CN108503734B - 主催化剂颗粒及抗冲共聚物的聚合方法 - Google Patents
主催化剂颗粒及抗冲共聚物的聚合方法 Download PDFInfo
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- CN108503734B CN108503734B CN201810337337.XA CN201810337337A CN108503734B CN 108503734 B CN108503734 B CN 108503734B CN 201810337337 A CN201810337337 A CN 201810337337A CN 108503734 B CN108503734 B CN 108503734B
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- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- LGROXJWYRXANBB-UHFFFAOYSA-N trimethoxy(propan-2-yl)silane Chemical compound CO[Si](OC)(OC)C(C)C LGROXJWYRXANBB-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6493—Catalysts containing a specific non-metal or metal-free compound organic containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361909461P | 2013-11-27 | 2013-11-27 | |
| US61/909461 | 2013-11-27 | ||
| CN201480064998.XA CN105764936B (zh) | 2013-11-27 | 2014-11-26 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480064998.XA Division CN105764936B (zh) | 2013-11-27 | 2014-11-26 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108503734A CN108503734A (zh) | 2018-09-07 |
| CN108503734B true CN108503734B (zh) | 2021-09-03 |
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| CN201810337337.XA Active CN108503734B (zh) | 2013-11-27 | 2014-11-26 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
| CN201480064998.XA Active CN105764936B (zh) | 2013-11-27 | 2014-11-26 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201480064998.XA Active CN105764936B (zh) | 2013-11-27 | 2014-11-26 | 主催化剂颗粒及抗冲共聚物的聚合方法 |
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| Country | Link |
|---|---|
| US (2) | US10059784B2 (https=) |
| EP (1) | EP3074435B1 (https=) |
| JP (2) | JP6573885B2 (https=) |
| KR (1) | KR102205993B1 (https=) |
| CN (2) | CN108503734B (https=) |
| BR (1) | BR112016012033B1 (https=) |
| ES (1) | ES2901954T3 (https=) |
| PL (1) | PL3074435T3 (https=) |
| RU (1) | RU2709203C1 (https=) |
| SA (1) | SA516371206B1 (https=) |
| WO (1) | WO2015081254A1 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US10059784B2 (en) * | 2013-11-27 | 2018-08-28 | W. R. Grace & Co.-Conn. | Procatalyst particles and polymerization process for impact copolymers |
| KR102763007B1 (ko) | 2016-08-30 | 2025-02-04 | 더블유.알. 그레이스 앤드 컴파니 -씨오엔엔. | 저회분 함량의 폴리올레핀들 및 그 제조방법 |
| CN110382563B (zh) * | 2017-03-17 | 2022-08-26 | Sabic环球技术有限责任公司 | 用于制备用于烯烃聚合的主催化剂的方法 |
| WO2019094216A1 (en) | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| WO2019094347A1 (en) * | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| KR20230091125A (ko) * | 2020-10-23 | 2023-06-22 | 더블유.알. 그레이스 앤드 캄파니-콘. | Voc 함량이 감소한 충격 저항성 폴리프로필렌 중합체 조성물 |
| BR112023025122A2 (pt) | 2021-06-25 | 2024-02-20 | Braskem Sa | Processo para polimerização preliminar de propileno, composição de polímero preliminar, aparelho para alimentar um sistema de catalisadores, e, reator de polimerização preliminar |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102325808A (zh) * | 2008-12-31 | 2012-01-18 | 陶氏环球技术有限责任公司 | 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法 |
| CN102325809A (zh) * | 2008-12-31 | 2012-01-18 | 陶氏环球技术有限责任公司 | 提高的前催化剂组合物和方法 |
| CN103380104A (zh) * | 2010-12-21 | 2013-10-30 | 陶氏环球技术有限责任公司 | 生产高熔体流动性基于丙烯的聚合物的方法和由其生产的产品 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4882380A (en) | 1987-07-07 | 1989-11-21 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of impact polypropylene copolymers |
| JPH0693061A (ja) * | 1992-09-16 | 1994-04-05 | Sumitomo Chem Co Ltd | ポリプロピレンブロック共重合体及びそのフィルム |
| US5885924A (en) * | 1995-06-07 | 1999-03-23 | W. R. Grace & Co.-Conn. | Halogenated supports and supported activators |
| FI981717L (fi) | 1998-08-07 | 2000-02-08 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö |
| FI981718A7 (fi) | 1998-08-07 | 2000-02-08 | Borealis As | Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö |
| US6825146B2 (en) | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| EP1668044B1 (en) * | 2003-09-23 | 2014-05-07 | W.R. Grace & CO. - CONN. | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
| US8788826B1 (en) | 2008-06-06 | 2014-07-22 | Marvell International Ltd. | Method and apparatus for dynamically allocating a mobile network prefix to a mobile terminal |
| RU2487897C2 (ru) * | 2008-08-21 | 2013-07-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Ударопрочный пропиленовый сополимер с высокой скоростью течения расплава и способ его получения |
| US8604118B2 (en) * | 2008-12-26 | 2013-12-10 | Dow Global Technologies Llc | Antifoulant for impact copolymers and method |
| JP5448702B2 (ja) * | 2009-10-14 | 2014-03-19 | 日本ポリプロ株式会社 | プロピレン系ブロック共重合体の製造方法 |
| JP2014500384A (ja) * | 2010-12-21 | 2014-01-09 | ダウ グローバル テクノロジーズ エルエルシー | アルコキシアルキルエステル内部電子供与体を有するプロ触媒組成物の製造方法および製品 |
| US20120157645A1 (en) * | 2010-12-21 | 2012-06-21 | Linfeng Chen | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same |
| US20120157295A1 (en) * | 2010-12-21 | 2012-06-21 | Linfeng Chen | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product |
| US9133286B2 (en) * | 2011-08-30 | 2015-09-15 | W. R. Grace & Co.-Conn | Production of substituted phenylene dibenzoate internal electron donor and procatalyst with same |
| US10059784B2 (en) | 2013-11-27 | 2018-08-28 | W. R. Grace & Co.-Conn. | Procatalyst particles and polymerization process for impact copolymers |
-
2014
- 2014-11-26 US US15/036,365 patent/US10059784B2/en active Active
- 2014-11-26 KR KR1020167016790A patent/KR102205993B1/ko active Active
- 2014-11-26 BR BR112016012033-7A patent/BR112016012033B1/pt active IP Right Grant
- 2014-11-26 WO PCT/US2014/067703 patent/WO2015081254A1/en not_active Ceased
- 2014-11-26 JP JP2016534668A patent/JP6573885B2/ja active Active
- 2014-11-26 PL PL14865185T patent/PL3074435T3/pl unknown
- 2014-11-26 CN CN201810337337.XA patent/CN108503734B/zh active Active
- 2014-11-26 EP EP14865185.4A patent/EP3074435B1/en active Active
- 2014-11-26 RU RU2016125244A patent/RU2709203C1/ru active
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- 2014-11-26 ES ES14865185T patent/ES2901954T3/es active Active
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2016
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2018
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2019
- 2019-02-07 JP JP2019020934A patent/JP6869276B2/ja active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102325808A (zh) * | 2008-12-31 | 2012-01-18 | 陶氏环球技术有限责任公司 | 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法 |
| CN102325809A (zh) * | 2008-12-31 | 2012-01-18 | 陶氏环球技术有限责任公司 | 提高的前催化剂组合物和方法 |
| CN102333796A (zh) * | 2008-12-31 | 2012-01-25 | 陶氏环球技术有限责任公司 | 基于丙烯的聚合物、制品、和生产它们的方法 |
| CN102482376A (zh) * | 2008-12-31 | 2012-05-30 | 陶氏环球技术有限责任公司 | 丙烯无规共聚物组合物，制品及方法 |
| CN102741341A (zh) * | 2008-12-31 | 2012-10-17 | 陶氏环球技术有限责任公司 | 丙烯抗冲共聚物和方法 |
| CN103380104A (zh) * | 2010-12-21 | 2013-10-30 | 陶氏环球技术有限责任公司 | 生产高熔体流动性基于丙烯的聚合物的方法和由其生产的产品 |
Also Published As
| Publication number | Publication date |
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| SA516371206B1 (ar) | 2019-07-31 |
| BR112016012033B1 (pt) | 2021-02-09 |
| JP6573885B2 (ja) | 2019-09-11 |
| JP2019131811A (ja) | 2019-08-08 |
| CN105764936A (zh) | 2016-07-13 |
| EP3074435B1 (en) | 2021-11-10 |
| RU2016125244A (ru) | 2018-01-09 |
| RU2709203C1 (ru) | 2019-12-17 |
| KR20160091952A (ko) | 2016-08-03 |
| PL3074435T3 (pl) | 2022-01-24 |
| JP2016538396A (ja) | 2016-12-08 |
| CN105764936B (zh) | 2018-05-11 |
| CN108503734A (zh) | 2018-09-07 |
| JP6869276B2 (ja) | 2021-05-12 |
| WO2015081254A1 (en) | 2015-06-04 |
| EP3074435A1 (en) | 2016-10-05 |
| US20180305479A1 (en) | 2018-10-25 |
| KR102205993B1 (ko) | 2021-01-21 |
| ES2901954T3 (es) | 2022-03-24 |
| US20160297906A1 (en) | 2016-10-13 |
| US10059784B2 (en) | 2018-08-28 |
| EP3074435A4 (en) | 2017-06-28 |
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