JP2021024807A - Hair cavity repairing agent and hair cavity repair method using the same - Google Patents

Abstract

To provide a hair cavity repairing agent that repairs cavities inside the hair and improves the gloss and elasticity of the hair and a hair cavity repairing method using the same.SOLUTION: A hair cavity repairing agent comprises (A) an organic acid and (B) a diester of a dicarboxylic acid represented by the general formula 1 with polyoxyethylene monoalkyl ether represented by the general formula 2. Here, the general formula 1 is HO-CO-R1-CO-OH (in the formula, R1 represents a straight chain, a branched chain, or a cyclic hydrocarbon group having 2 to 10 carbon atoms) and the general formula 2 is R2-(OCH2CH2)n-OH (in the formula, R2 is a straight chain, a branched chain, or a cyclic hydrocarbon group having 1 to 12 carbon atoms, and n represents an integer from 2 to 11).SELECTED DRAWING: None

Description

The present invention relates to a hair cavity repairing agent containing an organic acid, a diester of a dicarboxylic acid and a polyoxyethylene monoalkyl ether, and a hair cavity repairing method using the same.

Hair is continuously damaged on a daily basis by chemical treatments such as perm, bleaching, and hair coloring, ultraviolet rays from sunlight, hair washing, heat from a hair dryer, and brushing. Many studies on such damaged hair have been carried out for a long time. For example, Non-Patent Document 1 reports a study focusing on the inside of hair (medula). According to this document, when cavities are formed in the medula part, diffused reflection of light causes dullness and loss of transparency in the hair, and such cavities are caused by very routine treatments such as heat and brushing with a dryer. It has been reported that it will end up. As a method for repairing such a medula, Patent Document 1 describes that a low molecular weight compound such as an organic acid is effective. Further, Patent Documents 2 and 3 disclose hair cosmetics in which an organic acid and a specific organic solvent are used in combination as a means for improving the cavities inside the hair generated during coloring or drying with a dryer. However, even these hair cosmetics are not always sufficient as an effect of improving the cavities inside the hair.

JP 2000-109411 JP 2002-047142 JP-A-2004-256551

FRAGRANCE JOURNAL June 2000 issue (pages 11-15)

Provided is a hair cavity repairing agent that repairs cavities inside the hair and improves the gloss and elasticity of the hair, and a hair cavity repairing method using the same.

As a result of diligent studies to solve the above problems, the present inventors have found that a hair cavity repairing agent containing the following components (A) and (B) solves the above problems, and completed the present invention. I let you.
(A) Diester of organic acid (B) dicarboxylic acid represented by conversion 1 and polyoxyethylene monoalkyl ether represented by conversion 2 (Chemical formula 1) HO-CO-R1-CO-OH
(In the formula, R1 represents a linear, branched or cyclic hydrocarbon group having 2 to 10 carbon atoms).
(Chemical 2) R2- (OCH2CH2) n-OH
(In the formula, R2 is a linear, branched or cyclic hydrocarbon group having 1 to 12 carbon atoms.
n represents an integer of 2 to 11)

By using the hair cavity repairing agent of the present invention, the cavity inside the hair can be repaired, and the gloss and elasticity of the hair can be improved.

The present invention is a hair cavity repair agent containing the following components (A) and (B) as essential components.
(A) Diester of organic acid (B) dicarboxylic acid represented by conversion 1 and polyoxyethylene monoalkyl ether represented by conversion 2 (Chemical formula 1) HO-CO-R1-CO-OH
(In the formula, R1 represents a linear, branched or cyclic hydrocarbon group having 2 to 10 carbon atoms).
(Chemical 2) R2- (OCH2CH2) n-OH
(In the formula, R2 is a linear, branched or cyclic hydrocarbon group having 1 to 12 carbon atoms.
n represents an integer of 2 to 11)

The organic acid of the component (A) used in the present invention is acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, benzoic acid, salicylic acid, gallic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid. , Maleic acid, fumaric acid, phthalic acid, glycolic acid, lactic acid, malic acid, tartaric acid, citrate, gluconic acid, levulinic acid, ketoglutaric acid and the like. These may be used alone or in combination of two or more. Of these, malonic acid, succinic acid, maleic acid, lactic acid, and malic acid are preferred.

The amount of the component (A) used in the present invention to be added to the hair cavity repairing agent is not particularly limited, but is 0.001 to 10% by weight, preferably 0.005 to 5% by weight.

The diester of the component (B) used in the present invention is used for the purpose of promoting the penetration of the component (A) into the hair. The dicarboxylic acid represented by Chemical Acid 1 constituting the diester is a dicarboxylic acid in which R1 represents a linear, branched or cyclic hydrocarbon group having 2 to 10 carbon atoms, and specifically, succinic acid and glutaric acid. , Saturated linear dicarboxylic acids such as adipic acid, pimelli acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid; saturation of 2,2,4-trimethyladipic acid, 2,4,4-trimethyladiponic acid and the like. Branched chain dicarboxylic acids; examples thereof include cyclic dicarboxylic acids such as 1,2-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, phthalic acid, isophthalic acid, and terephthalic acid. Of these, succinic acid, adipic acid, azelaic acid, sebacic acid, and dodecanedioic acid are preferable as the saturated linear dicarboxylic acid, and cyclic dicarboxylic acid is preferable from the viewpoint of availability, economy, penetration promoting effect, and the like. 1,4-Cyclohexanedicarboxylic acid, phthalic acid and terephthalic acid are preferable. Further, among these, succinic acid, adipic acid and 1,4-cyclohexanedicarboxylic acid are preferable, and 1,4-cyclohexanedicarboxylic acid is most preferable.

On the other hand, as the polyoxyethylene monoalkyl ether represented by Chemical formula 2 constituting the diester, R2 is a linear, branched or cyclic hydrocarbon group having 1 to 12 carbon atoms, and n is an integer of 2 to 11. Is. Examples of linear, branched or cyclic hydrocarbon groups having 1 to 12 carbon atoms are methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, isobutyl group, n-pentyl group and n-hexyl group. , Cyclohexyl group, n-octyl group, 2-ethylhexyl group, n-decyl group, n-dodecyl group and the like, but from the viewpoint of reactivity at the time of esterification, diester performance, economy, etc., methyl group, ethyl group, etc. A group is preferable, and an ethyl group is particularly preferable. Further, from the viewpoint of economy, reactivity and the like, n is preferably 2 or 3, and as the polyoxyethylene monoalkyl ether represented by Chemical formula 2, diethylene glycol monoethyl ether and triethylene glycol monoethyl ether are preferable, and diethylene glycol is preferable. Monoethyl ether is most preferred.

The preferred compound as the diester of the component (B) used in the present invention is a combination of the above-mentioned preferred dicarboxylic acid and the preferred polyoxyethylene monoalkyl ether. Specifically, 1,4-cyclohexanedicarboxylic acid bis (diethylene glycol monoethyl ether) ester, 1,4-cyclohexanedicarboxylic acid bis (triethylene glycol monoethyl ether) ester, and adipate bis (diethylene glycol monoethyl ether) ester Preferably, 1,4-cyclohexanedicarboxylic acid bis (diethylene glycol monoethyl ether) ester is most preferable.

The amount of the component (B) used in the present invention to be added to the hair cavity repairing agent is not particularly limited, but is 0.001 to 5% by weight, preferably 0.005 to 2% by weight.

The hair cavity repair agent of the present invention preferably has a pH of 2 to 7, particularly 2 to 5. Acids or alkalis can be added and adjusted as appropriate to obtain a favorable pH.

A method for repairing a cavity generated inside the hair using the hair cavity repairing agent of the present invention is achieved by applying a composition containing the above-mentioned components (A) and (B) to the hair. If necessary, after application, washing with water and drying may be performed.

The hair cavity repair agent of the present invention includes additive components such as oily bases, surfactants, alcohols, moisturizers, polymers / thickening / gelling agents, which are added to water and ordinary cosmetics as needed. , Antioxidants, preservatives, bactericides, chelating agents, pH regulators / acids / alkalis, UV absorbers, whitening agents, solvents, keratin stripping / dissolving agents, antipruritic agents, anti-inflammatory agents, antiperspirants, refreshing agents, Antihistamines, astringents, stimulants, hair growth agents / blood circulation promoters, reducing agents / oxidizing agents, polymer powders, hydroxy acids, vitamins and their derivatives, sugars and their derivatives, organic acids, enzymes, nucleic acids Classes, hormones, inorganic powders, fragrances, pigments and the like may be contained to the extent that the effects of the present invention are not impaired.

Oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, araquil alcohol, behenyl alcohol, jojoba alcohol, chimil alcohol, seraquil alcohol, bacil alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimerdiol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Higher grades such as palmitooleic acid, oleic acid, linoleic acid, linoleic acid, erucic acid, docosahexaenoic acid, eikosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long-chain branched fatty acids, dimeric acid, hydrogenated dimeric acid, etc. Fatty acids and their aluminum salts, calcium salts, magnesium salts, zinc salts, potassium, sodium salts and other metal soaps, and amides and other nitrogen-containing derivatives; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin , Α-Olefin oligomers, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalane, vaseline, solid paraffin and other hydrocarbons; candelilla wax, carnauba wax, rice wax, wood wax, honey wax, montan wax , Ozokerite, Celesin, Paraffin Wax, Microcrystalin Wax, Petrolatum, Fisher Tropsch Wax, Polyethylene Wax, Ethylene-propylene Copolymer and other Waxes; Palm Oil, Palm Oil, Palm Core Oil, Saflower Oil, Olive Oil, Himasi Oil, Avocado Oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rose hip oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat Vegetable fats and oils such as germ oil, flaxseed oil, cotton seed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef fat, milk fat, Animal fats and oils such as horse fat, egg yolk oil, mink oil, turtle oil; animal waxes such as whale wax, lanolin, orange raffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption-purified lanolin, lanolin acetate, liquid acetate lanolin, hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine , Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin and other sphingolin lipids, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof, phospholipids such as lysolecithin; hydrogenated soybean phospholipids, partially hydrogenated soybeans Phosphorlipid derivatives such as phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, N-lauroyl Di-L-glutamate (cholesteryl / behenyl / octyldodecyl), N-lauroyl-di-L-glutamate (cholesteryl / octyldodecyl), di-lauroyl-L-glutamate (phytosteryl / behenyl / octyldodecyl), N-lauroyl- Di (phytosteryl / octyldodecyl) L-glutamate, acyl sarcosine alkyl esters such as N-lauroyl sarcosin isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, isostearyl Sterol esters such as soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long-chain branched fatty acid cholesteryl, long-chain α-hydroxy fatty acid cholesteryl; lipid complexes such as phospholipid / cholesterol complex, phospholipid / phytosterol complex; myristic acid Octyldodecyl, hexyldecyl myristate, octyldodecyl isostearate, cetyl pariminate, octyldodecyl palmitate, cetyl octanate, hexyldecyl octanoate, isotridesyl isononanoate, isononyl isononanoate, octyl isononanoate, isotolideyl isononanoate , Isotridecyl neopentate, Isostearyl neopentate, Octyldodecyl neodecanoate, Oleyl oleate, Octi oleate Ludodecyl, octyldodecyl ricinoleate, octyldodecyl lanolin fatty acid, dicaprylic carbonate, hexyldecyl dimethyloctanoate, octyldodecyl erucate, hardened isostearic acid castor oil, ethyl oleate, ethyl avocado fatty acid, isopropyl myristate, isopropyl palmitate, palmitin Octyl acid, isopropyl isostearate, isopropyl lanolin fatty acid, methylheptyl laurate, methylheptyl myristate, methylheptyl palmitate, methylheptyl isostearate, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyl sebacate Monoalcoholic carboxylic acid esters such as octyl, diisobutyl adipate, dioctyl adipate, dioctyl succinate, triethyl citrate; oxy such as cetyl lactate, diisostearyl malate, hydrogenated castor oil monoisostearate, γ-ercalactone Acid esters; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, glyceryl tri (caprylic acid / capric acid), tri (caprylic acid / capric acid / myristic acid / stearic acid) glyceryl, hydrogenated Rozin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl benoic acid, glyceryl trioctanoate, trimethylol propane triisostearate, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, dioctanoic acid 2-Butyl-2-ethyl-1,3-propanediol, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl, ditrimethylolpropane triethylhexanoate, ditrimethylol (isostearic acid / sebacic acid) Propane, pentaerythricyl triethylhexanoate, (hydroxystearic acid / stearic acid / logonic acid) dipentaerythrityl, diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl nonaisostearate-10, deca (erucic acid / isostearic acid / ricinoleic acid) Polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate (d. distearate) Polyhydric alcohol fatty acid esters such as (tyrene glycol), 3-methyl-1,5-pentanediol dineopenate, 2,4-diethyl-1,5-pentanediol dineopenate; alkyl ethers such as dicaprylyl ether; die Diisopropyl dimersinolate, diisostearyl dimerserinolate, dimerselyl dimerglinolate (isostearyl / phytosteryl), dimerglinolic acid (phytosteryl / behenyl), dimerserinolic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) ), Dimerdilinoleic acid Dimerdilinoleil, Diomadylinorail diisostearate, Dimersylinoleyl hydrogenated rosin condensate, Dimergylinoleic acid-cured castor oil, Dimericicic dimeric acid or Dimerdiol such as hydroxyalkyl Dimergylinoleil ether Derivatives of: Palm oil fatty acid monoethanolamide (cocamide MEA), palm oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide). MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA) and other fatty acid alkanolamides; dimethicone (dimethylpolysiloxane), highly polymerized dimethicone ( Highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, (aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin , Silicone rubber, amino-modified silicones such as aminopropyl dimethicone and amodimethicone, cationic-modified silicones, polyether-modified silicones such as dimethicone copolyol, polyglycerin-modified silicones, sugar-modified silicones, carboxylic acid-modified silicones, phosphate-modified silicones, sulfuric acid. Modified silicones, alkyl-modified silicones, fatty acid-modified silicones, alkyl ether-modified silicones, amino acid-modified silicones, peptide-modified silicones, fluorine-modified silicones, cation-modified and polyether-modified compounds Silicones such as licone, amino-modified and polyether-modified silicones, alkyl-modified and polyether-modified silicones, amidalkyl-modified silicones, aminoglycol-modified silicones, aminophenyl-modified silicones, polysiloxane / oxyalkylene copolymers; perfluorodecane, Fluoro-based oils such as perfluorooctane and perfluoropolyether are preferred.

Examples of the moisturizing agent / feel improving agent include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, and the like. Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymers and their polymers; diethylene glycol monoethyl ether Glycolalkyl ethers such as (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether; (eicosandioic acid / tetradecanedioic acid) polyglyceryl-10, polyglyceryl-10 tetradecanedioate, cyclohexanedicarboxylic acid Water-soluble esters such as bisethoxydiglycol; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, martitol; glucose, fructose, galactose, mannose, treose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, Trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, Heparin and derivatives, saccharides such as pectin, arabinogalactan, dextrin, dextran, glycogen, ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer and derivatives thereof; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate , Caronine sulfate, keratosulfate, dermatan sulfate; white jellyfish extract, white jellyfish polysaccharide; fluctanes such as inulin, levan; fucoidan; tuberose polysaccharide, naturally occurring polysaccharide; organic acids such as citric acid, tartaric acid, lactic acid and salts thereof. Urea; Salts such as 2-pyrrolidone-5-carboxylic acid and sodium thereof; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threoni Amino acids such as peptides, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and their salts; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen degradation Peptide, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin-degraded peptide, keratin-degraded peptide, hydrolyzed keratin, conchiolin-degraded peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean Protein peptides and derivatives thereof such as proteolytic peptides, wheat proteolytic peptides, hydrolyzed wheat proteins, casein-degrading peptides, acylated peptides; acylated peptides such as palmitoyl oligopeptides, palmitoyl pentapeptides, palmitoyl tetrapeptides; Peptides; Lactobacillus culture, yeast extract, eggshell membrane protein, submandibular gland mutin, hypotaurine, sesame lignan glycoside, glutathione, albumin, lactose; choline chloride, phosphorylcholine; placenta extract, aerastin, collagen, aloe extraction Peptides, Hamamelis water, Hechima water, Camomila extract, Kanzo extract, Comfrey extract, Silk extract, Izayoi rose extract, Peptide extract, Eucalyptus extract, Melilot extract and other animal / plant extracts, Natural ceramide (Types 1, 2, 3, 4, 5, 6), hydroxyceramides, pseudo-ceramides, sphingoglycolipids, ceramides and ceramides such as sugar ceramide-containing extracts are preferable.

Preferred examples of the surfactant include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, and polymer surfactants. The HLB of the surfactant is not particularly limited, and can be used from a low HLB of about 1 to a high HLB of about 20, and it is also preferable to combine a low HLB and a high HLB. Examples of preferred surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate and ammonium lauryl sulfate; laureth. Polyoxyethylene alkyl sulfates such as sodium sulfate and triethanolamine laureth sulfate; sodium cocoyl methyl taurine, potassium cocoyl methyl taurine, sodium lauroyl methyl taurine, sodium myristyl methyl taurine, sodium lauroyl methyl alanine, sodium lauroyl sarcosin, and lauroyl sarcosin triethanol. Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroyl glutamate; sodium cocoyl glutamate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine. , Acyl amino acid salts such as lysine Na dilauroyl glutamate; Polyoxyethylene alkyl ether acetate salts such as sodium laures acetate; Sulfonic acid ester salts such as sodium lauroyl monoethanolamide succinate; Fatty acid alkanolamide ether carboxylates; Acyl lates Polyoxyethylene fatty amine sulfate; fatty acid alkanolamide sulfate; hardened coconut oil fatty acid fatty acid glyceride sulfate such as sodium glycerin sulfate; alkylbenzene polyoxyethylene sulfate; olefin sulfonate such as α-olefin sulfonate; sulfosuccin Alkyl sulfosuccinates such as sodium lauryl sulphate, sodium dioctyl sulfosuccinate; alkyl ether sulfosuccinates such as sodium laures sulfosuccinate, monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate; tetradecyl Alkyl benzene sulfonates such as sodium benzene sulfonate, triethanolamine tetradecyl benzene sulfonic acid; alkyl naphthalene sulfonate; alkane sulfonate; α-sulfo fatty acid methyl ester salt; acyl acetylionate; alkyl glycidyl ether sulfonate Alkyl sulfoacetate; Alkyl ether phosphate such as sodium laureth phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monooles phosphate; Alkyl phosphate such as potassium lauryl phosphate; Sodium caseinate; Alkyl aryl ether Phosphate; fatty acid amide ether phosphate; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof; silicone-based such as carboxylic acid-modified silicone, phosphoric acid-modified silicone, sulfuric acid-modified silicone, etc. Anionic surfactants, etc .; Among nonionic surfactants, laures (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steares (polyoxyethylene stearyl ether), behenes (polyoxy) Polyoxyethylene alkyl ethers with various polyoxyethylene additions such as ethylene behenyl ethers), isosteares (polyoxyethylene isostearyl ethers), octyldodeces (polyoxyethylene octyldodecyl ethers); polyoxyethylene alkylphenyl ethers; Polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene cured castor oil monoisostearate, polyoxyethylene cured castor oil triisostearate, polyoxyethylene cured castor oil monopyroglutamic acid monoisostearic acid diester, poly Oxyethylene hardened bean oil and hardened bean oil derivatives such as maleic acid; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene polyoxy Protinic cetyl ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene glycerin ether, etc. Polyoxyethylene / polyoxypropylene alkyl ether; polyoxyethylene / polyoxypropylene glycol; (poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; Celyl, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, coconut oil fatty acid glyceryl, monocotton oil fatty acid glycerin, glycerin monoercaate, glycerin sesquioleate, α, α'-glycerin oleate Glycerin fatty acid partial esters such as acid glycerin malic acid; polyglyceryl-2, 3, 4, 4, 6, 8, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate- 2. Polyglyceryl decastearate-10, polyglyceryl isostearate-2, 3, 4, 4, 5, 6, 8, 10, 10, polyglyceryl diisostearate-2 (diglyceryl diisostearate), 3, 10, 10 , Polyglyceryl-2 triisostearate, Polyglyceryl-2 tetraisostearate, Polyglyceryl-10 decaisostearate, Polyglyceryl-2 oleate, 3, 4, 5, 5, 6, 8, Polyglyceryl dioleate- 6. Polyglycerin fatty acid ester such as polyglyceryl-2 trioleate, polyglyceryl-10 decaoleate; ethylene glycol monofatty acid ester such as ethylene glycol monostearate; propylene glycol monofatty acid ester such as propylene glycol monostearate; pentaerythritol moiety Fatite ester; sorbitol partial fatty acid ester; martitol partial fatty acid ester; martitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan Solbitan fatty acid esters such as trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; partial esters of sugar derivatives such as sucrose fatty acid ester, methylglucoside fatty acid ester, trehalose undecylate; Alkyl glucosides such as glucosides; alkyl polyglycosides; glycolipids such as mannosyl erythritol lipid; lanolin alcohol; reduced lanolin; polyoxyethylene distearate, polytylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene di Ole Polyoxyethylene fatty acid mono-and diesters such as alcohol; polyoxyethylene / propylene glycol fatty acid ester; polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate, etc. Polyoxyethylene glycerin fatty acid esters such as monooleate; polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, and polyoxyethylene sorbitan tetraoleate. Polyoxyethylene sorbitol fatty acid esters such as polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, and polyoxyethylene sorbitol monostearate; polyoxyethylene methyl glucoside fatty acid esters; poly Oxyethylene alkyl ether fatty acid esters; polyoxyethylene animal and vegetable oils and fats such as polyoxyethylene sorbitol honey; alkyl glyceryl ethers such as isostearyl glyceryl ethers, chimil alcohols, ceracyl alcohols, and batyl alcohols; Oxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponin and polysorbate; polyoxyethylene fatty acid amides; palm oil fatty acids monoethanolamide (cocamide MEA), palm oils Fatty acid diethanolamide (cocamide DEA), laurate monoethanolamide (lauramide MEA), laurate diethanolamide (lauramide DEA), laurate monoisopropanolamide (lauramide MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolami Alcohol alkanolamides such as ethylene de (partamide DEA) and coconut oil fatty acid methylethanolamide (cocamide methyl MEA); alkyldimethylamine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, behenamine oxide; alkylethoxydimethylamine Oxide; polyoxyethylene alkyl mercaptan; polysorbate such as dimethicone copolysorbate Ammonium-based nonionic surfactants such as ammonium-modified silicones, polysiloxane / oxyalkylene copolymers, polyglycerin-modified silicones, and sugar-modified silicones; among cationic surfactants, behentrimonium chloride and stealtrimonium chloride. Alkyltrimethylammonium chlorides such as cetrimonium chloride and lauryltrimonium chloride; alkyltrimethylammonium bromides such as stearyltrimonium bromide; dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; stearamidopropyldimethylamine, Fatty acid amidamines such as stearamide ethyl diethylamine and salts thereof; alkyl ether amines such as stearoxypropyl dimethylamine and salts thereof or quaternary salts; long-chain branched fatty acids ethyl sulfate (12-31) aminopropyl ethyl dimethyl ammonium, lanolin ethyl sulfate Fatty acid amide type quaternary ammonium salt such as fatty acid aminopropyl ethyl dimethyl ammonium; polyoxyethylene alkylamine and its salt or quaternary salt; alkylamine salt; fatty acid amide guanidium salt; alkyl etheraminemonium salt; alkyltrialkylene glycol Ammonium salt; benzalconium salt; benzethonium salt; pyridinium salt such as cetylpyridinium chloride; imidazolinium salt; alkylisoquinolinium salt; dialkylmoriphonium salt; polyamine fatty acid derivative; amino such as aminopropyldimethicone and amodimethicone Silicone-based cationic surfactants such as modified silicones, cationically modified silicones, cationically modified and polyether-modified silicones, amino-modified and polyether-modified silicones; among amphoteric surfactants, lauryl betaine (lauryl dimethylaminoacetate betaine) and the like. N-alkyl-N, N-dimethyl amino acid betaine; fatty acid amide alkyl-N, N-dimethylamino acid betaine such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline type betaine such as sodium cocoammonium acetate and sodium lauroammonium; alkyl Alkyl sulfobetaine such as dimethyl taurine; sulfuric acid type betaine such as alkyl dimethylaminoethanol sulfate ester; phosphoric acid type betaine such as alkyl dimethyl amino ethanol phosphate; phosphatidylcholine, phosphatidylethanola Sphingomyelin lipids such as min, phosphatidylserine, sphingomyelin, lysolecithin, hydrogenated soybean phospholipids, partially hydrogenated soybean phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids, phospholipids such as lecithin hydroxide; Silicone-based amphoteric surfactants and the like; As polymer surfactants, polyvinyl alcohol, sodium alginate, starch derivatives, traganth gum, acrylate / alkyl methacrylic acid copolymers; various silicone-based surfactants are preferable.

Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, farcerelan, karaya gum, trolley aoi, cara gum, tragant gum, pectin, pectic acid and sodium. Salts such as salts, salts such as alginic acid and sodium salts, mannan; starches such as rice, corn, potatoes, wheat; xanthan gum, dextran, succinoglucan, curdran, hyaluronic acid and its salts, zansan gum, purulan, gellan gum, chitin , Chitosan, agar, casso extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and salts such as sodium thereof, methyl hydroxypropyl cellulose, sodium cellulose sulfate, dialkyldimethyl Cellulose sulfate, crystalline cellulose, cellulose powder and other cellulose and derivatives thereof; starch-based polymers such as soluble starch, carboxymethyl starch, methylhydroxypropyl starch and methyl starch, hydroxypropyltrimonium chloride starch, corn starch aluminum octenyl succinate and the like. Alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), vinylpidridone / vinyl alcohol copolymer, polyvinylmethyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene Polyoxypropylene copolymer; amphoteric methacrylate copolymer such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrelites / stearyl acrylate / ethylamine methacrylate) copolymer; (dimethicone / vinyldimethicone) cloth Polymers, (alkyl acrylate / diacetone acrylamide) copolymers, (alkyl acrylate / diacetone acrylamide) copolymers AMP; partially saponified polyvinyl acetate, maleic acid copolymers; vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymers; Acrylic resin alkanolamine; polyester, water-dispersible polymer; polya Crylamide; polyacrylic acid ester copolymer such as ethyl polyacrylic acid, carboxyvinyl polymer, salt such as polyacrylic acid and sodium salt thereof, acrylic acid / methacrylic acid ester copolymer; acrylate / alkyl methacrylic acid Polymers: cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, acrylic acid such as polyquaternium-39. -Diallyldimethylammonium chloride-acrylamide copolymer, acrylic acid-cationized methacrylic acid ester copolymer, acrylic acid-cationized methacrylic acid amide copolymer, polyquaterium-47 and other acrylic acid-methyl acrylate-chloride Methacylamide propyltrimethylammonium copolymer, choline chloride methacrylate polymer; cationized oligosaccharide, cationized dextran, cationized polysaccharide such as guarhydroxypropyltrimonium chloride; polyethyleneimine; cationic polymer; polyquaternium-51 and the like. 2-Polymer of methacryloyloxyethyl phosphorylcholine and polymer with butyl methacrylate copolymer, etc .; acrylic resin emulsion, ethyl polyacrylate emulsion, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, synthetic Polymer emulsions such as latex; nitrocellulose; polyurethanes and various copolymers; various silicones; various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and Its salts; dextrin fatty acid esters such as dextrin palmitate, dextrin myristinate; silicic anhydride, fuming silica (ultrafine anhydrous silicic acid), aluminum magnesium silicate, sodium magnesium silicate, metal soap, metal dialkyl phosphate, Bentonite, hectrite, organically modified clay minerals, sucrose fatty acid esters, fructo-oligosaccharide fatty acid esters are preferred.

Examples of solvents and propellants include lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol, and isobutyl alcohol; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, and isopentyldiol. Kind: Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as: ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, glycol ether esters such as propylene glycol monoethyl ether acetate; glycol esters such as diethoxyethyl succinate and ethylene glycol disuccinate; benzyl Preferables include propellants such as alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation freon; LPG, dimethyl ether, and carbon dioxide.

Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; bisulfite derivatives such as propyl bisulfite; vitamin C (ascorbic acid) and / or its derivatives; erythorbic acid and its derivatives; Sulfites such as sodium sulfite; hydrogen sulfites such as sodium hydrogen sulfite; thiosulfites such as sodium bisulfite; metahydrosulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride are preferable. Is listed as. As the reducing agent, thioglycolic acid, cysteine, cysteamine and the like are preferable. As the oxidizing agent, hydrogen peroxide solution, ammonium persulfate, sodium bromate, percarbonate and the like are preferable.

Examples of antibacterial agents or preservatives include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane. 1,2-Alcandiols such as diols; Alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); Glycerin fatty acid esters such as glyceryl caprylate, glyceryl caprate, and glyceryl (caprylic acid / capric acid); Salicylic acid; Sodium benzoate; Isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; Imidazolinium urea; Dehydroacetic acid and its salts; Phenols; Halogenized bisphenols such as triclosan, acid amides, quaternary Ammonium salts; trichlorocarbanide, zincpyrythion, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophen, hinokithiol; phenol, isopropylphenol, cresol, timol, parachlorophenol, phenylphenol, Other phenols such as sodium phenylphenol; phenylethyl alcohol, photosensitizers, antibacterial zeolite, and silver ions are preferable, but when used as an antibacterial agent or an antiseptic for the purpose of preserving, cosmetics or skin. From the viewpoint of the safety of external preparations, phenoxyethanol; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol and 1,2-octanediol; alkylglyceryl such as 2-ethylhexylglyceryl ether. Ethers: It is more preferable to use glycerin fatty acid esters such as glyceryl caprylate, glyceryl caprate, and glyceryl (caprylic acid / capric acid).

Examples of the chelating agent include edetates (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytate; ethidroic acid and the like. Phosphonic acid and salts such as sodium salt thereof; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphate; sodium citrate, citric acid, alanine, dihydroxyethylglycine , Gluconic acid, ascorbic acid, succinic acid, tartrate acid are preferred. Acids and alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, and monoethanol. Amin, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxide Preferred are sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate and ammonium carbonate.

Powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, white mica, gold mica, synthetic mica, red mica, black mica, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, cay. Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (eg zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, dark blue, carbon black, titanium oxide, fine and ultrafine titanium oxide, zinc oxide , Fine particles and ultrafine zinc oxide, alumina, silica, fumigant silica (ultrafine anhydrous silicic acid), mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorine gold mica, fine particle composite powder, gold, aluminum, etc. Inorganic powders of various sizes and shapes, and these are treated with silicones such as hydrogen silicone and cyclic hydrogen silicone or other surface treatment agents such as silane or titanium coupling agents to make them hydrophobic or Inorganic powders such as hydrophilized powders; starch, cellulose, nylon powder, polyethylene powder, polymethylmethacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, polyester powder, benzoguanamine resin powder, polyethylene terephthalate. -Polymethylmethacrylate laminated powder, polyethylene terephthalate, aluminum, epoxy laminated powder, etc., urethane powder, silicone powder, Teflon (registered trademark) powder, and other organic powders and surface treatment powders of various sizes and shapes, organic and inorganic Composite powders are preferred. Inorganic salts include sodium chloride-containing salts such as salt, normal salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, ginger, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, etc. Aluminum / potassium sulfate (myoban), aluminum / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na / 2Na / 3Na phosphate, phosphoric acid Potassiums, calcium phosphates and magnesium phosphates are preferred.

Examples of the ultraviolet absorber include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, N, N-dimethylparaaminobenzoate ethyl. An benzoic acid-based ultraviolet absorber such as ester, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; anthranilic acid-based ultraviolet absorber such as homomentyl-N-acetylanthranilate; salicylic acid And salicylic acid-based ultraviolet absorbers such as sodium salt, amylsalicylate, menthylsalicylate, homomentylsalicylate, octylsalicylate, phenylsalicylate, benzylsalicylate, p-isopropanol phenylsalicylate; octylcinnamate, ethyl-4-isopropylcinnamate, methyl. -2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p-methoxy cinnamate, isopropyl-p-methoxy cinnamate, isoamyl-p-methoxy Synnamete, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenyl Ceramic acid-based ultraviolet absorbers such as cinnamate, 2-ethylhexyl α-cyano-β-phenyl cinnamate (octocrine), glycerylmono-2-ethylhexanoyl-diparamethoxycinnamate, ferulic acid and derivatives thereof; 2, 4-Dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2', 4,4'-tetrahydroxybenzophenone, 2-hydroxy- 4-Methoxybenzophenone (oxybenzon-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4' Benzophenones such as −phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone Ultraviolet absorbers; 3- (4'-methylbenziliden) -d, l-phenyl, 3-benziliden-d, l-phenyl; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 -Methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoilmethane; 5-( 3,3-Dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octylriazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate 2- (2'-Hydroxy-5'-methylphenyl) benzotriazole, 1- (3,4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentandione, dimethoxybenzilidendioxoimidazolidine propionic acid Hydantin derivatives such as 2-ethylhexyl, phenylbenzimidazole sulfonic acid, terephthalilidene dicanfursulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives are preferred.

Examples of vitamins and derivatives thereof include vitamin A such as retinol, retinol acetate, and retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxin hydrochloride, pyridoxin dioctanoate, pyridoxin dipalmitate, etc. Vitamin B group such as flavin adenin dinucleotide, cyanocobalamine, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin E such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphate ester salt such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate ester magnesium salt, tetra ascorbic acid Ascorbic acid fatty acid ester such as isoparmic acid ester, ascorbic stearate, ascorbic palmitate, ascorbic dipalmitate, alkyl ether ascorbic acid such as ethyl ether ascorbic acid, ascorbic acid glucoside such as -2-glucoside ascorbic acid and its fatty acid ester , Ascorbic acid derivatives such as tocopheryl ascorbic acid; tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, tocopherol ferulate, tocopherol derivatives such as tocopherol phosphate, and other vitamin derivatives, tocotrienol, and other various vitamin derivatives are preferable. Is listed as.

Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokithiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, difedramine hydrochloride, chlorpheniramine maleate; peach leaf extract. , Plant extracts such as Honoha extract are preferred. As hair growth agents, blood circulation promoters, and stimulants, plant extracts and tinctures such as senburi extract, capsicum tincture, ginger tincture, gypsum tincture extract, and cantalis tincture; capsaicin, nonylate warenylamide, zingerone, ictamol, and tannic acid. , Borneol, cyclanderate, cinnaridine, trazoline, acetylcholine, verapamil, cepharanthin, γ-orizanol, cepharanthin, vitamin E and derivatives such as tocopherol nicotinate / tocopherol acetate, γ-orizanol, nicotinic acid and nicotinic acid amide / benzyl nicotinate. Derivatives such as ester inositol hexanicotinate and nicotine alcohol, allantin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, flavanonol derivative, stigmasterol or stigmasterol and its glycoside, minoxidil are preferable. Is listed as. As the hormones, estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like are preferable. Other medicinal agents such as anti-wrinkle agents, anti-aging agents, tightening agents, cold sensitizers, warming agents, wound healing promoters, irritation palliatives, analgesics, cell activators, etc. include retinols, retinoic acids, retinoins. Tocopheryl acid; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and its glycosides / esterified products, hydroxycapric acid, long-chain α-hydroxy fatty acid, long-chain α-hydroxy fatty acid cholesteryl and other α- or β-Hydroxy acids and their derivatives; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosin; creatin; ceramides, spingosines; caffeine, xanthin and its derivatives; coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloids, fullerene and other antioxidant / active oxygen scavengers; catechins; quercetin and other flavones; isoflavones; gallic acid and ester sugar derivatives; tannins, sesamine, proto Polyphenols such as anthocyanidin, chlorogenic acid, apple polyphenols; derivatives such as rutin and glycosides; derivatives such as hesperidin and glycosides; lignan glycosides; kanzo extract-related substances such as glabridin, glabrene, liquilithin, isoliquilithin; lactoferrin Glycoside, gingerol; fragrance substances such as menthol, camphor, sedrol and derivatives thereof; capsaicin, vanillin and derivatives; insect repellents such as diethyl toluamide; complexes of physiologically active substances and cyclodextrins are preferred. Can be mentioned.

Plant / animal / microbial extracts include iris extract, acitaba extract, asunaro extract, asparagus extract, avocado extract, flaxseed extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo extract. , Inchikou extract, Uikyo extract, Ukon extract, Woolong tea extract, Uwaurushi extract, Agetsu extract, Echinashi leaf extract, Enmeisou extract, Ogon extract, Oubaku extract, Ouren extract, Omugi extract, Otanenjinjin extract, Otogirisou extract, Odori kosou extract, Ononis extract , Dutch mustard extract, orange extract, dried seawater, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk, cucumber extract, chamomile extract, oil-soluble chamomile extract, carrot extract, kawarayomogi Extract, crow wheat extract, calcade extract, kanzo extract, oil-soluble kanzo extract, kiwi extract, kiou extract, kikurage extract, kina extract, cucumber extract, kiri leaf extract, guanosine, guava extract, kujin extract, kuchinashi extract, kumazasa extract, clara extract, walnut Extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, quail extract, gentiana extract, gennoshouko extract, tea extract, yeast extract, koboku extract, coffee extract, gobo extract, rice extract, rice Fermented extract, fermented rice bran extract, rice germ oil, comfrey extract, collagen, moss peach extract, saishin extract, psycho extract, saitai extract, saffron extract, salvia extract, sabonsou extract, sasa extract, sanzashi extract, sansha extract, sansho Extract, Shiitake extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shimotsukesou extract, Jatoba extract, Shakuyaku extract, Shokyu extract, Shobu root extract, Shirakaba extract, White chrysanthemum extract, Sugina extract, Stevia extract, Stevia fermented product, Nishikawayanagi extract, Seiyoukizuta extract, Seiyousanzashi extract, Seiyouniwatoko extract, Seiyounokogirisou extract, Seiyouhakka extract, Sage extract, Zeniaoi extract, Senkyu extract, Senburi extract, Souhakuhi extract, Daiou extract, Dai Zu extract, Taisou extract, Thyme extract, Dandelion extract, Local clothing extract, Tea extract, Chouji extract, Chigaya extract, Chinpi extract, Tea tree oil, Jincha extract, Togarashi extract, Touki extract, Tokinsenka extract, Tounin extract, Tohi extract, Dokudami extract, Tomato Extract, Natto extract, Carrot extract, Garlic extract, Novara extract, Hibiscus extract, Bakumondou extract, Hass extract, Parsley extract, Birch extract, Honey, Hamamelis extract, Paris etalia extract, Hikiokoshi extract, Bisaborol, Hinoki extract, Bifizus bacterium extract, Biwa extract, Fukitanpopo extract, Fukinotou extract, Bukuryo extract, Butcher bloom extract, Grape extract, Grape seed extract, Propolis, Hechima extract, Benibana extract, Peppermint extract, Bodaiju extract, Button extract, Hop extract, Maikaika extract, Pine extract, Maronie extract , Mizubasho extract, Mukuroji extract, Melissa extract, Mozuku extract, Peach extract, Yagurumagiku extract, Eucalyptus extract, Yukinoshita extract, Yuzu extract, Yuri extract, Yokuinin extract, Yomogi extract, Lavender extract, Green tea extract, Eggshell membrane extract, Apple extract, Louis Boss tea extract , Reishi extract, lettuce extract, lemon extract, lotus extract, lotus extract, rose extract, rosemary extract, roman chamomile extract, royal jelly extract, crackle extract and the like are preferable.

Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, zinc paraphenol sulfonate and the like. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum / potassium sulfate, tannic acid and the like. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease and the like. Preferred examples of nucleic acids include ribonucleic acid and a salt thereof, deoxyribonucleic acid and a salt thereof, and disodium adenosine triphosphate.

Fragrances include acetylsedrene, amylcinnamaldehyde, allylamylglycolate, β-ionone, isoesuper, isobutylquinolin, iris oil, iron, indol, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragor, Eugenol, Oak Moss, Opoponax Resinoid, Orange Oil, Eugenol, Oranthiol, Galax Solid, Carbachlor, L-Carbon, Kamfer, Cannon, Carrot Seed Oil, Clove Oil, Methyl Caynate, Geraniol, Geranyl nitrile , Isobornyl acetate, Geranyl acetate, Dimethylbenzylcarvinyl acetate, Styralyl acetate, Cedril acetate, Telepinel acetate, pt-butylcyclohexyl acetate, Vetiberyl acetate, benzyl acetate, Linaryl acetate, Isopentyl salicylate, benzyl salicylate, Sandalwood oil, Santa roll, Cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citroneral, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylux Reginoid, Cedarwood Oil, Sedren, Sedrol, Celori Seed Oil, Thyme Oil, Damascon, Damasenon, Timor, Tuberose Absolute, Decanal, Decalactone, Terpineol, γ-Terpinen, Triplar, Nerol, Nonanar, 2,6-Nonadienor, Nonalactone, Pacholi Alcohol, vanilla absolute, vanillin, basil oil, patcholi oil, hydroxycitroneral, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitgrain oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian balsam, vetiver oil, vetiverol , Peppermint oil, pepper oil, heliotropin, bergamot oil, benzylbenzoate, borneol, milresinoid, muskketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-mentone, eucalyptus oil, β-yonone, lime oil , Lavender oil, D-limonen, linalol, lylar, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, synthetic fragrances such as various essential oils and natural Fragrances and various blended fragrances are preferred.

As pigments / colorants / dyes / pigments, brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, blue 204 , Blue 205, Blue 403, Blue 404, Green 3, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1, Red 105-1, Red 106, Red 2, Red 3, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207 , Red 208, Red 213, Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230-1, Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503 , Red No. 504, Red No. 505, Red No. 506, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 205, Orange No. 206, Orange No. 207, Orange No. 401, Orange No. 402, Orange No. 403, Yellow 201, Yellow 202-1, Yellow 202-2, Yellow 203, Yellow 204, Yellow 205, Yellow 4, Yellow 401, Yellow 402, Yellow 403-1, Yellow 404, Yellow Legal dyes such as 405, Yellow 406, Yellow 407, Yellow 5; Other acidic dyes such as Acid Red 14; Basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, HC Blue 2, Basic Blue 26 and other nitro dyes; Disperse dyes; Inorganic white pigments such as titanium dioxide and zinc oxide; Inorganic red pigments such as iron oxide (Bengala) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow such as yellow iron oxide and yellow clay System pigments: Inorganic black pigments such as black iron oxide and low-order titanium oxide; Inorganic substances such as mango violet and cobalt violet Purple pigments; Inorganic green pigments such as chromium oxide, chromium hydroxide, cobalt titanate; Inorganic blue pigments such as ultramarine and dark blue; Titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored oxidation Pearl pigments such as titanium coated mica, bismuth oxychloride, fish scale foil; metal powder pigments such as aluminum powder, copper powder, and gold; anthracinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsantin, chalcone, calsamine, Naftquinones such as quercetin, crosin, chlorophyll, curcumin, cochineal, and ciconin, bixins, flavones, betacyanidine, henna, hemoglobin, lycopene, riboflavin, natural pigments and dyes such as rutin; p-phenylenediamine, toluene-2,5 Oxidizing dyes such as -diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and salts thereof. Body and couplers; auto-oxidizing dyes such as indolin; dihydroxyacetones are preferred.

As the water, in addition to normal water and purified water, hard water, soft water, natural water, deep ocean water, electrolytic alkaline ionized water, electrolytically acidic ionized water, ionized water, and cluster water are preferable.

In addition to these, cosmetic raw material standards, compounding ingredient standards by cosmetic type, Japanese Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), non-pharmaceutical raw material standards, Japanese Pharmacy, pharmaceutical additives Ingredients described in standards, official standards for food additives, etc., and in Japanese and foreign patent gazettes and patent publication gazettes (including publication gazettes and republications) whose international patent classification IPC belongs to the classification of A61K7 and A61K8. It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the described ingredients, in known combinations, blending ratios, and blending amounts.

The hair cavity repairing agent of the present invention can also be incorporated into general hair cosmetics. To explain the types of hair cosmetics in more detail, shampoos such as oil shampoos, cream shampoos, conditioning shampoos, indulgence shampoos, hair coloring shampoos, and rinse-integrated shampoos; rinses, treatments, hair packs, hair foams, hair mousses, etc. Hair spray, hair mist, hair wax, hair gel, water grease, set lotion, color lotion, hair tonic, hair liquid, pomade, tic, hair cream, hair blow, split hair coat, hair oil, permanent wave agent, straight perm agent, oxidation Hair dyes, hair bleaches, hair color pretreatments, hair color aftertreatments, perma pretreatments, perma aftertreatments, hair manicures, and hair restorers are preferred.

The types of hair cosmetics include emulsified cosmetics such as oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, and O / W / O type, and oil-based makeup. Foods, solid cosmetics, aqueous liquid cosmetics, paste cosmetics, stick cosmetics, volatile oil type cosmetics, powder cosmetics, jelly cosmetics, gel cosmetics, paste cosmetics, high emulsification Emulsion types such as molecular type cosmetics, sheet type cosmetics, mist type cosmetics, and spray type cosmetics are preferable.

The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto.

A hair cavity repairing agent containing the components (A) and (B) of the present invention with the composition shown in Table 1 was prepared (Examples 1 to 5). As a comparison, an agent containing no component (B) was prepared (Comparative Examples 1 to 5). The obtained agent was evaluated for its hair cavity repair effect by the following method. In addition, the effect of improving the elasticity and luster of hair was evaluated by the following method. The results are also shown in the lower column of the table.

<Hair cavity repair effect>
Healthy black hair was bleached once with a commercially available two-agent bleaching agent to prepare damaged hair. Next, the tips of the damaged hair were cut to a length of about 5 cm, and both ends of the hair were fixed to the slide glass with an adhesive. The fixed hair was observed using a microscope (VHX-1000 manufactured by KEYENCE CORPORATION, magnification 175 times), and the presence or absence of cavities in the hair was confirmed. In the hair with cavities, the porous part of the medula was observed like white streaks in the center of the hair (Non-Patent Document 1). Therefore, the white streaks were used as the hollow part and the length thereof was measured. Then, the hair was immersed in 10 g of each agent at room temperature for 6 hours, rinsed with tap water at about 20 ° C., and dried with cold air from a dryer for 3 minutes. With respect to the obtained treated hair, the same part as before the treatment was observed again with a microscope, and the length of the cavity portion was measured. From the total length of the cavity part before treatment (L1) and the total length of the cavity part after treatment (L2), the cavity repair rate was calculated according to the following formula, used as an index for hair cavity repair, and the hair cavity repair effect was evaluated according to the following criteria. .. In addition, observation was carried out at 14 places for one hair, and this was carried out three times for one sample. FIG. 1 shows an example of microscopic observation.

Cavity repair rate (%) = (L1-L2) / L1 × 100

◎ ・ ・ ・ Cavity repair rate is 60% or more ○ ・ ・ ・ Cavity repair rate is 40% or more and less than 60% △ ・ ・ ・ Cavity repair rate is 20% or more and less than 40% × ・ ・ ・ Cavity repair rate is less than 20%

<Effect of improving elasticity and luster of hair>
Healthy black hair was bleached once with a commercially available two-agent bleaching agent to prepare damaged hair. Next, 3 g of damaged hair bundles were immersed in 30 g of a hair cavity repair agent at room temperature for 3 hours, rinsed with tap water, and dried with warm air from a dryer for 3 minutes. Regarding the obtained treated hair bundle, the effect of improving elasticity and luster was evaluated based on the sensuality of five panelists according to the following criteria.

◎ ・ ・ ・ Greatly improved compared to hair bundles before treatment (damaged hair) ○ ・ ・ ・ Improved compared to hair bundles before treatment (damaged hair) △ ・ ・ ・ Hair bundles before treatment (damaged) Slightly improved compared to hair) × ・ ・ ・ No change compared to hair bundle (damaged hair) before treatment

From the results shown in Table 1, it was found that the hair cavity repairing agent of the present invention has a high hair cavity repair rate and an excellent hair cavity repair effect as compared with the case where the component (B) is not blended. It was also found that it is also excellent in the effect of improving the elasticity and luster of hair.

A hair cosmetic containing the hair cavity repairing agent of the present invention described below was prepared. The obtained hair cosmetics improved the firmness of the hair and improved the gloss.

Example 6 Hair lotion
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.5
Glycerin 5.0
BG 3.0
Succinic acid 1.0
Hydroxyethyl cellulose 0.2
Phenoxyethanol 0.4
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
All components were uniformly stirred and mixed. The pH was adjusted to 6.0 with sodium hydroxide.

Example 7 Hair lotion
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.2
BG 3.0
Propanediol 2.0
Malonic acid 2.0
Lactic acid 2.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Xanthan gum 0.5
Methylparaben 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
All components were heated to about 80 ° C. and uniformly stirred and mixed. The pH was 2.2.

Example 8 Hair lotion
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 0.5
Neosolue-DiSM (Nippon Fine Chemical Co., Ltd.) 0.1
PEG-40 hydrogenated castor oil 0.2
Part B Glycerin 2.0
Propylene glycol 3.0
Inulin-SC (Nippon Fine Chemical Co., Ltd.) 1.0
Malic acid 0.05
Lactic acid 0.02
(Acrylate / Alkyl Acrylate (C10-30)) Cross Polymer 0.05
Amount of purified water totaling 100 Part C Phenoxyethanol 0.4
Ethanol 5.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Parts A and B were each heated to 80 ° C., and part B was added to part A and mixed uniformly. After cooling to around 50 ° C., part C was added to obtain a uniform liquid. The pH was adjusted to 6.0 with sodium hydroxide.

Example 9 Treatment Hair Mist
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Phytopresome MEL (Nippon Fine Chemical Co., Ltd.) 2.0
Glycerin 5.0
BG 3.0
Stealtrimonium chloride 0.2
Part B purified water 40.0
Part C NanoRepair-CMC 10.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Succinic acid 2.0
Glutamic acid 0.1
Phenylalanine 0.05
Cysteine 0.2
Glycine 0.3
Hydroxyethyl cellulose 0.05
Phenoxyethanol 0.4
Ethanol 5.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
A part and B part were each heated to 60 ° C., and A part was added to B part to prepare an aqueous dispersion. Further, part C was added with stirring to obtain a uniform liquid. The pH was adjusted to 4.0 with arginine.

Example 10 Non-silicone shampoo
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Neosolue-Aquilio 1.0
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.03
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 0.5
Laureth-4 Carboxylate Na (28%) 10.0
Laureth-6 Carboxylic Acid 4.0
Cocamidopropyl Betaine (30%) 10.0
Lauroylmethylalanine Na (30%) 5.0
Cocamidomethyl MEA 3.0
Coconut oil fatty acid PEG-7 glyceryl 5.0
Polyquaternium-10 0.8
Glycol distearate 0.5
Polyquaternium-7 0.5
EDTA-2Na 0.05
Succinic acid 0.1
Malic acid 0.1
Methylparaben 0.2
Phenoxyethanol 0.4
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
All components were heated at about 80 ° C. and uniformly stirred and mixed. The pH was adjusted to 6.0 with sodium hydroxide.

Example 11 Hair treatment that does not wash away
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Polyquaternium-37 2.0
Squalene 2.0
PPG-3 Caprilyl Ether 2.0
Microcrystalline wax 0.1
Lanolin alcohol 0.2
Montan wax 0.1
Polyethylene wax 0.1
Beeswax 0.1
Japan wax 0.2
Celesin 0.1
Dicapric acid PG 1.0
Almond oil 0.5
Ethylhexyl ethylhexanoate 1.0
Candelilla wax extract 0.1
Octyldodecyl erucate 4.5
Tocopherol acetate 0.02
Elcalactone MCT (Nippon Fine Chemical Co., Ltd.) 2.0
Dipentaerythrityl tripolyhydroxystearate 1.5
PPG-5 Phytosteryl 0.5
Glycerin 4.0
Sorbitol 2.0
Phenoxyethanol 0.5
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.5
Part B Hydrolyzed Conchiolin 0.1
Panthenol 0.1
Hydroxypropyltrimonium hyaluronate 0.01
Polyquaternium-11 0.2
Glycosyl trehalose 0.1
Glyceryl glucoside 0.3
Part C Purified water Amount totaling 100 Hydroxypropyl starch phosphoric acid 1.0
Malonic acid 0.1
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part C was uniformly dispersed and heated to about 80 ° C. Next, part A was heated to about 80 ° C. to dissolve it. Part C was added while stirring, and after mixing uniformly, the mixture was cooled to about 40 ° C. Then, each part B was added and mixed uniformly. The pH was adjusted to 6.0 with arginine.

Example 12 Hair treatment that does not wash away
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 1.0
FineNeo-EHS (Nippon Fine Chemical Co., Ltd.) 1.0
Setrimonium chloride (25%) 2.8
Ercolano LH (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 0.2
PPG-3 Caprilyl Ether 1.0
Methyl heptyl myristate 0.5
Cetyl ethylhexanoate 0.3
Isononyl isononanoate 0.3
Tridecyl neopentate 0.5
Myristyl isooctanoate 0.3
Neopentyl glycol diethylhexanate 0.3
Isobutyl isostearate 0.3
Glyceryl triisostearate 0.3
Trimethylolpropane triisostearate 0.3
Broccoli seed oil 0.3
Sphinganin 0.01
Glycerin 1.0
Part B Methylparaben 0.1
Amount of purified water totaling 100 Phenoxyethanol 0.5
Part C NanoRepair-CMC5 (Nippon Fine Chemical Co., Ltd.) 5.0
NanoRepair-EL (Nippon Fine Chemical Co., Ltd.) 1.0
Polyquaternium-6 0.6
Polyquaternium-7 0.4
Polyquaternium-39 0.5
Part D Carrageenan 0.1
Hydroxypropyl chitosan 0.05
Hydroxypropyl Methyl Cellulose 0.1
Tuberose polysaccharide 0.1
Catified guar gum 0.05
Succinic acid 1.3
Maleic acid 0.5
Purified water 20.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80 ° C. and dissolved. Next, part A was heated to about 80 ° C. to dissolve it. Part D was dispersed to prepare a viscous liquid. Part A was added to part B with stirring, mixed uniformly, and then cooled to about 40 ° C. Next, parts C and D were added and mixed uniformly. The pH was 2.4.

Example 13 Non-rinse scalp / hair treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 1.0
Ethanol 40.0
Glycyrrhetinic acid 0.02
PPG-3 Caprilyl Ether 0.3
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 1.5
PEG / PPG-20 / 20 Dimethicone 0.2
PEG-12 Dimethicone 0.4
Hydrogenated retinol 0.1
Trishexyldecanoic acid pyridoxine 0.05
Bisglyceryl ascorbic acid 0.3
Hexil 3-glyceryl ascorbic acid 0.3
Part B Purified water Amount totaling 100 (Acrylate / Alkyl acrylate (C10-30)) Cross polymer 0.4
Carbomer 0.05
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
(Acryloyl dimethyl taurine ammonium / VP) copolymer 0.05
(Acryloyldimethyltaurine ammonium / Behenez methacrylic acid-25) Crosspolymer 0.1
Hydroxypropyl chitosan 0.1
Methylparaben 0.1
Phenoxyethanol 0.2
Part C malic acid 0.5
3-O-ethylascorbic acid (Nippon Fine Chemical Co., Ltd.) 0.05
Nicotinamide 0.3
Pyridoxine hydrochloride 0.1
Caffeine 0.1
Glucosyl trehalose 0.1
Purified water 10.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 50 ° C. and dissolved. Next, part B was uniformly dispersed to obtain a viscous liquid. Part A was added to part B with stirring and mixed uniformly. Then part C was added and mixed uniformly. The pH was adjusted to 4.0 with triethanolamine.

Example 14 Hair treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A LUSPLAN DD-DHR (Nippon Fine Chemical Co., Ltd.) 0.5
Dodecane 1.5
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 0.2
Candelilla wax 0.2
Cetyl Esters 0.3
Stearyl ethyl hexaneate 1.0
Cetearyl alcohol 3.5
PEG-200 0.5
Hydroxyethyl cellulose 0.4
Setrimonium chloride (30%) 1.0
Behentrimonium chloride (80%) 1.0
Trideces-6 0.3
BHT 0.03
Part B Methylparaben 0.2
Malic acid 0.1
Lactic acid 0.05
Amount of purified water totaling 100 Part C PPG-3 myristyl 0.5
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 1.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80 ° C. and dissolved. Part A was added to another container, and the mixture was heated and dissolved. Part B was gradually added to part A and mixed uniformly. Part C was added with stirring at about 50 ° C. to make it uniform. The pH was 3.5.

Example 15 Non-silicone hair treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 0.5
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.5
LUSPLAN DD-DA5 (Nippon Fine Chemical Co., Ltd.) 0.05
Propanediol 3.0
Behenamide propyl dimethylamine 1.5
Cetanol 2.2
Stearyl alcohol 0.8
Hydrogenated rapeseed oil alcohol 0.5
Neopentyl glycol diethylhexaneate 0.8
Jojoba seed oil 1.0
Glyceryl stearate 0.4
Propylparaben 0.1
Cocamide MEA 0.8
Caesar Pineia Spinosa Hydroxypropyltrimonium Chloride 0.1
Rice bran wax 0.5
Glycerin 1.0
Part B Methylparaben 0.1
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.5
Lactic acid 0.4
Succinic acid 0.1
Amount of purified water totaling 100 Part C Methyl heptyl caprylate 1.0
Polyquaternium-7 0.15
Myristic acid PPG-3 benzyl ether 0.5
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was uniformly mixed at about 80 ° C. Part B, which was set aside separately, was heated to about 60 ° C. to make it uniform. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part C was added and mixed uniformly. The pH was 3.1.

Example 16 Non-silicone hair treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 1.0
FineNeo-MCT (Nippon Fine Chemical Co., Ltd.) 0.6
Stearyl alcohol 2.0
Cetanol 1.2
Stealtrimonium chloride 1.0
PEG-45M 0.8
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.3
Totsubaki Seed Oil 0.4
Hydroxyethylurea 0.5
Dicaprilyl Carbonate 2.0
PPG-1 / PEG-1 stearamine 1.0
Squalene 0.1
Isosetes-10 0.5
Sunflower wax 0.8
Cocoyl Arginine Ethyl PCA 0.2
Phenoxyethanol 0.2
Tocopherol 0.05
Part B DPG 2.2
Glycerin 1.3
Sorbitol 3.5
BG 1.0
Hydroxycellulose 0.07
Phenoxyethanol 0.2
Malonic acid 0.3
Malic acid 0.2
EDTA-2Na 0.01
Amount of purified water totaling 100 Part C Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Polyquaternium-61 0.3
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was uniformly mixed at about 80 ° C. Part B, which was set aside separately, was heated to about 60 ° C. to make it uniform. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part C was added and mixed uniformly. The pH was 3.3.

Example 17 Non-silicone hair treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 2.0
LUSPLAN DD-DA7 (Nippon Fine Chemical Co., Ltd.) 0.1
Cetearyl alcohol 3.0
PPG-1 / PEG-1 stearamine 0.8
Behenamide propyl dimethylamine 1.0
Ethylhexyl palmitate 1.0
Dextrin palmitate 0.5
Inulin stearate 0.5
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 1.0
Hybrid sunflower oil 1.0
DPG 1.8
Glycerin 4.0
Mineral oil 0.5
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 1.0
PEG-160M 0.5
Rice bran wax 1.0
Part B Lecithin Hydroxide 0.2
Succinic acid 0.2
Lactic acid 0.2
Maleic acid 0.1
Hydrolyzed starch 0.4
Na 0.05 hyaluronate
Inulin-SC (Nippon Fine Chemical Co., Ltd.) 1.0
Hydroxypropyl Methyl Cellulose 0.1
Amount of purified water totaling 100 Part C Polyquaternium-107 0.5
Neopentyl glycol diheptate 2.0
Ethylhexyl isononanoate 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container, and the mixture was heated and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 50 ° C. and mixed uniformly. The pH was adjusted to 5.0 with sodium hydroxide.

Example 18 Non-silicone treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 0.3
Neosolue-Aqua (Nippon Fine Chemical Co., Ltd.) 0.2
Stearyl alcohol 3.0
Behentrimonium chloride 1.0
Stealtrimonium chloride 0.5
Stearamidopropyl dimethylamine 0.1
Hydrogenated polyisobutene 1.0
Hydrogenated polydecene 0.6
Camellia seed oil 0.5
Zika fever ether 3.0
Dilauroyl lysine Na 0.1
Ascorbyl dipalmitate 0.1
BG 3.0
Tocopherol 0.1
Phenoxyethanol 0.4
Part B Na hydrogen carbonate 0.4
Malic acid 1.0
Amount of purified water totaling 100 Locust Bean Hydroxypropyltrimonium Chloride 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container, and the mixture was heated and dissolved. Part B was gradually added to part A, mixed uniformly, emulsified, and then cooled to about 40 ° C. The pH was 3.6.

Example 19 Non-silicone treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-S (Nippon Fine Chemical Co., Ltd.) 0.5
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 0.3
Behentrimonium metosulfate 1.3
Setrimonium chloride 0.3
Paraffin 1.0
Hydroxypropyltrimonium hyaluronate 0.2
Isostearic acid hydrogenated castor oil 1.0
Squalene 2.0
Tocopherol acetate 0.05
Diethyl sebacate 2.0
Candelilla wax 0.3
Rice bran wax 0.2
Apricot kernel oil 1.0
DPG 2.0
Propanediol 1.0
Benzyl alcohol 0.5
Glycerin 1.0
PEG-7 propyl heptyl ether 0.8
PEG-180M 0.3
Part B Methylisothiazolinone 0.005
EDTA-2Na 0.03
Succinic acid 0.6
Zinc chloride 0.1
Amount of purified water totaling 100 Polyquaternium-10 0.2
Part C LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.05
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 0.5
FineNeo-EHS (Nippon Fine Chemical Co., Ltd.) 0.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container, and the mixture was heated and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 50 ° C. and mixed uniformly. The pH was 4.1.

Example 20 Shampoo for dandruff
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aquio (Nippon Fine Chemical Co., Ltd.) 0.05
Lauroylmethylalanine Na (30%) 13.0
Cocamidopropyl Betaine (30%) 20.0
Cocoyl Glutamic Acid TEA (30%) 5.0
Cocamide DEA 1.0
Glycerin 1.0
Glyceryl caprylate 0.4
Glyceryl undecylenate 0.1
Neosolue-Aqua (Nippon Fine Chemical Co., Ltd.) 1.0
Sorbitol 1.6
Miconazole nitrate 0.75
Glycol distearate 1.5
Polyquaternium-7 0.3
Part B malonic acid 2.0
Na benzoate 0.4
Na chloride 0.2
Amount of purified water totaling 100 Part C Swertia japonica extract 3.0
Polyquaternium-10 0.2
Guar Hydroxypropyltrimonium Chloride 0.1
Polyquaternium-47 0.1
Piroctone olamine 0.1
Purified water 9.7
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was placed in a separate container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C. The pH was adjusted to 5.0 with sodium hydroxide.

Example 21 Shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Neosolue-Aquio (Nippon Fine Chemical Co., Ltd.) 0.2
Neosolue-DiSM (Nippon Fine Chemical Co., Ltd.) 0.5
PPG-3 Caprilyl Ether 0.2
Ammonium Laureth Sulfate 5.0
Sodium Laureth Sulfate (25%) 10.0
Lauryl hydroxysultaine (30%) 10.0
Lauric acid K 1.0
Glycol distearate 0.5
Toluenesulfonic acid 0.3
Stearoxypropyl dimethylamine 0.5
PPG-17 0.3
Dimethicone (6cs) 0.1
PEG-9 Dimethicone 0.1
Amodimethicone 0.1
FineNeo-EHS (Nippon Fine Chemical Co., Ltd.) 1.0
Neopentyl glycol diethylhexanate 0.4
Lanolin fatty acid 0.3
Isodecyl glyceryl ether 0.4
Cocamide MEA 1.0
Laureth-4 0.3
Laureth-16 0.2
Stairless-6 0.2
Phenoxyethanol 0.3
Part B Malonic acid 0.1
Methylparaben 0.2
Na benzoate 0.3
Amount of purified water totaling 100 Part C NanoRepair-CMC (Nippon Fine Chemical Co., Ltd.) 5.0
Polyquaternium-10 0.2
Guar Hydroxypropyltrimonium Chloride 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 3.0
Purified water 6.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was uniformly mixed at about 80 ° C. Part B, which was set aside separately, was heated to about 60 ° C. to make it uniform. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part C was added and mixed uniformly. The pH was 5.6.

Example 22 Non-Silicone Hair Hair Treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Plandoll-LG3 1.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.5
Glyceryl stearate (SE) 4.5
Stairless-10 4.0
Cetanol 4.0
Stealtrimonium chloride (63%) 1.8
Behentrimonium chloride (80%) 1.0
Part B Methylparaben 0.2
Glycerin 3.0
Maleic acid 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part B was heated to about 80 ° C. and dissolved. Part A was added to another container, and the mixture was heated and dissolved. Part B was gradually added to part A and mixed uniformly. The pH was 3.2.

Example 23 Hair treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 1.0
Behentrimonium chloride (80%) 2.4
Cetanol 5.2
Glyceryl stearate 1.2
FineNeo-EHS (Nippon Fine Chemical Co., Ltd.) 0.4
Cyclopentasiloxane 0.8
Dimethiconol 0.1
Part B Methylparaben 0.1
Propylparaben 0.1
Malic acid 0.1
Citric acid 0.1
Amount of purified water totaling 100 Part C Aminoethylaminopropylsiloxane ・
Dimethylsiloxane copolymer emulsion 2.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Parts A and B were taken and heated to about 80 ° C., and each was uniformly mixed. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled (part D). Part C was added to part D and mixed uniformly. The pH was adjusted to 6.0 with arginine.

Example 24 Hair Treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 2.0
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 1.0
Cetanol 6.0
Dimethicone (1000cs) 2.0
Aminopropyl Dimethicone 0.4
Behentrimonium chloride (80%) 2.4
Distearyldimonium chloride (75%) 0.8
Glyceryl stearate 0.8
Part B succinic acid 2.0
Phenoxyethanol 0.5
Amount of purified water totaling 100 Part C Hydrolyzed keratin (20%) 1.5
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container, and the mixture was heated and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 40 ° C. and mixed uniformly. The pH was 3.1.

Example 25 Hair Treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aquio (Nippon Fine Chemical Co., Ltd.) 0.2
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 2.0
Dodecane 3.0
Behenyl alcohol 4.0
Cetanol 2.0
Behentrimonium chloride 2.0
Stearamidopropyl dimethylamine 1.0
Glyceryl stearate 0.4
PPG-9 diglyceryl 0.2
Polyglyceryl diisostearate-2 0.1
Hydrogenated lecithin 0.1
Adsorption purified lanolin 0.2
Neopentyl glycol dioctanoate 0.5
FineNeo-EHS (Nippon Fine Chemical Co., Ltd.) 0.5
Tocopherol 0.05
Part B glycerin 0.2
DPG 0.2
Hydrolyzed collagen 0.1
Panthenol 0.1
Hydroxycellulose 0.02
Polyquaternium-10 0.05
Phenoxyethanol 0.2
Maleic acid 0.1
Citric acid 0.4
Edetonic acid 3Na 0.01
Pentetic acid 0.02
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved uniformly. B was placed in another container and heated to about 80 ° C. to uniformly dissolve it. Part B was gradually added to part A, mixed uniformly, and cooled. The pH was adjusted to 5.0 with arginine.

Example 26 Hair restorer
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Phytopresome Cera-23 (Nippon Fine Chemical Co., Ltd.) 0.05
BG 5.0
Glycerin 3.0
1,2-Pentanediol 5.0
Phytopresome MEL (Nippon Fine Chemical Co., Ltd.) 1.0
Polysorbate-20 0.1
LP70H (Nippon Fine Chemical) 0.02
Part B Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.5
DPG 2.0
Lactic acid 0.3
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.01
Purified water 50.0
Part C ethanol 10.0
Menthol 0.1
Mentyl glyceryl ether 0.15
Panthenyl ethyl ether 0.2
Camphor 0.1
Cordyceps extract 1.0
Swertia japonica extract 1.0
Loquat leaf extract 1.0
Hydrolyzed hyaluronic acid 0.02
Cyclic lysophosphatidic acid Na 0.001
Pepper extract 0.01
Betaine 0.3
Trehalose 0.2
Cymene-5-all 0.1
Tocopherol acetate 0.05
β-Glycyrrhetinic acid 0.05
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
A part and B part were each heated to 70 ° C., and A part was added while stirring part B with a propeller (500 rpm) to prepare a nanovesicle solution. Further, after cooling, part C mixed in advance was added to obtain a uniform liquid. The pH was adjusted to 5.1 with arginine.

Example 27 Leave-on treatment compounding amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 1.50
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 2.50
Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 2.00
Myristyl Alcohol 5.00
Behenyl alcohol 1.00
Oleyl alcohol 1.00
Dimethylpropylamide stearate 2.00
Na cocoamphoacetate (30%) 2.00
Glyceryl stearate 0.40
Myristic acid 0.60
Phenoxyethanol 0.40
Part B Lactic acid 1.00
Malonic acid 0.50
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved uniformly. Part B was heated to about 80 ° C. and dissolved. Part B was gradually added to part A and mixed uniformly. The pH was adjusted to 4.5 with sodium hydroxide.

Example 28 Leave on Hair Treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A PrimeLipid PI (Nippon Fine Chemical Co., Ltd.) 0.2
Phytopresome MEL (Nippon Fine Chemical Co., Ltd.) 1.5
Polysorbate 80 0.1
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 2.0
Setrimonium chloride (25%) 3.8
Isostearic acid 0.02
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 1.0
Caprylyl glucoside (50%) 0.8
Glycerin 4.0
1,2-Hexanediol 2.0
Phenoxyethanol 0.5
Part B Ethanol 5.0
Part C succinic acid 1.0
Hydrolyzed keratin 0.2
Hydrolyzed silk 0.1
Hydrolyzed conchiolin 0.1
Polyquaternium-6 0.6
Polyquaternium-7 0.4
Polyquaternium-39 0.5
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part C was heated to about 80 ° C. and dissolved. Next, part A was heated to about 80 ° C. to dissolve it. Part C was added while stirring, and after mixing uniformly, the mixture was cooled to about 40 ° C. Then, part B was added and mixed uniformly. The pH was 3.4.

Example 29 Non-Silicone Out Bath Hair Treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Elcalactone MCT (Nippon Fine Chemical Co., Ltd.) 1.20
LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.05
FineNeo-EHSU (Nippon Fine Chemical Co., Ltd.) 0.396
LUSPAN PI-DA (Nippon Fine Chemical Co., Ltd.) 0.004
Cetearyl alcohol 2.00
Setes-20 0.40
Glyceryl stearate 0.20
Stearamidopropyl dimethylamine 0.20
Isostearyl alcohol 0.10
PG 3.00
Part B
Amount of purified water totaling 100 Lactic acid 0.05
Part C Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.50
Hydroxyethyl cellulose 0.20
Ethanol 10.00
Phenoxyethanol 0.5
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A and part B were heated to about 80 ° C., and part B was added and emulsified while stirring part A. After cooling to about 50 ° C., part C was added and mixed uniformly. The pH was 6.1.

Example 30 Hair wax
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Microcrystalline Wax 10.0
Ercolano LH (Nippon Fine Chemical Co., Ltd.) 4.0
Candelilla Row 2.0
Beeswax 2.0
Stearic acid 4.0
Cetearyl alcohol 4.0
Polyglyceryl stearate-10 2.0
FineNeo-IOP (Nippon Fine Chemical Co., Ltd.) 2.0
Glyceryl stearate 0.6
Tocopherol 0.05
Part B
Amount of purified water totaling 100 Phenoxyethanol 0.4
Methylparaben 0.1
Part C Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.2
Inulin-SC (Nippon Fine Chemical Co., Ltd.) 1.0
Succinic acid 0.3
Purified water 20.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A and part B were heated to about 80 ° C., and part B was added and emulsified while stirring part A. After cooling to about 50 ° C., part C was added and mixed uniformly. The pH was adjusted to 7.0 with sodium hydroxide.

Example 31 Styling milk
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A LUSPLAN SR-DP4 (Nippon Fine Chemical Co., Ltd.) 1.0
Stearyl alcohol 1.7
Neosolue-IPP (Nippon Fine Chemical Co., Ltd.) 1.2
Stearamidopropyl dimethylamine 1.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.2
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 0.2
Setes-20 0.3
Part B Phenoxyethanol 0.4
Lactic acid 0.5
Amount of purified water totaling 100 Part C Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 0.5
Hydroxyethyl cellulose 0.4
BG 2.0
Purified water 30.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Parts A and B were mixed at about 80 ° C., respectively. Part B was added to part A for emulsification, cooled to about 60 ° C., and then part C was added. It was cooled to about 40 ° C. and mixed with part D to make it uniform. The pH was 4.2.

Example 32 Styling gel
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Phytopresome MEL (Nippon Fine Chemical Co., Ltd.) 1.5
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 2.0
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.5
Glycerin 3.0
PG 2.0
BG 5.0
Part B Lactic acid 0.3
Phenoxyethanol 0.5
Hydroxyethyl cellulose 0.4
(Acrylate / Alkyl Acrylate (C10-30)) Cross Polymer
0.5
(Acryloyl dimethyl taurine ammonium / VP) copolymer
0.05
Carbomer 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A and B were mixed at about 60 ° C., respectively. Part A was added while stirring part B with a propeller and mixed uniformly. The pH was adjusted to 6.0 with sodium hydroxide.

Example 33 Moose
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 0.2
Ethanol 5.0
Polyethylene glycol oleyl ether (20) 1.0
Acrylic resin alkanolamine solution 3.0
Diethylaminopropylamide stearate 0.5
Pyrrolidone carboxylic acid 0.2
Malic acid 0.1
Preservatives, fragrances 1.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
The above components were mixed, and the obtained base and LPG were mixed at a ratio of base: LPG = 92: 8 to obtain an injection type mousse. The pH was 5.1.

Example 34 Hair cream
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 0.5
Stearic acid 2.0
Lanolin 3.0
Paraffin wax 2.0
Liquid paraffin 38.0
Glycerin monostearate (SE) 1.0
Sorbitan monostearate 1.0
Polyoxyethylene cetyl ether 1.5
Preservative Appropriate amount B part 1,3-butylene glycol 3.0
Succinic acid 0.5
Appropriate amount of fragrance Amount of purified water that makes a total of 100 ----------------------------------------------------------------------------
(Preparation method)
Part A was mixed at 80 ° C. Part B excluding the fragrance was mixed, heated to 80 ° C. and mixed with part A to make it uniform. After cooling to 50 ° C., a fragrance was added. The pH was adjusted to 5.5 with triethanolamine.

Example 35 Styling milk
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Phytocompo-C (Nippon Fine Chemical Co., Ltd.) 1.0
Glycerin 5.0
BG 8.0
Part B Elcalactone MCT (Nippon Fine Chemical Co., Ltd.) 1.0
LUSPLAN DD-IS (Nippon Fine Chemical Co., Ltd.) 1.0
Cetearyl alcohol 1.0
FineNeo-IPP (Nippon Fine Chemical Co., Ltd.) 2.0
LUSPLAN SR-DM4 1.0
Setes-20 0.3
Part C methylparaben 0.1
Amount of purified water totaling 100 Part D Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 0.5
Carbomer (2%) 5.0
Xanthan gum 0.5
Malonic acid 0.2
Phenoxyethanol 0.4
Purified water 30.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
pH 6.0
(Preparation method)
Disperse part A evenly. Parts B and C are each heated and dissolved at about 70 ° C. After gradually adding the B part to the A part, the C part is gradually added and emulsified. Cool while stirring, add part D at 45 ° C, and stir. The pH was adjusted to 6.5 with sodium hydroxide.

Example 36 Hair Color Treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 1.0
Stealtrimonium chloride (70%) 2.5
Ercolano CA-NH (Nippon Fine Chemical Co., Ltd.) 0.3
Cocamide DEA 1.0
Inulin stearate 0.5
Lanolin alcohol 0.2
Montan wax 0.1
Polyethylene wax 0.1
Beeswax 0.1
Dextrin palmitate 0.3
Celesin 0.1
Capric acid PPG-3 1.0
Dicapric acid PG 1.0
Ethylhexyl ethylhexanoate 1.0
Dicaprilyl Carbonate 1.5
Glycerin 4.0
Setes-7 1.0
Isostearyl alcohol 0.3
Rice bran oil 0.5
Glyceryl stearate 0.5
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 1.5
Hydrogenated polydecene 0.1
Macademia Nut Fatty Acid Ethyl 1.0
Lysine dilauroyl glutamate Na 0.1
Behendimonium stearyl ethyl phosphate 0.1
Tocopherol 0.05
Phenoxyethanol 0.3
Part C purified water 10.0
BG 2.0
Acylated hydrolyzed collagen 0.1
Panthenol 0.1
Hydroxyethyl cellulose 0.1
Polyquaternium-64 0.1
Polyquaternium-51 0.01
Polyquaternium-49 0.2
Phenoxyethanol 0.4
PCA-Na 0.1
Malic acid 0.1
Part D Purified water Amount totaling 100 Basic blue 99 0.1
Basic tea 16 0.13
HC Blue 2 0.05
HC Yellow 2 0.03
HC Red 3 0.1
Hydroxyethylurea 0.5
Ammonium hydrogen carbonate 1.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A, which had been uniformly mixed in advance, was added to part B, and the mixture was heated to about 80 ° C. to dissolve it (part E). Part D was heated to about 80 ° C. in another container to dissolve it. While stirring part D in part E, the mixture was gradually added and mixed uniformly, and then rapidly cooled (part F). Part C was added to part F at about 40 ° C to make it uniform. The pH was adjusted to 5.0 with arginine.

Example 37 Hair manicure
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Ethanol 10.0
Carnauba wax 0.01
Setes-10 1.0
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 2.5
PPG-3 Caprilyl Ether 1.0
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 1.0
Decanoate PPG-3 0.5
Dicapric acid PG 0.5
Dicaprilyl Carbonate 0.5
Part B Purple 401 0.2
Black 401 0.1
Orange 205 0.1
Red 102 0.1
Benzyl alcohol 8.0
Ethanol 10.0
Part C Purified water Total amount (acryloyldimethyltaurine ammonium / VP) copolymer 3.0
Glycolic acid 2.0
Succinic acid 2.0
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 2.0
Hydroxypropyl xanthan gum 0.2
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Parts A and C were mixed and made uniform. Part B was added to part C with stirring and mixed uniformly, then part A was added at about 60 ° C. and mixed uniformly. The pH was 2.6.

In the above formulation, the details of the ingredients described by the product names are as follows.

〇LUS PLAN DD-IS: Dimersy linoleyl diisostearate 〇LUSPLAN PI-DA: Dimer dilinoleate di (isostearyl / phytosteryl)
〇LUSPLAN DD-DHR: Dimerge linoleyl hydrogenated rosin condensate 〇LUSPLAN DD-DA5: Dimerge linoleic acid Dimerge linoleyl 〇LUSPLAN DD-DA7: Dimerge linoleic acid Dimerge linoleil 〇LUSPLAN SR-DM4: Die Dimaryllinoleic acid dimersylinorail, tri (caprylic acid / capric acid) glyceryl 〇LUS PLAN SR-DP4: dimaryllinoleyl dimerginoleate, pentaerythrityl tetraisostearate 〇Inulin-SC: inulin 〇NanoRepair-EL: γ -Docosalactone, soysterol-containing composition 〇NanoRepair-CMC: quaternium-18, quaternium-33, cholesterol, ceramide 2, ceramide 3, ceramide 6, PG-containing composition 〇NanoRepair-CMC5: ceramide 1, ceramide 2, ceramide 3 , Ceramide 5, Ceramide 6, Cholesterol, Quotanium-33-Containing Composition 〇 Neosolue-Aquio: Cyclohexanedicarboxylic Acid Bisethoxydiglycol 〇 Neosolue-Aqua: (Eicosandioic Acid / Tetradecanoic Acid) Polyglyceryl-10, Glycerin 〇 Neosolue-AquaS : (Eicosandioic acid / tetradecanoic acid) polyglyceryl-10, glycerin 〇 Neosolue-DiSM: diisostearyl malate 〇 Neosolue-MP: methylpentanediol dineeopentane 〇 Neosolue-DE: diethylpentanediol dineeopentane 〇 FineNeo-EHS: Diethylhexyl sebacate 〇FineNeo-EHSU: diethylhexyl succinate 〇FineNeo-MCT: tri (caprylic acid / capric acid) glyceryl 〇FineNeo-IPP: isopropyl palmitate 〇FineNeo-IOP: ethylhexyl palmitate 〇Plandol- Dicarboxylic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
〇Plandol-S: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
〇Plandol-G: Dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl)
〇Plandol-DP: Bisdiglyceryl polyacyl adipate-2
〇Plandol-ISS: Phytosteryl isostearate 〇Plandol-SUN: Sunflower seed oil fatty acid phytosteryl 〇Plandol-MAS: Macademia nut oil fatty acid phytosteryl 〇Plandol-LG1: Di (phytosteryl / octyldodecyl) lauroyl glutamate
〇Plandol-LG2: Di-lauroyl glutamate (phytosteryl / octyldodecyl)
〇Plandol-LG3: Di-lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
〇Plandol-LG4: Di lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
〇 Phytocompo-C: Hydrogenated lecithin, phytosterols, ceramide 2, ceramide 3, ceramide 6II
〇 Phytopresome Cera23: Hydrogenated lecithin, phytosterols, ceramide 2, ceramide 3
〇Phytopresome MEL: Glycolipid, hydrogenated lecithin, BG, purified water 〇PrimeLipid PI: Hydrogenated lecithin, lecithin, phytosterols, tocopherol 〇Tremoist-TP: White jellyfish polysaccharide 〇Tremost-SL: White jellyfish polysaccharide 1%
〇 LP70H: Hydrogenated lysolecithin 〇 Elcalactone MCT: γ-docosalactone, tri (caprylic acid / capric acid) glyceryl 〇 Elcalactone DES: γ-docosalactone, diethyl sebacate 〇 Ecolano LH: Lanolin wax 〇 Ecolano CA-NH: Quotanium -33, BG

It is a microscope image of the hair before and after the treatment with the hair cavity repair agent of Example 4.

Claims (5)

A hair cavity repair agent containing the following components (A) and (B).
(A) Diester of organic acid (B) dicarboxylic acid represented by conversion 1 and polyoxyethylene monoalkyl ether represented by conversion 2 (Chemical formula 1) HO-CO-R1-CO-OH
(In the formula, R1 represents a linear, branched or cyclic hydrocarbon group having 2 to 10 carbon atoms).
(Chemical 2) R2- (OCH2CH2) n-OH
(In the formula, R2 is a linear, branched or cyclic hydrocarbon group having 1 to 12 carbon atoms.
n represents an integer of 2 to 11) Ingredient (A) is acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, benzoic acid, salicylic acid, gallic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, phthalic acid, The hair cavity repairing agent according to claim 1, wherein the hair cavity repairing agent is one or more selected from glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and gluconic acid. The hair cavity repair agent according to claim 1 or 2, wherein the component (B) is a diester of cyclohexanedicarboxylic acid and diethylene glycol monoethyl ether. A method for repairing a cavity generated inside a hair using the hair cavity repairing agent according to any one of claims 1 to 3. A hair cosmetic containing the hair cavity repairing agent according to any one of claims 1 to 3.