JP3693362B2 - 触媒組成物およびfccガソリン中の硫黄低減法 - Google Patents
触媒組成物およびfccガソリン中の硫黄低減法 Download PDFInfo
- Publication number
- JP3693362B2 JP3693362B2 JP01498194A JP1498194A JP3693362B2 JP 3693362 B2 JP3693362 B2 JP 3693362B2 JP 01498194 A JP01498194 A JP 01498194A JP 1498194 A JP1498194 A JP 1498194A JP 3693362 B2 JP3693362 B2 JP 3693362B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- zinc
- alumina
- composition
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011593 sulfur Substances 0.000 title claims description 67
- 229910052717 sulfur Inorganic materials 0.000 title claims description 67
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 65
- 239000000203 mixture Substances 0.000 title claims description 48
- 239000003054 catalyst Substances 0.000 title claims description 37
- 238000000034 method Methods 0.000 title claims description 20
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 53
- 239000011701 zinc Substances 0.000 claims description 20
- 239000010457 zeolite Substances 0.000 claims description 16
- 229910052725 zinc Inorganic materials 0.000 claims description 16
- 238000004523 catalytic cracking Methods 0.000 claims description 13
- 229910021536 Zeolite Inorganic materials 0.000 claims description 12
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000011159 matrix material Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 6
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 5
- 239000002808 molecular sieve Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 4
- 239000012013 faujasite Substances 0.000 claims description 2
- 239000000017 hydrogel Substances 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 12
- 239000007767 bonding agent Substances 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- 230000008859 change Effects 0.000 description 22
- 239000002841 Lewis acid Substances 0.000 description 21
- 150000007517 lewis acids Chemical class 0.000 description 21
- 238000009835 boiling Methods 0.000 description 19
- 238000004231 fluid catalytic cracking Methods 0.000 description 17
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 14
- 238000012360 testing method Methods 0.000 description 12
- 241000894007 species Species 0.000 description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 229930192474 thiophene Natural products 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000005336 cracking Methods 0.000 description 8
- -1 magnesium aluminate Chemical class 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 230000008929 regeneration Effects 0.000 description 7
- 238000011069 regeneration method Methods 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- 229910052746 lanthanum Inorganic materials 0.000 description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- 239000002879 Lewis base Substances 0.000 description 5
- 239000002283 diesel fuel Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 4
- 229910052761 rare earth metal Inorganic materials 0.000 description 4
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 4
- XQQBUAPQHNYYRS-UHFFFAOYSA-N 2-methylthiophene Chemical compound CC1=CC=CS1 XQQBUAPQHNYYRS-UHFFFAOYSA-N 0.000 description 3
- 229910017090 AlO 2 Inorganic materials 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 3
- QENGPZGAWFQWCZ-UHFFFAOYSA-N Methylthiophene Natural products CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000000975 co-precipitation Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 150000007527 lewis bases Chemical class 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- JCCCMAAJYSNBPR-UHFFFAOYSA-N 2-ethylthiophene Chemical compound CCC1=CC=CS1 JCCCMAAJYSNBPR-UHFFFAOYSA-N 0.000 description 1
- BTXIJTYYMLCUHI-UHFFFAOYSA-N 2-propylthiophene Chemical compound CCCC1=CC=CS1 BTXIJTYYMLCUHI-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000269350 Anura Species 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- MTDRVSSSPQLYEK-UHFFFAOYSA-N [O-2].[Nd+3].[O-2].[La+3] Chemical compound [O-2].[Nd+3].[O-2].[La+3] MTDRVSSSPQLYEK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000000712 atomic emission detection Methods 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 229910001680 bayerite Inorganic materials 0.000 description 1
- 230000003542 behavioural effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229910001679 gibbsite Inorganic materials 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- WZRWMBWPUCWZNN-UHFFFAOYSA-N nonane-4-thiol Chemical compound CCCCCC(S)CCC WZRWMBWPUCWZNN-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 229910052566 spinel group Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/010,035 US5376608A (en) | 1993-01-27 | 1993-01-27 | Sulfur reduction in FCC gasoline |
| US010035 | 1993-01-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06277519A JPH06277519A (ja) | 1994-10-04 |
| JP3693362B2 true JP3693362B2 (ja) | 2005-09-07 |
Family
ID=21743475
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP01498194A Expired - Fee Related JP3693362B2 (ja) | 1993-01-27 | 1994-01-14 | 触媒組成物およびfccガソリン中の硫黄低減法 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5376608A (index.php) |
| EP (1) | EP0609971B1 (index.php) |
| JP (1) | JP3693362B2 (index.php) |
| KR (1) | KR100301883B1 (index.php) |
| CN (1) | CN1049678C (index.php) |
| CA (1) | CA2113219C (index.php) |
| DE (1) | DE69414278T2 (index.php) |
| ES (1) | ES2122154T3 (index.php) |
| TW (1) | TW287120B (index.php) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5376608A (en) * | 1993-01-27 | 1994-12-27 | W. R. Grace & Co.-Conn. | Sulfur reduction in FCC gasoline |
| US6482313B1 (en) | 1994-10-03 | 2002-11-19 | Exxonmobil Research And Engineering Company | FCC process incorporating crystalline microporous oxide catalysts having increased Lewis acidity |
| US6673734B1 (en) | 1994-10-03 | 2004-01-06 | Exxonmobil Research And Engineering Company | Crystalline microporous oxide catalysts having increased Lewis acidity and methods for the preparation thereof |
| US6036847A (en) * | 1996-03-26 | 2000-03-14 | W. R. Grace & Co.-Conn. | Compositions for use in catalytic cracking to make reduced sulfur content gasoline |
| NO317500B1 (no) | 1998-03-13 | 2004-11-08 | Statoil Asa | Fremgangsmate og sammensetning for reduksjon av svovelinnholdet i en hydrokarbonblanding, samt anvendelse derav |
| US6974787B2 (en) | 1998-08-31 | 2005-12-13 | Exxonmobil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US20020153283A1 (en) * | 1998-12-28 | 2002-10-24 | Arthur W Chester | Gasoline sulfur reduction in fluid catalytic cracking |
| US6852214B1 (en) | 1998-08-31 | 2005-02-08 | Mobil Oil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US6846403B2 (en) * | 1998-12-28 | 2005-01-25 | Mobil Oil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US7803267B2 (en) * | 1998-12-28 | 2010-09-28 | W. R. Grace & Co.-Conn. | Gasoline sulfur reduction in fluid catalytic cracking |
| CN1122702C (zh) * | 1998-12-29 | 2003-10-01 | 中国石油化工集团公司 | 一种烃类催化裂化硫转移助剂及其使用方法 |
| US6635169B1 (en) | 1999-09-20 | 2003-10-21 | Mobil Oil Corporation | Method for reducing gasoline sulfur in fluid catalytic cracking |
| JP4609961B2 (ja) * | 2000-01-28 | 2011-01-12 | Jx日鉱日石エネルギー株式会社 | 硫黄化合物の除去方法 |
| CN1102640C (zh) * | 2000-07-11 | 2003-03-05 | 石油大学(华东) | 用于精制轻质油品的催化裂化脱硫催化剂 |
| US6635168B2 (en) * | 2001-04-13 | 2003-10-21 | W. R. Grace & Co.-Conn | Gasoline sulfur reduction catalyst for fluid catalytic cracking process |
| US6558533B2 (en) | 2001-04-13 | 2003-05-06 | W.R. Grace & Co.-Conn | Process for sulfur removal from hydrocarbon liquids |
| US7153413B2 (en) * | 2001-07-10 | 2006-12-26 | W.R. Grace &Co.-Conn. | Gasoline sulfur reduction in fluid catalytic cracking |
| AU2003242751A1 (en) | 2002-06-28 | 2004-01-19 | Albemarle Netherlands B.V. | Fcc catalyst for reducing the sulfur content in gasoline and diesel |
| US7449104B2 (en) * | 2002-07-05 | 2008-11-11 | Conocophilips Company | Integrated catalytic cracking and desulfurization system |
| EP1403358A1 (en) * | 2002-09-27 | 2004-03-31 | ENI S.p.A. | Process and catalysts for deep desulphurization of fuels |
| US7507686B2 (en) * | 2002-12-03 | 2009-03-24 | W. R. Grace & Co. - Conn. | Gasoline sulfur reduction in fluid catalytic cracking |
| US7160438B2 (en) * | 2002-12-19 | 2007-01-09 | W.R. Grace & Co. - Conn. | Process for removal of nitrogen containing contaminants from gas oil feedstreams |
| US7087156B2 (en) * | 2002-12-19 | 2006-08-08 | W.R. Grace & Co. - Conn. | Process for removal of nitrogen containing contaminants from gas oil feedstreams |
| CN1261216C (zh) * | 2003-05-30 | 2006-06-28 | 中国石油化工股份有限公司 | 一种含分子筛的烃类裂化催化剂及其制备方法 |
| CN1261528C (zh) | 2003-06-30 | 2006-06-28 | 中国石油化工股份有限公司 | 一种具有脱硫作用的裂化催化剂 |
| US7347930B2 (en) * | 2003-10-16 | 2008-03-25 | China Petroleum & Chemical Corporation | Process for cracking hydrocarbon oils |
| US8084383B2 (en) * | 2004-03-16 | 2011-12-27 | W.R. Grace & Co.-Conn. | Gasoline sulfur reduction catalyst for fluid catalytic cracking process |
| US20050205466A1 (en) * | 2004-03-19 | 2005-09-22 | Beswick Colin L | Zn-containing FCC catalyst and use thereof for the reduction of sulfur in gasoline |
| TWI523688B (zh) * | 2005-02-25 | 2016-03-01 | W R 康格雷氏公司 | 減少觸媒裂解石油餾分之硫含量之方法及流體觸媒裂解程序 |
| CN100404128C (zh) * | 2005-05-12 | 2008-07-23 | 中国石油天然气股份有限公司 | 一种降低汽油硫含量的催化裂化助剂、制备方法及应用 |
| CN101855013B (zh) * | 2006-03-15 | 2013-05-01 | 巴斯福催化剂公司 | 用于在催化裂化过程中降低汽油硫含量的催化剂组合物 |
| US8409428B2 (en) | 2006-06-28 | 2013-04-02 | Saudi Arabian Oil Company | Catalyst additive for reduction of sulfur in catalytically cracked gasoline |
| US8623199B2 (en) | 2006-06-28 | 2014-01-07 | Saudi Arabian Oil Company | Clay additive for reduction of sulfur in catalytically cracked gasoline |
| JP5008666B2 (ja) | 2006-06-28 | 2012-08-22 | 出光興産株式会社 | 脱硫機能付加流動接触分解触媒及びその製造方法並びに該脱硫機能付加流動接触分解触媒を用いた低硫黄接触分解ガソリンの製造方法 |
| US8901026B2 (en) * | 2007-02-21 | 2014-12-02 | W. R. Grace & Co.-Conn. | Gasoline sulfur reduction catalyst for fluid catalytic cracking process |
| CN105148895A (zh) * | 2008-07-30 | 2015-12-16 | 沙特阿拉伯石油公司 | 金属粘土基fcc汽油降硫添加剂组合物 |
| CN101921611B (zh) * | 2009-06-12 | 2013-07-31 | 中国石油天然气股份有限公司 | 一种降低汽油硫含量的催化裂化方法及系统 |
| US8905478B2 (en) * | 2010-03-17 | 2014-12-09 | Britax Child Safety, Inc. | Child safety seat with structural support |
| US20140235429A1 (en) * | 2011-10-12 | 2014-08-21 | Indian Oil Corporation Ltd. | Process for enhancing nickel tolerance of heavy hydrocarbon cracking catalysts |
| CN103055919B (zh) * | 2011-10-18 | 2015-08-26 | 中国石油化工股份有限公司 | 一种蒸汽裂解制丙烯的规整结构催化剂 |
| WO2013064955A2 (en) | 2011-11-03 | 2013-05-10 | Indian Oil Corporation Ltd. | Process for reduction of sulfur in fcc liquid products through the use of carbon monoxide as a reducing agent |
| CN104549475B (zh) * | 2013-10-29 | 2017-02-08 | 中国石油天然气股份有限公司 | 一种催化裂化汽油脱硫催化剂组合物的制备方法 |
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- 1993-01-27 US US08/010,035 patent/US5376608A/en not_active Expired - Lifetime
- 1993-11-24 TW TW082109900A patent/TW287120B/zh not_active IP Right Cessation
-
1994
- 1994-01-11 CA CA002113219A patent/CA2113219C/en not_active Expired - Lifetime
- 1994-01-12 KR KR1019940000546A patent/KR100301883B1/ko not_active Expired - Fee Related
- 1994-01-14 JP JP01498194A patent/JP3693362B2/ja not_active Expired - Fee Related
- 1994-01-18 EP EP94250006A patent/EP0609971B1/en not_active Expired - Lifetime
- 1994-01-18 ES ES94250006T patent/ES2122154T3/es not_active Expired - Lifetime
- 1994-01-18 DE DE69414278T patent/DE69414278T2/de not_active Expired - Lifetime
- 1994-01-27 CN CN94101167A patent/CN1049678C/zh not_active Expired - Lifetime
- 1994-08-30 US US08/297,738 patent/US5525210A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| TW287120B (index.php) | 1996-10-01 |
| CA2113219A1 (en) | 1994-07-28 |
| CN1049678C (zh) | 2000-02-23 |
| CA2113219C (en) | 2002-11-12 |
| JPH06277519A (ja) | 1994-10-04 |
| US5525210A (en) | 1996-06-11 |
| DE69414278T2 (de) | 1999-06-10 |
| ES2122154T3 (es) | 1998-12-16 |
| US5376608A (en) | 1994-12-27 |
| EP0609971A1 (en) | 1994-08-10 |
| KR940018134A (ko) | 1994-08-16 |
| CN1093735A (zh) | 1994-10-19 |
| EP0609971B1 (en) | 1998-11-04 |
| DE69414278D1 (de) | 1998-12-10 |
| KR100301883B1 (ko) | 2001-11-30 |
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