CN114630712A - 新型过渡金属催化剂 - Google Patents

新型过渡金属催化剂 Download PDF

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Publication number
CN114630712A
CN114630712A CN202080076801.XA CN202080076801A CN114630712A CN 114630712 A CN114630712 A CN 114630712A CN 202080076801 A CN202080076801 A CN 202080076801A CN 114630712 A CN114630712 A CN 114630712A
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CN
China
Prior art keywords
transition metal
ligand
metal catalyst
formula
catalyst
Prior art date
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Pending
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CN202080076801.XA
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English (en)
Chinese (zh)
Inventor
维尔纳·邦拉蒂
弗雷德里克·布儒瓦
乔纳森·艾伦·米德洛克
克里斯托夫·斯帕罗
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DSM IP Assets BV
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DSM IP Assets BV
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Publication of CN114630712A publication Critical patent/CN114630712A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0033—Iridium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0269—Complexes comprising ligands derived from the natural chiral pool or otherwise having a characteristic structure or geometry
    • B01J2531/0275—Complexes comprising ligands derived from the natural chiral pool or otherwise having a characteristic structure or geometry derived from amino acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN202080076801.XA 2019-11-07 2020-11-02 新型过渡金属催化剂 Pending CN114630712A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP19207604.0 2019-11-07
EP19207604 2019-11-07
PCT/EP2020/080685 WO2021089482A1 (en) 2019-11-07 2020-11-02 New transition metal catalyst

Publications (1)

Publication Number Publication Date
CN114630712A true CN114630712A (zh) 2022-06-14

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202080076801.XA Pending CN114630712A (zh) 2019-11-07 2020-11-02 新型过渡金属催化剂

Country Status (6)

Country Link
US (1) US20230001399A1 (https=)
EP (1) EP4055025A1 (https=)
JP (1) JP2023500501A (https=)
CN (1) CN114630712A (https=)
BR (1) BR112022008568A2 (https=)
WO (1) WO2021089482A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119613312A (zh) * 2024-12-30 2025-03-14 石河子大学 一种具有c2轴对称结构的手性伯胺催化剂及其制备方法和应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1537088A (zh) * 2000-12-01 2004-10-13 转移氢化方法和催化剂
CN1974010A (zh) * 2000-07-07 2007-06-06 Dsmip财产有限公司 不对称(转移)氢化催化剂
CN101817785A (zh) * 2003-08-26 2010-09-01 洛桑联邦理工学院 基于结合有腈官能团的咪唑鎓的离子液体
CN107980011A (zh) * 2015-05-28 2018-05-01 巴斯夫欧洲公司 均相催化还原胺化羰基化合物的方法
CN108368145A (zh) * 2015-12-18 2018-08-03 利兹大学 金属络合物

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9706321D0 (en) * 1997-03-26 1997-05-14 Zeneca Ltd Catalytic hydrogenation
JP5847386B2 (ja) * 2010-09-15 2016-01-20 関東化學株式会社 アミン化合物の製造方法
US9108986B2 (en) * 2011-07-15 2015-08-18 Hamari Chemicals, Ltd. Method for producing optically active tetrahydroquinolines

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1974010A (zh) * 2000-07-07 2007-06-06 Dsmip财产有限公司 不对称(转移)氢化催化剂
CN1537088A (zh) * 2000-12-01 2004-10-13 转移氢化方法和催化剂
CN101817785A (zh) * 2003-08-26 2010-09-01 洛桑联邦理工学院 基于结合有腈官能团的咪唑鎓的离子液体
CN107980011A (zh) * 2015-05-28 2018-05-01 巴斯夫欧洲公司 均相催化还原胺化羰基化合物的方法
CN108368145A (zh) * 2015-12-18 2018-08-03 利兹大学 金属络合物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
HIROKI FUJIEDA ET AL: "New synthetic route to the important (S)-5-(1-(tert-butoxycarbonyl)pyrrolidin-2-yl)-2-methylthiophene-3-carboxylic acid intermediatefor the synthesis of a novel glucokinase activator" *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119613312A (zh) * 2024-12-30 2025-03-14 石河子大学 一种具有c2轴对称结构的手性伯胺催化剂及其制备方法和应用

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Publication number Publication date
US20230001399A1 (en) 2023-01-05
JP2023500501A (ja) 2023-01-06
WO2021089482A1 (en) 2021-05-14
EP4055025A1 (en) 2022-09-14
BR112022008568A2 (pt) 2022-08-09

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