JP2021138799A - 光硬化性塗料組成物 - Google Patents
光硬化性塗料組成物 Download PDFInfo
- Publication number
- JP2021138799A JP2021138799A JP2020035410A JP2020035410A JP2021138799A JP 2021138799 A JP2021138799 A JP 2021138799A JP 2020035410 A JP2020035410 A JP 2020035410A JP 2020035410 A JP2020035410 A JP 2020035410A JP 2021138799 A JP2021138799 A JP 2021138799A
- Authority
- JP
- Japan
- Prior art keywords
- acrylate
- coating composition
- meth
- weight
- photocurable coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 16
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 14
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003999 initiator Substances 0.000 claims abstract description 8
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 46
- 238000000576 coating method Methods 0.000 claims description 23
- 239000011248 coating agent Substances 0.000 claims description 22
- 239000011347 resin Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 7
- 239000002987 primer (paints) Substances 0.000 abstract 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 7
- -1 2-hydroxypropyl Chemical group 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 5
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 5
- 229910052753 mercury Inorganic materials 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 230000001588 bifunctional effect Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229940105990 diglycerin Drugs 0.000 description 3
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 2
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical class O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- KCZQSKKNAGZQSZ-UHFFFAOYSA-N 1,3,5-tris(6-isocyanatohexyl)-1,3,5-triazin-2,4,6-trione Chemical compound O=C=NCCCCCCN1C(=O)N(CCCCCCN=C=O)C(=O)N(CCCCCCN=C=O)C1=O KCZQSKKNAGZQSZ-UHFFFAOYSA-N 0.000 description 1
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- WMYINDVYGQKYMI-UHFFFAOYSA-N 2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol Chemical compound CCC(CO)(CO)COCC(CC)(CO)CO WMYINDVYGQKYMI-UHFFFAOYSA-N 0.000 description 1
- HEQOJEGTZCTHCF-UHFFFAOYSA-N 2-amino-1-phenylethanone Chemical compound NCC(=O)C1=CC=CC=C1 HEQOJEGTZCTHCF-UHFFFAOYSA-N 0.000 description 1
- ZWVHTXAYIKBMEE-UHFFFAOYSA-N 2-hydroxyacetophenone Chemical compound OCC(=O)C1=CC=CC=C1 ZWVHTXAYIKBMEE-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- URLYGBGJPQYXBN-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methyl prop-2-enoate Chemical compound OCC1CCC(COC(=O)C=C)CC1 URLYGBGJPQYXBN-UHFFFAOYSA-N 0.000 description 1
- GUCYFKSBFREPBC-UHFFFAOYSA-N [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=C(C)C=C1C GUCYFKSBFREPBC-UHFFFAOYSA-N 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- 238000007607 die coating method Methods 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 238000007561 laser diffraction method Methods 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
前記(A)として6官能ウレタンアクリレート(HDIとペンタエリスリトールトリアクリレートの反応物)を、前記(B)としてアロニックスMT−3533(商品名:東亜合成社製、水酸基価190〜210mgKOH/g)及びアロニックスMT-3548(商品名:東亜合成社製、水酸基価250〜300mgKOH/g)を、(c1)としてACEMATT OK607(商品名:エボニック社製、疎水性シリカ、平均粒径4.4μm)を、(c2)としてミズカシルP−758C(商品名:水澤化学製、親水性シリカ、平均粒径12μm)を、(D)としてOmniradMBF−S(商品名:IGM社製、フェニルグリオキシル酸エステル系)を、(E)としてライトエステルHOP(N)(商品名:共栄社化学社製、2-ヒドロキシプロピルメタクリレート)を、その他モノマーとしてMIRAMER M200(商品名:MIWON社製、1.6ヘキサンジオールジアクリレート)を、レベリング剤としてBYK102(商品名:ビックケミージャパン社製)を、表1記載の配合で均一に溶解分散するまで撹拌して実施例1〜5の光硬化性塗料組成物を調整した。
実施例で用いた材料の他、オリゴマーとしてMIRAMER PE210(商品名:MIWON社製、ビスフェノールA型エポキシジアクリレート、)を、モノマーとしてMIRAMER M340(商品名:MIWON社製、ペンタエリスリトールトリアクリレート、水酸基価130〜140mgKOH/g)を、表1記載の配合で均一に溶解分散するまで撹拌して比較例1〜6の光硬化性塗料組成物を調整した。
厚み6mmの珪酸カルシウム板(商品名:ヒシタイカ アイカテック建材社製)上に、シーラーとしてアイトロンZ-140(商品名:アイカ工業社製、ウレタン系)を塗布し、その上に目止め層としてアイトロンZ-983S-13及びZ-983W-14(商品名:アイカ工業社製、エポキシアクリレート系)を用いて2層の目止め層を形成し、その上にアクリルウレタン系塗料を用い85g/m2での化粧層を形成後、上記塗料組成物を10g/m2の厚みで塗布し、その後光源としてアイグランデージECS4011GX/N(アイグラフィックス社製、高圧水銀ランプ)を用い、照射強度100mW/cm2、積算光量800mJ/cm2露光条件で硬化し試験片とした。
Claims (5)
- 多官能ウレタンアクリレートオリゴマー(A)と、水酸基価が160〜330mgKOH/gのペンタエリスリトールトリアクリレート(B)と、平均粒子径が異なる2種類のシリカ(C)と、光重合開始剤(D)と、を含み、前記(C)の平均粒子径が1〜8μm(c1)と、10〜20μm(c2)であることを特徴とする光硬化性塗料組成物。
- 更に水酸基を有する単官能(メタ)アクリレートモノマー(E)を含むことを特徴とする請求項1記載の光硬化性塗料組成物。
- 前記(A)の配合量が、組成物固形分の全量に対し20〜50重量%である事を特徴とする請求項1又は2いずれか記載の光硬化性塗料組成物。
- 前記(B)の配合量が、樹脂固形分に対し3〜35重量%である事を特徴とする請求項1〜3いずれか記載の光硬化性塗料組成物。
- アクリル系樹脂塗料のトップコート樹脂であることを特徴とする請求項1〜4いずれか記載の光硬化性塗料組成物。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2020035410A JP7420595B2 (ja) | 2020-03-03 | 2020-03-03 | 光硬化性塗料組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2020035410A JP7420595B2 (ja) | 2020-03-03 | 2020-03-03 | 光硬化性塗料組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2021138799A true JP2021138799A (ja) | 2021-09-16 |
JP7420595B2 JP7420595B2 (ja) | 2024-01-23 |
Family
ID=77667955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2020035410A Active JP7420595B2 (ja) | 2020-03-03 | 2020-03-03 | 光硬化性塗料組成物 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP7420595B2 (ja) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007118596A (ja) * | 2005-09-30 | 2007-05-17 | Dainippon Printing Co Ltd | 化粧シート |
JP2018002987A (ja) * | 2016-07-08 | 2018-01-11 | 中国塗料株式会社 | 光硬化性樹脂組成物、該組成物から形成される硬化被膜および被膜付き基材、並びに硬化被膜および被膜付き基材の製造方法 |
JP2018024744A (ja) * | 2016-08-09 | 2018-02-15 | 東洋インキScホールディングス株式会社 | 艶消し被覆組成物、化粧材及びその製造方法 |
WO2018062074A1 (ja) * | 2016-09-27 | 2018-04-05 | 東レフィルム加工株式会社 | 軟質樹脂層の転写用フィルム |
JP2018178066A (ja) * | 2017-04-21 | 2018-11-15 | 宇部興産株式会社 | 水性艶消し塗料及びそれを用いた積層体 |
-
2020
- 2020-03-03 JP JP2020035410A patent/JP7420595B2/ja active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007118596A (ja) * | 2005-09-30 | 2007-05-17 | Dainippon Printing Co Ltd | 化粧シート |
JP2018002987A (ja) * | 2016-07-08 | 2018-01-11 | 中国塗料株式会社 | 光硬化性樹脂組成物、該組成物から形成される硬化被膜および被膜付き基材、並びに硬化被膜および被膜付き基材の製造方法 |
JP2018024744A (ja) * | 2016-08-09 | 2018-02-15 | 東洋インキScホールディングス株式会社 | 艶消し被覆組成物、化粧材及びその製造方法 |
WO2018062074A1 (ja) * | 2016-09-27 | 2018-04-05 | 東レフィルム加工株式会社 | 軟質樹脂層の転写用フィルム |
JP2018178066A (ja) * | 2017-04-21 | 2018-11-15 | 宇部興産株式会社 | 水性艶消し塗料及びそれを用いた積層体 |
Also Published As
Publication number | Publication date |
---|---|
JP7420595B2 (ja) | 2024-01-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5235263B2 (ja) | 活性エネルギー線硬化型樹脂組成物及びその製造方法、並びにそれを用いたコーティング剤組成物 | |
JP5252839B2 (ja) | 活性エネルギー線硬化型エマルジョン組成物、及び、コーティング剤組成物 | |
JP6294999B1 (ja) | 環状オレフィン系樹脂基材上に硬化被膜を形成するための活性エネルギー線硬化型組成物及びハードコートフィルムの製造方法 | |
JP2010024255A (ja) | 活性エネルギー線硬化型樹脂組成物及びコーティング剤組成物 | |
JP2007016145A (ja) | 活性エネルギー線硬化型樹脂組成物 | |
JP2007016215A (ja) | 活性エネルギー線硬化型樹脂組成物及びコーティング剤組成物 | |
JP6837869B2 (ja) | 床材用活性エネルギー線硬化型樹脂組成物、被膜付き床材、被膜付き床材の製造方法および床材の汚染防止方法 | |
WO2014081004A1 (ja) | 活性エネルギー線硬化性樹脂組成物、コーティング剤組成物、及び積層体 | |
JP4189197B2 (ja) | ポリイソシアネート系誘導体及びそれを用いた活性エネルギー線硬化型樹脂組成物 | |
JP2014122338A (ja) | 活性エネルギー線硬化性樹脂組成物、コーティング剤組成物、及び積層体 | |
JP5089889B2 (ja) | ハードコート剤組成物および成形品 | |
JP2006213802A (ja) | 活性エネルギー線硬化型樹脂組成物 | |
JPWO2018105442A1 (ja) | 活性エネルギー線硬化型樹脂組成物及び積層フィルム | |
JP7420595B2 (ja) | 光硬化性塗料組成物 | |
JP4289605B2 (ja) | 活性エネルギー線硬化型樹脂組成物 | |
JP2020059811A (ja) | 床材用活性エネルギー線硬化樹脂組成物 | |
JP2017101100A (ja) | 活性エネルギー線硬化性樹脂組成物及びコーティング剤組成物 | |
JP2022055408A (ja) | 光硬化性トップコート樹脂組成物 | |
JP6938889B2 (ja) | 活性エネルギー線硬化性樹脂組成物及びコーティング剤 | |
JP2022153309A (ja) | 活性エネルギー線硬化性組成物及びその硬化物 | |
JP2006077200A (ja) | 活性エネルギー線硬化性組成物 | |
WO2018181972A1 (ja) | 活性エネルギー線硬化性樹脂組成物及びコーティング剤 | |
JP2019044138A (ja) | 多孔質基材用光硬化性シーラー組成物、硬化被膜付き多孔質基材、該基材の製造方法、多孔質基材の目止め方法および着色多孔質基材の製造方法 | |
JP2020152741A (ja) | トップコート用活性エネルギー線硬化型塗料組成物 | |
WO2022180887A1 (ja) | 電子線硬化型組成物、および食品包装材料 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20221114 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20230821 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20231002 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20231016 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20231225 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20240111 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 7420595 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |