JP3588135B2 - 乾燥ロイコ硫化染料 - Google Patents
乾燥ロイコ硫化染料 Download PDFInfo
- Publication number
- JP3588135B2 JP3588135B2 JP29016893A JP29016893A JP3588135B2 JP 3588135 B2 JP3588135 B2 JP 3588135B2 JP 29016893 A JP29016893 A JP 29016893A JP 29016893 A JP29016893 A JP 29016893A JP 3588135 B2 JP3588135 B2 JP 3588135B2
- Authority
- JP
- Japan
- Prior art keywords
- sulfur dye
- drying
- leuco
- dried
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000988 sulfur dye Substances 0.000 title claims description 28
- 238000001035 drying Methods 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 28
- 239000002245 particle Substances 0.000 claims description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
- 239000007789 gas Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000004043 dyeing Methods 0.000 claims description 16
- 238000001694 spray drying Methods 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- 238000005507 spraying Methods 0.000 claims description 11
- 239000000758 substrate Substances 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- -1 alkali metal sulfite Chemical class 0.000 claims description 7
- 239000011541 reaction mixture Substances 0.000 claims description 6
- 238000006722 reduction reaction Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 229910052945 inorganic sulfide Inorganic materials 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 150000001728 carbonyl compounds Chemical class 0.000 claims description 3
- QTWZICCBKBYHDM-UHFFFAOYSA-N leucomethylene blue Chemical compound C1=C(N(C)C)C=C2SC3=CC(N(C)C)=CC=C3NC2=C1 QTWZICCBKBYHDM-UHFFFAOYSA-N 0.000 claims description 3
- 230000002829 reductive effect Effects 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 238000004458 analytical method Methods 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 230000035945 sensitivity Effects 0.000 claims 1
- 239000000047 product Substances 0.000 description 21
- 239000007921 spray Substances 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000843 powder Substances 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 210000002268 wool Anatomy 0.000 description 6
- 239000000975 dye Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- XLSMFKSTNGKWQX-UHFFFAOYSA-N hydroxyacetone Chemical compound CC(=O)CO XLSMFKSTNGKWQX-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 2
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- VYZAHLCBVHPDDF-UHFFFAOYSA-N Dinitrochlorobenzene Chemical compound [O-][N+](=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 VYZAHLCBVHPDDF-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229930194542 Keto Natural products 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 150000001323 aldoses Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004807 desolvation Methods 0.000 description 1
- 239000011363 dried mixture Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229940017705 formaldehyde sulfoxylate Drugs 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002402 hexoses Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B49/00—Sulfur dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0077—Preparations with possibly reduced vat, sulfur or indigo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB929224368A GB9224368D0 (en) | 1992-11-20 | 1992-11-20 | Improvements in or relating to organic compounds |
| GB9224368:2 | 1992-11-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06212084A JPH06212084A (ja) | 1994-08-02 |
| JP3588135B2 true JP3588135B2 (ja) | 2004-11-10 |
Family
ID=10725424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29016893A Expired - Fee Related JP3588135B2 (ja) | 1992-11-20 | 1993-11-19 | 乾燥ロイコ硫化染料 |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JP3588135B2 (ko) |
| KR (1) | KR100295722B1 (ko) |
| CN (1) | CN1051785C (ko) |
| BR (1) | BR9304762A (ko) |
| CH (1) | CH686084A5 (ko) |
| DE (1) | DE4338312A1 (ko) |
| ES (1) | ES2073373B1 (ko) |
| FR (1) | FR2698371B1 (ko) |
| GB (2) | GB9224368D0 (ko) |
| IT (1) | IT1262445B (ko) |
| TR (1) | TR28694A (ko) |
| TW (1) | TW349979B (ko) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19502968A1 (de) * | 1995-01-31 | 1996-08-01 | Basf Ag | Leukoküpenfarbstoff-Präparationen in Granulatform |
| GB9504870D0 (en) * | 1995-03-10 | 1995-04-26 | Sandoz Ltd | Improvements in or relating to organic compounds |
| US20030149288A1 (en) * | 2000-04-18 | 2003-08-07 | Natural Asa | Conjugated linoleic acid powder |
| CN100494288C (zh) * | 2004-12-27 | 2009-06-03 | 阮加根 | 硫化黑染料的制备工艺及其产品 |
| CN102174272A (zh) * | 2011-03-17 | 2011-09-07 | 浙江长征化工有限公司 | 一种硫化黑染料的制备方法及产品 |
| WO2024156891A1 (en) * | 2023-01-27 | 2024-08-02 | Philip Morris Products S.A. | Pouch for oral use, method for producing a dry substrate, and use of a composition comprising glycerol for reducing dust formation of a dry substrate |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4917706B2 (en) * | 1988-02-01 | 1996-02-20 | Sandoz Ltd | Liquid compositions of prereduced sulfur dyes and production thereof |
| DE4215678A1 (de) * | 1991-05-23 | 1992-11-26 | Sandoz Ag | Trockene leukoschwefelfarbstoffe |
-
1992
- 1992-11-20 GB GB929224368A patent/GB9224368D0/en active Pending
-
1993
- 1993-11-10 DE DE4338312A patent/DE4338312A1/de not_active Withdrawn
- 1993-11-16 CH CH342093A patent/CH686084A5/de not_active IP Right Cessation
- 1993-11-16 IT ITRM930764A patent/IT1262445B/it active IP Right Grant
- 1993-11-17 FR FR9313816A patent/FR2698371B1/fr not_active Expired - Fee Related
- 1993-11-18 GB GB9323809A patent/GB2273103B/en not_active Expired - Fee Related
- 1993-11-18 BR BR9304762A patent/BR9304762A/pt not_active IP Right Cessation
- 1993-11-19 KR KR1019930024771A patent/KR100295722B1/ko not_active IP Right Cessation
- 1993-11-19 ES ES09302423A patent/ES2073373B1/es not_active Expired - Fee Related
- 1993-11-19 TR TR01075/93A patent/TR28694A/xx unknown
- 1993-11-19 JP JP29016893A patent/JP3588135B2/ja not_active Expired - Fee Related
- 1993-11-19 CN CN93115065A patent/CN1051785C/zh not_active Expired - Fee Related
- 1993-11-25 TW TW081104058A01A patent/TW349979B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| CH686084A5 (de) | 1995-12-29 |
| DE4338312A1 (de) | 1994-05-26 |
| BR9304762A (pt) | 1994-05-24 |
| KR100295722B1 (ko) | 2001-11-30 |
| FR2698371A1 (fr) | 1994-05-27 |
| CN1051785C (zh) | 2000-04-26 |
| TR28694A (tr) | 1997-01-08 |
| GB9224368D0 (en) | 1993-01-13 |
| ITRM930764A1 (it) | 1995-05-16 |
| ITRM930764A0 (it) | 1993-11-16 |
| GB9323809D0 (en) | 1994-01-05 |
| ES2073373B1 (es) | 1996-02-16 |
| CN1088236A (zh) | 1994-06-22 |
| GB2273103A (en) | 1994-06-08 |
| KR940011585A (ko) | 1994-06-21 |
| IT1262445B (it) | 1996-06-19 |
| GB2273103B (en) | 1996-04-24 |
| TW349979B (en) | 1999-01-11 |
| JPH06212084A (ja) | 1994-08-02 |
| FR2698371B1 (fr) | 1995-08-18 |
| ES2073373A1 (es) | 1995-08-01 |
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| A61 | First payment of annual fees (during grant procedure) |
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