JP2020527185A - ゴム組成物 - Google Patents
ゴム組成物 Download PDFInfo
- Publication number
- JP2020527185A JP2020527185A JP2020501499A JP2020501499A JP2020527185A JP 2020527185 A JP2020527185 A JP 2020527185A JP 2020501499 A JP2020501499 A JP 2020501499A JP 2020501499 A JP2020501499 A JP 2020501499A JP 2020527185 A JP2020527185 A JP 2020527185A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- weight
- parts
- rubber composition
- synthetic rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 139
- 239000005060 rubber Substances 0.000 title claims abstract description 139
- 239000000203 mixture Substances 0.000 title claims abstract description 79
- 229920003051 synthetic elastomer Polymers 0.000 claims description 88
- 239000005061 synthetic rubber Substances 0.000 claims description 88
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 54
- 239000005062 Polybutadiene Substances 0.000 claims description 40
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 39
- 229920002857 polybutadiene Polymers 0.000 claims description 38
- 229920002554 vinyl polymer Polymers 0.000 claims description 29
- 239000000377 silicon dioxide Substances 0.000 claims description 26
- 239000000178 monomer Substances 0.000 claims description 21
- 150000001993 dienes Chemical class 0.000 claims description 20
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 18
- 125000000524 functional group Chemical group 0.000 claims description 18
- 239000000945 filler Substances 0.000 claims description 16
- 239000010734 process oil Substances 0.000 claims description 14
- 229920003244 diene elastomer Polymers 0.000 claims description 12
- 238000004073 vulcanization Methods 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 11
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000006229 carbon black Substances 0.000 claims description 4
- 230000003712 anti-aging effect Effects 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 238000005299 abrasion Methods 0.000 abstract description 15
- 238000010586 diagram Methods 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 description 59
- 239000000126 substance Substances 0.000 description 38
- 230000000052 comparative effect Effects 0.000 description 36
- 229920003048 styrene butadiene rubber Polymers 0.000 description 32
- 239000003921 oil Substances 0.000 description 27
- 150000001875 compounds Chemical class 0.000 description 22
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 19
- -1 4-cyclohexyl Chemical group 0.000 description 18
- 230000000694 effects Effects 0.000 description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 15
- 239000004606 Fillers/Extenders Substances 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 12
- 230000000704 physical effect Effects 0.000 description 11
- 125000001424 substituent group Chemical group 0.000 description 11
- 229910052744 lithium Inorganic materials 0.000 description 10
- 244000043261 Hevea brasiliensis Species 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 239000003607 modifier Substances 0.000 description 9
- 229920003052 natural elastomer Polymers 0.000 description 9
- 229920001194 natural rubber Polymers 0.000 description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 239000007822 coupling agent Substances 0.000 description 8
- 125000000753 cycloalkyl group Chemical group 0.000 description 8
- 239000000446 fuel Substances 0.000 description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 8
- 239000011787 zinc oxide Substances 0.000 description 8
- 235000014692 zinc oxide Nutrition 0.000 description 8
- 235000021355 Stearic acid Nutrition 0.000 description 7
- 239000002174 Styrene-butadiene Substances 0.000 description 7
- 230000009477 glass transition Effects 0.000 description 7
- 150000005309 metal halides Chemical class 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 7
- 239000008117 stearic acid Substances 0.000 description 7
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 238000005096 rolling process Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- OKJPEAGHQZHRQV-UHFFFAOYSA-N Triiodomethane Natural products IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 5
- 230000020169 heat generation Effects 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910001507 metal halide Inorganic materials 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 238000005191 phase separation Methods 0.000 description 5
- 239000004636 vulcanized rubber Substances 0.000 description 5
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 4
- RCJMVGJKROQDCB-UHFFFAOYSA-N 2-methylpenta-1,3-diene Chemical compound CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 description 4
- LQIIEHBULBHJKX-UHFFFAOYSA-N 2-methylpropylalumane Chemical compound CC(C)C[AlH2] LQIIEHBULBHJKX-UHFFFAOYSA-N 0.000 description 4
- CJSBUWDGPXGFGA-UHFFFAOYSA-N 4-methylpenta-1,3-diene Chemical compound CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 238000003917 TEM image Methods 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 125000000304 alkynyl group Chemical group 0.000 description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical group C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 125000004404 heteroalkyl group Chemical group 0.000 description 4
- 125000000623 heterocyclic group Chemical group 0.000 description 4
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002168 alkylating agent Substances 0.000 description 3
- 229940100198 alkylating agent Drugs 0.000 description 3
- JMBNQWNFNACVCB-UHFFFAOYSA-N arsenic tribromide Chemical compound Br[As](Br)Br JMBNQWNFNACVCB-UHFFFAOYSA-N 0.000 description 3
- 229940077468 arsenic tribromide Drugs 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 3
- 125000002993 cycloalkylene group Chemical group 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 150000002366 halogen compounds Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- APPOKADJQUIAHP-GGWOSOGESA-N (2e,4e)-hexa-2,4-diene Chemical compound C\C=C\C=C\C APPOKADJQUIAHP-GGWOSOGESA-N 0.000 description 2
- BOGRNZQRTNVZCZ-AATRIKPKSA-N (3e)-3-methylpenta-1,3-diene Chemical compound C\C=C(/C)C=C BOGRNZQRTNVZCZ-AATRIKPKSA-N 0.000 description 2
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 2
- BOGRNZQRTNVZCZ-UHFFFAOYSA-N 1,2-dimethyl-butadiene Natural products CC=C(C)C=C BOGRNZQRTNVZCZ-UHFFFAOYSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- CJTZXIJETZZARD-UHFFFAOYSA-N 1-iodo-2,2-dimethylpropane Chemical compound CC(C)(C)CI CJTZXIJETZZARD-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 2
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 2
- DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 2
- ILAHWRKJUDSMFH-UHFFFAOYSA-N boron tribromide Chemical compound BrB(Br)Br ILAHWRKJUDSMFH-UHFFFAOYSA-N 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
- VPCAAUUIFCAFRZ-UHFFFAOYSA-N butylalumane Chemical compound CCCC[AlH2] VPCAAUUIFCAFRZ-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- BLHLJVCOVBYQQS-UHFFFAOYSA-N ethyllithium Chemical compound [Li]CC BLHLJVCOVBYQQS-UHFFFAOYSA-N 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- PSCMQHVBLHHWTO-UHFFFAOYSA-K indium(iii) chloride Chemical compound Cl[In](Cl)Cl PSCMQHVBLHHWTO-UHFFFAOYSA-K 0.000 description 2
- AFRJJFRNGGLMDW-UHFFFAOYSA-N lithium amide Chemical compound [Li+].[NH2-] AFRJJFRNGGLMDW-UHFFFAOYSA-N 0.000 description 2
- UBJFKNSINUCEAL-UHFFFAOYSA-N lithium;2-methylpropane Chemical compound [Li+].C[C-](C)C UBJFKNSINUCEAL-UHFFFAOYSA-N 0.000 description 2
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 2
- XBEREOHJDYAKDA-UHFFFAOYSA-N lithium;propane Chemical compound [Li+].CC[CH2-] XBEREOHJDYAKDA-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- NRQNMMBQPIGPTB-UHFFFAOYSA-N methylaluminum Chemical compound [CH3].[Al] NRQNMMBQPIGPTB-UHFFFAOYSA-N 0.000 description 2
- DVSDBMFJEQPWNO-UHFFFAOYSA-N methyllithium Chemical compound C[Li] DVSDBMFJEQPWNO-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- 150000002900 organolithium compounds Chemical class 0.000 description 2
- NHKJPPKXDNZFBJ-UHFFFAOYSA-N phenyllithium Chemical compound [Li]C1=CC=CC=C1 NHKJPPKXDNZFBJ-UHFFFAOYSA-N 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000005077 polysulfide Substances 0.000 description 2
- 229920001021 polysulfide Polymers 0.000 description 2
- 150000008117 polysulfides Polymers 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 239000012763 reinforcing filler Substances 0.000 description 2
- 239000005049 silicon tetrachloride Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 2
- QPBYLOWPSRZOFX-UHFFFAOYSA-J tin(iv) iodide Chemical compound I[Sn](I)(I)I QPBYLOWPSRZOFX-UHFFFAOYSA-J 0.000 description 2
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 2
- CSRZQMIRAZTJOY-UHFFFAOYSA-N trimethylsilyl iodide Chemical compound C[Si](C)(C)I CSRZQMIRAZTJOY-UHFFFAOYSA-N 0.000 description 2
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- BHHYHSUAOQUXJK-UHFFFAOYSA-L zinc fluoride Chemical compound F[Zn]F BHHYHSUAOQUXJK-UHFFFAOYSA-L 0.000 description 2
- WCFQIFDACWBNJT-UHFFFAOYSA-N $l^{1}-alumanyloxy(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]O[Al] WCFQIFDACWBNJT-UHFFFAOYSA-N 0.000 description 1
- VQCPDMARLUVHOA-UHFFFAOYSA-N (4-methylphenyl)-(2-methylpropyl)alumane Chemical compound C1(=CC=C(C=C1)[AlH]CC(C)C)C VQCPDMARLUVHOA-UHFFFAOYSA-N 0.000 description 1
- JBMXTJBHVMDDQY-UHFFFAOYSA-N (4-methylphenyl)-octylalumane Chemical compound C1(=CC=C(C=C1)[AlH]CCCCCCCC)C JBMXTJBHVMDDQY-UHFFFAOYSA-N 0.000 description 1
- SVJIEGOVQBGOSU-UHFFFAOYSA-N (4-methylphenyl)-propan-2-ylalumane Chemical compound C1(=CC=C(C=C1)[AlH]C(C)C)C SVJIEGOVQBGOSU-UHFFFAOYSA-N 0.000 description 1
- PRPLGWFQYUPYBN-UHFFFAOYSA-N (4-methylphenyl)-propylalumane Chemical compound C1(=CC=C(C=C1)[AlH]CCC)C PRPLGWFQYUPYBN-UHFFFAOYSA-N 0.000 description 1
- AAAXMNYUNVCMCJ-UHFFFAOYSA-N 1,3-diiodopropane Chemical compound ICCCI AAAXMNYUNVCMCJ-UHFFFAOYSA-N 0.000 description 1
- OFDISMSWWNOGFW-UHFFFAOYSA-N 1-(4-ethoxy-3-fluorophenyl)ethanamine Chemical compound CCOC1=CC=C(C(C)N)C=C1F OFDISMSWWNOGFW-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- RRRXUCMQOPNVAT-UHFFFAOYSA-N 1-ethenyl-4-(4-methylphenyl)benzene Chemical compound C1=CC(C)=CC=C1C1=CC=C(C=C)C=C1 RRRXUCMQOPNVAT-UHFFFAOYSA-N 0.000 description 1
- VVTGQMLRTKFKAM-UHFFFAOYSA-N 1-ethenyl-4-propylbenzene Chemical compound CCCC1=CC=C(C=C)C=C1 VVTGQMLRTKFKAM-UHFFFAOYSA-N 0.000 description 1
- OIEANVCCDIRIDJ-UHFFFAOYSA-N 1-ethenyl-5-hexylnaphthalene Chemical compound C1=CC=C2C(CCCCCC)=CC=CC2=C1C=C OIEANVCCDIRIDJ-UHFFFAOYSA-N 0.000 description 1
- CBXRMKZFYQISIV-UHFFFAOYSA-N 1-n,1-n,1-n',1-n',2-n,2-n,2-n',2-n'-octamethylethene-1,1,2,2-tetramine Chemical compound CN(C)C(N(C)C)=C(N(C)C)N(C)C CBXRMKZFYQISIV-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 1
- JRCZSHDOYYZKAW-UHFFFAOYSA-N 2-(4-methylphenyl)ethylalumane Chemical compound C1(=CC=C(C=C1)CC[AlH2])C JRCZSHDOYYZKAW-UHFFFAOYSA-N 0.000 description 1
- ZFFBIQMNKOJDJE-UHFFFAOYSA-N 2-bromo-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(Br)C(=O)C1=CC=CC=C1 ZFFBIQMNKOJDJE-UHFFFAOYSA-N 0.000 description 1
- YVSMQHYREUQGRX-UHFFFAOYSA-N 2-ethyloxaluminane Chemical compound CC[Al]1CCCCO1 YVSMQHYREUQGRX-UHFFFAOYSA-N 0.000 description 1
- ANGGPYSFTXVERY-UHFFFAOYSA-N 2-iodo-2-methylpropane Chemical compound CC(C)(C)I ANGGPYSFTXVERY-UHFFFAOYSA-N 0.000 description 1
- YRVRZDIWEXCJSX-UHFFFAOYSA-N 2-methyl-3-(3-triethoxysilylpropyl)thiirane-2-carboxylic acid Chemical compound CCO[Si](OCC)(OCC)CCCC1SC1(C)C(O)=O YRVRZDIWEXCJSX-UHFFFAOYSA-N 0.000 description 1
- TUZANDMTFCYPOY-UHFFFAOYSA-N 2-methylpropyl(phenyl)alumane Chemical compound C1(=CC=CC=C1)[AlH]CC(C)C TUZANDMTFCYPOY-UHFFFAOYSA-N 0.000 description 1
- GNOMLLKHNCKJRX-UHFFFAOYSA-N 2-phenylethylalumane Chemical compound C1(=CC=CC=C1)CC[AlH2] GNOMLLKHNCKJRX-UHFFFAOYSA-N 0.000 description 1
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- LOSLJXKHQKRRFN-UHFFFAOYSA-N 2-trimethoxysilylethanethiol Chemical compound CO[Si](OC)(OC)CCS LOSLJXKHQKRRFN-UHFFFAOYSA-N 0.000 description 1
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- PEGCFRJASNUIPX-UHFFFAOYSA-L ditert-butyltin(2+);dichloride Chemical compound CC(C)(C)[Sn](Cl)(Cl)C(C)(C)C PEGCFRJASNUIPX-UHFFFAOYSA-L 0.000 description 1
- QPADTPIHSPAZLQ-UHFFFAOYSA-N ethyl 5-nitronaphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCC)=CC=CC2=C1[N+]([O-])=O QPADTPIHSPAZLQ-UHFFFAOYSA-N 0.000 description 1
- NARCMUVKZHPJHP-UHFFFAOYSA-L ethyl(diiodo)alumane Chemical compound [I-].[I-].CC[Al+2] NARCMUVKZHPJHP-UHFFFAOYSA-L 0.000 description 1
- RXBOMHDFBHOQHF-UHFFFAOYSA-N ethyl(triiodo)silane Chemical compound CC[Si](I)(I)I RXBOMHDFBHOQHF-UHFFFAOYSA-N 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- UGUZZPBNTADPIT-UHFFFAOYSA-L ethylaluminum(2+);difluoride Chemical compound [F-].[F-].CC[Al+2] UGUZZPBNTADPIT-UHFFFAOYSA-L 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- GNTRBBGWVVMYJH-UHFFFAOYSA-M fluoro(dimethyl)alumane Chemical compound [F-].C[Al+]C GNTRBBGWVVMYJH-UHFFFAOYSA-M 0.000 description 1
- UPWPDUACHOATKO-UHFFFAOYSA-K gallium trichloride Chemical compound Cl[Ga](Cl)Cl UPWPDUACHOATKO-UHFFFAOYSA-K 0.000 description 1
- SRVXDMYFQIODQI-UHFFFAOYSA-K gallium(iii) bromide Chemical compound Br[Ga](Br)Br SRVXDMYFQIODQI-UHFFFAOYSA-K 0.000 description 1
- WXXZSFJVAMRMPV-UHFFFAOYSA-K gallium(iii) fluoride Chemical compound F[Ga](F)F WXXZSFJVAMRMPV-UHFFFAOYSA-K 0.000 description 1
- DWRNSCDYNYYYHT-UHFFFAOYSA-K gallium(iii) iodide Chemical compound I[Ga](I)I DWRNSCDYNYYYHT-UHFFFAOYSA-K 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- CBEQRNSPHCCXSH-UHFFFAOYSA-N iodine monobromide Chemical compound IBr CBEQRNSPHCCXSH-UHFFFAOYSA-N 0.000 description 1
- PDJAZCSYYQODQF-UHFFFAOYSA-N iodine monofluoride Chemical compound IF PDJAZCSYYQODQF-UHFFFAOYSA-N 0.000 description 1
- AGQPHHBPENBBIO-UHFFFAOYSA-M iodo(dioctyl)alumane Chemical compound [I-].CCCCCCCC[Al+]CCCCCCCC AGQPHHBPENBBIO-UHFFFAOYSA-M 0.000 description 1
- NNRANHIFAQDLRA-UHFFFAOYSA-N iodo(triphenyl)silane Chemical compound C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(I)C1=CC=CC=C1 NNRANHIFAQDLRA-UHFFFAOYSA-N 0.000 description 1
- MBZZFFPUTBWWTG-UHFFFAOYSA-M iodo-bis(2-methylpropyl)alumane Chemical compound [I-].CC(C)C[Al+]CC(C)C MBZZFFPUTBWWTG-UHFFFAOYSA-M 0.000 description 1
- SNHMUERNLJLMHN-UHFFFAOYSA-N iodobenzene Chemical compound IC1=CC=CC=C1 SNHMUERNLJLMHN-UHFFFAOYSA-N 0.000 description 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
- XJTQJERLRPWUGL-UHFFFAOYSA-N iodomethylbenzene Chemical compound ICC1=CC=CC=C1 XJTQJERLRPWUGL-UHFFFAOYSA-N 0.000 description 1
- FMKOJHQHASLBPH-UHFFFAOYSA-N isopropyl iodide Chemical compound CC(C)I FMKOJHQHASLBPH-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- CETVQRFGPOGIQJ-UHFFFAOYSA-N lithium;hexane Chemical compound [Li+].CCCCC[CH2-] CETVQRFGPOGIQJ-UHFFFAOYSA-N 0.000 description 1
- NRUBUZBAZRTHHX-UHFFFAOYSA-N lithium;propan-2-ylazanide Chemical compound [Li+].CC(C)[NH-] NRUBUZBAZRTHHX-UHFFFAOYSA-N 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 description 1
- WRYKIHMRDIOPSI-UHFFFAOYSA-N magnesium;benzene Chemical compound [Mg+2].C1=CC=[C-]C=C1.C1=CC=[C-]C=C1 WRYKIHMRDIOPSI-UHFFFAOYSA-N 0.000 description 1
- IWCVDCOJSPWGRW-UHFFFAOYSA-M magnesium;benzene;chloride Chemical compound [Mg+2].[Cl-].C1=CC=[C-]C=C1 IWCVDCOJSPWGRW-UHFFFAOYSA-M 0.000 description 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
- LWLPYZUDBNFNAH-UHFFFAOYSA-M magnesium;butane;bromide Chemical compound [Mg+2].[Br-].CCC[CH2-] LWLPYZUDBNFNAH-UHFFFAOYSA-M 0.000 description 1
- QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 description 1
- NXPHGHWWQRMDIA-UHFFFAOYSA-M magnesium;carbanide;bromide Chemical compound [CH3-].[Mg+2].[Br-] NXPHGHWWQRMDIA-UHFFFAOYSA-M 0.000 description 1
- CCERQOYLJJULMD-UHFFFAOYSA-M magnesium;carbanide;chloride Chemical compound [CH3-].[Mg+2].[Cl-] CCERQOYLJJULMD-UHFFFAOYSA-M 0.000 description 1
- VXWPONVCMVLXBW-UHFFFAOYSA-M magnesium;carbanide;iodide Chemical compound [CH3-].[Mg+2].[I-] VXWPONVCMVLXBW-UHFFFAOYSA-M 0.000 description 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 description 1
- FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 description 1
- YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 description 1
- RVOYYLUVELMWJF-UHFFFAOYSA-N magnesium;hexane Chemical compound [Mg+2].CCCCC[CH2-].CCCCC[CH2-] RVOYYLUVELMWJF-UHFFFAOYSA-N 0.000 description 1
- WCFJMDWWJOCLSJ-UHFFFAOYSA-N magnesium;methanidylbenzene Chemical compound [Mg+2].[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1 WCFJMDWWJOCLSJ-UHFFFAOYSA-N 0.000 description 1
- SCEZYJKGDJPHQO-UHFFFAOYSA-M magnesium;methanidylbenzene;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C1=CC=CC=C1 SCEZYJKGDJPHQO-UHFFFAOYSA-M 0.000 description 1
- DQZLQYHGCKLKGU-UHFFFAOYSA-N magnesium;propane Chemical compound [Mg+2].C[CH-]C.C[CH-]C DQZLQYHGCKLKGU-UHFFFAOYSA-N 0.000 description 1
- ZEOFKBGXHPLJHV-UHFFFAOYSA-N methyl carboniodidate Chemical compound COC(I)=O ZEOFKBGXHPLJHV-UHFFFAOYSA-N 0.000 description 1
- QQHNGZNHRRLNKI-UHFFFAOYSA-N methyl carbonobromidate Chemical compound COC(Br)=O QQHNGZNHRRLNKI-UHFFFAOYSA-N 0.000 description 1
- XMJHPCRAQCTCFT-UHFFFAOYSA-N methyl chloroformate Chemical compound COC(Cl)=O XMJHPCRAQCTCFT-UHFFFAOYSA-N 0.000 description 1
- 239000005055 methyl trichlorosilane Substances 0.000 description 1
- XBKBZMOLSULOEA-UHFFFAOYSA-L methylaluminum(2+);dibromide Chemical compound C[Al](Br)Br XBKBZMOLSULOEA-UHFFFAOYSA-L 0.000 description 1
- YSTQWZZQKCCBAY-UHFFFAOYSA-L methylaluminum(2+);dichloride Chemical compound C[Al](Cl)Cl YSTQWZZQKCCBAY-UHFFFAOYSA-L 0.000 description 1
- UEBCFKSPKUURKQ-UHFFFAOYSA-L methylaluminum(2+);difluoride Chemical compound [F-].[F-].[Al+2]C UEBCFKSPKUURKQ-UHFFFAOYSA-L 0.000 description 1
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- PVWOIHVRPOBWPI-UHFFFAOYSA-N n-propyl iodide Chemical compound CCCI PVWOIHVRPOBWPI-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- JXRJZEIFKKYMBS-UHFFFAOYSA-N octyl(phenyl)alumane Chemical compound C1(=CC=CC=C1)[AlH]CCCCCCCC JXRJZEIFKKYMBS-UHFFFAOYSA-N 0.000 description 1
- SOEVKJXMZBAALG-UHFFFAOYSA-N octylalumane Chemical compound CCCCCCCC[AlH2] SOEVKJXMZBAALG-UHFFFAOYSA-N 0.000 description 1
- 150000002901 organomagnesium compounds Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- QDUCABQBSRSYCO-UHFFFAOYSA-N phenyl(propan-2-yl)alumane Chemical compound C1(=CC=CC=C1)[AlH]C(C)C QDUCABQBSRSYCO-UHFFFAOYSA-N 0.000 description 1
- ZKGDHJAHOGRQEP-UHFFFAOYSA-N phenyl(propyl)alumane Chemical compound C1(=CC=CC=C1)[AlH]CCC ZKGDHJAHOGRQEP-UHFFFAOYSA-N 0.000 description 1
- ANRQGKOBLBYXFM-UHFFFAOYSA-M phenylmagnesium bromide Chemical compound Br[Mg]C1=CC=CC=C1 ANRQGKOBLBYXFM-UHFFFAOYSA-M 0.000 description 1
- 239000005054 phenyltrichlorosilane Substances 0.000 description 1
- UXCDUFKZSUBXGM-UHFFFAOYSA-N phosphoric tribromide Chemical compound BrP(Br)(Br)=O UXCDUFKZSUBXGM-UHFFFAOYSA-N 0.000 description 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
- PZHNNJXWQYFUTD-UHFFFAOYSA-N phosphorus triiodide Chemical compound IP(I)I PZHNNJXWQYFUTD-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- ZYTJPPRBIGGXRO-UHFFFAOYSA-N propan-2-ylalumane Chemical compound C(C)(C)[AlH2] ZYTJPPRBIGGXRO-UHFFFAOYSA-N 0.000 description 1
- RIBFXMJCUYXJDZ-UHFFFAOYSA-N propanoyl bromide Chemical compound CCC(Br)=O RIBFXMJCUYXJDZ-UHFFFAOYSA-N 0.000 description 1
- RZWZRACFZGVKFM-UHFFFAOYSA-N propanoyl chloride Chemical compound CCC(Cl)=O RZWZRACFZGVKFM-UHFFFAOYSA-N 0.000 description 1
- GLCSNYFRXVGJJF-UHFFFAOYSA-N propanoyl iodide Chemical compound CCC(I)=O GLCSNYFRXVGJJF-UHFFFAOYSA-N 0.000 description 1
- OBRKWFIGZSMARO-UHFFFAOYSA-N propylalumane Chemical compound [AlH2]CCC OBRKWFIGZSMARO-UHFFFAOYSA-N 0.000 description 1
- MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical group CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- VTQZBGAODFEJOW-UHFFFAOYSA-N selenium tetrabromide Chemical compound Br[Se](Br)(Br)Br VTQZBGAODFEJOW-UHFFFAOYSA-N 0.000 description 1
- LNBXMNQCXXEHFT-UHFFFAOYSA-N selenium tetrachloride Chemical compound Cl[Se](Cl)(Cl)Cl LNBXMNQCXXEHFT-UHFFFAOYSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- AIFMYMZGQVTROK-UHFFFAOYSA-N silicon tetrabromide Chemical compound Br[Si](Br)(Br)Br AIFMYMZGQVTROK-UHFFFAOYSA-N 0.000 description 1
- JHGCXUUFRJCMON-UHFFFAOYSA-J silicon(4+);tetraiodide Chemical compound [Si+4].[I-].[I-].[I-].[I-] JHGCXUUFRJCMON-UHFFFAOYSA-J 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000005649 substituted arylene group Chemical group 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- XCOKHDCPVWVFKS-UHFFFAOYSA-N tellurium tetraiodide Chemical compound I[Te](I)(I)I XCOKHDCPVWVFKS-UHFFFAOYSA-N 0.000 description 1
- RKSOPLXZQNSWAS-UHFFFAOYSA-N tert-butyl bromide Chemical compound CC(C)(C)Br RKSOPLXZQNSWAS-UHFFFAOYSA-N 0.000 description 1
- CUDGTZJYMWAJFV-UHFFFAOYSA-N tetraiodogermane Chemical compound I[Ge](I)(I)I CUDGTZJYMWAJFV-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- JTDNNCYXCFHBGG-UHFFFAOYSA-L tin(ii) iodide Chemical compound I[Sn]I JTDNNCYXCFHBGG-UHFFFAOYSA-L 0.000 description 1
- LTSUHJWLSNQKIP-UHFFFAOYSA-J tin(iv) bromide Chemical compound Br[Sn](Br)(Br)Br LTSUHJWLSNQKIP-UHFFFAOYSA-J 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 description 1
- JKNHZOAONLKYQL-UHFFFAOYSA-K tribromoindigane Chemical compound Br[In](Br)Br JKNHZOAONLKYQL-UHFFFAOYSA-K 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- FVRKTAOFDKFAMI-UHFFFAOYSA-M tributylstannanylium;bromide Chemical compound [Br-].CCCC[Sn+](CCCC)CCCC FVRKTAOFDKFAMI-UHFFFAOYSA-M 0.000 description 1
- ORVMIVQULIKXCP-UHFFFAOYSA-N trichloro(phenyl)silane Chemical compound Cl[Si](Cl)(Cl)C1=CC=CC=C1 ORVMIVQULIKXCP-UHFFFAOYSA-N 0.000 description 1
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1
- ZIYNWDQDHKSRCE-UHFFFAOYSA-N tricyclohexylalumane Chemical compound C1CCCCC1[Al](C1CCCCC1)C1CCCCC1 ZIYNWDQDHKSRCE-UHFFFAOYSA-N 0.000 description 1
- FBBATURSCRIBHN-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSCCC[Si](OCC)(OCC)OCC FBBATURSCRIBHN-UHFFFAOYSA-N 0.000 description 1
- KLFNHRIZTXWZHT-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltrisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSCCC[Si](OCC)(OCC)OCC KLFNHRIZTXWZHT-UHFFFAOYSA-N 0.000 description 1
- QKJGTZOWMVHEHS-UHFFFAOYSA-N triethoxy-[3-(phenyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSC1=CC=CC=C1 QKJGTZOWMVHEHS-UHFFFAOYSA-N 0.000 description 1
- PPLMQFARLJLZAO-UHFFFAOYSA-N triethyl(iodo)silane Chemical compound CC[Si](I)(CC)CC PPLMQFARLJLZAO-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- KQPIFPBKXYBDGV-UHFFFAOYSA-M triethylstannanylium;bromide Chemical compound CC[Sn](Br)(CC)CC KQPIFPBKXYBDGV-UHFFFAOYSA-M 0.000 description 1
- PRFPAWZEYOPUKM-UHFFFAOYSA-M triethylstannanylium;iodide Chemical compound CC[Sn](I)(CC)CC PRFPAWZEYOPUKM-UHFFFAOYSA-M 0.000 description 1
- JNLSTWIBJFIVHZ-UHFFFAOYSA-K trifluoroindigane Chemical compound F[In](F)F JNLSTWIBJFIVHZ-UHFFFAOYSA-K 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- ARIHFGQDMNMGQJ-UHFFFAOYSA-N triiodo(methyl)silane Chemical compound C[Si](I)(I)I ARIHFGQDMNMGQJ-UHFFFAOYSA-N 0.000 description 1
- HBVCQKOZPHBDAR-UHFFFAOYSA-N triiodo(phenyl)silane Chemical compound I[Si](I)(I)C1=CC=CC=C1 HBVCQKOZPHBDAR-UHFFFAOYSA-N 0.000 description 1
- RMUKCGUDVKEQPL-UHFFFAOYSA-K triiodoindigane Chemical compound I[In](I)I RMUKCGUDVKEQPL-UHFFFAOYSA-K 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JSXKIRYGYMKWSK-UHFFFAOYSA-N trimethoxy-[2-(2-trimethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CO[Si](OC)(OC)CCSSSSCC[Si](OC)(OC)OC JSXKIRYGYMKWSK-UHFFFAOYSA-N 0.000 description 1
- JTTSZDBCLAKKAY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSCCC[Si](OC)(OC)OC JTTSZDBCLAKKAY-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
- MZGUIAFRJWSYJJ-UHFFFAOYSA-M trimethylstannanylium;bromide Chemical compound C[Sn](C)(C)Br MZGUIAFRJWSYJJ-UHFFFAOYSA-M 0.000 description 1
- XGRPNCOKLIMKBN-UHFFFAOYSA-M trimethylstannanylium;iodide Chemical compound C[Sn](C)(C)I XGRPNCOKLIMKBN-UHFFFAOYSA-M 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- JOJQVUCWSDRWJE-UHFFFAOYSA-N tripentylalumane Chemical compound CCCCC[Al](CCCCC)CCCCC JOJQVUCWSDRWJE-UHFFFAOYSA-N 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- RTAKQLTYPVIOBZ-UHFFFAOYSA-N tritert-butylalumane Chemical compound CC(C)(C)[Al](C(C)(C)C)C(C)(C)C RTAKQLTYPVIOBZ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- UAYWVJHJZHQCIE-UHFFFAOYSA-L zinc iodide Chemical compound I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/22—Incorporating nitrogen atoms into the molecule
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
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Abstract
【選択図】図1
Description
本出願は、2018年5月17日付韓国特許出願第10−2018−0056729号に基づいた優先権の利益を主張し、当該韓国特許出願の文献に開示された全ての内容は本明細書の一部として含まれる。
δ=17.17+0.0272(スチレン重量%)−0.0069(ビニル重量%)
本発明は、耐磨耗性に優れつつも引張特性及び粘弾性特性が改善されたゴム組成物を提供する。
本発明の一実施形態において、前記第1合成ゴムは、結合スチレン含量が30重量%以上の溶液重合共役ジエン系ゴムのものであってよい。
R1からR3は、互いに独立して水素と、炭素数1から30のアルキル基と、炭素数2から30のアルケニル基と、炭素数2から30のアルキニル基と、炭素数1から30のヘテロアルキル基と、炭素数2から30のヘテロアルケニル基と、炭素数2から30のヘテロアルキニル基と、炭素数5から30のシクロアルキル基と、炭素数6から30のアリール基と、又は炭素数3から30のヘテロ環基であり、R4は、単一結合と、置換基で置換又は非置換された炭素数1から20のアルキレン基と、置換基で置換又は非置換された炭素数5から20のシクロアルキレン基と、又は置換基で置換又は非置換された炭素数6から20のアリレン基であり、ここで、前記置換基は、炭素数1から10のアルキル基、炭素数5から10のシクロアルキル基、又は炭素数6から20のアリール基であり、R5は、炭素数1から30のアルキル基と、炭素数2から30のアルケニル基と、炭素数2から30のアルキニル基と、炭素数1から30のヘテロアルキル基と、炭素数2から30のヘテロアルケニル基と、炭素数2から30のヘテロアルキニル基と、炭素数5から30のシクロアルキル基と、炭素数6から30のアリール基と、炭素数3から30のヘテロ環基と、又は下記化学式1a又は化学式1bで表される官能基であり、nは1から5の整数であり、R5のうち少なくとも一つは、下記化学式1a又は化学式1bで表される官能基であり、nが2から5の整数の場合、複数のR5は互いに同一か異なっていてよく、
R10は、置換基で置換又は非置換された炭素数1から20のアルキレン基と、置換基で置換又は非置換された炭素数5から20のシクロアルキレン基と、又は置換基で置換又は非置換された炭素数6から20のアリレン基であり、ここで、前記置換基は、炭素数1から10のアルキル基、炭素数5から10のシクロアルキル基、又は炭素数5から20のアリール基であり、
R11及びR12は、互いに独立して炭素数1から30のアルキル基と、炭素数2から30のアルケニル基と、炭素数2から30のアルキニル基と、炭素数1から30のヘテロアルキル基と、炭素数2から30のヘテロアルケニル基と、炭素数2から30のヘテロアルキニル基と、炭素数5から30のシクロアルキル基と、炭素数6から30のアリール基と、炭素数3から30のヘテロ環基である。
本発明の一実施形態において、前記第2合成ゴムは、前述した通り少なくとも一末端に官能基が結合されているリチウム触媒化変性ブタジエン系ゴムであってよい。
本発明の一実施形態において、前記充填剤は、ゴム成分と混合されゴム組成物の物性を改善させる役割をするものであり、具体的にはシリカであってよい。
これによって前記ゴム組成物は、タイヤトレッド、アンダートレッド、サイドウォール、カカスコーティングゴム、ベルトコーティングゴム、ビードフィラー、チェーファー、又はビードコーティングゴム等のタイヤの各部材や防塵ゴム、ベルトコンベヤー、ホース等の各種工業用ゴム製品の製造に有用である。
溶液重合した両末端変性スチレン−ブタジエンゴム(スチレン含量39重量%、ビニル含量25重量%、エクステンダー油含量5重量%)(MF3925、LG化学)63重量部(ゴム成分60重量部、オイル3重量部)、一末端変性リチウム触媒化ブタジエンゴム(ビニル含量10重量%、エクステンダー油含量5重量%)(LG F0010、LG化学)42重量部(ゴム成分40重量部、オイル2重量部)、シリカ70重量部、カップリング剤5.6重量部、プロセス油25.0重量部、酸化亜鉛3重量部、ステアリン酸1重量部を配合して1次配合物を製造し、ここに硫黄粉末1.5重量部、加硫促進剤2.8重量部を配合してゴム組成物を製造した。このとき、溶液重合した両末端変性スチレン−ブタジエンゴムと一末端変性リチウム触媒化ブタジエンゴムの溶解度パラメーターの差(△)は、0.96であった(溶液重合した両末端スチレン−ブタジエンゴムの溶解度パラメーター=18.06、一末端変性リチウム触媒化ブタジエンゴムの溶解度パラメーター=17.10)。
溶液重合した両末端変性スチレン−ブタジエンゴム(スチレン含量43重量%、ビニル含量25重量%、エクステンダー油含量5重量%)(MF4325、LG化学)63重量部(ゴム成分60重量部、オイル3重量部)、一末端変性リチウム触媒化ブタジエンゴム(ビニル含量10重量%、エクステンダー油含量5重量%)(LG F0010、LG化学)42重量部(ゴム成分40重量部、オイル2重量部)、シリカ70重量部、カップリング剤5.6重量部、プロセス油25.0重量部、酸化亜鉛3重量部、ステアリン酸1重量部を配合して1次配合物を製造し、ここに硫黄粉末1.5重量部、加硫促進剤2.8重量部を配合してゴム組成物を製造した。このとき、溶液重合した両末端変性スチレン−ブタジエンゴムと一末端変性リチウム触媒化ブタジエンゴムの溶解度パラメーターの差(△)は、1.07であった(溶液重合した両末端スチレン−ブタジエンゴムの溶解度パラメーター=18.17、一末端変性リチウム触媒化ブタジエンゴムの溶解度パラメーター=17.10)。
溶液重合した両末端変性スチレン−ブタジエンゴム(スチレン含量39重量%、ビニル含量25重量%、エクステンダー油含量5重量%)(MF3925、LG化学)78.8重量部(ゴム成分75重量部、オイル3.8重量部)、一末端変性リチウム触媒化ブタジエンゴム(ビニル含量10重量%、エクステンダー油含量5重量%)(LG F0010、LG化学)26.3重量部(ゴム成分25重量部、オイル1.3重量部)、シリカ90重量部、カップリング剤7.2重量部、プロセス油34.9重量部、酸化亜鉛3重量部、ステアリン酸1重量部を配合して1次配合物を製造し、ここに硫黄粉末1.5重量部、加硫促進剤2.8重量部を配合してゴム組成物を製造した。このとき、溶液重合した両末端変性スチレン−ブタジエンゴムと一末端変性リチウム触媒化ブタジエンゴムの溶解度パラメーターの差(△)は、0.96であった(溶液重合した両末端スチレン−ブタジエンゴムの溶解度パラメーター=18.06、一末端変性リチウム触媒化ブタジエンゴムの溶解度パラメーター=17.10)。
溶液重合した単末端スチレン−ブタジエンゴム(スチレン含量21重量%、ビニル含量50重量%、エクステンダー油含量5重量%)(F2150、LG化学)63重量部(ゴム成分60重量部、オイル3重量部)、未変性希土類触媒化ブタジエンゴム(CB24、Lanxess)40重量部、シリカ70重量部、カップリング剤5.6重量部、プロセス油27.0重量部、酸化亜鉛3重量部、ステアリン酸1重量部を配合して1次配合物を製造し、ここに硫黄粉末1.5重量部、加硫促進剤2.8重量部を配合してゴム組成物を製造した。このとき、溶液重合した単末端スチレン−ブタジエンゴムと希土類触媒化ブタジエンゴムの溶解度パラメーターの差(△)は、0.23であった(溶液重合した単末端変性スチレン−ブタジエンゴムの溶解度パラメーター=17.40、希土類触媒化ブタジエンゴムの溶解度パラメーター=17.17)。
溶液重合した両末端変性スチレン−ブタジエンゴム(スチレン含量39重量%、ビニル含量25重量%、エクステンダー油含量5重量%)(MF3925、LG化学)63重量部(ゴム成分60重量部、オイル3重量部)、未変性希土類触媒化ブタジエンゴム(CB24、Lanxess)40重量部、シリカ70重量部、カップリング剤5.6重量部、プロセス油27.0重量部、酸化亜鉛3重量部、ステアリン酸1重量部を配合して1次配合物を製造し、ここに硫黄粉末1.5重量部、加硫促進剤2.8重量部を配合してゴム組成物を製造した。このとき、溶液重合した両末端スチレン−ブタジエンゴムと希土類触媒化ブタジエンゴムの溶解度パラメーターの差(△)は、0.89であった(溶液重合した両末端スチレン−ブタジエンゴムの溶解度パラメーター=18.06、未変性希土類触媒化ブタジエンゴムの溶解度パラメーター=17.17)。
溶液重合した単末端スチレン−ブタジエンゴム(スチレン含量21重量%、ビニル含量50重量%、エクステンダー油含量5重量%)(F2150、LG化学)63重量部(ゴム成分60重量部、オイル3重量部)、単末端変性リチウム触媒化ブタジエンゴム(ビニル含量10重量%、エクステンダー油含量5重量%)(LG F0010、LG化学)42重量部(ゴム成分40重量部、オイル2重量部)、シリカ70重量部、カップリング剤5.6重量部、プロセス油25.0重量部、酸化亜鉛3重量部、ステアリン酸1重量部を配合して1次配合物を製造し、ここに硫黄粉末1.5重量部、加硫促進剤2.8重量部を配合してゴム組成物を製造した。このとき、溶液重合した両末端スチレン−ブタジエンゴムと希土類触媒化ブタジエンゴムの溶解度パラメーターの差(△)は、0.30であった(溶液重合した単末端スチレン−ブタジエンゴムの溶解度パラメーター=17.40、単末端リチウム触媒化ブタジエンゴムの溶解度パラメーター=17.10)。
溶液重合した両末端変性スチレン−ブタジエンゴム(スチレン含量39重量%、ビニル含量25重量%、エクステンダー油含量5重量%)(MF3925、LG化学)78.8重量部(ゴム成分75重量部、オイル3.8重量部)、未変性希土類触媒化ブタジエンゴム(CB24、Lanxess)25重量部、シリカ90重量部、カップリング剤7.2重量部、プロセス油36.2重量部、酸化亜鉛3重量部、ステアリン酸1重量部を配合して1次配合物を製造し、ここに硫黄粉末1.5重量部、加硫促進剤2.8重量部を配合してゴム組成物を製造した。このとき、溶液重合した両末端スチレン−ブタジエンゴムと希土類触媒化ブタジエンゴムの溶解度パラメーターの差(△)は、0.89であった(溶液重合した両末端スチレン−ブタジエンゴムの溶解度パラメーター=18.06、未変性希土類触媒化ブタジエンゴムの溶解度パラメーター=17.17)。
前記実施例及び比較例で製造された各ゴム組成物及びこれから製造された成型品の物性を比較分析するために、引張特性、耐磨耗性及び粘弾性特性をそれぞれ測定し、その結果を下記表1及び表2に示した。また、前記実施例及び比較例の各ゴム組成物の製造に用いられたゴム成分及びその他成分と各含量も、表1及び表2に共に示した。
引張特性は、ASTM 412の引張試験法に準じて各試験片を製造し、前記試験片の切断時の引張強度及び300%伸張時の引張応力(300%モデュラス)を測定した。具体的に、引張特性はUniversal Test Machin 4204(Instron社)引張試験機器を利用し、室温で50cm/minの速度で測定した。
前記引張特性と同じ方法で製造されたゴム試料の耐磨耗性を、DIN摩耗試験機器を利用して磨耗紙が付けられた回転ドラム(Drum)に10Nの荷重を付加し、ゴム試料をドラムの回転方向の直角方向に移動させた後、摩耗された損失重量を測定しており、比較例2の損失重量を基準に指数化して示した。ドラムの回転速度は40rpmであり、試験完了時の試料の全体移動距離は40mである。損失重量の指数値が大きいほど耐磨耗性に優れたものを示す。
粘弾性特性は、動的機械分析機(TA社、ARES G2)を利用してねじりモードで周波数10Hz、各測定温度(−100℃〜80℃)で変形を変化させG’’(dynamic loss modulus、E’’)とtanδを測定した。0℃の低温におけるtanδの指数値が高いものであるほど濡れた路面への抵抗性(制動性能)に優れ、60℃の高温におけるtanδの指数値が高いほどヒステリシス損失が少なく、低走行抵抗性(燃費性能)に優れることを示す。
TEMイメージは、Titan G2 80−200 Field Emission Transmission Electron Microscope装備(TEI社)を利用して各ゴム組成物をミクロトームにより薄片に製作し、20K〜200Kの倍率で測定しており、結果は図2に示した。
Claims (11)
- 第1合成ゴムと、
第2合成ゴムと、
充填剤とを含み、
前記第1合成ゴムと第2合成ゴムは、溶解度パラメーターの差が0.6より大きく、
前記第1合成ゴムは、結合スチレン含量が30重量%以上の溶液重合共役ジエン系ゴムであり、
前記第2合成ゴムは、少なくとも一末端に官能基が結合されているリチウム触媒化変性ブタジエン系ゴムである、ゴム組成物。 - 前記第1合成ゴムと第2合成ゴムは、溶解度パラメーターの差が0.8より大きく、1.1以下である、請求項1に記載のゴム組成物。
- 前記第1合成ゴムは、スチレン結合含量が38重量%以上55重量%以下の溶液重合共役ジエン系ゴムである、請求項1に記載のゴム組成物。
- 前記第1合成ゴムは、共役ジエン系単量体由来の繰り返し単位及び芳香族ビニル系単量体由来の繰り返し単位を含む溶液重合共役ジエン系ゴムである、請求項1に記載のゴム組成物。
- 前記第1合成ゴムは、少なくとも一末端に官能基が結合されている変性共役ジエン系ゴムである、請求項1に記載のゴム組成物。
- 前記第2合成ゴムは、重合体内のビニル結合の含量が50重量%以下である、請求項1に記載のゴム組成物。
- 前記ゴム組成物は、前記第1合成ゴム及び前記第2合成ゴムを含むゴム成分100重量部に対して、前記第1合成ゴムを30重量部から90重量部と、前記第2合成ゴムを10重量部から70重量部と、前記充填剤を30重量部から200重量部とを含む、請求項1に記載のゴム組成物。
- 前記充填剤は、シリカ又はカーボンブラックである、請求項1に記載のゴム組成物。
- 前記ゴム組成物は、加硫剤を含む、請求項1に記載のゴム組成物。
- 前記ゴム組成物は、加硫促進剤、プロセス油及び老化防止剤の中から選択される一つ以上の添加剤を含む、請求項1に記載のゴム組成物。
- 請求項1に記載のゴム組成物を用いて製造されたタイヤ。
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2022249767A1 (ja) * | 2021-05-28 | 2022-12-01 | 株式会社ブリヂストン | タイヤ用ゴム組成物、トレッドゴム及びタイヤ |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013256585A (ja) * | 2012-06-12 | 2013-12-26 | Sumitomo Rubber Ind Ltd | トレッド用ゴム組成物及び空気入りタイヤ |
JP2016065175A (ja) * | 2014-09-25 | 2016-04-28 | 住友ゴム工業株式会社 | タイヤ |
JP2017171707A (ja) * | 2016-03-18 | 2017-09-28 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物およびタイヤ |
WO2019163773A1 (ja) * | 2018-02-21 | 2019-08-29 | 日本ゼオン株式会社 | ゴム架橋物 |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6296545A (ja) * | 1985-10-23 | 1987-05-06 | Yokohama Rubber Co Ltd:The | タイヤトレツド用ゴム組成物 |
JPH0627219B2 (ja) * | 1986-09-08 | 1994-04-13 | 日本合成ゴム株式会社 | ポリブタジエンゴム組成物 |
US5910544A (en) | 1995-11-02 | 1999-06-08 | The Yokohama Rubber Co., Ltd. | Thermoplastic elastomer composition and process for production thereof and low permeability hose using the same |
EP0857761B1 (en) | 1996-05-29 | 2007-01-03 | The Yokohama Rubber Co., Ltd. | Process for making a pneumatic tire having an almost impermeable thermoplastic elastomer composition in gas-barrier layer |
KR100285229B1 (ko) | 1999-03-03 | 2001-03-15 | 조충환 | 용액 중합 스티렌-부타디엔 고무 및 부타디엔 고무의 제조방법 |
FR2854635B1 (fr) * | 2003-05-07 | 2006-07-14 | Michelin Soc Tech | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique, et ces copolymeres |
JP4698135B2 (ja) * | 2003-09-05 | 2011-06-08 | 旭化成ケミカルズ株式会社 | オレフィン系樹脂組成物 |
CN101784595A (zh) * | 2007-08-14 | 2010-07-21 | 帝斯曼知识产权资产管理有限公司 | 橡胶反硫化 |
WO2010104149A1 (ja) * | 2009-03-11 | 2010-09-16 | Jsr株式会社 | ゴム組成物及び空気入りタイヤ |
KR101132791B1 (ko) * | 2009-12-21 | 2012-04-02 | 한국타이어 주식회사 | 타이어 트레드용 고무 조성물 및 이를 이용하여 제조한 타이어 |
KR101132780B1 (ko) * | 2009-12-22 | 2012-04-09 | 한국타이어 주식회사 | 타이어 트레드용 고무 조성물 및 이를 이용하여 제조한 타이어 |
JP5845883B2 (ja) | 2010-12-28 | 2016-01-20 | 日本ゼオン株式会社 | 変性共役ジエン系ゴム組成物の製造方法、ゴム組成物の製造方法、ゴム架橋物の製造方法及びタイヤの製造方法 |
JP5776356B2 (ja) | 2011-06-16 | 2015-09-09 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物 |
US20130245198A1 (en) * | 2012-03-14 | 2013-09-19 | Ralf Mruk | Pneumatic tire |
MY169946A (en) | 2012-07-30 | 2019-06-19 | Ube Industries | Method of producing modified cis-1, 4-polybutadiene |
US20140135437A1 (en) * | 2012-11-15 | 2014-05-15 | The Goodyear Tire & Rubber Company | Tire with rubber tread containing combination of resin and vegetable oil, particularly soybean oil |
EP2960288B1 (en) | 2013-02-25 | 2019-10-30 | The Yokohama Rubber Co., Ltd. | Rubber composition for tire tread, and pneumatic tire |
JP6096535B2 (ja) | 2013-02-28 | 2017-03-15 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 透明かつ強靭なゴム組成物およびその製造方法 |
DE102013110719A1 (de) | 2013-09-27 | 2015-04-02 | Continental Reifen Deutschland Gmbh | Schwefelvernetzbare Kautschukmischung und Fahrzeugluftreifen |
CN104086822A (zh) * | 2014-07-02 | 2014-10-08 | 安徽宁国尚鼎橡塑制品有限公司 | 一种汽车用高性能橡胶材料及其制备方法 |
JP2016030799A (ja) * | 2014-07-29 | 2016-03-07 | 株式会社クラレ | 加硫ゴム、加硫ゴムの製造方法及びタイヤ |
EP3029102A1 (en) * | 2014-12-05 | 2016-06-08 | Lanxess Elastomers B.V. | Vulcanizable rubber composition |
JP2017048336A (ja) * | 2015-09-03 | 2017-03-09 | 株式会社クラレ | ゴム組成物及びタイヤ |
JP6578162B2 (ja) * | 2015-09-03 | 2019-09-18 | 株式会社クラレ | ゴム組成物及びタイヤ |
KR102019841B1 (ko) * | 2015-12-22 | 2019-09-10 | 주식회사 엘지화학 | 변성 공액 디엔계 중합체의 제조방법 및 이에 의해 제조된 변성 공액 디엔계 중합체 |
KR101923160B1 (ko) * | 2015-12-24 | 2018-11-29 | 주식회사 엘지화학 | 변성 공액디엔계 중합체, 이의 제조방법 및 변성제 |
JP2017214493A (ja) * | 2016-05-31 | 2017-12-07 | 株式会社クラレ | ゴム組成物及びタイヤ |
EP3677634B1 (en) * | 2017-09-01 | 2022-03-23 | Kuraray Co., Ltd. | Rubber composition for high grip tire |
-
2018
- 2018-05-17 KR KR1020180056729A patent/KR102251267B1/ko active IP Right Grant
-
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- 2019-04-10 US US16/628,472 patent/US11597828B2/en active Active
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- 2019-04-10 EP EP19803179.1A patent/EP3632976A4/en active Pending
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013256585A (ja) * | 2012-06-12 | 2013-12-26 | Sumitomo Rubber Ind Ltd | トレッド用ゴム組成物及び空気入りタイヤ |
JP2016065175A (ja) * | 2014-09-25 | 2016-04-28 | 住友ゴム工業株式会社 | タイヤ |
JP2017171707A (ja) * | 2016-03-18 | 2017-09-28 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物およびタイヤ |
WO2019163773A1 (ja) * | 2018-02-21 | 2019-08-29 | 日本ゼオン株式会社 | ゴム架橋物 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022249767A1 (ja) * | 2021-05-28 | 2022-12-01 | 株式会社ブリヂストン | タイヤ用ゴム組成物、トレッドゴム及びタイヤ |
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