JP2020506992A - マイクロカプセルを有する洗濯洗剤シート - Google Patents
マイクロカプセルを有する洗濯洗剤シート Download PDFInfo
- Publication number
- JP2020506992A JP2020506992A JP2019542171A JP2019542171A JP2020506992A JP 2020506992 A JP2020506992 A JP 2020506992A JP 2019542171 A JP2019542171 A JP 2019542171A JP 2019542171 A JP2019542171 A JP 2019542171A JP 2020506992 A JP2020506992 A JP 2020506992A
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- Prior art keywords
- laundry detergent
- detergent sheet
- weight
- microcapsules
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003205 fragrance Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 24
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- 239000003945 anionic surfactant Substances 0.000 claims description 19
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- 239000002243 precursor Substances 0.000 claims description 16
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
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Abstract
Description
(a)少なくとも1種の界面活性剤と、(b)少なくとも1種の成膜剤と、(c)脆砕性マイクロカプセルと、を含む非繊維性洗濯洗剤シートであって、非繊維性洗濯洗剤シートは0.1mm〜2mmの範囲の厚さと、少なくとも5:1の長さ対厚さのアスペクト比と、少なくとも5:1の幅対厚さのアスペクト比と、を有する、非繊維性洗濯洗剤シートを提供する。
本発明の一態様は、脆砕性PMCを含む非繊維性洗濯洗剤シートを提供する。「脆砕性」とは、直接的な外部圧力又は剪断力を受けた際に、マイクロカプセルが破裂、又は破断して開く性質を指す。本発明の目的のために、使用されるマイクロカプセルは、処理される布地に付着している間に、そのカプセルを含有する布地が操作されるときに磨耗すること又は取り扱われることで受ける力によって破裂し得る(それによってカプセルの内容物を放出する)場合、「脆砕性」である。脆砕性香料マイクロカプセルは、大部分がシシクロデキストリンから構成されるマイクロカプセルなどの水分活性化マイクロカプセルとは区別される。
a)第1の乳化剤及び第1の樹脂の総溶液重量に基づいて20%〜90%、40%〜80%、又は更には60%〜80%の水を含み得る、第1の溶液を調製する工程であって、上記の第1の乳化剤と上記の第1の樹脂との比が、0.1:0〜10:0、約0.1:1〜10:1、0.5:1〜3:1、又は更には0.8:1〜1.1:1である、工程と、
b)第2の乳化剤及び第2の樹脂の総溶液重量に基づいて約20重量%〜約95重量%の水を含み得る、第2の溶液を調製する工程であって、上記の第2の乳化剤と上記の第2の樹脂との比が、0:1〜約3:1、0.04:1〜0.2:1、又は更には0.05:1〜0.15:1である、工程と、
c)本明細書に開示される香料を含み得るコア材料と、上記の第1の溶液とを組み合わせて、第1の組成物を形成する工程と、
d)上記の第1組成物を乳化させる工程と、
e)上記の第1の組成物と上記の第2の溶液とを組み合わせて、第2の組成物を形成し、所望により任意の加工助剤と上記の第2の組成物とを組み合わせる工程であって、上記の第1の組成物と上記の第2の溶液とを任意の順序で組み合わせることができるが、一態様では、上記の第2の溶液を上記の第1の組成物に添加するか、又は上記の第2の溶液と上記の第1の組成物とを同時に組み合わせる、工程と、
f)上記の第2の組成物を、少なくとも15分間、少なくとも1時間、又は更には4時間〜100時間にわたって、25℃〜100℃、45℃〜90℃、又は更には50℃〜80℃の熱の温度で混合し、所望により任意の加工助剤を上記の第2の組成物に組み合わせる工程と、
g)工程f)中又はそれ以降で、所望により任意のスカベンジャー材料、構造化剤、及び/又は抗凝集剤を、上記の第2の組成物と組み合わせる工程であって、かかる材料は任意の順序で組み合わされてもよいが、一態様では、スカベンジャー材料を最初に、任意の構造化剤を2番目に組み合わせ、続いて抗凝集剤を組み合わせる、工程と、
h)所望により、上記の第2の組成物を噴霧乾燥する工程。
本発明の一態様は、マイクロカプセルスラリーを含み、好ましくは、マイクロカプセルは脆砕性マイクロカプセルであり、更により好ましくはマイクロカプセルスラリータンク内に含有される脆砕性香料マイクロカプセルである。
非繊維性洗濯洗剤シートを作製する工程について説明する。
本発明の非繊維性洗濯洗剤シートは、アニオン性界面活性剤、ノニオン性界面活性剤、両性界面活性剤、カチオン性界面活性剤、及びこれらの組み合わせからなる群から選択される少なくとも1種の界面活性剤を含んでよい。かかる少なくとも1種の界面活性剤は、非繊維性洗濯洗剤シート中に、非繊維性洗濯洗剤シートの総重量に対して約5重量%〜約90重量%、好ましくは約10重量%〜約90重量%、より好ましくは約20重量%〜約90重量%、更により好ましくは約30重量%〜約90重量%、最も好ましくは約50重量%〜約90重量%の範囲の量で存在し得る界面活性剤系を形成する。
本発明の洗濯洗剤シートを形成するのに好適なアニオン性界面活性剤は、C6〜C20の直鎖状又は分枝鎖状アルキルベンゼンスルホネート(LAS)、C6〜C20の直鎖状又は分枝鎖状アルキルサルフェート(AS)、C6〜C20の直鎖状又は分枝鎖状アルキルアルコキシル化サルフェート(AAS)、C6〜C20の直鎖状又は分枝鎖状アルキルスルホネート、C6〜C20の直鎖状又は分枝鎖状アルキルカルボキシレート、C6〜C20の直鎖状又は分枝鎖状アルキルホスフェート、C6〜C20の直鎖状又は分枝鎖状アルキルホスホネート、及びこれらの組み合わせからなる群から容易に選択され得る。本発明の好ましいアニオン性界面活性剤は、LAS、AS、AAS、及びこれらの組み合わせからなる群から選択される。洗濯洗剤シート中のアニオン性界面活性剤の総量は、非繊維性洗濯洗剤シートの総重量に対して5重量%〜90重量%、好ましくは10重量%〜80重量%、より好ましくは20重量%〜75重量%、最も好ましくは30重量%〜70重量%の範囲であり得る。
本発明の非繊維性洗濯洗剤シートを形成するために特に好ましい種類のアニオン性界面活性剤は、C6〜C18のアルキルサルフェートであり、これは以下では「ミッドカットAS」と称され、その各々は、約6個〜約18個の炭素原子を含有する分枝鎖状又は直鎖状の非アルコキシル化アルキル基を有する。本発明の特に好ましい実施形態では、ミッドカットASは、洗濯洗剤シート中の主界面活性剤として存在し、すなわち、これは上記のシート中の全界面活性剤の総重量に対して50重量%超の量で存在し、一方で、他のアニオン性界面活性剤(LAS及び/又はAASなど)は、かかるミッドカットASのための共界面活性剤として存在する。
本発明の非繊維性洗濯洗剤シートは、主界面活性剤として単独で、又は好ましくは本明細書の上記に記載したその共界面活性剤としてのミッドカットASとの組み合わせでのいずれかで、C6〜C20の直鎖状アルキルベンゼンスルホネート(LAS)を含有することができる。本発明の特に好ましい実施形態では、LASは、洗濯洗剤シート中の主界面活性剤として存在し、すなわち、これは上記のシート中の全界面活性剤の総重量に対して50重量%超の量で存在し、一方で、他のアニオン性界面活性剤(ミッドカットAS及び/又はAASなど)は、かかるLASのための共界面活性剤として存在する。
本発明の非繊維性洗濯洗剤シートは、主界面活性剤として単独で、又は好ましくは本明細書の上記に記載した共界面活性剤としてのミッドカットAS及び/又はLASとの組み合わせでのいずれかで、約0.1〜約5の範囲の平均アルコキシル化度を有するC10〜C20の直鎖状又は分枝鎖状アルキルアルコキシサルフェートト(AAS)を含有することができる。
R−O−(C2H4O)X−SO3 −M+ (I)
[式中、Rは、飽和又は不飽和のいずれかで、10個〜20個の炭素原子を有する直鎖状又は分枝鎖状アルキル鎖であり、xの平均は1〜3であり、Mは、アルカリ金属イオン、アンモニウム、又は置換アンモニウムからなる群から選択される。]を有する、C10〜C20の直鎖状又は分枝鎖状アルキルエトキシサルフェート(AES)である。好ましくは、Rは、12個〜16個の炭素原子を有する、直鎖状又は分枝鎖状アルキル鎖であり、xの平均は3であり、Mはナトリウムである。本発明の実施に最も好ましいアニオン性界面活性剤は、約3の平均エトキシル化度を有するラウリル硫酸エーテルナトリウムである。
本発明の非繊維性洗濯洗剤シートは、本明細書で上述したアニオン性界面活性剤と組み合わせて使用される、1種以上のノニオン性界面活性剤を含有してよい。かかるノニオン性界面活性剤は、かかる非繊維性洗濯洗剤シートに対して総重量の1重量%〜40重量%、好ましくは2重量%〜30重量%、より好ましくは5重量%〜25重量%、最も好ましくは10重量%〜20重量%の範囲の量で存在し得る。
本発明の非繊維性洗濯洗剤シートは、所望により、洗浄性能を補助若しくは向上させるために、又はシートの美観を改良するための、1種以上のその他の補助洗剤成分を含んでよい。かかる補助洗剤成分の例示的な例としては、(1)炭酸塩(重炭酸塩及びセスキ炭酸塩を含む)、硫酸塩、リン酸塩(トリポリリン酸塩、ピロリン酸塩、及びガラス質ポリマーメタリン酸塩によって例示される)、ホスホン酸塩、フィチン酸、ケイ酸塩、ゼオライト、クエン酸塩、ポリカルボン酸塩及びその塩(例えば、メリト酸、コハク酸、オキシジコハク酸、ポリマレイン酸、ベンゼン1,3,5−トリカルボン酸、カルボキシメチルオキシコハク酸、及びこれらの可溶性塩)、エーテルヒドロキシポリカルボン酸塩、無水マレイン酸とエチレン若しくはビニルメチルエーテルとのコポリマー、1,3,5−トリヒドロキシベンゼン−2,4,6−トリスルホン酸、3,3−ジカルボキシ−4−オキサ−1,6−ヘキサンジオエート、ポリ酢酸(例えば、エチレンジアミン四酢酸及びニトリロ三酢酸)及びその塩、脂肪酸(例えば、C12〜C18モノカルボン酸)などの無機並びに/又は有機ビルダー;(2)アミノカルボン酸塩、アミノホスホン酸塩、多官能的に置換された芳香族キレート剤、及びこれらの混合物からなる群から選択される、鉄及び/又はマンガンキレート剤などのキレート剤;(3)水溶性エトキシル化アミン(特に、エトキシル化テトラエチレンペンタミン)などの粘土汚れ除去/再付着防止剤;(4)ポリマーポリカルボキシレート及びポリエチレングリコール、アクリル/マレイン酸系コポリマー、及びこれらのの水溶性塩、ヒドロキシプロピルアクリレート、マレイン酸/アクリル/ビニルアルコールターポリマー、ポリエチレングリコール(PEG)、ポリアスパルテート及びポリグルタメートなどの、ポリマー分散剤;(5)スチルベン、ピラゾリン、クマリン、カルボン酸、メチンシアニン、ジベンゾチフェン−5,5−ジオキシド、アゾール、5員及び6員環複素環などの誘導体が挙げられるがこれらに限定されない、光学増白剤;(6)モノカルボン脂肪酸及びその可溶性塩、高分子量炭化水素(例えば、パラフィン、ハロパラフィン、脂肪酸エステル、一価アルコールの脂肪酸エステル、脂肪族C18〜C40ケトンなど)、N−アルキル化アミノトリアジン、プロピレンオキシド、モノステアリルホスフェート、シリコーン又はその誘導体、二級アルコール(例えば、2−アルキルアルカノール)、並びにかかるアルコールとシリコーン油との混合物などの抑泡剤;(7)C10〜C16アルカノールアミド、C10〜C14モノエタノール及びジエタノールアミド、高起泡性界面活性剤(例えば、アミンオキシド、ベタイン、及びスルタイン)、並びに可溶性マグネシウム塩(例えば、MgCl2、MgSO4など)などの発泡促進剤;(8)スメクタイト粘土、アミン柔軟剤、及びカチオン性柔軟剤などの布地柔軟剤;(9)ポリビニルピロリドンポリマー、ポリアミンN−オキシドポリマー、N−ビニルピロリドン及びN−ビニルイミダゾールのコポリマー、マンガンフタロシアニン、ペルオキシダーゼ、並びにこれらの混合物などの移染防止剤;(10)プロテアーゼ、アミラーゼ、リパーゼ、セルラーゼ、及びペルオキシダーゼ、並びにこれらの混合物などの酵素;(11)カルシウム及び/又はマグネシウムイオンの水溶性供給源、ホウ酸又はホウ酸塩(酸化ホウ素、ホウ砂、及び他のアルカリ金属ホウ酸塩など)を含む酵素安定剤;(12)過炭酸塩(例えば、炭酸ナトリウム過酸化水素化物、ピロリン酸ナトリウム過酸化水素化物、尿素過酸化水素化物、及び過酸化ナトリウム)、過硫酸塩、過ホウ酸塩、マグネシウムモノペルオキシフタレート六水和物、メタクロロ過安息香酸のマグネシウム塩、4−ノニルアミノ−4−オキソペルオキシ酪酸及びジペルオキシドデカン二酸、6−ノニルアミノ−6−オキソペルオキシカプロン酸、及び光活性化漂白剤(例えば、スルホネート化亜鉛及び/又はアルミニウムフタロシアニン)などの漂白剤;(13)ノナノイルオキシベンゼンスルホネート(nonanoyloxybenzene sulfonate、NOBS)、テトラアセチルエチレンジアミン(tetraacetyl ethylene diamine、TAED)、(6−オクタンアミドカプロイル)オキシベンゼンスルホネート、(6−ノナンアミドカプロイル)オキシベンゼンスルホネート、(6−デカンアミドカプロイル)オキシベンゼンスルホネート、及びこれらの混合物を含むアミド由来の漂白活性化剤、ベンゾオキサジン型活性化剤、アシルラクタム活性化剤(特にアシルカプロラクタム及びアシルバレロラクタム)などの漂白活性化剤;並びに(14)キャリア、ヒドロトロープ、加工助剤、染料又は顔料、及び固体充填剤が挙げられるがこれらに限定されない、任意のその他の公知の洗剤補助成分、が挙げられる。
本発明の非繊維性洗濯洗剤シートは、上述の界面活性剤及び上記の補助洗剤成分に加えて、少なくとも1種の成膜剤を含有する。かかる少なくとも1種の成膜剤は、合成又は天然のいずれかの起源の水溶性ポリマーから選択することができ、化学的及び/又は物理的に改質されてもよい。
Claims (15)
- (a)少なくとも1種の界面活性剤と、
(b)少なくとも1種の成膜剤と、
(c)脆砕性マイクロカプセルと、
を含む非繊維性洗濯洗剤シートであって、
前記洗濯洗剤シートは完全に又は実質的に水溶性であり、前記洗濯洗剤シートは0.1mm〜10mmの範囲の厚さと、少なくとも5:1の長さ対厚さのアスペクト比と、少なくとも5:1の幅対厚さのアスペクト比と、を有する、非繊維性洗濯洗剤シート。 - 前記脆砕性マイクロカプセルは脆砕性香料マイクロカプセルであり、好ましくは、前記香料マイクロカプセルのシェル壁は、ポリエチレン、ポリアミド、ポリスチレン、ポリイソプレン、ポリカーボネート、ポリエステル、ポリアクリレート、アミノプラスト、又はこれらの組み合わせからなる群から選択される材料を含み、より好ましくは、前記非繊維性洗濯洗剤シートは、前記非繊維性洗濯洗剤シートの0.1重量%〜10重量%、好ましくは0.5重量%〜7重量%、あるいは1重量%〜6重量%の前記脆砕性マイクロカプセルを含む、請求項1に記載の非繊維性洗濯洗剤シート。
- 前記脆砕性マイクロカプセルのシェルは水溶性カチオン性ポリマーによってコーティングされ、好ましくは、前記水溶性カチオン性ポリマーは、多糖類、カチオン変性デンプン及びカチオン変性グアー、ポリシロキサン、ポリハロゲン化ジメチルジアリルアンモニウム、ポリ塩化ジメチルジアリルアンモニウムとビニルピロリドンとのコポリマー、アクリルアミド、イミダゾール、ハロゲン化イミダゾリニウム及びハロゲン化イミダゾリウム、並びにポリビニルアミン及びそのN−ビニルホルムアミドとのコポリマーからなる群から選択される、請求項1又は2に記載の非繊維性洗濯洗剤シート。
- 前記少なくとも1種の界面活性剤は、かかる非繊維性洗濯洗剤シートの総重量に対して5重量%〜90重量%、好ましくは20重量%〜90重量%、より好ましくは30重量%〜90重量%、最も好ましくは50重量%〜90重量%の範囲の量で存在する、請求項1〜3のいずれか一項に記載の非繊維性洗濯洗剤シート。
- C6〜C20の直鎖状アルキルベンゼンスルホネート(LAS)、C6〜C20の直鎖状又は分枝鎖状アルキルサルフェート(AS)、0.1〜10の範囲の重量平均アルコキシル化度を有するC6〜C20の直鎖状又は分枝鎖状アルキルアルコキシサルフェート(AAS)、及びこれらの組み合わせからなる群から選択される1種以上のアニオン性界面活性剤を含む、請求項1〜4のいずれか一項に記載の非繊維性洗濯洗剤シート。
- (1)主界面活性剤として1種以上のC6〜C18の直鎖状又は分枝鎖状AS界面活性剤と、(2)共界面活性剤として1種以上のC6〜C20のLAS及び/又はC6〜C20の直鎖状若しくは分岐鎖状AASと、を含み、前記主界面活性剤は、前記シート中の全界面活性剤の総重量に対して50重量%超の量で存在し、前記1種以上のC6〜C18の直鎖状又は分枝鎖状AS界面活性剤は、好ましくはC12〜C14の直鎖状又は分枝鎖状AS界面活性剤である、請求項1〜5のいずれか一項に記載の非繊維性洗濯洗剤シート。
- (1)主界面活性剤として1種以上のC6〜C20のLAS界面活性剤と、(2)共界面活性剤として1種以上のC6〜C18の直鎖状若しくは分枝鎖状AS及び/又はC6〜C20の直鎖状若しくは分岐鎖状AASと、を含み、前記主界面活性剤は、前記シート中の全界面活性剤の総重量に対して50重量%超の量で存在する、請求項1〜5のいずれか一項に記載の非繊維性洗濯洗剤シート。
- かかる非繊維性洗濯洗剤シートの総重量の1重量%〜40重量%、好ましくは2重量%〜30重量%、より好ましくは5重量%〜25重量%、最も好ましくは10重量%〜20重量%の範囲の量で1種以上のノニオン性界面活性剤を更に含み、前記1種以上のノニオン性界面活性剤は、好ましくは、アルキルアルコキシル化アルコール及びその組み合わせからなる群から選択される、請求項5〜7のいずれか一項に記載の非繊維性洗濯洗剤シート。
- 前記少なくとも1種の成膜剤は、かかる非繊維性洗濯洗剤シートの総重量に対して1重量%〜70重量%、好ましくは2重量%〜60重量%、より好ましくは5重量%〜50重量%、最も好ましくは10重量%〜40重量%の範囲の量で存在し、前記少なくとも1種の成膜剤は1種以上の水溶性ポリマーを含み、好ましくは前記1種以上の水溶性ポリマーは、ポリアルキレングリコール、ポリビニルアルコール、デンプン又は変性デンプン、セルロース又は変性セルロース、ポリアクリレート、ポリメタクリレート、ポリアクリルアミド、ポリビニルピロリドン、及びこれらの組み合わせからなる群から選択され、より好ましくは前記1種以上の水溶性ポリマーは、ポリエチレングリコール、ポリビニルアルコール、デンプン又は変性デンプン、セルロース又は変性セルロース、及びこれらの組み合わせからなる群から選択される、請求項1〜8のいずれか一項に記載の非繊維性洗濯洗剤シート。
- 前駆体非繊維性洗濯洗剤シートにマイクロカプセルを分配する工程を含む、非繊維性洗濯洗剤シートの作製方法であって、前記前駆体非繊維性洗濯洗剤シートは、(a)少なくとも1種の界面活性剤と、(b)少なくとも1種の成膜剤と、(c)0.1mm〜10mmの範囲の厚さと、を含む、方法。
- 前記マイクロカプセルはマイクロカプセルスラリーとして分配され、好ましくは前記マイクロカプセルは脆砕性マイクロカプセルであり、より好ましくは前記脆砕性マイクロカプセルは脆砕性香料マイクロカプセルであり、更により好ましくは前記香料マイクロカプセルのシェル壁は、ポリエチレン、ポリアミド、ポリスチレン、ポリイソプレン、ポリカーボネート、ポリエステル、ポリアクリレート、アミノプラスト、又はこれらの組み合わせからなる群から選択される材料を含む、請求項10に記載の方法。
- 前記マイクロカプセルスラリーが、
(a)前記マイクロカプセルスラリーの75%重量%未満の水、好ましくは5重量%〜50重量%の水、あるいは20重量%〜75重量%の水と、
(b)構造化剤、好ましくは、塩、ポリマー、又はこれらの組み合わせから選択される構造化剤と、を含む、請求項11に記載の方法。 - 前記マイクロカプセルスラリーは、前記マイクロカプセルスラリーが分配される前駆体洗濯洗剤シートの温度の少なくとも約±30℃、好ましくは±20℃、好ましくは±10℃以内で加熱され、
好ましくは前記マイクロカプセルスラリーは、前記前駆体非繊維性洗濯洗剤シートの分配時に、50℃〜100℃、好ましくは55℃〜99℃、より好ましくは60℃〜98℃の温度である、請求項10〜12のいずれか一項に記載の方法。 - 前記マイクロカプセルは粉末又は乾燥形態で分配され、
好ましくは、前記粉末又は乾燥形態は、前記粉末又は乾燥形態の0重量%〜5重量%、好ましくは0重量%〜3重量%、より好ましくは1重量%〜1重量%の水を含有する、請求項10又は11に記載の方法。 - 前記マイクロカプセルを前記前駆体非繊維性洗濯洗剤シートに分配する工程の前に、前記前駆体非繊維性洗濯洗剤シートを刻印又はエンボス加工する工程を更に含む、請求項10〜14のいずれか一項に記載の方法。
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EP3577205A4 (en) | 2020-10-28 |
CN110225967A (zh) | 2019-09-10 |
US20180223225A1 (en) | 2018-08-09 |
US20230272312A1 (en) | 2023-08-31 |
US20210040420A1 (en) | 2021-02-11 |
MX2019009276A (es) | 2019-09-19 |
WO2018141096A1 (en) | 2018-08-09 |
KR20190100965A (ko) | 2019-08-29 |
RU2742886C1 (ru) | 2021-02-11 |
US11680232B2 (en) | 2023-06-20 |
CA3050343A1 (en) | 2018-08-09 |
BR112019015854A2 (pt) | 2020-04-07 |
EP3577205A1 (en) | 2019-12-11 |
JP6882496B2 (ja) | 2021-06-02 |
KR102360241B1 (ko) | 2022-02-10 |
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