JP2021042372A - 積層造形のための金属前駆体を含む微粒子組成物及びそれに関連する方法 - Google Patents
積層造形のための金属前駆体を含む微粒子組成物及びそれに関連する方法 Download PDFInfo
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- JP2021042372A JP2021042372A JP2020147978A JP2020147978A JP2021042372A JP 2021042372 A JP2021042372 A JP 2021042372A JP 2020147978 A JP2020147978 A JP 2020147978A JP 2020147978 A JP2020147978 A JP 2020147978A JP 2021042372 A JP2021042372 A JP 2021042372A
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- copper
- metal
- thermoplastic
- nanoparticles
- metal precursor
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- 239000002184 metal Substances 0.000 title claims abstract description 263
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- 239000011159 matrix material Substances 0.000 claims description 26
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- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 21
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- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 10
- 229910052787 antimony Inorganic materials 0.000 claims description 10
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 10
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- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 10
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- RAOSIAYCXKBGFE-UHFFFAOYSA-K [Cu+3].[O-]P([O-])([O-])=O Chemical compound [Cu+3].[O-]P([O-])([O-])=O RAOSIAYCXKBGFE-UHFFFAOYSA-K 0.000 claims description 9
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- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- 239000011777 magnesium Substances 0.000 claims description 9
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 9
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Abstract
Description
−酸化銅、又は銅と、アンチモン、アルミニウム、セシウム、コバルト、クロム、マグネシウム、マンガン、ニッケル、スズ、チタン、銀、鉄、亜鉛、及びジルコニウムから選択される金属との混合酸化物。銅の混合酸化物の具体例としては、例えば、銅クロム酸化物スピネル(クロム酸銅)、銅アルミニウム酸化物、銅鉄酸化物等が挙げられる。クロム酸銅は、例えば、Nd:YAGレーザーを用いるなどして、1060nmのパルスレーザー放出波長で好適に活性化され得る。
−水酸化銅、水酸化銅、リン酸銅、硫酸銅、銅チオシアネート、又はこれらの任意の組み合わせ。別途記載のない限り、これらの銅塩は、+2酸化状態(銅塩)中に銅を含有する。銅チオシアネートは、+1又は+2酸化状態のいずれかで存在し得る。
−銅、銀、パラジウム、又はこれらの任意の組み合わせから選択される金属を含む金属−有機錯体(金属−配位子錯体)。好適な金属−有機錯体としては、例えば、金属モノカルボン酸錯体、金属ジカルボキシレート錯体、金属アセチルアセトネート錯体、金属サリチルアルジミナト錯体等を挙げられ得る。好適な金属−有機錯体の具体例としては、シュウ酸銅及びオレイン酸銅などのカルボン酸銅及びジカルボキシレート;アセチルアセトナート;銅サレン(サレン=N,N’−ビス(サリチリデン)エチレンジアミン);銀ネオデカン酸塩などの銀カルボン酸塩、並びに酢酸パラジウム及びネオデカン酸パラジウムなどのカルボン酸パラジウム、が挙げられ得るが、これらに限定されない。パラジウム含有金属−有機錯体は、エキシマレーザーなどの電磁スペクトルの紫外領域内で放出されるパルスレーザーを用いて金属に変換され得る。対照的に、いくつかの銀含有金属有機錯体は、電磁スペクトルの可視領域内で放射されるパルスレーザーを使用して、金属に好適に変換され得る。
開示項
複数の熱可塑性微粒子のそれぞれの外側表面上に配置された複数のナノ粒子であって、複数の酸化物ナノ粒子、カーボンブラック、又はこれらの任意の組み合わせを含む、複数のナノ粒子を更に含む、第1節に記載の微粒子組成物。
熱可塑性ポリマーと混合された赤外線吸収剤を更に含む、第1節に記載の微粒子組成物。
微粒子固結によって形成され、熱可塑性ポリマーを含むポリマーマトリックスと、
ポリマーマトリックスと混合された金属前駆体であって、金属前駆体が、レーザー照射に曝露されると金属アイランドを形成するように活性化可能である、金属前駆体と、を含む、印刷物。
ポリマーマトリックスと混合された複数のナノ粒子であって、複数の酸化物ナノ粒子、カーボンブラック、又はこれらの任意の組み合わせを含む、複数のナノ粒子を更に含む、第13節に記載の印刷物。
ポリマーマトリックスと混合された赤外線吸収剤を更に含む、第13節に記載の印刷物。
熱可塑性ポリマーと、熱可塑性ポリマーと混合された金属前駆体とを含む複数の熱可塑性微粒子を含む微粒子組成物を粉末床に堆積させることであって、金属前駆体が、レーザー照射に曝露されると金属アイランドを形成するように活性化可能である、堆積させることと、
粉末床の複数の熱可塑性微粒子の一部を固結させて、金属前駆体が金属に依然として実質的に変換されていない印刷物を形成することと、を含む、方法。
無電解めっきを実行して、複数の不連続な金属アイランドを相互接続する1つ以上の導電性トレースを形成することを更に含む、第35節に記載の方法。
熱可塑性ポリマーと金属前駆体とを、熱可塑性ポリマーの融点又は軟化温度以上の加熱温度で分散媒中で混ぜ合わせることであって、
熱可塑性ポリマー及び分散媒が、加熱温度で実質的に不混和性であり、金属前駆体が、レーザー照射に曝露されると金属アイランドを形成するように活性化可能である、混ぜ合わせることと、
加熱温度で金属前駆体の存在下で、熱可塑性ポリマーを液化液滴として分散させるのに十分な剪断力を加えることと、
液化液滴が形成された後、少なくとも固化状態の熱可塑性微粒子が形成される温度まで分散媒を冷却することであって、熱可塑性微粒子が、熱可塑性ポリマーと、熱可塑性ポリマーと混合された金属前駆体の少なくとも一部とを含む、冷却することと、
分散媒から熱可塑性微粒子を分離することと、を含む、方法。
ナノ粒子を分散媒中の熱可塑性ポリマーと金属前駆体と混ぜ合わせることであって、複数のナノ粒子が、複数の酸化物ナノ粒子、カーボンブラック、又はこれらの任意の組み合わせを含む、混ぜ合わせること、を更に含み、
ナノ粒子の少なくとも一部が、熱可塑性微粒子のそれぞれの外側表面上に配置される、第39節に記載の方法。
赤外線吸収剤を分散媒に混ぜ合わせることであって、赤外線吸収剤が、熱可塑性微粒子中の熱可塑性ポリマーと混合される、混ぜ合わせること、を更に含む、第39節に記載の方法。
Claims (20)
- 微粒子組成物であって、
熱可塑性ポリマーと、前記熱可塑性ポリマーと混合された金属前駆体とを含む複数の熱可塑性微粒子であって、前記金属前駆体が、レーザー照射に曝露されると金属アイランドを形成するように活性化可能である、複数の熱可塑性微粒子を含む、微粒子組成物。 - 前記複数の熱可塑性微粒子のそれぞれの外側表面上に配置された複数のナノ粒子であって、複数の酸化物ナノ粒子、カーボンブラック、又はこれらの任意の組み合わせを含む、複数のナノ粒子を更に含む、請求項1に記載の微粒子組成物。
- 前記複数の酸化物ナノ粒子が、複数のシリカナノ粒子を含む、請求項2に記載の微粒子組成物。
- 前記金属前駆体が、赤外パルスレーザー又は近赤外パルスレーザーによって活性化可能である、請求項1に記載の微粒子組成物。
- 前記金属前駆体が、約1020nm〜約1070nmの範囲の波長で活性化可能である、請求項1に記載の微粒子組成物。
- 前記金属前駆体が、酸化銅;銅と、アンチモン、アルミニウム、セシウム、コバルト、クロム、マグネシウム、マンガン、ニッケル、スズ、チタン、銀、鉄、亜鉛、及びジルコニウムからなる群から選択される金属との混合酸化物;銅クロム酸化物スピネル;銅アルミニウム酸化物;水酸化銅;水酸化銅リン酸塩;リン酸銅;硫酸銅;チオシアン酸銅;銅、銀、パラジウム、及びこれらの任意の組み合わせからなる群から選択される金属を含む金属有機錯体;並びにこれらの任意の組み合わせからなる群から選択される少なくとも1つの材料を含む、請求項1に記載の微粒子組成物。
- 前記熱可塑性ポリマーと混合された赤外線吸収剤を更に含む、請求項1に記載の微粒子組成物。
- 前記赤外線吸収剤が、非化学量論的金属酸化物を含む、請求項8に記載の微粒子組成物。
- 印刷物であって、
微粒子固結によって形成され、熱可塑性ポリマーを含むポリマーマトリックスと、
前記ポリマーマトリックスと混合された金属前駆体であって、レーザー照射に曝露されると金属アイランドを形成するように活性化可能である、金属前駆体と、を含む、印刷物。 - 前記ポリマーマトリックスと混合された複数のナノ粒子であって、複数の酸化物ナノ粒子、カーボンブラック、又はこれらの任意の組み合わせを含む、複数のナノ粒子を更に含む、請求項9に記載の印刷物。
- 前記複数の酸化物ナノ粒子が、複数のシリカナノ粒子を含む、請求項10に記載の印刷物。
- 前記金属前駆体が、赤外パルスレーザー又は近赤外パルスレーザーによって活性化可能である、請求項9に記載の印刷物。
- 前記金属前駆体が、酸化銅;銅と、アンチモン、アルミニウム、セシウム、コバルト、クロム、マグネシウム、マンガン、ニッケル、スズ、チタン、銀、鉄、亜鉛、及びジルコニウムからなる群から選択される金属との混合酸化物;銅クロム酸化物スピネル;銅アルミニウム酸化物;水酸化銅;水酸化銅リン酸塩;リン酸銅;硫酸銅;チオシアン酸銅;銅、銀、パラジウム、及びこれらの任意の組み合わせからなる群から選択される金属を含む金属有機錯体;並びにこれらの任意の組み合わせからなる群から選択される少なくとも1つの材料を含む、請求項9に記載の印刷物。
- 方法であって、
熱可塑性ポリマーと、前記熱可塑性ポリマーと混合された金属前駆体とを含む複数の熱可塑性微粒子を含む微粒子組成物を粉末床に堆積させることであって、前記金属前駆体が、レーザー照射に曝露されると金属アイランドを形成するように活性化可能である、堆積させることと、
前記粉末床の前記複数の熱可塑性微粒子の一部を固結させて、前記金属前駆体が金属に依然として実質的に変換されていない印刷物を形成することと、を含む、方法。 - 前記複数の熱可塑性微粒子が、前記複数の熱可塑性微粒子のそれぞれの外側表面上に配置された複数のナノ粒子を更に含み、前記複数のナノ粒子が、複数の酸化物ナノ粒子、カーボンブラック、又はこれらの任意の組み合わせを含む、請求項14に記載の方法。
- 前記複数の酸化物ナノ粒子が、複数のシリカナノ粒子を含む、請求項15に記載の方法。
- 前記金属前駆体が、酸化銅;銅と、アンチモン、アルミニウム、セシウム、コバルト、クロム、マグネシウム、マンガン、ニッケル、スズ、チタン、銀、鉄、亜鉛、及びジルコニウムからなる群から選択される金属との混合酸化物;銅クロム酸化物スピネル;銅アルミニウム酸化物;水酸化銅;水酸化銅リン酸塩;リン酸銅;硫酸銅;チオシアン酸銅;銅、銀、パラジウム、及びこれらの任意の組み合わせからなる群から選択される金属を含む金属有機錯体;並びにこれらの任意の組み合わせからなる群から選択される少なくとも1つの材料を含む、請求項14に記載の方法。
- 前記金属前駆体が、赤外パルスレーザー又は近赤外パルスレーザーで活性化可能である、請求項14に記載の方法。
- パルスレーザーを使用して前記印刷物内の前記金属前駆体の一部を活性化して、前記印刷物の表面上に所定のパターンの複数の不連続な金属アイランドを形成することを更に含む、請求項14に記載の方法。
- 無電解めっきを実行して、前記複数の不連続な金属アイランドを相互接続する1つ以上の導電性トレースを形成することを更に含む、請求項19に記載の方法。
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