TW360988B - Method of treating lithium manganese oxide spinel - Google Patents
Method of treating lithium manganese oxide spinelInfo
- Publication number
- TW360988B TW360988B TW086109862A TW86109862A TW360988B TW 360988 B TW360988 B TW 360988B TW 086109862 A TW086109862 A TW 086109862A TW 86109862 A TW86109862 A TW 86109862A TW 360988 B TW360988 B TW 360988B
- Authority
- TW
- Taiwan
- Prior art keywords
- spinel
- manganese oxide
- lithium manganese
- carbon dioxide
- treatment
- Prior art date
Links
- 229910052596 spinel Inorganic materials 0.000 title abstract 9
- 239000011029 spinel Substances 0.000 title abstract 9
- 229910002102 lithium manganese oxide Inorganic materials 0.000 title abstract 4
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 8
- 239000001569 carbon dioxide Substances 0.000 abstract 4
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 239000011261 inert gas Substances 0.000 abstract 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M lithium hydroxide Inorganic materials [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- -1 e.g Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000001307 helium Substances 0.000 abstract 1
- 229910052734 helium Inorganic materials 0.000 abstract 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 abstract 1
- 229910001416 lithium ion Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
- C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/30—Three-dimensional structures
- C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/679,497 US5733685A (en) | 1996-07-12 | 1996-07-12 | Method of treating lithium manganese oxide spinel |
| US08/757,055 US5783328A (en) | 1996-07-12 | 1996-11-26 | Method of treating lithium manganese oxide spinel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW360988B true TW360988B (en) | 1999-06-11 |
Family
ID=27102255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW086109862A TW360988B (en) | 1996-07-12 | 1997-07-12 | Method of treating lithium manganese oxide spinel |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5783328A (enExample) |
| EP (1) | EP0910873B1 (enExample) |
| JP (1) | JP4197054B2 (enExample) |
| CN (1) | CN1195334C (enExample) |
| AR (1) | AR007848A1 (enExample) |
| AT (1) | ATE371959T1 (enExample) |
| AU (1) | AU3596097A (enExample) |
| CA (1) | CA2259574A1 (enExample) |
| DE (1) | DE69738068T2 (enExample) |
| TW (1) | TW360988B (enExample) |
| WO (1) | WO1998002930A1 (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU4706597A (en) * | 1996-10-10 | 1998-05-05 | Merck Patent Gmbh | Modified electrode material and its use |
| US6869547B2 (en) * | 1996-12-09 | 2005-03-22 | Valence Technology, Inc. | Stabilized electrochemical cell active material |
| US6183718B1 (en) * | 1996-12-09 | 2001-02-06 | Valence Technology, Inc. | Method of making stabilized electrochemical cell active material of lithium manganese oxide |
| CN1246203A (zh) | 1997-01-31 | 2000-03-01 | 默克专利股份有限公司 | 新型二氧化锰电极、其制备方法和用途 |
| JP4185191B2 (ja) * | 1998-07-31 | 2008-11-26 | 松下電器産業株式会社 | スピネル型マンガン酸リチウムの製造方法 |
| US6322744B1 (en) | 1999-02-17 | 2001-11-27 | Valence Technology, Inc. | Lithium manganese oxide-based active material |
| KR100307160B1 (ko) * | 1999-03-06 | 2001-09-26 | 김순택 | 리튬 이차 전지용 양극 활물질 및 그 제조 방법 |
| US6506518B1 (en) * | 1999-04-27 | 2003-01-14 | Shin-Kobe Electric Machinery Co., Ltd. | Lithium secondary battery |
| US6468695B1 (en) * | 1999-08-18 | 2002-10-22 | Valence Technology Inc. | Active material having extended cycle life |
| US6455200B1 (en) | 1999-09-02 | 2002-09-24 | Illinois Institute Of Technology | Flame-retardant additive for li-ion batteries |
| US6730435B1 (en) * | 1999-10-26 | 2004-05-04 | Sumitomo Chemical Company, Limited | Active material for non-aqueous secondary battery, and non-aqueous secondary battery using the same |
| DE10014884A1 (de) | 2000-03-24 | 2001-09-27 | Merck Patent Gmbh | Beschichtete Lithium-Mischoxid-Partikel und ein Verfahren zu deren Herstellung |
| DE10016024A1 (de) | 2000-03-31 | 2001-10-04 | Merck Patent Gmbh | Aktives Anodenmaterial in elektrochemischen Zellen und Verfahren zu deren Herstellung |
| CN1263182C (zh) | 2000-09-25 | 2006-07-05 | 三星Sdi株式会社 | 用于可充电锂电池的正电极活性材料及其制备方法 |
| CN1269240C (zh) * | 2000-09-25 | 2006-08-09 | 三星Sdi株式会社 | 制备可充电锂电池的正极活性材料的方法 |
| US6984469B2 (en) * | 2000-09-25 | 2006-01-10 | Samsung Sdi Co., Ltd. | Positive active material for rechargeable lithium batteries and method of preparing same |
| US7138209B2 (en) * | 2000-10-09 | 2006-11-21 | Samsung Sdi Co., Ltd. | Positive active material for rechargeable lithium battery and method of preparing same |
| KR100428616B1 (ko) | 2001-01-19 | 2004-04-27 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 양극 활물질 및 그의 제조 방법 |
| US6558844B2 (en) | 2001-01-31 | 2003-05-06 | Wilmont F. Howard, Jr. | Stabilized spinel battery cathode material and methods |
| KR100728108B1 (ko) * | 2001-04-02 | 2007-06-13 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 양극 및 그의 제조 방법 |
| KR100420034B1 (ko) * | 2001-10-17 | 2004-02-25 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 양극 활물질의 제조방법 |
| JP5135664B2 (ja) * | 2003-12-05 | 2013-02-06 | 日産自動車株式会社 | 非水電解質リチウムイオン電池用正極材料およびこれを用いた電池 |
| CN1315217C (zh) * | 2004-04-22 | 2007-05-09 | 天津大学 | 针管式锂锰电池及其制造方法 |
| US7709149B2 (en) * | 2004-09-24 | 2010-05-04 | Lg Chem, Ltd. | Composite precursor for aluminum-containing lithium transition metal oxide and process for preparation of the same |
| CN1855587B (zh) * | 2005-04-28 | 2010-05-05 | 比亚迪股份有限公司 | 一种电池正极的制备方法和采用该正极的锂离子电池的制备方法 |
| JP2010177030A (ja) * | 2009-01-29 | 2010-08-12 | Nippon Chem Ind Co Ltd | リチウム系複合酸化物の表面処理剤、リチウム系複合酸化物の表面処理液、リチウムイオン二次電池用電解液、表面処理リチウムイオン二次電池用正極活物質及びその製造方法、表面処理リチウムイオン二次電池用負極活物質及びその製造方法、並びにリチウムイオン二次電池及びその製造方法 |
| US8999009B2 (en) | 2012-03-07 | 2015-04-07 | A123 Systems Llc | Surface modification of battery materials and method for making a battery |
| CN105050960A (zh) | 2013-02-01 | 2015-11-11 | 特罗诺克斯有限公司 | 改善的锂锰氧化物组合物 |
| US9905850B2 (en) | 2013-07-26 | 2018-02-27 | Lg Chem, Ltd. | Polycrystalline lithium manganese oxide particles, preparation method thereof, and cathode active material including the same |
| US9905851B2 (en) | 2013-07-26 | 2018-02-27 | Lg Chem, Ltd. | Cathode active material and method of preparing the same |
| US10236499B2 (en) | 2013-07-26 | 2019-03-19 | Lg Chem, Ltd. | Polycrystalline lithium manganese oxide particles, preparation method thereof, and cathode active material including the same |
| CN105830260B (zh) * | 2013-11-29 | 2018-10-26 | 汉阳大学校产学协力团 | 用于全固态锂二次电池的活性材料，其制造方法和包含其的全固态锂二次电池 |
| CN105838895B (zh) * | 2016-05-16 | 2017-11-17 | 长沙矿冶研究院有限责任公司 | 一种从含锂富锰渣中提取锂和锰的方法 |
| CN110148712B (zh) * | 2018-02-11 | 2021-05-25 | 湖南杉杉能源科技股份有限公司 | 一种复合包覆改性的富锂锰正极材料及其制备方法 |
| US11621412B2 (en) * | 2021-03-08 | 2023-04-04 | Sk On Co., Ltd. | Cathode active material for lithium secondary battery and lithium secondary battery including the same |
| CN113321244B (zh) * | 2021-05-19 | 2022-09-20 | 上海大学 | 一种表面改性的层状氧化物正极材料的制备方法及应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2196785B (en) * | 1986-10-29 | 1990-05-23 | Sony Corp | Organic electrolyte secondary cell |
| JP3028582B2 (ja) * | 1990-10-09 | 2000-04-04 | ソニー株式会社 | 非水電解質二次電池 |
| US5266299A (en) * | 1991-01-28 | 1993-11-30 | Bell Communications Research, Inc. | Method of preparing LI1+XMN204 for use as secondary battery electrode |
| US5135732A (en) * | 1991-04-23 | 1992-08-04 | Bell Communications Research, Inc. | Method for preparation of LiMn2 O4 intercalation compounds and use thereof in secondary lithium batteries |
| JP3238954B2 (ja) * | 1992-09-25 | 2001-12-17 | 三洋電機株式会社 | 非水系二次電池 |
| GB9305440D0 (en) * | 1993-03-17 | 1993-05-05 | Dowty Electronic Components | Lithiated manganese oxide |
| GB9305457D0 (en) * | 1993-03-17 | 1993-05-05 | Dowty Electronic Components | Lithiated manganese oxide |
| US5425932A (en) * | 1993-05-19 | 1995-06-20 | Bell Communications Research, Inc. | Method for synthesis of high capacity Lix Mn2 O4 secondary battery electrode compounds |
| CA2114493C (en) * | 1994-01-28 | 1999-01-12 | Jeffrey Raymond Dahn | Method for increasing the reversible capacity of lithium transition metal oxide cathodes |
| US5820790A (en) * | 1994-11-11 | 1998-10-13 | Japan Storage Battery Co., Ltd. | Positive electrode for non-aqueous cell |
| US5597664A (en) * | 1995-09-07 | 1997-01-28 | Kerr-Mcgee Corporation | Lithium manganese oxide compound and method of preparation |
-
1996
- 1996-11-26 US US08/757,055 patent/US5783328A/en not_active Expired - Lifetime
-
1997
- 1997-07-08 WO PCT/US1997/011816 patent/WO1998002930A1/en not_active Ceased
- 1997-07-08 EP EP97932523A patent/EP0910873B1/en not_active Expired - Lifetime
- 1997-07-08 DE DE69738068T patent/DE69738068T2/de not_active Expired - Fee Related
- 1997-07-08 JP JP50608798A patent/JP4197054B2/ja not_active Expired - Fee Related
- 1997-07-08 AU AU35960/97A patent/AU3596097A/en not_active Abandoned
- 1997-07-08 CA CA002259574A patent/CA2259574A1/en not_active Abandoned
- 1997-07-08 CN CNB971970491A patent/CN1195334C/zh not_active Expired - Fee Related
- 1997-07-08 AT AT97932523T patent/ATE371959T1/de not_active IP Right Cessation
- 1997-07-11 AR ARP970103089A patent/AR007848A1/es unknown
- 1997-07-12 TW TW086109862A patent/TW360988B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2259574A1 (en) | 1998-01-22 |
| CN1195334C (zh) | 2005-03-30 |
| EP0910873A1 (en) | 1999-04-28 |
| ATE371959T1 (de) | 2007-09-15 |
| WO1998002930A1 (en) | 1998-01-22 |
| CN1227672A (zh) | 1999-09-01 |
| JP4197054B2 (ja) | 2008-12-17 |
| AR007848A1 (es) | 1999-11-24 |
| JP2001527686A (ja) | 2001-12-25 |
| US5783328A (en) | 1998-07-21 |
| AU3596097A (en) | 1998-02-09 |
| DE69738068D1 (de) | 2007-10-11 |
| DE69738068T2 (de) | 2008-05-21 |
| EP0910873B1 (en) | 2007-08-29 |
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