JP2022511475A - 液体媒体からガスを放出する方法および装置 - Google Patents
液体媒体からガスを放出する方法および装置 Download PDFInfo
- Publication number
- JP2022511475A JP2022511475A JP2021531504A JP2021531504A JP2022511475A JP 2022511475 A JP2022511475 A JP 2022511475A JP 2021531504 A JP2021531504 A JP 2021531504A JP 2021531504 A JP2021531504 A JP 2021531504A JP 2022511475 A JP2022511475 A JP 2022511475A
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- JP
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- Prior art keywords
- reactor
- gas
- hydrogen
- liquid
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- 238000000034 method Methods 0.000 title claims abstract description 38
- 238000007599 discharging Methods 0.000 claims abstract description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 120
- 239000001257 hydrogen Substances 0.000 claims description 83
- 229910052739 hydrogen Inorganic materials 0.000 claims description 83
- 239000007789 gas Substances 0.000 claims description 71
- 239000003054 catalyst Substances 0.000 claims description 39
- 238000006243 chemical reaction Methods 0.000 claims description 35
- 239000000446 fuel Substances 0.000 claims description 33
- 238000009434 installation Methods 0.000 claims description 17
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- 229910052751 metal Inorganic materials 0.000 description 8
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 238000009835 boiling Methods 0.000 description 7
- 238000012546 transfer Methods 0.000 description 6
- RQOCUPXJUOOIRL-UHFFFAOYSA-N 1,3-dicyclohexylpropan-2-ylbenzene Chemical compound C(C1CCCCC1)C(C1=CC=CC=C1)CC1CCCCC1 RQOCUPXJUOOIRL-UHFFFAOYSA-N 0.000 description 5
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- NMTMUASYSMIDRL-UHFFFAOYSA-N 1-(cyclohexylmethyl)-2-methylbenzene Chemical compound CC1=CC=CC=C1CC1CCCCC1 NMTMUASYSMIDRL-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
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- 230000008901 benefit Effects 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 239000011949 solid catalyst Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229920000867 polyelectrolyte Polymers 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- LAIUFBWHERIJIH-UHFFFAOYSA-N 3-Methylheptane Chemical compound CCCCC(C)CC LAIUFBWHERIJIH-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
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- 230000007423 decrease Effects 0.000 description 2
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- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
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- 229910052733 gallium Inorganic materials 0.000 description 2
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- -1 hydrogen compound Chemical class 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- JXPOLSKBTUYKJB-UHFFFAOYSA-N xi-2,3-Dimethylhexane Chemical compound CCCC(C)C(C)C JXPOLSKBTUYKJB-UHFFFAOYSA-N 0.000 description 2
- WGECXQBGLLYSFP-UHFFFAOYSA-N (+-)-2,3-dimethyl-pentane Natural products CCC(C)C(C)C WGECXQBGLLYSFP-UHFFFAOYSA-N 0.000 description 1
- PKQYSCBUFZOAPE-UHFFFAOYSA-N 1,2-dibenzyl-3-methylbenzene Chemical compound C=1C=CC=CC=1CC=1C(C)=CC=CC=1CC1=CC=CC=C1 PKQYSCBUFZOAPE-UHFFFAOYSA-N 0.000 description 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical compound C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- GSXWVOZWKACRTO-UHFFFAOYSA-N 1-ethyl-2,3,3a,4,5,6,7,7a-octahydroindole Chemical compound C1CCCC2N(CC)CCC21 GSXWVOZWKACRTO-UHFFFAOYSA-N 0.000 description 1
- ZXZHBAFJRJGZJJ-UHFFFAOYSA-N 9-butyl-1,2,3,4,4a,4b,5,6,7,8,8a,9a-dodecahydrocarbazole Chemical compound C(CCC)N1C2CCCCC2C2CCCCC12 ZXZHBAFJRJGZJJ-UHFFFAOYSA-N 0.000 description 1
- FUUPYXUBNPJSOA-UHFFFAOYSA-N 9-ethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9a-dodecahydrocarbazole Chemical compound C12CCCCC2N(CC)C2C1CCCC2 FUUPYXUBNPJSOA-UHFFFAOYSA-N 0.000 description 1
- CBCPBBJQRBQOQC-UHFFFAOYSA-N 9-propan-2-yl-1,2,3,4,4a,4b,5,6,7,8,8a,9a-dodecahydrocarbazole Chemical compound C12CCCCC2N(C(C)C)C2C1CCCC2 CBCPBBJQRBQOQC-UHFFFAOYSA-N 0.000 description 1
- LUTBBBWWISEHTH-UHFFFAOYSA-N 9-propyl-1,2,3,4,4a,4b,5,6,7,8,8a,9a-dodecahydrocarbazole Chemical compound C(CC)N1C2CCCCC2C2CCCCC12 LUTBBBWWISEHTH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000004941 influx Effects 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0015—Organic compounds; Solutions thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
- C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102018221447.6 | 2018-12-11 | ||
| DE102018221447.6A DE102018221447A1 (de) | 2018-12-11 | 2018-12-11 | Verfahren und Anlage zum Freisetzen von Gas aus einem flüssigen Medium |
| PCT/EP2019/083711 WO2020120261A1 (de) | 2018-12-11 | 2019-12-04 | Verfahren und anlage zum freisetzen von gas aus einem flüssigen medium |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2022511475A true JP2022511475A (ja) | 2022-01-31 |
Family
ID=68808366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021531504A Pending JP2022511475A (ja) | 2018-12-11 | 2019-12-04 | 液体媒体からガスを放出する方法および装置 |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP3894351A1 (ko) |
| JP (1) | JP2022511475A (ko) |
| KR (1) | KR20210098987A (ko) |
| DE (1) | DE102018221447A1 (ko) |
| WO (1) | WO2020120261A1 (ko) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102021202170A1 (de) * | 2021-03-05 | 2022-10-20 | Hydrogenious Lohc Technologies Gmbh | Verfahren und Anlage zum Bereitstellen von gereinigtem Wasserstoffgas |
| EP4282816A1 (en) | 2022-05-25 | 2023-11-29 | Umicore AG & Co. KG | Catalytic system for storing and releasing of hydrogen from liquid organic hydrogen carriers |
| EP4362146A1 (en) | 2022-10-26 | 2024-05-01 | Umicore AG & Co. KG | Phosphorus doped pgm-type catalysts and catalytic system for storing and releasing of hydrogen of organic hydrogen carriers |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001198469A (ja) * | 1999-11-05 | 2001-07-24 | Sekisui Chem Co Ltd | 水素貯蔵・供給用金属担持触媒及びこれを利用した水素貯蔵・供給システム |
| JP2006188425A (ja) * | 2005-01-04 | 2006-07-20 | Air Products & Chemicals Inc | マイクロチャネル触媒反応装置中の液体燃料の脱水素化 |
| JP2009242232A (ja) * | 2008-03-31 | 2009-10-22 | General Electric Co <Ge> | 水素貯蔵材料及び関連システム |
| US20160061383A1 (en) * | 2014-09-03 | 2016-03-03 | Hydrogenious Technologies Gmbh | Arrangement and method for operating hydrogen filling stations |
| DE102016222596A1 (de) * | 2016-11-16 | 2018-05-17 | Hydrogenious Technologies Gmbh | Verfahren zum Bereitstellen von Wasserstoffgas, Dehydrier-Reaktor und Transport-Container |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7101530B2 (en) * | 2003-05-06 | 2006-09-05 | Air Products And Chemicals, Inc. | Hydrogen storage by reversible hydrogenation of pi-conjugated substrates |
| CN103748034B (zh) * | 2011-08-11 | 2015-10-21 | 丰田自动车株式会社 | 氢精制装置及其使用方法 |
| DE102015225394A1 (de) * | 2015-12-16 | 2017-06-22 | Siemens Aktiengesellschaft | Verfahren zur Energieerzeugung sowie Energieerzeugungsvorrichtung, insbesondere für mobile Anwendungen |
| DE102017201454A1 (de) * | 2017-01-30 | 2018-08-02 | Friedrich-Alexander-Universität Erlangen-Nürnberg | Vorrichtung und Verfahren zum Bereitstellen von Wasserstoffgas |
| DE102017217748A1 (de) * | 2017-10-05 | 2019-04-11 | Hydrogenious Technologies Gmbh | Anlage und Verfahren zur Bereitstellung und weiteren Nutzung von Wasserstoffgas |
-
2018
- 2018-12-11 DE DE102018221447.6A patent/DE102018221447A1/de active Pending
-
2019
- 2019-12-04 WO PCT/EP2019/083711 patent/WO2020120261A1/de unknown
- 2019-12-04 KR KR1020217016446A patent/KR20210098987A/ko active Search and Examination
- 2019-12-04 EP EP19816641.5A patent/EP3894351A1/de active Pending
- 2019-12-04 JP JP2021531504A patent/JP2022511475A/ja active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001198469A (ja) * | 1999-11-05 | 2001-07-24 | Sekisui Chem Co Ltd | 水素貯蔵・供給用金属担持触媒及びこれを利用した水素貯蔵・供給システム |
| JP2006188425A (ja) * | 2005-01-04 | 2006-07-20 | Air Products & Chemicals Inc | マイクロチャネル触媒反応装置中の液体燃料の脱水素化 |
| JP2009242232A (ja) * | 2008-03-31 | 2009-10-22 | General Electric Co <Ge> | 水素貯蔵材料及び関連システム |
| US20160061383A1 (en) * | 2014-09-03 | 2016-03-03 | Hydrogenious Technologies Gmbh | Arrangement and method for operating hydrogen filling stations |
| DE102016222596A1 (de) * | 2016-11-16 | 2018-05-17 | Hydrogenious Technologies Gmbh | Verfahren zum Bereitstellen von Wasserstoffgas, Dehydrier-Reaktor und Transport-Container |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2020120261A1 (de) | 2020-06-18 |
| EP3894351A1 (de) | 2021-10-20 |
| KR20210098987A (ko) | 2021-08-11 |
| DE102018221447A1 (de) | 2020-06-18 |
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