JP4090998B2 - 機械的特性と加工性が改善されたブロック共重合体組成物 - Google Patents
機械的特性と加工性が改善されたブロック共重合体組成物 Download PDFInfo
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- JP4090998B2 JP4090998B2 JP2003564132A JP2003564132A JP4090998B2 JP 4090998 B2 JP4090998 B2 JP 4090998B2 JP 2003564132 A JP2003564132 A JP 2003564132A JP 2003564132 A JP2003564132 A JP 2003564132A JP 4090998 B2 JP4090998 B2 JP 4090998B2
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- 229920000642 polymer Polymers 0.000 claims description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 239000007822 coupling agent Substances 0.000 claims description 10
- 238000005984 hydrogenation reaction Methods 0.000 claims description 10
- 239000005062 Polybutadiene Substances 0.000 claims description 9
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- 239000002356 single layer Substances 0.000 claims description 9
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- 239000010410 layer Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 4
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- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
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- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Chemical class C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Chemical class O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
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- 239000004743 Polypropylene Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
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- WQONPSCCEXUXTQ-UHFFFAOYSA-N 1,2-dibromobenzene Chemical compound BrC1=CC=CC=C1Br WQONPSCCEXUXTQ-UHFFFAOYSA-N 0.000 description 2
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 2
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920002633 Kraton (polymer) Polymers 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
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- 239000004698 Polyethylene Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- BYLOHCRAPOSXLY-UHFFFAOYSA-N dichloro(diethyl)silane Chemical compound CC[Si](Cl)(Cl)CC BYLOHCRAPOSXLY-UHFFFAOYSA-N 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 2
- 210000004177 elastic tissue Anatomy 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 2
- PCPYTNCQOSFKGG-ONEGZZNKSA-N (1e)-1-chlorobuta-1,3-diene Chemical compound Cl\C=C\C=C PCPYTNCQOSFKGG-ONEGZZNKSA-N 0.000 description 1
- AONKGGMHQHWMSM-UHFFFAOYSA-N 1,1,1-tribromopropane Chemical compound CCC(Br)(Br)Br AONKGGMHQHWMSM-UHFFFAOYSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- AVGQTJUPLKNPQP-UHFFFAOYSA-N 1,1,1-trichloropropane Chemical compound CCC(Cl)(Cl)Cl AVGQTJUPLKNPQP-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- APQIUTYORBAGEZ-UHFFFAOYSA-N 1,1-dibromoethane Chemical compound CC(Br)Br APQIUTYORBAGEZ-UHFFFAOYSA-N 0.000 description 1
- ATWLRNODAYAMQS-UHFFFAOYSA-N 1,1-dibromopropane Chemical compound CCC(Br)Br ATWLRNODAYAMQS-UHFFFAOYSA-N 0.000 description 1
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
- VPBZZPOGZPKYKX-UHFFFAOYSA-N 1,2-diethoxypropane Chemical compound CCOCC(C)OCC VPBZZPOGZPKYKX-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000001559 benzoic acids Chemical class 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- DBKNQKMXXOSIOX-UHFFFAOYSA-N butyl(dichloro)silane Chemical compound CCCC[SiH](Cl)Cl DBKNQKMXXOSIOX-UHFFFAOYSA-N 0.000 description 1
- FYDLBBUBQFJOJT-UHFFFAOYSA-L butyl(dichloro)tin Chemical compound CCCC[Sn](Cl)Cl FYDLBBUBQFJOJT-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- LIQOCGKQCFXKLF-UHFFFAOYSA-N dibromo(dimethyl)silane Chemical compound C[Si](C)(Br)Br LIQOCGKQCFXKLF-UHFFFAOYSA-N 0.000 description 1
- XKBAVCUSVIEVHR-UHFFFAOYSA-N dibromo(methyl)silane Chemical compound C[SiH](Br)Br XKBAVCUSVIEVHR-UHFFFAOYSA-N 0.000 description 1
- FJBFPHVGVWTDIP-UHFFFAOYSA-N dibromomethane Chemical compound BrCBr FJBFPHVGVWTDIP-UHFFFAOYSA-N 0.000 description 1
- VJIYRPVGAZXYBD-UHFFFAOYSA-N dibromosilane Chemical compound Br[SiH2]Br VJIYRPVGAZXYBD-UHFFFAOYSA-N 0.000 description 1
- NJKDOKBDBHYMAH-UHFFFAOYSA-N dibutyl(dichloro)silane Chemical compound CCCC[Si](Cl)(Cl)CCCC NJKDOKBDBHYMAH-UHFFFAOYSA-N 0.000 description 1
- QSHZUFRQHSINTB-UHFFFAOYSA-L dibutyltin(2+);dibromide Chemical compound CCCC[Sn](Br)(Br)CCCC QSHZUFRQHSINTB-UHFFFAOYSA-L 0.000 description 1
- YFAXVVMIXZAKSR-UHFFFAOYSA-L dichloro(diethyl)stannane Chemical compound CC[Sn](Cl)(Cl)CC YFAXVVMIXZAKSR-UHFFFAOYSA-L 0.000 description 1
- NRAYZPGATNMOSB-UHFFFAOYSA-N dichloro(dihexyl)silane Chemical compound CCCCCC[Si](Cl)(Cl)CCCCCC NRAYZPGATNMOSB-UHFFFAOYSA-N 0.000 description 1
- PKKGKUDPKRTKLJ-UHFFFAOYSA-L dichloro(dimethyl)stannane Chemical compound C[Sn](C)(Cl)Cl PKKGKUDPKRTKLJ-UHFFFAOYSA-L 0.000 description 1
- SYAXPJDYXAPBDK-UHFFFAOYSA-L dichloro(ethyl)tin Chemical compound CC[Sn](Cl)Cl SYAXPJDYXAPBDK-UHFFFAOYSA-L 0.000 description 1
- NYKYPUSQZAJABL-UHFFFAOYSA-N dichloro(hexyl)silane Chemical compound CCCCCC[SiH](Cl)Cl NYKYPUSQZAJABL-UHFFFAOYSA-N 0.000 description 1
- NENHTYKSUUMRCM-UHFFFAOYSA-L dichloro(hexyl)tin Chemical compound CCCCCC[Sn](Cl)Cl NENHTYKSUUMRCM-UHFFFAOYSA-L 0.000 description 1
- KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 description 1
- BQWHLOCBVNERCO-UHFFFAOYSA-L dichloro(methyl)tin Chemical compound C[Sn](Cl)Cl BQWHLOCBVNERCO-UHFFFAOYSA-L 0.000 description 1
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- AIFMYMZGQVTROK-UHFFFAOYSA-N silicon tetrabromide Chemical compound Br[Si](Br)(Br)Br AIFMYMZGQVTROK-UHFFFAOYSA-N 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- YFRLQYJXUZRYDN-UHFFFAOYSA-K trichloro(methyl)stannane Chemical compound C[Sn](Cl)(Cl)Cl YFRLQYJXUZRYDN-UHFFFAOYSA-K 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/914—Polymer from conjugated diene hydrocarbon or halohydrocarbons having more than 50 per cent 1,2-microstructure
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02075463A EP1333058A1 (en) | 2002-01-31 | 2002-01-31 | Modified styrenic block copolymer and compounds thereof having improved mechanical properties and processability |
| EP02079462 | 2002-10-24 | ||
| PCT/EP2003/000278 WO2003064528A2 (en) | 2002-01-31 | 2003-01-13 | Block copolymer compositions, having improved mechanical properties and processability |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005516099A JP2005516099A (ja) | 2005-06-02 |
| JP2005516099A5 JP2005516099A5 (enExample) | 2005-11-17 |
| JP4090998B2 true JP4090998B2 (ja) | 2008-05-28 |
Family
ID=27664991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003564132A Expired - Lifetime JP4090998B2 (ja) | 2002-01-31 | 2003-01-13 | 機械的特性と加工性が改善されたブロック共重合体組成物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7186779B2 (enExample) |
| EP (1) | EP1470190B1 (enExample) |
| JP (1) | JP4090998B2 (enExample) |
| CN (1) | CN1286904C (enExample) |
| AU (1) | AU2003202559A1 (enExample) |
| WO (1) | WO2003064528A2 (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1286903C (zh) * | 2002-01-31 | 2006-11-29 | 克拉通聚合物研究有限公司 | 具有改善机械性能和加工性能的嵌段共聚物组合物 |
| US7517932B2 (en) * | 2003-03-24 | 2009-04-14 | Kraton Polymers U.S. Llc | Poly(styrene-butadiene-styrene)polymers having a high vinyl content in the butadiene block and hot melt adhesive composition comprising said polymers |
| BRPI0508388A (pt) * | 2004-03-03 | 2007-08-07 | Kraton Polymers Res Bv | fibra bicomponente, artigo, e, processo para produzir a fibra bicomponente |
| EP1723199A1 (en) * | 2004-03-03 | 2006-11-22 | KRATON Polymers Research B.V. | Polymeric compositions containing block copolymers having high flow and high elasticity |
| US20120114786A1 (en) * | 2004-05-25 | 2012-05-10 | Watson James B | Live bacteria product |
| US7645507B2 (en) | 2005-10-24 | 2010-01-12 | Kraton Polymers U.S. Llc | Protective films and pressure sensitive adhesives |
| ATE444335T1 (de) * | 2005-12-22 | 2009-10-15 | Dow Global Technologies Inc | Mischungen aus styren-block-copolymeren und propylen-alpha-olefin-copolymere |
| US7990679B2 (en) * | 2006-07-14 | 2011-08-02 | Dais Analytic Corporation | Nanoparticle ultracapacitor |
| WO2008039779A2 (en) * | 2006-09-25 | 2008-04-03 | Dais Analytic Corporation | Enhanced hvac system and method |
| WO2008089484A1 (en) * | 2007-01-20 | 2008-07-24 | Dais Analytic Corporation | Multi-phase selective mass transfer through a membrane |
| US8586637B2 (en) * | 2007-06-26 | 2013-11-19 | Dais Analytic Corporation | Stable and compatible polymer blends |
| US20090018253A1 (en) * | 2007-07-09 | 2009-01-15 | Eastman Chemical Company | Perfromance additives for thermoplastic elastomers |
| KR101193772B1 (ko) * | 2007-12-21 | 2012-10-23 | 크레이튼 폴리머즈 유.에스. 엘엘씨 | 연질 탄성중합체 필름 |
| US9013155B2 (en) | 2010-01-09 | 2015-04-21 | Dais Analytic Corporation | Energy storage devices including a solid multilayer electrolyte |
| US9393557B2 (en) | 2010-01-09 | 2016-07-19 | Dais Analytic Corporation | Anionic exchange electrolyte polymer membranes |
| US9293269B2 (en) | 2012-02-08 | 2016-03-22 | Dais Analytic Corporation | Ultracapacitor tolerating electric field of sufficient strength |
| JP6026255B2 (ja) | 2012-12-07 | 2016-11-16 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 塗装面の保護フィルム用粘着剤組成物およびその調製方法 |
| JP2015034274A (ja) * | 2013-07-09 | 2015-02-19 | 出光興産株式会社 | 弾性フィルム |
| CN111333795B (zh) | 2015-02-24 | 2023-04-07 | 株式会社可乐丽 | 氢化嵌段共聚物、树脂组合物以及使用它们得到的制品 |
| EP3348396B1 (en) * | 2015-09-09 | 2019-08-14 | Asahi Kasei Kabushiki Kaisha | Film |
| CN108779221B (zh) | 2016-03-24 | 2022-07-05 | 科腾聚合物美国有限责任公司 | 半结晶嵌段共聚物和得自其的组合物 |
| CN109415475B (zh) | 2016-06-30 | 2022-04-05 | 科腾聚合物美国有限责任公司 | 性能改进的高乙烯基嵌段共聚物组合物及其用途 |
| KR102373304B1 (ko) | 2018-03-30 | 2022-03-15 | 주식회사 엘지화학 | 블록 공중합체 조성물 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3113986A (en) | 1962-01-08 | 1963-12-10 | Hercules Powder Co Ltd | Hydrogenation of unsaturated hydrocarbons |
| USRE27145E (en) | 1969-05-20 | 1971-06-22 | Side-chain | |
| US4226952A (en) | 1979-08-20 | 1980-10-07 | The Firestone Tire & Rubber Company | Thermoplastic elastomer blends of alpha-olefin polymers and hydrogenated medium and high vinyl butadiene polymers |
| US4663220A (en) | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
| CA1309530C (en) * | 1986-07-07 | 1992-10-27 | Glenn Roy Himes | Styrene-ethylene/butylene block copolymer blends with improved oil absorption resistance |
| US4789699A (en) | 1986-10-15 | 1988-12-06 | Kimberly-Clark Corporation | Ambient temperature bondable elastomeric nonwoven web |
| US5191024A (en) | 1989-05-19 | 1993-03-02 | Japan Synthetic Rubber Co., Ltd. | Hydrogenated diene block copolymer and composition comprising the same |
| US4970259A (en) | 1989-08-16 | 1990-11-13 | Shell Oil Company | Elastomeric film composition |
| JP2779001B2 (ja) * | 1989-08-17 | 1998-07-23 | 株式会社クラレ | 樹脂組成物 |
| US5093422A (en) | 1990-04-23 | 1992-03-03 | Shell Oil Company | Low stress relaxation extrudable elastomeric composition |
| US5039755A (en) | 1990-05-29 | 1991-08-13 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers |
| US5589542A (en) | 1993-11-03 | 1996-12-31 | Shell Oil Company | Multiblock hydrogenated polymers for adhesives |
| US5705556A (en) | 1996-03-05 | 1998-01-06 | Shell Oil Company | Modified styrenic block copolymer compounds having improved elastic performance |
| EP0909294B1 (en) * | 1996-07-03 | 2000-03-08 | Shell Internationale Researchmaatschappij B.V. | High 1,2-content thermoplastic elastomer oil polyolefin composition |
| TW416971B (en) * | 1996-07-31 | 2001-01-01 | Shell Internattonale Res Mij B | Oil gel formulations containing high vinyl content hydrogenated styrene-butadiene-styrene block copolymers |
| US5777043A (en) * | 1997-03-05 | 1998-07-07 | Shell Oil Company | Sealant formulations containing high vinyl content hydrogenated styrene-butadiene-styrene block copolymers |
| US6042907A (en) * | 1997-08-28 | 2000-03-28 | Owens-Illinois Labels Inc. | Coextrusion of multilayer film for container sleeve labels |
| WO1999045064A1 (en) * | 1998-03-02 | 1999-09-10 | Kureha Chemical Industry Co., Ltd. | Polypropylene resin compositions and packaging stretched film made thereof |
| MY133783A (en) | 1999-07-28 | 2007-11-30 | Dow Global Technologies Inc | Hydrogenated block polymers having elasticity and articles made therefrom |
| US6630532B1 (en) * | 1999-09-15 | 2003-10-07 | Kraton Polymer U.S. Llc | Modified styrenic block copolymer compounds having improved elastic performance |
| EP1322707A1 (en) | 2000-10-04 | 2003-07-02 | Kraton Polymers Research B.V. | An elastomeric film and fiber grade thermoplastic elastomer composition |
-
2003
- 2003-01-13 JP JP2003564132A patent/JP4090998B2/ja not_active Expired - Lifetime
- 2003-01-13 WO PCT/EP2003/000278 patent/WO2003064528A2/en not_active Ceased
- 2003-01-13 EP EP03701508.8A patent/EP1470190B1/en not_active Expired - Lifetime
- 2003-01-13 US US10/510,360 patent/US7186779B2/en not_active Expired - Lifetime
- 2003-01-13 CN CNB038004429A patent/CN1286904C/zh not_active Expired - Lifetime
- 2003-01-13 AU AU2003202559A patent/AU2003202559A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CN1286904C (zh) | 2006-11-29 |
| AU2003202559A1 (en) | 2003-09-02 |
| CN1553936A (zh) | 2004-12-08 |
| US7186779B2 (en) | 2007-03-06 |
| WO2003064528A2 (en) | 2003-08-07 |
| WO2003064528A3 (en) | 2004-04-01 |
| US20050222356A1 (en) | 2005-10-06 |
| EP1470190A2 (en) | 2004-10-27 |
| JP2005516099A (ja) | 2005-06-02 |
| EP1470190B1 (en) | 2019-08-07 |
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