JP2019131822A5 - - Google Patents
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- Publication number
- JP2019131822A5 JP2019131822A5 JP2019072070A JP2019072070A JP2019131822A5 JP 2019131822 A5 JP2019131822 A5 JP 2019131822A5 JP 2019072070 A JP2019072070 A JP 2019072070A JP 2019072070 A JP2019072070 A JP 2019072070A JP 2019131822 A5 JP2019131822 A5 JP 2019131822A5
- Authority
- JP
- Japan
- Prior art keywords
- blowing agent
- amine
- hydrohaloolefin
- weight
- containing catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000000034 method Methods 0.000 claims description 32
- 239000004604 Blowing Agent Substances 0.000 claims description 29
- 150000001412 amines Chemical class 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 19
- 239000006260 foam Substances 0.000 claims description 16
- 229920005862 polyol Polymers 0.000 claims description 9
- 150000003077 polyols Chemical class 0.000 claims description 9
- 239000002798 polar solvent Substances 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 claims description 6
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 claims description 5
- 238000000354 decomposition reaction Methods 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- 239000012948 isocyanate Substances 0.000 claims description 4
- 150000002513 isocyanates Chemical class 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- -1 fluorocarbons Chemical class 0.000 claims 5
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 claims 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 3
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 claims 2
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 claims 2
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 claims 2
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims 2
- 150000002170 ethers Chemical class 0.000 claims 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims 2
- 150000007524 organic acids Chemical class 0.000 claims 2
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 claims 2
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims 1
- GIWQSPITLQVMSG-UHFFFAOYSA-N 1,2-dimethylimidazole Chemical compound CC1=NC=CN1C GIWQSPITLQVMSG-UHFFFAOYSA-N 0.000 claims 1
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 claims 1
- MELCWEWUZODSIS-UHFFFAOYSA-N 2-[2-(diethylamino)ethoxy]-n,n-diethylethanamine Chemical compound CCN(CC)CCOCCN(CC)CC MELCWEWUZODSIS-UHFFFAOYSA-N 0.000 claims 1
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 claims 1
- ZWXQPERWRDHCMZ-UHFFFAOYSA-N 2-methyl-n-propan-2-ylpropan-2-amine Chemical compound CC(C)NC(C)(C)C ZWXQPERWRDHCMZ-UHFFFAOYSA-N 0.000 claims 1
- NGRYSBPZIYVTHZ-UHFFFAOYSA-N 3-[3-(dimethylamino)propoxy]-n,n-dimethylpropan-1-amine Chemical compound CN(C)CCCOCCCN(C)C NGRYSBPZIYVTHZ-UHFFFAOYSA-N 0.000 claims 1
- JLEIRAYWBMNMKU-UHFFFAOYSA-N 3-ethylpentan-3-amine Chemical compound CCC(N)(CC)CC JLEIRAYWBMNMKU-UHFFFAOYSA-N 0.000 claims 1
- ZMSQJSMSLXVTKN-UHFFFAOYSA-N 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine Chemical compound C1COCCN1CCOCCN1CCOCC1 ZMSQJSMSLXVTKN-UHFFFAOYSA-N 0.000 claims 1
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 claims 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims 1
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 claims 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 claims 1
- GSCCALZHGUWNJW-UHFFFAOYSA-N N-Cyclohexyl-N-methylcyclohexanamine Chemical compound C1CCCCC1N(C)C1CCCCC1 GSCCALZHGUWNJW-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 239000001273 butane Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims 1
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 claims 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000005187 foaming Methods 0.000 claims 1
- 150000008282 halocarbons Chemical class 0.000 claims 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 239000001282 iso-butane Substances 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- VMOWKUTXPNPTEN-UHFFFAOYSA-N n,n-dimethylpropan-2-amine Chemical compound CC(C)N(C)C VMOWKUTXPNPTEN-UHFFFAOYSA-N 0.000 claims 1
- ASKYIFBXGFWCBG-UHFFFAOYSA-N n-benzyl-n-methylcyclopentanamine Chemical compound C1CCCC1N(C)CC1=CC=CC=C1 ASKYIFBXGFWCBG-UHFFFAOYSA-N 0.000 claims 1
- WFMUJLWWGDJDBF-UHFFFAOYSA-N n-benzyl-n-methylpropan-2-amine Chemical compound CC(C)N(C)CC1=CC=CC=C1 WFMUJLWWGDJDBF-UHFFFAOYSA-N 0.000 claims 1
- OBYVIBDTOCAXSN-UHFFFAOYSA-N n-butan-2-ylbutan-2-amine Chemical compound CCC(C)NC(C)CC OBYVIBDTOCAXSN-UHFFFAOYSA-N 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- FUUUBHCENZGYJA-UHFFFAOYSA-N n-cyclopentylcyclopentanamine Chemical compound C1CCCC1NC1CCCC1 FUUUBHCENZGYJA-UHFFFAOYSA-N 0.000 claims 1
- BBPKSHICVYBPRR-UHFFFAOYSA-N n-propan-2-yl-n-(2,2,2-trifluoroethyl)butan-2-amine Chemical compound CCC(C)N(C(C)C)CC(F)(F)F BBPKSHICVYBPRR-UHFFFAOYSA-N 0.000 claims 1
- CATWEXRJGNBIJD-UHFFFAOYSA-N n-tert-butyl-2-methylpropan-2-amine Chemical compound CC(C)(C)NC(C)(C)C CATWEXRJGNBIJD-UHFFFAOYSA-N 0.000 claims 1
- MTEWAFVECQBILW-UHFFFAOYSA-N n-tert-butylcyclohexanamine Chemical compound CC(C)(C)NC1CCCCC1 MTEWAFVECQBILW-UHFFFAOYSA-N 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 238000004806 packaging method and process Methods 0.000 claims 1
- 230000035939 shock Effects 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 claims 1
- BZVJOYBTLHNRDW-UHFFFAOYSA-N triphenylmethanamine Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(N)C1=CC=CC=C1 BZVJOYBTLHNRDW-UHFFFAOYSA-N 0.000 claims 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 claims 1
- 238000010792 warming Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 15
- 238000006731 degradation reaction Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23283609P | 2009-08-11 | 2009-08-11 | |
| US61/232,836 | 2009-08-11 | ||
| US12/847,381 US9695267B2 (en) | 2009-08-11 | 2010-07-30 | Foams and foamable compositions containing halogenated olefin blowing agents |
| US12/847,381 | 2010-07-30 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016196404A Division JP2017039942A (ja) | 2009-08-11 | 2016-10-04 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2019131822A JP2019131822A (ja) | 2019-08-08 |
| JP2019131822A5 true JP2019131822A5 (https=) | 2020-01-16 |
Family
ID=43586743
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012524735A Expired - Fee Related JP6004939B2 (ja) | 2009-08-11 | 2010-08-02 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
| JP2014130250A Ceased JP2014205845A (ja) | 2009-08-11 | 2014-06-25 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
| JP2016196404A Withdrawn JP2017039942A (ja) | 2009-08-11 | 2016-10-04 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
| JP2019072070A Pending JP2019131822A (ja) | 2009-08-11 | 2019-04-04 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
Family Applications Before (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012524735A Expired - Fee Related JP6004939B2 (ja) | 2009-08-11 | 2010-08-02 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
| JP2014130250A Ceased JP2014205845A (ja) | 2009-08-11 | 2014-06-25 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
| JP2016196404A Withdrawn JP2017039942A (ja) | 2009-08-11 | 2016-10-04 | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US9695267B2 (https=) |
| EP (1) | EP2464684B1 (https=) |
| JP (4) | JP6004939B2 (https=) |
| CN (2) | CN102575045B (https=) |
| BR (1) | BR112012003038A2 (https=) |
| CA (1) | CA2770673A1 (https=) |
| ES (1) | ES2795021T3 (https=) |
| IN (1) | IN2012DN01280A (https=) |
| MX (1) | MX2012001820A (https=) |
| PL (1) | PL2464684T3 (https=) |
| WO (1) | WO2011019528A2 (https=) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013504656A (ja) * | 2009-09-09 | 2013-02-07 | アーケマ・インコーポレイテッド | ハロゲン化オレフィン発泡剤を使用した、改良されたポリウレタン発泡プロセス、およびフォームの性質 |
| US20120046372A1 (en) * | 2010-08-18 | 2012-02-23 | Honeywell International Inc. | Blowing agents, foamable compositions and foams |
| US9556303B2 (en) * | 2011-02-21 | 2017-01-31 | Honeywell International Inc. | Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents |
| US20140171527A1 (en) * | 2011-02-21 | 2014-06-19 | Honeywell International Inc. | Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same |
| CN103619955A (zh) * | 2011-02-21 | 2014-03-05 | 霍尼韦尔国际公司 | 含有卤代烯烃发泡剂的聚氨酯泡沫预混料和由其制得的泡沫 |
| US20120313035A1 (en) * | 2011-06-08 | 2012-12-13 | Honeywell International Inc. | Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same |
| ES2674330T3 (es) * | 2011-04-15 | 2018-06-28 | Arkema, Inc. | Estabilidad mejorada de mezclas de poliuretano y poliol que contienen agente de soplado olefínico halogenado |
| CN103547552B (zh) * | 2011-05-19 | 2017-02-08 | 阿科玛股份有限公司 | 氯三氟丙烯的不可燃氯组合物 |
| CA2843012A1 (en) * | 2011-07-28 | 2013-01-31 | Honeywell International Inc. | Foams and flame resistant articles made from foams containing 1-chloro-3,3,3-trifluoropropene (1233zd) |
| RU2611493C2 (ru) * | 2011-08-01 | 2017-02-27 | Басф Се | Вспениваемые гидрофторолефинами/водой системы для жестких пеноматериалов |
| KR20140105739A (ko) * | 2011-12-09 | 2014-09-02 | 허니웰 인터내셔널 인코포레이티드 | Hcfo 또는 hfo 발포제를 함유하는 폼 및 폼으로 형성된 물품 |
| CN103509168B (zh) * | 2012-06-15 | 2018-04-27 | 科思创聚合物（中国）有限公司 | 微孔聚氨酯的组合物、制备方法及其应用 |
| PT2875068T (pt) * | 2012-07-19 | 2017-11-14 | Honeywell Int Inc | Agentes de expansão para espuma de poliestireno extrudido e espuma de poliestireno extrudido e métodos de formação de espuma |
| US9522973B2 (en) * | 2012-10-02 | 2016-12-20 | Covestro Llc | Polyurethane and polyisocyanurate rigid foams for roofing insulation |
| WO2014137969A1 (en) * | 2013-03-06 | 2014-09-12 | Honeywell International Inc. | Storage stable foamable compositions containing 1,1,1,4,4,4-hexafluoro-2-butene |
| CA3122485C (en) | 2013-03-15 | 2023-08-08 | Owens Corning Intellectual Capital, Llc | Processing aids for use in manufacturing extruded polystyrene foams using low global warming potential blowing agents |
| ES2869388T3 (es) * | 2014-03-20 | 2021-10-25 | Dow Global Technologies Llc | Mezclas formuladas reactivas con isocianato que incluyen agente de expansión a base de olefina |
| WO2016011219A1 (en) * | 2014-07-16 | 2016-01-21 | Owens Corning Intellectual Capital, Llc | Non-voc processing aids for use in manufacturing foams using low global warming potential blowing agents |
| JP6626674B2 (ja) | 2014-10-08 | 2019-12-25 | 積水ソフランウイズ株式会社 | 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法 |
| EP3268419A1 (en) | 2015-03-13 | 2018-01-17 | Basf Se | Method of forming a polyrethane foam article |
| DK3310835T3 (da) * | 2015-06-18 | 2022-12-05 | Basf Se | Fremgangsmåde til fremstilling af hårdt polyurethan-skum |
| JP6926660B2 (ja) * | 2016-05-17 | 2021-08-25 | 東ソー株式会社 | ハロアルケン発泡ポリウレタン製造用のアミン触媒組成物 |
| JP6903427B2 (ja) * | 2016-12-20 | 2021-07-14 | 日清紡ケミカル株式会社 | ２液型プレミックス組成物、裏込め注入用硬質ポリイソシアヌレートフォーム及び裏込め注入工法 |
| US11649315B2 (en) * | 2017-09-14 | 2023-05-16 | Huntsman International Llc | Polyurethane insulation foam composition comprising halogenated olefins and a tertiary amine compound |
| CN111263780B (zh) * | 2017-11-01 | 2022-04-05 | Ａｇｃ株式会社 | 硬质发泡合成树脂的制造方法 |
| CN112368315B (zh) * | 2018-06-27 | 2023-07-04 | 巴斯夫欧洲公司 | 制备硬质聚氨酯泡沫的方法及其作为绝热材料的用途 |
| JP7508443B2 (ja) * | 2018-08-16 | 2024-07-01 | ビーエーエスエフ ソシエタス・ヨーロピア | 環境に優しいポリウレタンスプレーフォーム系 |
| CN112638977B (zh) * | 2018-08-16 | 2024-03-19 | 巴斯夫欧洲公司 | 多异氰酸酯组合物、由其获得的聚氨酯泡沫及其用途 |
| US11578165B2 (en) | 2019-01-21 | 2023-02-14 | Talaco Holdings, LLC | Methods of making foams exhibiting desired properties from aromatic polyester polyether polyols derived from polyethylene terephthalates and foams made therefrom |
| ES2968185T3 (es) * | 2019-12-17 | 2024-05-08 | Basf Se | Un proceso de formación de espuma flexible para producir artículos con aislamiento térmico |
| JP7445290B2 (ja) * | 2020-01-31 | 2024-03-07 | アップコン株式会社 | ビバリウム装飾品 |
| KR102160534B1 (ko) * | 2020-02-07 | 2020-09-28 | 최규술 | 준불연 폴리우레탄 폼블록 및 그 제조방법 |
| EP4157910B1 (en) * | 2020-06-02 | 2025-02-26 | Huntsman International LLC | Use of epoxy compounds as carbon dioxide scavengers in pir comprising foams for superior thermal insulation properties |
| US11655328B2 (en) | 2020-09-02 | 2023-05-23 | Ventrex Systems, LLC | Dimensionally stable closed-cell and rigid foams produced with methylal blowing agent |
| JP7568523B2 (ja) * | 2021-01-20 | 2024-10-16 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板の製造方法 |
| US11753516B2 (en) | 2021-10-08 | 2023-09-12 | Covestro Llc | HFO-containing compositions and methods of producing foams |
| JP2025502041A (ja) * | 2022-01-13 | 2025-01-24 | ハネウェル・インターナショナル・インコーポレーテッド | 改善された特性を有する低密度熱硬化性発泡体 |
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2010
- 2010-07-30 US US12/847,381 patent/US9695267B2/en active Active
- 2010-08-02 CA CA2770673A patent/CA2770673A1/en not_active Abandoned
- 2010-08-02 CN CN201080045617.5A patent/CN102575045B/zh active Active
- 2010-08-02 WO PCT/US2010/044064 patent/WO2011019528A2/en not_active Ceased
- 2010-08-02 MX MX2012001820A patent/MX2012001820A/es unknown
- 2010-08-02 ES ES10808524T patent/ES2795021T3/es active Active
- 2010-08-02 EP EP10808524.2A patent/EP2464684B1/en active Active
- 2010-08-02 PL PL10808524T patent/PL2464684T3/pl unknown
- 2010-08-02 CN CN201610882776.XA patent/CN107022103B/zh active Active
- 2010-08-02 IN IN1280DEN2012 patent/IN2012DN01280A/en unknown
- 2010-08-02 JP JP2012524735A patent/JP6004939B2/ja not_active Expired - Fee Related
- 2010-08-02 BR BR112012003038A patent/BR112012003038A2/pt not_active Application Discontinuation
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2014
- 2014-06-25 JP JP2014130250A patent/JP2014205845A/ja not_active Ceased
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2016
- 2016-10-04 JP JP2016196404A patent/JP2017039942A/ja not_active Withdrawn
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2017
- 2017-06-30 US US15/639,455 patent/US20180016379A1/en not_active Abandoned
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2019
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