JP2019131811A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2019131811A5 JP2019131811A5 JP2019020934A JP2019020934A JP2019131811A5 JP 2019131811 A5 JP2019131811 A5 JP 2019131811A5 JP 2019020934 A JP2019020934 A JP 2019020934A JP 2019020934 A JP2019020934 A JP 2019020934A JP 2019131811 A5 JP2019131811 A5 JP 2019131811A5
- Authority
- JP
- Japan
- Prior art keywords
- weight
- propylene
- impact copolymer
- propylene impact
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002245 particle Substances 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 36
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 36
- 229920001577 copolymer Polymers 0.000 claims 32
- 238000000034 method Methods 0.000 claims 23
- 238000006116 polymerization reaction Methods 0.000 claims 15
- 229920000642 polymer Polymers 0.000 claims 9
- -1 1,4-phenylene aromatic diester Chemical class 0.000 claims 8
- 125000004432 carbon atom Chemical group C* 0.000 claims 8
- 239000002243 precursor Substances 0.000 claims 5
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 3
- 239000005977 Ethylene Substances 0.000 claims 3
- 229920001971 elastomer Polymers 0.000 claims 3
- 239000000806 elastomer Substances 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 230000002140 halogenating effect Effects 0.000 claims 2
- 125000005842 heteroatom Chemical group 0.000 claims 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 238000004062 sedimentation Methods 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- VHAIZXGRFIPEHM-UHFFFAOYSA-N 2-[5-tert-butyl-2-(2-carboxyphenyl)-3-methylphenyl]benzoic acid Chemical compound C=1C=CC=C(C(O)=O)C=1C=1C(C)=CC(C(C)(C)C)=CC=1C1=CC=CC=C1C(O)=O VHAIZXGRFIPEHM-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
- 150000001336 alkenes Chemical group 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 230000026030 halogenation Effects 0.000 claims 1
- 238000005658 halogenation reaction Methods 0.000 claims 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical group Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 claims 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361909461P | 2013-11-27 | 2013-11-27 | |
| US61/909,461 | 2013-11-27 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016534668A Division JP6573885B2 (ja) | 2013-11-27 | 2014-11-26 | プロ触媒粒子及びインパクトコポリマーの重合方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019131811A JP2019131811A (ja) | 2019-08-08 |
| JP2019131811A5 true JP2019131811A5 (https=) | 2020-11-26 |
| JP6869276B2 JP6869276B2 (ja) | 2021-05-12 |
Family
ID=53199650
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016534668A Active JP6573885B2 (ja) | 2013-11-27 | 2014-11-26 | プロ触媒粒子及びインパクトコポリマーの重合方法 |
| JP2019020934A Active JP6869276B2 (ja) | 2013-11-27 | 2019-02-07 | プロ触媒粒子及びインパクトコポリマーの重合方法 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016534668A Active JP6573885B2 (ja) | 2013-11-27 | 2014-11-26 | プロ触媒粒子及びインパクトコポリマーの重合方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US10059784B2 (https=) |
| EP (1) | EP3074435B1 (https=) |
| JP (2) | JP6573885B2 (https=) |
| KR (1) | KR102205993B1 (https=) |
| CN (2) | CN105764936B (https=) |
| BR (1) | BR112016012033B1 (https=) |
| ES (1) | ES2901954T3 (https=) |
| PL (1) | PL3074435T3 (https=) |
| RU (1) | RU2709203C1 (https=) |
| SA (1) | SA516371206B1 (https=) |
| WO (1) | WO2015081254A1 (https=) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105764936B (zh) * | 2013-11-27 | 2018-05-11 | 格雷斯公司 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
| KR102763007B1 (ko) | 2016-08-30 | 2025-02-04 | 더블유.알. 그레이스 앤드 컴파니 -씨오엔엔. | 저회분 함량의 폴리올레핀들 및 그 제조방법 |
| WO2018167305A1 (en) * | 2017-03-17 | 2018-09-20 | Sabic Global Technologies B.V. | Process for preparing a procatalyst for polymerization of olefins |
| WO2019094216A1 (en) * | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| WO2019094347A1 (en) * | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| KR20230091125A (ko) * | 2020-10-23 | 2023-06-22 | 더블유.알. 그레이스 앤드 캄파니-콘. | Voc 함량이 감소한 충격 저항성 폴리프로필렌 중합체 조성물 |
| EP4359448A1 (en) | 2021-06-25 | 2024-05-01 | Braskem, S.A. | Propylene preliminary polymerization |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4882380A (en) | 1987-07-07 | 1989-11-21 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of impact polypropylene copolymers |
| JPH0693061A (ja) * | 1992-09-16 | 1994-04-05 | Sumitomo Chem Co Ltd | ポリプロピレンブロック共重合体及びそのフィルム |
| US5885924A (en) | 1995-06-07 | 1999-03-23 | W. R. Grace & Co.-Conn. | Halogenated supports and supported activators |
| FI981718L (fi) | 1998-08-07 | 2000-02-08 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö |
| FI981717A7 (fi) * | 1998-08-07 | 2000-02-08 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö |
| US6825146B2 (en) | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| EP1668044B1 (en) | 2003-09-23 | 2014-05-07 | W.R. Grace & CO. - CONN. | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
| US8788826B1 (en) | 2008-06-06 | 2014-07-22 | Marvell International Ltd. | Method and apparatus for dynamically allocating a mobile network prefix to a mobile terminal |
| EP2315790B1 (en) * | 2008-08-21 | 2018-04-25 | W.R. Grace & CO. - CONN. | High melt flow propylene impact copolymer and method |
| US8604118B2 (en) * | 2008-12-26 | 2013-12-10 | Dow Global Technologies Llc | Antifoulant for impact copolymers and method |
| PL2373702T3 (pl) * | 2008-12-31 | 2018-07-31 | W.R. Grace & Co.-Conn. | Kompozycja prekatalizatora z wewnętrznym donorem w postaci podstawionego aromatycznego diestru 1,2-fenylenowego oraz sposób |
| JP5731988B2 (ja) * | 2008-12-31 | 2015-06-10 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | プロピレン系ポリマー、物品およびその製造プロセス |
| JP5448702B2 (ja) * | 2009-10-14 | 2014-03-19 | 日本ポリプロ株式会社 | プロピレン系ブロック共重合体の製造方法 |
| US20120157645A1 (en) | 2010-12-21 | 2012-06-21 | Linfeng Chen | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same |
| JP2014500384A (ja) * | 2010-12-21 | 2014-01-09 | ダウ グローバル テクノロジーズ エルエルシー | アルコキシアルキルエステル内部電子供与体を有するプロ触媒組成物の製造方法および製品 |
| US20120157295A1 (en) * | 2010-12-21 | 2012-06-21 | Linfeng Chen | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product |
| MX2013007356A (es) * | 2010-12-21 | 2014-01-23 | Dow Global Technologies Llc | Proceso para producir polimeros basados en propileno con alto indice de fluidez y productos preparados a partir de los mismos. |
| US9133286B2 (en) * | 2011-08-30 | 2015-09-15 | W. R. Grace & Co.-Conn | Production of substituted phenylene dibenzoate internal electron donor and procatalyst with same |
| CN105764936B (zh) | 2013-11-27 | 2018-05-11 | 格雷斯公司 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
-
2014
- 2014-11-26 CN CN201480064998.XA patent/CN105764936B/zh active Active
- 2014-11-26 US US15/036,365 patent/US10059784B2/en active Active
- 2014-11-26 RU RU2016125244A patent/RU2709203C1/ru active
- 2014-11-26 BR BR112016012033-7A patent/BR112016012033B1/pt active IP Right Grant
- 2014-11-26 EP EP14865185.4A patent/EP3074435B1/en active Active
- 2014-11-26 CN CN201810337337.XA patent/CN108503734B/zh active Active
- 2014-11-26 JP JP2016534668A patent/JP6573885B2/ja active Active
- 2014-11-26 KR KR1020167016790A patent/KR102205993B1/ko active Active
- 2014-11-26 WO PCT/US2014/067703 patent/WO2015081254A1/en not_active Ceased
- 2014-11-26 ES ES14865185T patent/ES2901954T3/es active Active
- 2014-11-26 PL PL14865185T patent/PL3074435T3/pl unknown
-
2016
- 2016-05-26 SA SA516371206A patent/SA516371206B1/ar unknown
-
2018
- 2018-06-27 US US16/019,693 patent/US20180305479A1/en not_active Abandoned
-
2019
- 2019-02-07 JP JP2019020934A patent/JP6869276B2/ja active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2019131811A5 (https=) | ||
| CN102597022B (zh) | 用于制备耐冲击丙烯聚合物组合物的方法 | |
| US10647788B2 (en) | Self-limiting catalyst system with controlled aluminum to SCA ratio and method | |
| CN1140545C (zh) | 聚丁烯-1(共)聚合物及其制备方法 | |
| US9663647B2 (en) | Producing propylene impact copolymers and products | |
| EP0685497A1 (en) | Stereospecific catalyst system for polymerisation of olefins | |
| EP3060588B1 (en) | Process for the preparation of porous propylene polymers | |
| MX2011001970A (es) | Composicion de catalizador con agente de control de selectividad mezclado y metodo de polimerizacion que la usa. | |
| JP2019151680A (ja) | α−オレフィン重合用固体触媒成分、α−オレフィン重合用固体触媒成分の製造方法、α−オレフィン重合用触媒、及びそれを用いたα−オレフィン重合体の製造方法 | |
| KR101146472B1 (ko) | 모노카르복실산 에스테르 내부 공여체를 갖는 자가-소멸촉매 조성물 및 프로필렌 중합 방법 | |
| JP2016538396A5 (https=) | ||
| CN116057079A (zh) | 固体状钛催化剂成分、烯烃聚合用催化剂、烯烃的聚合方法和丙烯聚合物 | |
| KR101109345B1 (ko) | 모노카르복실산 에스테르 내부 공여체를 갖는 촉매 조성물및 프로필렌 중합 방법 | |
| US7141635B2 (en) | Catalyst composition and polymerization process using mixtures of selectivity control agents | |
| US20060223956A1 (en) | Catalyst composition with mixed sca and propylene polymerization process | |
| KR101185329B1 (ko) | 오손 방지제의 존재 하의 올레핀 중합 방법 | |
| EP1877450B1 (en) | Novel combinations of silane electron donors for use in catalyst compositions | |
| US20150284488A1 (en) | Process for the preparation of propylene random copolymers | |
| JP2007321136A (ja) | ポリプロピレン系ブロック共重合体の製造方法 | |
| JP7186594B2 (ja) | プロピレン系重合体の製造方法 | |
| JP2004269808A (ja) | オレフィン類重合用固体触媒成分及び触媒 | |
| KR100822616B1 (ko) | 좁은 분자량 분포를 가지는 초고분자량 폴리올레핀 중합용촉매 및 이의 제조방법 | |
| KR20230091122A (ko) | 프로필렌-부텐 공중합체, 이의 제조 방법 및 사용 |