JP4191610B2 - 改良された流動性を有するアイオノマー/高密度ポリエチレン混合物 - Google Patents
改良された流動性を有するアイオノマー/高密度ポリエチレン混合物 Download PDFInfo
- Publication number
- JP4191610B2 JP4191610B2 JP2003564128A JP2003564128A JP4191610B2 JP 4191610 B2 JP4191610 B2 JP 4191610B2 JP 2003564128 A JP2003564128 A JP 2003564128A JP 2003564128 A JP2003564128 A JP 2003564128A JP 4191610 B2 JP4191610 B2 JP 4191610B2
- Authority
- JP
- Japan
- Prior art keywords
- ionomer
- weight
- density polyethylene
- mixture
- high density
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 82
- 229920001903 high density polyethylene Polymers 0.000 title claims description 67
- 239000004700 high-density polyethylene Substances 0.000 title claims description 67
- 229920000554 ionomer Polymers 0.000 title claims description 55
- 229920001577 copolymer Polymers 0.000 claims description 37
- 239000000155 melt Substances 0.000 claims description 24
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 19
- 239000005977 Ethylene Substances 0.000 claims description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 18
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 16
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 16
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 11
- 239000004698 Polyethylene Substances 0.000 claims description 9
- -1 polyethylene Polymers 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 5
- 238000002474 experimental method Methods 0.000 description 22
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 17
- 239000000654 additive Substances 0.000 description 17
- 229920000642 polymer Polymers 0.000 description 16
- 239000002253 acid Substances 0.000 description 13
- 229920003182 Surlyn® Polymers 0.000 description 12
- 239000005035 Surlyn® Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 10
- 230000000996 additive effect Effects 0.000 description 9
- 230000000704 physical effect Effects 0.000 description 9
- 238000007792 addition Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000003365 glass fiber Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920001169 thermoplastic Polymers 0.000 description 6
- 239000004416 thermosoftening plastic Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 4
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000012963 UV stabilizer Substances 0.000 description 2
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- CTYWXRDQWMRIIM-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)prop-2-enoic acid Chemical compound CC(C)(C)C1=CC(C=CC(O)=O)=CC(C(C)(C)C)=C1O CTYWXRDQWMRIIM-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229920003317 Fusabond® Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 210000003195 fascia Anatomy 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 238000004452 microanalysis Methods 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- AZSKHRTUXHLAHS-UHFFFAOYSA-N tris(2,4-di-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(=O)(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C AZSKHRTUXHLAHS-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C08L23/0876—Salts thereof, i.e. ionomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/057,117 US6596815B1 (en) | 2002-01-25 | 2002-01-25 | Ionomer/high density polyethylene blends with improved flow |
| PCT/US2003/001793 WO2003064521A1 (en) | 2002-01-25 | 2003-01-22 | Ionomer/high density polyethylene blends with improved flow |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005516097A JP2005516097A (ja) | 2005-06-02 |
| JP2005516097A5 JP2005516097A5 (enExample) | 2006-03-16 |
| JP4191610B2 true JP4191610B2 (ja) | 2008-12-03 |
Family
ID=22008612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003564128A Expired - Fee Related JP4191610B2 (ja) | 2002-01-25 | 2003-01-22 | 改良された流動性を有するアイオノマー/高密度ポリエチレン混合物 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6596815B1 (enExample) |
| EP (1) | EP1468046A1 (enExample) |
| JP (1) | JP4191610B2 (enExample) |
| CN (1) | CN100404605C (enExample) |
| WO (1) | WO2003064521A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6953619B2 (en) * | 2003-02-12 | 2005-10-11 | E. I. Du Pont De Nemours And Company | Conductive thermoplastic compositions and antennas thereof |
| WO2006102673A1 (en) * | 2005-03-24 | 2006-09-28 | E. I. Du Pont De Nemours And Company | Transponder overmolded with ethylene copolymers |
| US20080161470A1 (en) * | 2006-12-28 | 2008-07-03 | Stewart Carl Feinberg | Composition comprising polyvinyl chloride and elastomer |
| CN103265746A (zh) * | 2013-04-23 | 2013-08-28 | 蓝星(北京)特种纤维技术研发中心有限公司 | 一种聚乙烯组合物及其制备方法 |
| US9199132B2 (en) | 2013-11-04 | 2015-12-01 | Acushnet Company | Compositions incorporating ethylene acid (E/X) ionomers and non-ionomeric softening polymers for golf ball constructions and methods relating thereto |
| US10441849B2 (en) | 2013-12-31 | 2019-10-15 | Acushnet Company | Golf ball incorporating at least one layer of neutralized acid polymer composition containing low molecular weight acid wax(es) as sole acid polymer component and low molecular weight non-acid wax(es) in the non-acid polymer component |
| US10105576B2 (en) | 2013-12-31 | 2018-10-23 | Acushnet Company | Golf ball incorporating at least one layer of plasticized neutralized acid polymer composition containing low molecular weight acid wax(es) as sole acid polymer component and method of making |
| US10105575B2 (en) | 2013-12-31 | 2018-10-23 | Acushnet Company | Golf ball incorporating at least one layer of neutralized acid polymer composition containing low molecular weight acid wax(es) as sole acid polymer component and method of making |
| US10427006B2 (en) | 2013-12-31 | 2019-10-01 | Acushnet Company | Golf ball incorporating at least one layer of plasticized neutralized acid polymer composition containing low molecular weight acid wax(es) as sole acid polymer component and low molecular weight non-acid wax(es) in the non-acid polymer component |
| CN107075005B (zh) | 2014-10-15 | 2020-07-10 | 日本聚乙烯株式会社 | 乙烯系离聚物的制造方法和乙烯系离聚物 |
| WO2017087776A1 (en) * | 2015-11-19 | 2017-05-26 | Dow Global Technologies Llc | Polymer blends for use in multilayer structure and multilayer structures comprising the same |
| CN110114402B (zh) * | 2016-11-18 | 2022-08-26 | 陶氏环球技术有限责任公司 | 供用于多层结构中的聚合物掺合物和包括所述聚合物掺合物的多层结构 |
| CN114456474B (zh) * | 2021-11-24 | 2023-12-29 | 中国石油化工股份有限公司 | 一种薄壁多层中空吹塑材料及其制备方法 |
| CN117050412B (zh) * | 2023-08-28 | 2025-09-26 | 江南大学 | 一种高耐环境应力开裂高密度聚乙烯组合物及其制备方法 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4351931A (en) | 1961-06-26 | 1982-09-28 | E. I. Du Pont De Nemours And Company | Polyethylene copolymers |
| NL129542C (enExample) | 1961-08-31 | 1900-01-01 | ||
| US3520861A (en) | 1968-12-26 | 1970-07-21 | Dow Chemical Co | Copolymers of ethylene |
| US4026967A (en) | 1976-06-25 | 1977-05-31 | E. I. Du Pont De Nemours And Company | Process for making grafted polymeric material |
| US4252924A (en) | 1979-04-05 | 1981-02-24 | E. I. Du Pont De Nemours And Company | Continuous process for the preparation of nonrandom ethylene/acid copolymer |
| US4248990A (en) | 1979-04-05 | 1981-02-03 | E. I. Du Pont De Nemours & Company | Nonrandom copolymers of ethylene and unsaturated acid |
| US4387188A (en) * | 1981-02-23 | 1983-06-07 | E. I. Du Pont De Nemours And Company | Molding resins based on blends of acid copolymer/linear polyolefin/reinforcing fiber |
| US4550141A (en) * | 1983-08-22 | 1985-10-29 | E. I. Du Pont De Nemours And Company | Blends of ionomer with propylene copolymer |
| US5091478A (en) | 1986-11-14 | 1992-02-25 | E. I. Du Pont De Nemours And Company | Partially grafted thermoplastic compositions |
| GB8801813D0 (en) * | 1988-01-27 | 1988-02-24 | Raychem Sa Nv | Adhesive composition |
| US5089332A (en) | 1989-11-14 | 1992-02-18 | E. I. Du Pont De Nemours And Company | Laminates with adhesive layer of white-pigmented, melt-stable ethylene/carboxylic acid copolymer compositions |
| US4992486A (en) | 1989-11-14 | 1991-02-12 | E. I. Du Pont De Nemours And Company | White-pigmented, melt-stable ethylene/carboxylic acid copolymer compositions |
| US5160788A (en) | 1991-02-11 | 1992-11-03 | E. I. Du Pont De Nemours And Company | Laminates with adhesive layers of fire retardant, melt stable ethylene/carboxylic acid copolymer compositions |
| US5118746A (en) | 1991-02-11 | 1992-06-02 | E. I. Du Pont De Nemours And Company | Fire retardant melt stable ethylene/carboxylic acid copolymer composition |
| US5972444A (en) * | 1991-10-15 | 1999-10-26 | The Dow Chemical Company | Polyolefin compositions with balanced shrink properties |
| US5631328A (en) * | 1993-10-27 | 1997-05-20 | Chevron Chemical Company | Low-haze ionomers of copolymers of alpha-olefins, carboxylic acid esters, and optional comonomers, and processes for making and acidifying these ionomers |
| US5721314A (en) | 1993-12-07 | 1998-02-24 | E. I. Du Pont De Nemours And Company | Thermoformable thermoplastic polymer alloy compositions |
| US5643999A (en) | 1995-03-28 | 1997-07-01 | E. I. Du Pont De Nemours And Company | Co-extrudable adhesives with good age-down resistance |
| JPH09314657A (ja) * | 1996-05-30 | 1997-12-09 | Sekisui Chem Co Ltd | ポリエチレン成形体の製造方法 |
| US6132883A (en) * | 1997-05-02 | 2000-10-17 | 3M Innovative Properties Company | Transparent powder coating compositions for protecting surfaces |
| US6268437B1 (en) * | 1998-07-31 | 2001-07-31 | Bridgestone Sports Co., Ltd. | Golf ball and cover stock |
| US6207761B1 (en) | 1999-03-18 | 2001-03-27 | A. Schulman, Inc. | Ionomer/rubber/polyolefin blend and uses thereof |
| US6569947B1 (en) * | 2002-01-25 | 2003-05-27 | E. I. Du Pont De Nemours And Company | Ionomer/high density polyethylene blends with improved impact |
| US6756443B2 (en) * | 2002-01-25 | 2004-06-29 | E. I. Du Pont De Nemours And Company | Ionomer/polyamide blends with improved flow and impact properties |
-
2002
- 2002-01-25 US US10/057,117 patent/US6596815B1/en not_active Expired - Lifetime
-
2003
- 2003-01-22 EP EP03710709A patent/EP1468046A1/en not_active Withdrawn
- 2003-01-22 JP JP2003564128A patent/JP4191610B2/ja not_active Expired - Fee Related
- 2003-01-22 WO PCT/US2003/001793 patent/WO2003064521A1/en not_active Ceased
- 2003-01-22 CN CNB038027313A patent/CN100404605C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005516097A (ja) | 2005-06-02 |
| EP1468046A1 (en) | 2004-10-20 |
| US6596815B1 (en) | 2003-07-22 |
| CN1622973A (zh) | 2005-06-01 |
| CN100404605C (zh) | 2008-07-23 |
| WO2003064521A1 (en) | 2003-08-07 |
| HK1076830A1 (zh) | 2006-01-27 |
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