JP4187953B2 - 窒素含有金属粉末の製造方法 - Google Patents
窒素含有金属粉末の製造方法 Download PDFInfo
- Publication number
- JP4187953B2 JP4187953B2 JP2001246570A JP2001246570A JP4187953B2 JP 4187953 B2 JP4187953 B2 JP 4187953B2 JP 2001246570 A JP2001246570 A JP 2001246570A JP 2001246570 A JP2001246570 A JP 2001246570A JP 4187953 B2 JP4187953 B2 JP 4187953B2
- Authority
- JP
- Japan
- Prior art keywords
- nitrogen
- metal
- powder
- tantalum
- niobium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 139
- 239000002184 metal Substances 0.000 title claims description 139
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 title claims description 85
- 239000000843 powder Substances 0.000 title claims description 83
- 238000004519 manufacturing process Methods 0.000 title claims description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 182
- 229910052757 nitrogen Inorganic materials 0.000 claims description 84
- 150000003839 salts Chemical class 0.000 claims description 54
- 239000007789 gas Substances 0.000 claims description 53
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 51
- 238000006243 chemical reaction Methods 0.000 claims description 47
- 238000000034 method Methods 0.000 claims description 43
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 42
- 229910052715 tantalum Inorganic materials 0.000 claims description 32
- 239000003638 chemical reducing agent Substances 0.000 claims description 27
- 229910052758 niobium Inorganic materials 0.000 claims description 26
- 239000010955 niobium Substances 0.000 claims description 26
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 claims description 22
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 18
- 229910052708 sodium Inorganic materials 0.000 claims description 18
- 239000011734 sodium Substances 0.000 claims description 18
- 238000004220 aggregation Methods 0.000 claims description 16
- 230000002776 aggregation Effects 0.000 claims description 16
- 229910001362 Ta alloys Inorganic materials 0.000 claims description 5
- RHDUVDHGVHBHCL-UHFFFAOYSA-N niobium tantalum Chemical compound [Nb].[Ta] RHDUVDHGVHBHCL-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 3
- 239000003990 capacitor Substances 0.000 description 31
- 239000002245 particle Substances 0.000 description 23
- 230000003647 oxidation Effects 0.000 description 18
- 238000007254 oxidation reaction Methods 0.000 description 18
- 238000006722 reduction reaction Methods 0.000 description 17
- 239000000126 substance Substances 0.000 description 17
- 229910001873 dinitrogen Inorganic materials 0.000 description 15
- 239000010408 film Substances 0.000 description 15
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 12
- 239000002994 raw material Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 11
- 238000005259 measurement Methods 0.000 description 9
- 229910052721 tungsten Inorganic materials 0.000 description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 239000011164 primary particle Substances 0.000 description 8
- 238000004438 BET method Methods 0.000 description 7
- 238000002441 X-ray diffraction Methods 0.000 description 7
- 229910052786 argon Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 230000007423 decrease Effects 0.000 description 7
- 229910052749 magnesium Inorganic materials 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- 150000004767 nitrides Chemical class 0.000 description 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 230000007774 longterm Effects 0.000 description 6
- 238000005121 nitriding Methods 0.000 description 6
- 239000011698 potassium fluoride Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 235000003270 potassium fluoride Nutrition 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
- 239000006104 solid solution Substances 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000006392 deoxygenation reaction Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 description 4
- APLLYCDGAWQGRK-UHFFFAOYSA-H potassium;hexafluorotantalum(1-) Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[K+].[Ta+5] APLLYCDGAWQGRK-UHFFFAOYSA-H 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- 238000011105 stabilization Methods 0.000 description 4
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 3
- 241000723346 Cinnamomum camphora Species 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000005587 bubbling Effects 0.000 description 3
- 229960000846 camphor Drugs 0.000 description 3
- 229930008380 camphor Natural products 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000012300 argon atmosphere Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- FTPUNAWAGWERLA-UHFFFAOYSA-G dipotassium;heptafluoroniobium(2-) Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[F-].[K+].[K+].[Nb+5] FTPUNAWAGWERLA-UHFFFAOYSA-G 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000011163 secondary particle Substances 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- OEIMLTQPLAGXMX-UHFFFAOYSA-I tantalum(v) chloride Chemical compound Cl[Ta](Cl)(Cl)(Cl)Cl OEIMLTQPLAGXMX-UHFFFAOYSA-I 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910001257 Nb alloy Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- JRFKUVDHIAAEOU-UHFFFAOYSA-N [F-].[F-].[F-].[F-].[F-].[F-].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+] Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+] JRFKUVDHIAAEOU-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- CFJRGWXELQQLSA-UHFFFAOYSA-N azanylidyneniobium Chemical compound [Nb]#N CFJRGWXELQQLSA-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910012375 magnesium hydride Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000484 niobium oxide Inorganic materials 0.000 description 1
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- AOLPZAHRYHXPLR-UHFFFAOYSA-I pentafluoroniobium Chemical class F[Nb](F)(F)(F)F AOLPZAHRYHXPLR-UHFFFAOYSA-I 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- VBKNTGMWIPUCRF-UHFFFAOYSA-M potassium;fluoride;hydrofluoride Chemical compound F.[F-].[K+] VBKNTGMWIPUCRF-UHFFFAOYSA-M 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- WTKKCYNZRWIVKL-UHFFFAOYSA-N tantalum Chemical compound [Ta+5] WTKKCYNZRWIVKL-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/048—Electrodes or formation of dielectric layers thereon characterised by their structure
- H01G9/052—Sintered electrodes
- H01G9/0525—Powder therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/14—Treatment of metallic powder
- B22F1/145—Chemical treatment, e.g. passivation or decarburisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001246570A JP4187953B2 (ja) | 2001-08-15 | 2001-08-15 | 窒素含有金属粉末の製造方法 |
| CNB028159039A CN1265919C (zh) | 2001-08-15 | 2002-08-13 | 含氮金属粉末及其制造方法和采用该粉末的多孔质烧结体及固体电解电容器 |
| EP02762773.6A EP1418012B1 (en) | 2001-08-15 | 2002-08-13 | NITROGEN−CONTAINING METAL POWDER AND METHOD FOR PRODUCING THE SAME, AND POROUS SINTERED PRODUCT AND SOLID ELECTROLYTIC CAPACITOR USING THE SAME |
| PCT/JP2002/008254 WO2003015961A1 (fr) | 2001-08-15 | 2002-08-13 | Poudre metallique contenant de l'azote et procede de production de cette poudre, produit fritte poreux et condensateur electrolytique solide utilisant ledit produit |
| CN2006100877447A CN1872461B (zh) | 2001-08-15 | 2002-08-13 | 含氮金属粉末及其制造方法和采用该粉末的多孔质烧结体及固体电解电容器 |
| EP10012641A EP2305401A1 (en) | 2001-08-15 | 2002-08-13 | Nitrogen containing metal powder and method for producing the same, and porous sintered and solid electrolytic capacitor using the same |
| PT2762773T PT1418012E (pt) | 2001-08-15 | 2002-08-13 | Pó metálico contendo azoto e método para a sua produção, e produto sinterizado poroso e condensador electrolítico sólido que o utiliza |
| US10/486,521 US6876542B2 (en) | 2001-08-15 | 2002-08-13 | Nitrogen containing metal powder, production process therefor, and porous sintered body and solid electrolytic capacitor using same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001246570A JP4187953B2 (ja) | 2001-08-15 | 2001-08-15 | 窒素含有金属粉末の製造方法 |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007274384A Division JP2008095200A (ja) | 2007-10-22 | 2007-10-22 | 窒素含有金属粉末およびその製造方法ならびにそれを用いた多孔質焼結体および固体電解コンデンサ |
| JP2008174868A Division JP2009007675A (ja) | 2008-07-03 | 2008-07-03 | 窒素含有金属粉末およびそれを用いた多孔質焼結体および固体電解コンデンサ |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003055702A JP2003055702A (ja) | 2003-02-26 |
| JP2003055702A5 JP2003055702A5 (enExample) | 2007-09-13 |
| JP4187953B2 true JP4187953B2 (ja) | 2008-11-26 |
Family
ID=19076090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001246570A Expired - Lifetime JP4187953B2 (ja) | 2001-08-15 | 2001-08-15 | 窒素含有金属粉末の製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6876542B2 (enExample) |
| EP (2) | EP1418012B1 (enExample) |
| JP (1) | JP4187953B2 (enExample) |
| CN (2) | CN1872461B (enExample) |
| PT (1) | PT1418012E (enExample) |
| WO (1) | WO2003015961A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011174130A (ja) * | 2010-02-24 | 2011-09-08 | Cabot Supermetal Kk | 窒素含有金属粉末の製造方法 |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6432161B1 (en) * | 2000-02-08 | 2002-08-13 | Cabot Supermetals K.K. | Nitrogen-containing metal powder, production process thereof, and porous sintered body and solid electrolytic capacitor using the metal powder |
| JP4727160B2 (ja) * | 2003-04-28 | 2011-07-20 | 昭和電工株式会社 | 弁作用金属焼結体、その製造方法及び固体電解コンデンサ |
| US7713466B2 (en) | 2003-04-28 | 2010-05-11 | Showa Denko K.K. | Valve acting metal sintered body, production method therefor and solid electrolytic capacitor |
| WO2005099935A1 (ja) | 2004-04-15 | 2005-10-27 | Jfe Mineral Company, Ltd. | タンタル粉末およびそれを用いた固体電解コンデンサ |
| US20060269436A1 (en) * | 2005-05-31 | 2006-11-30 | Cabot Corporation | Process for heat treating metal powder and products made from the same |
| PT2169086E (pt) * | 2005-09-16 | 2015-02-17 | Starck H C Gmbh | Pó de metal refratário |
| GB0622463D0 (en) * | 2006-11-10 | 2006-12-20 | Avx Ltd | Powder modification in the manufacture of solid state capacitor anodes |
| CN100528418C (zh) * | 2008-01-11 | 2009-08-19 | 宁夏东方钽业股份有限公司 | 含氮均匀的阀金属粉末及其制造方法,阀金属坯块和阀金属烧结体以及电解电容器的阳极 |
| JP2010095763A (ja) * | 2008-10-16 | 2010-04-30 | Asahi Kasei Chemicals Corp | 高温での強度に優れた金属粉末製造用容器 |
| US8430944B2 (en) * | 2008-12-22 | 2013-04-30 | Global Advanced Metals, Usa, Inc. | Fine particle recovery methods for valve metal powders |
| GB0902486D0 (en) * | 2009-02-13 | 2009-04-01 | Metalysis Ltd | A method for producing metal powders |
| CN102601380B (zh) * | 2011-12-21 | 2015-05-20 | 中国科学院过程工程研究所 | 一种立方铜粉及其制备方法 |
| JP6077274B2 (ja) * | 2012-11-15 | 2017-02-08 | グローバルアドバンストメタルジャパン株式会社 | 窒素含有タンタル粉末およびその製造方法 |
| CN103192088B (zh) * | 2013-02-20 | 2015-05-20 | 上海交通大学 | 锥状磁性镍纳米晶的制备方法 |
| JP6367356B2 (ja) * | 2013-12-10 | 2018-08-01 | ニンシア オリエント タンタル インダストリー カンパニー、 リミテッド | 高窒素含有量を有するコンデンサグレードのタンタル粉末の調製方法、その方法により調製したコンデンサグレードのタンタル粉末、並びにタンタル粉末から調製したアノード及びコンデンサ |
| TWI483274B (zh) | 2013-12-30 | 2015-05-01 | Ind Tech Res Inst | 複合電極及電解電容器 |
| CN104858436B (zh) * | 2014-02-21 | 2018-01-16 | 宁夏东方钽业股份有限公司 | 高可靠高比容电解电容器用钽粉的制备方法 |
| JP5898297B2 (ja) * | 2014-11-20 | 2016-04-06 | グローバルアドバンストメタルジャパン株式会社 | 窒素含有金属粉末の製造方法 |
| WO2016138001A1 (en) | 2015-02-23 | 2016-09-01 | Nanoscale Powders LLC | Methods for producing metal powders |
| JP2016166422A (ja) * | 2016-04-12 | 2016-09-15 | グローバルアドバンストメタルジャパン株式会社 | 窒素含有金属粉末の製造方法 |
| EP3486338B1 (en) * | 2016-07-13 | 2023-06-21 | Ningxia Orient Tantalum Industry Co., Ltd. | Flaky tantalum powder and method for preparing the same |
| US20180144874A1 (en) | 2016-10-21 | 2018-05-24 | Global Advanced Metals, Usa, Inc. | Tantalum Powder, Anode, And Capacitor Including Same, And Manufacturing Methods Thereof |
| WO2019089926A1 (en) * | 2017-11-01 | 2019-05-09 | University Of Virginia Patent Foundation | Sintered electrode cells for high energy density batteries and related methods thereof |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4019998A (en) * | 1974-09-27 | 1977-04-26 | The Procter & Gamble Company | Process for preparing a pyrophosphate-silicate detergent product |
| US4684399A (en) | 1986-03-04 | 1987-08-04 | Cabot Corporation | Tantalum powder process |
| DE4214722C2 (de) | 1992-05-04 | 1994-08-25 | Starck H C Gmbh Co Kg | Feinteilige Metallpulver |
| US5448447A (en) | 1993-04-26 | 1995-09-05 | Cabot Corporation | Process for making an improved tantalum powder and high capacitance low leakage electrode made therefrom |
| EP0665302B1 (en) * | 1994-01-26 | 2000-05-03 | H.C. Starck, INC. | Nitriding tantalum powder |
| US6165623A (en) | 1996-11-07 | 2000-12-26 | Cabot Corporation | Niobium powders and niobium electrolytic capacitors |
| PT964936E (pt) * | 1997-02-19 | 2002-03-28 | Starck H C Gmbh | Po de tantalo seu processo de producao e anodos sinterizados produzidos a partir deste po |
| CZ300529B6 (cs) | 1997-02-19 | 2009-06-10 | H.C. Starck Gmbh | Práškový tantal, zpusob jeho výroby a z nej vyrobené anody a kondezátory |
| US5914671A (en) | 1997-02-27 | 1999-06-22 | Micron Communications, Inc. | System and method for locating individuals and equipment, airline reservation system, communication system |
| JP3254163B2 (ja) | 1997-02-28 | 2002-02-04 | 昭和電工株式会社 | コンデンサ |
| WO1999036811A1 (en) | 1998-01-15 | 1999-07-22 | Ciena Corporation | Optical interference filter |
| US6051044A (en) | 1998-05-04 | 2000-04-18 | Cabot Corporation | Nitrided niobium powders and niobium electrolytic capacitors |
| JP2000031029A (ja) | 1998-07-08 | 2000-01-28 | Canon Inc | 半導体露光装置およびデバイス製造方法 |
| DE19847012A1 (de) * | 1998-10-13 | 2000-04-20 | Starck H C Gmbh Co Kg | Niobpulver und Verfahren zu dessen Herstellung |
| JP3871824B2 (ja) | 1999-02-03 | 2007-01-24 | キャボットスーパーメタル株式会社 | 高容量コンデンサー用タンタル粉末 |
| US6558447B1 (en) * | 1999-05-05 | 2003-05-06 | H.C. Starck, Inc. | Metal powders produced by the reduction of the oxides with gaseous magnesium |
| JP4049964B2 (ja) | 2000-02-08 | 2008-02-20 | キャボットスーパーメタル株式会社 | 窒素含有金属粉末およびその製造方法ならびにそれを用いた多孔質焼結体および固体電解コンデンサー |
| US6432161B1 (en) | 2000-02-08 | 2002-08-13 | Cabot Supermetals K.K. | Nitrogen-containing metal powder, production process thereof, and porous sintered body and solid electrolytic capacitor using the metal powder |
| JP2002030301A (ja) | 2000-07-12 | 2002-01-31 | Showa Kyabotto Super Metal Kk | 窒素含有金属粉末およびその製造方法ならびにそれを用いた多孔質焼結体および固体電解コンデンサ |
| JP2002093666A (ja) | 2000-09-20 | 2002-03-29 | Showa Denko Kk | ニオブ粉、それを用いた焼結体及びそれを用いたコンデンサ |
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2001
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- 2002-08-13 US US10/486,521 patent/US6876542B2/en not_active Expired - Lifetime
- 2002-08-13 CN CNB028159039A patent/CN1265919C/zh not_active Expired - Fee Related
- 2002-08-13 PT PT2762773T patent/PT1418012E/pt unknown
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011174130A (ja) * | 2010-02-24 | 2011-09-08 | Cabot Supermetal Kk | 窒素含有金属粉末の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1872461B (zh) | 2011-06-29 |
| EP1418012B1 (en) | 2013-05-22 |
| JP2003055702A (ja) | 2003-02-26 |
| CN1872461A (zh) | 2006-12-06 |
| EP1418012A4 (en) | 2007-03-28 |
| CN1541147A (zh) | 2004-10-27 |
| CN1265919C (zh) | 2006-07-26 |
| WO2003015961A1 (fr) | 2003-02-27 |
| PT1418012E (pt) | 2013-06-04 |
| US20040205947A1 (en) | 2004-10-21 |
| EP2305401A1 (en) | 2011-04-06 |
| US6876542B2 (en) | 2005-04-05 |
| EP1418012A1 (en) | 2004-05-12 |
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