JP2023500501A - 新規の遷移金属触媒 - Google Patents

新規の遷移金属触媒 Download PDF

Info

Publication number
JP2023500501A
JP2023500501A JP2022525801A JP2022525801A JP2023500501A JP 2023500501 A JP2023500501 A JP 2023500501A JP 2022525801 A JP2022525801 A JP 2022525801A JP 2022525801 A JP2022525801 A JP 2022525801A JP 2023500501 A JP2023500501 A JP 2023500501A
Authority
JP
Japan
Prior art keywords
transition metal
metal catalyst
formula
ligand
catalyst according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2022525801A
Other languages
English (en)
Japanese (ja)
Other versions
JP2023500501A5 (https=
Inventor
ワーナー ボンラス,
フレデリック ブルジョワ,
ジョナサン, アラン メドロック,
クリストフ シュパール,
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DSM IP Assets BV
Original Assignee
DSM IP Assets BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DSM IP Assets BV filed Critical DSM IP Assets BV
Publication of JP2023500501A publication Critical patent/JP2023500501A/ja
Publication of JP2023500501A5 publication Critical patent/JP2023500501A5/ja
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0033Iridium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/64Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0269Complexes comprising ligands derived from the natural chiral pool or otherwise having a characteristic structure or geometry
    • B01J2531/0275Complexes comprising ligands derived from the natural chiral pool or otherwise having a characteristic structure or geometry derived from amino acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/827Iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2022525801A 2019-11-07 2020-11-02 新規の遷移金属触媒 Pending JP2023500501A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP19207604.0 2019-11-07
EP19207604 2019-11-07
PCT/EP2020/080685 WO2021089482A1 (en) 2019-11-07 2020-11-02 New transition metal catalyst

Publications (2)

Publication Number Publication Date
JP2023500501A true JP2023500501A (ja) 2023-01-06
JP2023500501A5 JP2023500501A5 (https=) 2023-06-23

Family

ID=68502843

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2022525801A Pending JP2023500501A (ja) 2019-11-07 2020-11-02 新規の遷移金属触媒

Country Status (6)

Country Link
US (1) US20230001399A1 (https=)
EP (1) EP4055025A1 (https=)
JP (1) JP2023500501A (https=)
CN (1) CN114630712A (https=)
BR (1) BR112022008568A2 (https=)
WO (1) WO2021089482A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119613312A (zh) * 2024-12-30 2025-03-14 石河子大学 一种具有c2轴对称结构的手性伯胺催化剂及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002501490A (ja) * 1997-03-26 2002-01-15 アベシア・リミテッド 転移水素化方法及び触媒
JP2012062270A (ja) * 2010-09-15 2012-03-29 Kanto Chem Co Inc アミン化合物の製造方法
JP2017095462A (ja) * 2011-07-15 2017-06-01 浜理薬品工業株式会社 光学活性テトラヒドロキノリン類の製造方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1015655C2 (nl) * 2000-07-07 2002-01-08 Dsm Nv Katalysator voor de asymmetrische hydrogenering.
GB0029356D0 (en) * 2000-12-01 2001-01-17 Avecia Ltd Transfer hydrogenation
ATE526314T1 (de) * 2003-08-26 2011-10-15 Ecole Polytech Ionische flüssigkeiten basierend auf imidazoliumsalzen mit einer nitrilfunktionalität
JP6948952B2 (ja) * 2015-05-28 2021-10-13 ビーエイエスエフ・ソシエタス・エウロパエアBasf Se 均一系触媒によるカルボニル化合物の還元的アミノ化法
GB201522437D0 (en) * 2015-12-18 2016-02-03 Univ Leeds Tethered ligands

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002501490A (ja) * 1997-03-26 2002-01-15 アベシア・リミテッド 転移水素化方法及び触媒
JP2012062270A (ja) * 2010-09-15 2012-03-29 Kanto Chem Co Inc アミン化合物の製造方法
JP2017095462A (ja) * 2011-07-15 2017-06-01 浜理薬品工業株式会社 光学活性テトラヒドロキノリン類の製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SYNTHETIC COMMUNICATIONS, vol. 49, no. 6, JPN7024003181, 2019, pages 814 - 822, ISSN: 0005380737 *

Also Published As

Publication number Publication date
US20230001399A1 (en) 2023-01-05
CN114630712A (zh) 2022-06-14
WO2021089482A1 (en) 2021-05-14
EP4055025A1 (en) 2022-09-14
BR112022008568A2 (pt) 2022-08-09

Similar Documents

Publication Publication Date Title
US9416100B2 (en) Process for hydrogenating ketones in the presence of Ru(II) catalysts
EP1276745B1 (en) Ruthenium-diphosphine complexes and their use as catalysts
Jiang et al. New chiral ligands for catalytic asymmetric transfer hydrogenation of ketones
JP4500289B2 (ja) 2,3−ビス(ジアルキルホスフィノ)ピラジン誘導体及びその製造方法、並びに該誘導体を配位子とする金属錯体
EP1849792B1 (en) Biphosphine ruthenium complexes with chiral diamine ligands as catalysts
JP2010512379A (ja) プロセス
WO2008012240A1 (en) Asymmetric hydrogenation of 1,1,1-trifluoroacetone
JP2007528837A (ja) ヒドロコドンおよびヒドロモルフォンの触媒的製造方法
JP2023500501A (ja) 新規の遷移金属触媒
JP6476497B2 (ja) 光学活性化合物の製造方法、及び新規な金属−ジアミン錯体
CA2253888C (en) Process for manufacture of trans-(r,r)-actinol
RU2446154C2 (ru) Сульфонилированные дифенилэтилендиамины, способ их получения и применение в катализе гидрирования с переносом водорода
WO2003082885A1 (en) Phosphinometallocenylamides as novel ligands for asymmetric catalysis
WO2009122408A1 (en) STABLE C - (sup3) - CYCLOMETALATED PINCER COMPLEXES, THEIR PREPARATION AND USE AS CATALYSTS
US9029571B2 (en) Device and method for evaluating organic material for organic solar cell
JP3682517B2 (ja) イミンおよびエナミンの製造方法
JP2005306804A (ja) 光学活性3−キヌクリジノールの製造方法
CN121914052A (zh) 一种手性5,7-二氟色满-4-醇的合成方法
CN121342889A (zh) 用于不饱和酮不对称氢化反应的手性氮氮膦化合物、制备方法及应用
JP2018127405A (ja) ブロナンセリンの製造方法
CN121627764A (zh) 一种具有顺式构型的2,3-二氢苯并[d] [1,3]氧杂磷杂茂配体及其制备方法和应用
WO2007035901A2 (en) Bifunctional catalysts for isomerization of unsaturated hydrocarbons
CN121873134A (zh) 一种环二烯羰基金属化合物的制备方法
JP3624302B2 (ja) 新規パラジウム−ピリジニルピラゾール錯体
WO2009030626A1 (en) New phosphine-phosphite ligands

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20230615

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20230615

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20240614

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20240730

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20250128