JP2020530504A - ワイヤおよびケーブル絶縁層ならびにジャケット層のための湿気硬化性組成物 - Google Patents
ワイヤおよびケーブル絶縁層ならびにジャケット層のための湿気硬化性組成物 Download PDFInfo
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- JP2020530504A JP2020530504A JP2020503293A JP2020503293A JP2020530504A JP 2020530504 A JP2020530504 A JP 2020530504A JP 2020503293 A JP2020503293 A JP 2020503293A JP 2020503293 A JP2020503293 A JP 2020503293A JP 2020530504 A JP2020530504 A JP 2020530504A
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Classifications
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- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
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- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D5/18—Fireproof paints including high temperature resistant paints
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
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Abstract
Description
元素周期表へのいかなる参照も、CRC Press,Inc.,1990−1991によって出版されたものへの参照である。この周期表の元素の族への参照は、族の番号付与の新しい表記法による。
Mポリエチレン=(a)(Mポリスチレン)bを誘導することによって決定される。
この式において、a=0.4316であり、b=1.0である。
Mw=Ε(wi)(Mi)
に従って、通常の様式で計算され、式中、wiおよびMiは、それぞれ、GPCカラムから溶出するi番目の画分の重量画分および分子量である。一般に、エチレンポリマーのMwは、42,000〜64,000、好ましくは44,000〜61,000、より好ましくは46,000〜55,000の範囲である。
一実施形態では、本開示は、被覆導体のためのジャケット層として使用するための架橋性組成物を提供する。本明細書で使用される場合、「ジャケット層」は、絶縁層を包含する。一実施形態では、ジャケット層は、絶縁層である。
架橋性組成物は、シラン官能基化ポリオレフィンを含む。
Si−g−PEのベースエチレン系ポリマーは、ベースエチレン系ポリマーの総重量に基づいて、50重量%、または55重量%、または60重量%、または65重量%、または70重量%、または80重量%、または90重量%、または95重量%〜97重量%、または98重量%、または99重量%、または100重量%のエチレンを含む。
(i)0.850g/cc、または0.860g/cc、または0.875g/cc、または0.890g/cc〜0.900g/cc、または0.910g/cc、または0.915g/cc、または0.920g/cc、または0.925g/cc、または0.930g/cc、または0.935g/ccの密度、および
(ii)0.1g/10分、または0.5g/10分、または1.0g/10分、または2g/10分、または5g/10分、または8g/10分、または10g/10分、または15g/10分、または20g/10分、または25g/10分、または30g/10分〜30g/10分、または35g/10分、または45g/10分、または50g/10分、または55g/10分、または60g/10分、または65g/10分、または70g/10分、または75g/10分、または80g/10分、または85g/10分、または90g/10分のメルトインデックス。一実施形態では、シラングラフト化エチレン系ポリマーは、特性(i)および(ii)の両方を有する。
架橋性組成物は、充填剤を含み、充填剤は、充填剤の総重量に基づいて、50重量%超のシリカ(二酸化ケイ素(SiO2))を含む。
絶縁またはジャケット層は、反応性直鎖状シリコーン含有ポリマー、非反応性直鎖状シリコーン含有ポリマー、および/または非反応性分岐状シリコーン含有ポリマーから選択されるシリコーン含有ポリマーを含む。一実施形態では、シリコーン含有ポリマーは、反応性直鎖状シリコーン含有ポリマーまたは非反応性直鎖状シリコーン含有ポリマーである。
一実施形態では、組成物は、ルイス酸およびブレンステッド酸および塩基などのシラノール縮合触媒を含む。「シラノール縮合触媒」は、シラノール官能基化ポリオレフィンの架橋を促進する。ルイス酸は、ルイス塩基からの電子対を受け入れることができる化学種である。ルイス塩基は、電子対をルイス酸に供与することができる化学種である。好適なルイス酸の非限定的な例としては、ジブチルスズジラウレート(DBTDL)、ジメチルヒドロキシスズオレエート、ジオクチルスズマレエート、ジ−n−ブチルスズマレエート、ジブチルスズジアセテート、ジブチルスズジオクトエート、第一スズアセテート、第一スズオクトエート、ならびにナフテン酸鉛、カプリル酸亜鉛、およびナフテン酸コバルトなどの様々な他の有機金属化合物が挙げられる。好適なルイス塩基の非限定的な例としては、一級、二級、および三級アミンが挙げられる。「シラノール縮合触媒は、典型的には、湿気硬化用途に使用される。
一実施形態では、架橋性組成物は、1つ以上の任意の添加剤を含む。好適な添加剤の非限定的な例としては、金属不活性化剤、湿気捕捉剤、酸化防止剤、ブロッキング防止剤、安定剤、着色剤、紫外線(UV)吸収剤または安定剤(例えば、ヒンダードアミン光安定剤(HALS)および酸化チタン)、他の難燃剤、相溶化剤、充填剤、および加工助剤が挙げられる。UV安定剤の非限定的な例としては、ヒンダードが挙げられる。
一実施形態では、絶縁またはジャケット層は、架橋性組成物の反応生成物であり、架橋性組成物は、(A)シラン官能基化ポリオレフィンと、(B)充填剤であって、充填剤の総重量に基づいて、50重量%超のシリカを含む、充填剤と、(C)シリコーン含有ポリマーと、(D)架橋性組成物の総重量に基づいて、0.002重量%〜20重量%のシラノール縮合触媒と、を含む。
一実施形態では、架橋性組成物を使用して、ジャケット層を形成する。一実施形態では、ジャケット層は、絶縁層である。
(i)金属を含まない、および/または
(ii)1.10オーム以上、または1.15オーム、または1.20オーム、または1.25オーム〜1.30オーム、または1.35オーム、または1.40オーム、または1.45オーム、または1.50オーム、または1.55オームの湿潤絶縁抵抗比オームである、および/または
(iii)水平燃焼テストに合格する。
(i)金属を含まない、および/または
(ii)1.10以上、または1.15、または1.20、または1.25〜1.30、または1.35、または1.40、または1.45、または1.50、または1.55の湿潤絶縁抵抗比である、および/または
(iii)水平燃焼テストに合格する。
(i)金属を含まない、および/または
(ii)1.10以上、または1.15、または1.20、または1.25〜1.30、または1.35、または1.40、または1.45、または1.50、または1.55の湿潤絶縁抵抗比である、および/または
(iii)水平燃焼テストに合格する。
(i)金属を含まない、および/または
(ii)1.10以上、または1.15、または1.20、または1.25〜1.30、または1.35、または1.40、または1.45、または1.50、または1.55の湿潤絶縁抵抗比である、および/または
(iii)水平燃焼テストに合格する。
一実施形態では、本開示は、導体上の被覆を備える被覆導体であって、被覆が、(A)架橋されたシラン官能基化ポリオレフィンと、(B)充填剤であって、充填剤の総重量に基づいて、50重量%超のシリカを含む、充填剤と、(C)シリコーン含有ポリマーと、(D)被覆の総重量に基づいて、0.00重量%〜20重量%のシラノール縮合触媒と、を含む。
(i)被覆が金属を含まない、および/または
(ii)1.10以上、または1.15、または1.20、または1.25〜1.30、または1.35、または1.40、または1.45、または1.50、または1.55の湿潤絶縁抵抗比である、および/または
(iii)被覆導体が水平燃焼テストに合格する。
(i)被覆が金属を含まない、および/または
(ii)1.10以上、または1.15、または1.20、または1.25〜1.30、または1.35、または1.40、または1.45、または1.50、または1.55の湿潤絶縁抵抗比である、および/または
(iii)被覆導体が水平燃焼テストに合格する。
(i)被覆が金属を含まない、および/または
(ii)1.10以上、または1.15、または1.20、または1.25〜1.30、または1.35、または1.40、または1.45、または1.50、または1.55の湿潤絶縁抵抗比である、および/または
(iii)被覆導体が水平燃焼テストに合格する。
(i)被覆が金属を含まない、および/または
(ii)1.10以上、または1.15、または1.20、または1.25〜1.30、または1.35、または1.40、または1.45、または1.50、または1.55の湿潤絶縁抵抗比である、および/または
(iii)被覆導体が水平燃焼テストに合格する。
ENGAGE 8402は、0.902g/ccの密度、および30g/10分のMIを有するエチレン−オクテンコポリマーである。
シラングラフト化ポリエチレンは、二軸押出機による反応性押出によって調製される。ベース樹脂(ENGAGE 8402)の総重量に基づいて、1.8重量%のビニルトリメトキシシラン(VTMS)と、ベース樹脂(ENGAGE 8402)の総重量に基づいて、900ppmのLuperox 101とを秤量して一緒に混合した後、約10〜15分間磁気攪拌して、一様な液体混合物を達成する。混合物をスケール上に留置し、液体ポンプ注入に接続する。ENGAGE 8402を、ZSK−30押出機のメインフィーダーに供給する。ZSK−30のバレル温度プロファイルを以下のように設定する。
Claims (17)
- 架橋性組成物であって、
(A)シラン官能基化ポリオレフィンと、
(B)充填剤であって、前記充填剤の総重量に基づいて、50重量%超のシリカを含む、充填剤と、
(C)反応性直鎖状シリコーン含有ポリマー、非反応性直鎖状シリコーン含有ポリマー、および非反応性分岐状シリコーン含有ポリマーからなる群から選択される、シリコーン含有ポリマーと、
(D)前記架橋性組成物の総重量に基づいて、0.00重量%〜20重量%のシラノール縮合触媒と、を含む、架橋性組成物。 - 被覆導体のためのジャケット層であって、前記絶縁またはジャケット層が、
(A)架橋されたシラン官能基化ポリオレフィンと、
(B)充填剤であって、前記充填剤の総重量に基づいて、50重量%超のシリカを含む、充填剤と、
(C)反応性直鎖状シリコーン含有ポリマー、非反応性直鎖状シリコーン含有ポリマー、および反応性分岐状シリコーン含有ポリマーからなる群から選択される、シリコーン含有ポリマーと、
(D)前記ジャケット層の総重量に基づいて、0.00重量%〜10重量%のシラノール縮合触媒と、を含む、ジャケット層。 - 前記架橋されたシラン官能基化ポリオレフィンが、シラングラフト化エチレン系ポリマーである、請求項2に記載のジャケット層。
- 前記充填剤が、前記充填剤の総重量に基づいて、90重量%超〜100重量%のシリカを含む、請求項2および3のいずれか一項に記載のジャケット層。
- 前記充填剤が、シリカのみからなる、請求項2〜4のいずれか一項に記載のジャケット層。
- 前記シリコーン含有ポリマーが、反応性直鎖状ポリシロキサンおよび非反応性直鎖状ポリシロキサンからなる群から選択される、請求項2〜5のいずれか一項に記載のジャケット層。
- 前記ジャケット層の総重量に基づいて、
(A)前記架橋されたシラングラフト化ポリオレフィンが、架橋されたシラングラフト化ポリエチレンである、20重量%〜80重量%の前記架橋されたシラン官能基化ポリオレフィンと、
(B)20重量%〜80重量%の前記充填剤と、
(C)4重量%〜20重量%の前記シリコーン含有ポリマーと、を含む、請求項2〜6のいずれか一項に記載のジャケット層。 - 前記充填剤が、前記充填剤の総重量に基づいて、0重量%〜0.5重量%の金属を含む、請求項2〜7のいずれか一項に記載のジャケット層。
- 前記絶縁またはジャケット層が、前記充填剤の総重量に基づいて、0重量%〜0.3重量%の金属を含む、請求項8に記載のジャケット層。
- 1.10〜1.70の湿潤絶縁抵抗比を有する、請求項2〜9のいずれか一項に記載のジャケット層。
- 前記ジャケット層が、水平燃焼試験に合格する、請求項2〜10のいずれか一項に記載のジャケット層。
- 前記ジャケット層が、金属不活性化剤、湿気捕捉剤、および酸化防止剤のうちの少なくとも1つをさらに含む、請求項2〜11のいずれか一項に記載のジャケット層。
- 前記ジャケット層が、絶縁層である、請求項2〜12のいずれか一項に記載のジャケット層。
- 被覆導体であって、
導体と、
前記導体上の被覆と、を備え、前記被覆が、
(A)架橋されたシラン官能基化ポリオレフィンと、
(B)充填剤であって、前記充填剤の総重量に基づいて、50重量%超のシリカを含む、充填剤と、
(C)反応性直鎖状シリコーン含有ポリマー、非反応性直鎖状シリコーン含有ポリマー、または反応性分岐状シリコーン含有ポリマーからなる群から選択される、シリコーン含有ポリマーと、
(D)前記被覆の総重量に基づいて、0.00重量%〜20重量%のシラノール縮合触媒と、を含む、被覆導体。 - 前記被覆が、前記充填剤の総重量に基づいて、0重量%〜0.3重量%の金属を含む、請求項14に記載の被覆導体。
- 前記被覆導体が、1.10〜1.70の湿潤絶縁抵抗比を有する、請求項14および15のいずれか一項に記載の被覆導体。
- 前記被覆導体が、水平燃焼試験に合格する、請求項14〜16のいずれか一項に記載の被覆導体。
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US20200152347A1 (en) | 2020-05-14 |
CN111052265A (zh) | 2020-04-21 |
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CA3071397A1 (en) | 2019-02-07 |
BR112020001937A2 (pt) | 2020-07-28 |
KR102540458B1 (ko) | 2023-06-12 |
KR20200037274A (ko) | 2020-04-08 |
EP3662488A1 (en) | 2020-06-10 |
JP7182600B2 (ja) | 2022-12-02 |
EP3662488B1 (en) | 2023-06-21 |
RU2769510C2 (ru) | 2022-04-01 |
US11361879B2 (en) | 2022-06-14 |
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