JP2544636B2 - 洗剤粉末及びその製造方法 - Google Patents
洗剤粉末及びその製造方法Info
- Publication number
- JP2544636B2 JP2544636B2 JP62274583A JP27458387A JP2544636B2 JP 2544636 B2 JP2544636 B2 JP 2544636B2 JP 62274583 A JP62274583 A JP 62274583A JP 27458387 A JP27458387 A JP 27458387A JP 2544636 B2 JP2544636 B2 JP 2544636B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- powder
- spray
- detergent active
- exceeding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000843 powder Substances 0.000 title claims description 109
- 239000003599 detergent Substances 0.000 title claims description 55
- 238000004519 manufacturing process Methods 0.000 title claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 51
- 239000002245 particle Substances 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 41
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 22
- 150000003839 salts Chemical class 0.000 claims description 20
- 239000002002 slurry Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 17
- 239000003792 electrolyte Substances 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 15
- 238000001694 spray drying Methods 0.000 claims description 14
- 239000004615 ingredient Substances 0.000 claims description 11
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 235000012217 sodium aluminium silicate Nutrition 0.000 claims description 8
- 239000000429 sodium aluminium silicate Substances 0.000 claims description 7
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 229920005646 polycarboxylate Polymers 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 239000002585 base Substances 0.000 description 41
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 23
- 239000003945 anionic surfactant Substances 0.000 description 20
- 229910052938 sodium sulfate Inorganic materials 0.000 description 14
- 235000011152 sodium sulphate Nutrition 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000007921 spray Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000004115 Sodium Silicate Substances 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- -1 primary alcohol sulfate Chemical class 0.000 description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
- 229910052911 sodium silicate Inorganic materials 0.000 description 6
- 239000010457 zeolite Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000011343 solid material Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 150000003138 primary alcohols Chemical class 0.000 description 3
- 150000003333 secondary alcohols Chemical class 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 238000002459 porosimetry Methods 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000001226 reprecipitation Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- PTHBKNSHSCMKBV-UHFFFAOYSA-N 4,6,8-trihydroxy-3-(2-hydroxyethyl)-2,3-dihydronaphtho[2,3-f][1]benzofuran-5,10-dione Chemical compound O=C1C2=CC(O)=CC(O)=C2C(=O)C2=C1C=C1OCC(CCO)C1=C2O PTHBKNSHSCMKBV-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920002344 Sokalan® PA 110 S Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000003416 augmentation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- UPBDXRPQPOWRKR-UHFFFAOYSA-N furan-2,5-dione;methoxyethene Chemical compound COC=C.O=C1OC(=O)C=C1 UPBDXRPQPOWRKR-UHFFFAOYSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- KGZJRXKGJRJKCB-UHFFFAOYSA-N hanf Chemical compound C=1C=CC=CC=1CC(C(=O)NC(CCCNC(N)=N)C(=O)NC(CC=1C=CC(O)=CC=1)C(O)=O)NC(=O)C(CO)NC(=O)C(CC(N)=O)NC(=O)C(CS)NC(=O)CNC(=O)C(CC(C)C)NC(=O)CNC(=O)C(CO)NC(=O)C(CCC(N)=O)NC(=O)C(C)NC(=O)CNC(=O)C(C(C)CC)NC(=O)C(CCCNC(N)=N)NC(=O)C(CC(O)=O)NC(=O)C(CCSC)NC(=O)C(CCCNC(N)=N)NC(=O)CNC(=O)CNC(=O)C(NC(=O)C(CS)NC(=O)C(CO)NC(=O)C(CO)NC(=O)C(CCCNC(N)=N)NC(=O)C(CCCNC(N)=N)NC(=O)C(CC(C)C)NC(=O)C(N)CO)CC1=CC=CC=C1 KGZJRXKGJRJKCB-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000004482 other powder Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000001007 puffing effect Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- PTHBKNSHSCMKBV-ZETCQYMHSA-N versicol Natural products OCC[C@H]1COc2cc3C(=O)c4cc(O)cc(O)c4C(=O)c3c(O)c12 PTHBKNSHSCMKBV-ZETCQYMHSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8626082 | 1986-10-31 | ||
| GB868626082A GB8626082D0 (en) | 1986-10-31 | 1986-10-31 | Detergent powders |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63122797A JPS63122797A (ja) | 1988-05-26 |
| JP2544636B2 true JP2544636B2 (ja) | 1996-10-16 |
Family
ID=10606625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62274583A Expired - Lifetime JP2544636B2 (ja) | 1986-10-31 | 1987-10-29 | 洗剤粉末及びその製造方法 |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0270240B1 (tr) |
| JP (1) | JP2544636B2 (tr) |
| KR (1) | KR920001993B1 (tr) |
| AU (1) | AU602932B2 (tr) |
| BR (1) | BR8705812A (tr) |
| CA (1) | CA1303938C (tr) |
| DE (1) | DE3787511T2 (tr) |
| ES (1) | ES2059393T3 (tr) |
| GB (1) | GB8626082D0 (tr) |
| TR (1) | TR24414A (tr) |
| ZA (1) | ZA878120B (tr) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1286563C (en) * | 1986-04-04 | 1991-07-23 | Jan Hendrik Eertink | Detergent powders and processes for preparing them |
| GB8810193D0 (en) * | 1988-04-29 | 1988-06-02 | Unilever Plc | Detergent compositions & process for preparing them |
| US5024782A (en) * | 1989-06-16 | 1991-06-18 | The Clorox Company | Zeolite agglomeration process and product |
| GB8918984D0 (en) * | 1989-08-21 | 1989-10-04 | Unilever Plc | Detergent compositions |
| GB8924294D0 (en) * | 1989-10-27 | 1989-12-13 | Unilever Plc | Detergent compositions |
| GB9012612D0 (en) * | 1990-06-06 | 1990-07-25 | Unilever Plc | Detergents compositions |
| DE4100306A1 (de) * | 1991-01-08 | 1992-07-09 | Henkel Kgaa | Kornfoermige, leicht loesliche trockenkonzentrate von inhaltsstoffen aus wasch- und/oder reinigungsmitteln und verfahren zu ihrer herstellung |
| DE4104085A1 (de) * | 1991-02-11 | 1992-08-13 | Henkel Kgaa | Granulares additiv fuer wasch- und reinigungsmittel |
| GB9104547D0 (en) * | 1991-03-05 | 1991-04-17 | Unilever Plc | Detergent compositions |
| DE4211699A1 (de) * | 1992-04-08 | 1993-10-14 | Henkel Kgaa | Verfahren zur Erhöhung des Schüttgewichts sprühgetrockneter Waschmittel |
| ES2116311T3 (es) * | 1992-07-15 | 1998-07-16 | Procter & Gamble | Procedimiento y composiciones para detergentes compactos. |
| JPH08501118A (ja) * | 1992-09-08 | 1996-02-06 | ユニリーバー・ナームローゼ・ベンノートシヤープ | 洗剤組成物及びその製造方法 |
| GB9313878D0 (en) * | 1993-07-05 | 1993-08-18 | Unilever Plc | Detergent composition or component containing anionic surfactant and process for its preparation |
| GB9317180D0 (en) * | 1993-08-18 | 1993-10-06 | Unilever Plc | Granular detergent compositions containing zeolite and process for their preparation |
| EP0653481A1 (en) * | 1993-11-11 | 1995-05-17 | The Procter & Gamble Company | Granular detergent composition |
| EP0745119B1 (de) * | 1994-02-18 | 1999-12-08 | Henkel-Ecolab GmbH & Co. OHG | Verfahren zur herstellung von sprühgetrockneten granulaten |
| WO1996018714A1 (fr) * | 1994-12-15 | 1996-06-20 | Nippon Shokubai Co., Ltd. | Adjuvant pour detergent, son procede de fabrication et composition detergente le contenant |
| DE19500644B4 (de) * | 1995-01-12 | 2010-09-09 | Henkel Ag & Co. Kgaa | Sprühgetrocknetes Waschmittel oder Komponente hierfür |
| GB9510695D0 (en) * | 1995-05-26 | 1995-07-19 | Unilever Plc | Detergent composition and process for its production |
| GB9625066D0 (en) * | 1996-12-02 | 1997-01-22 | Unilever Plc | Process for the production of a detergent composition |
| GB0125212D0 (en) | 2001-10-19 | 2001-12-12 | Unilever Plc | Detergent compositions |
| EP1529834A1 (en) * | 2003-11-10 | 2005-05-11 | The Procter & Gamble Company | Detergent particles |
| EP1529833A1 (en) * | 2003-11-10 | 2005-05-11 | The Procter & Gamble Company | Detergent particles |
| JP5705525B2 (ja) * | 2010-12-16 | 2015-04-22 | 花王株式会社 | ゼオライト複合粒子群 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IN161821B (tr) * | 1981-02-26 | 1988-02-06 | Colgate Palmolive Co | |
| US4379080A (en) * | 1981-04-22 | 1983-04-05 | The Procter & Gamble Company | Granular detergent compositions containing film-forming polymers |
| JPS6042279B2 (ja) * | 1982-05-25 | 1985-09-20 | 花王株式会社 | 洗浄剤組成物 |
| GR81618B (tr) * | 1983-06-15 | 1984-12-11 | Procter & Gamble | |
| US4609473A (en) * | 1984-11-26 | 1986-09-02 | Colgate Palmolive Company | Bentonite-sulfate fabric softening particulate agglomerate, processes for manufacture and use thereof, and detergent compositions containing it |
| ZA858950B (en) * | 1984-12-03 | 1987-07-29 | Colgate Palmolive Co | Antistatic built synthetic organic detergent composition |
| DE3444960A1 (de) * | 1984-12-10 | 1986-06-12 | Henkel KGaA, 4000 Düsseldorf | Koerniges adsorptionsmittel |
| GB8504733D0 (en) * | 1985-02-23 | 1985-03-27 | Procter & Gamble Ltd | Detergent compositions |
| JPH0665720B2 (ja) * | 1985-04-03 | 1994-08-24 | 花王株式会社 | 濃縮粉末洗剤組成物 |
| DE3514364A1 (de) * | 1985-04-20 | 1986-10-23 | Henkel KGaA, 4000 Düsseldorf | Koerniges waschmittel mit verbessertem reinigungsvermoegen |
| GB8526999D0 (en) * | 1985-11-01 | 1985-12-04 | Unilever Plc | Detergent compositions |
| JPS62167399A (ja) * | 1986-01-17 | 1987-07-23 | 花王株式会社 | 高密度粒状洗剤の製法 |
| GB8609044D0 (en) * | 1986-04-14 | 1986-05-21 | Unilever Plc | Detergent powders |
-
1986
- 1986-10-31 GB GB868626082A patent/GB8626082D0/en active Pending
-
1987
- 1987-10-26 CA CA000550260A patent/CA1303938C/en not_active Expired - Lifetime
- 1987-10-28 AU AU80416/87A patent/AU602932B2/en not_active Ceased
- 1987-10-29 ZA ZA878120A patent/ZA878120B/xx unknown
- 1987-10-29 EP EP87309570A patent/EP0270240B1/en not_active Revoked
- 1987-10-29 JP JP62274583A patent/JP2544636B2/ja not_active Expired - Lifetime
- 1987-10-29 ES ES87309570T patent/ES2059393T3/es not_active Expired - Lifetime
- 1987-10-29 DE DE87309570T patent/DE3787511T2/de not_active Expired - Lifetime
- 1987-10-30 BR BR8705812A patent/BR8705812A/pt not_active IP Right Cessation
- 1987-10-31 KR KR1019870012175A patent/KR920001993B1/ko not_active IP Right Cessation
- 1987-11-02 TR TR87/0749A patent/TR24414A/tr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0270240B1 (en) | 1993-09-22 |
| KR880005245A (ko) | 1988-06-28 |
| ZA878120B (en) | 1989-07-26 |
| DE3787511D1 (de) | 1993-10-28 |
| TR24414A (tr) | 1991-10-08 |
| BR8705812A (pt) | 1988-05-31 |
| EP0270240A2 (en) | 1988-06-08 |
| AU602932B2 (en) | 1990-11-01 |
| CA1303938C (en) | 1992-06-23 |
| DE3787511T2 (de) | 1994-01-20 |
| JPS63122797A (ja) | 1988-05-26 |
| EP0270240A3 (en) | 1990-01-03 |
| GB8626082D0 (en) | 1986-12-03 |
| ES2059393T3 (es) | 1994-11-16 |
| AU8041687A (en) | 1988-05-05 |
| KR920001993B1 (ko) | 1992-03-09 |
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