998-01-22 |
| CN1227672A (zh) | 1999-09-01 |
| TW360988B (en) | 1999-06-11 |
| AR007848A1 (es) | 1999-11-24 |
| JP2001527686A (ja) | 2001-12-25 |
| US5783328A (en) | 1998-07-21 |
| AU3596097A (en) | 1998-02-09 |
| DE69738068D1 (de) | 2007-10-11 |
| DE69738068T2 (de) | 2008-05-21 |
| EP0910873B1 (en) | 2007-08-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4197054B2 (ja) | 酸化マンガンリチウムスピネルを処理する方法 | |
| US5733685A (en) | Method of treating lithium manganese oxide spinel | |
| JP3860542B2 (ja) | リチウム２次電池の正極活物質及びその製造方法 | |
| JP4362021B2 (ja) | リチウム二次電池用正極活物質 | |
| KR100694658B1 (ko) | 도핑 계면층 및 외막을 포함하고 있는 분말화 리튬전이금속 산화물 및 그것의 제조방법 | |
| KR102539249B1 (ko) | 리튬 이온 배터리용 캐소드 활성 물질의 제조 방법 | |
| CN108987683B (zh) | 一种碳包覆三元正极材料的制备方法 | |
| US20010016285A1 (en) | Positive active material for rechargeable lithium battery and method of preparing same | |
| JP2004536420A (ja) | 安定化スピネル電池カソード材料及び方法 | |
| JP2001043860A (ja) | リチウム二次電池用正極活物質及びその製造方法 | |
| CN111261851B (zh) | 一种锂离子电池三元正极材料及其制备方法 | |
| CN105409038A (zh) | 包覆的富锂层状氧化物及其制备 | |
| CN113247966A (zh) | 富锂锰基前驱体、正极材料及其制备方法 | |
| CN111600014A (zh) | 一种改性的高比容量高镍三元正极材料及其制备方法 | |
| Dumaz et al. | Kinetics analysis of the electro-catalyzed degradation of high potential LiNi0, 5Mn1, 5O4 active materials | |
| CN115986111B (zh) | 一种钠离子电池层状氧化物正极材料及其制备方法与应用 | |
| CN116169267A (zh) | 一种v2o5包覆的改性富锂正极材料及其制备方法和用途 | |
| MXPA99000479A (es) | Metodo de tratamiento de espinela de oxido de litio manganeso | |
| JP7788452B2 (ja) | コーティングされたカソード活物質の製造方法 | |
| EP4218066B1 (en) | METHOD FOR MANUFACTURING A COATED CATHODE ACTIVE MATERIAL | |
| WO2025139802A1 (zh) | 一种改性镍基正极材料及其制备方法和锂离子电池 | |
| MXPA97009535A (en) | Improved process for the manufacture of a lithium-manganese litificum oxide spinela |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20040701 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20040701 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080401 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080703 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20080701 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20080811 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20080826 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A712 Effective date: 20080815 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20080924 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20111010 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| LAPS | Cancellation because of no payment of annual fees |