JP2018537567A5 - - Google Patents
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- JP2018537567A5 JP2018537567A5 JP2018528662A JP2018528662A JP2018537567A5 JP 2018537567 A5 JP2018537567 A5 JP 2018537567A5 JP 2018528662 A JP2018528662 A JP 2018528662A JP 2018528662 A JP2018528662 A JP 2018528662A JP 2018537567 A5 JP2018537567 A5 JP 2018537567A5
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- JP
- Japan
- Prior art keywords
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- polymer
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- monomers
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000178 monomer Substances 0.000 claims description 93
- 229920000642 polymer Polymers 0.000 claims description 86
- 229920006243 acrylic copolymer Polymers 0.000 claims description 47
- 239000000203 mixture Substances 0.000 claims description 46
- 229920001169 thermoplastic Polymers 0.000 claims description 30
- 229920002554 vinyl polymer Polymers 0.000 claims description 29
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 15
- 238000005227 gel permeation chromatography Methods 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 14
- -1 vinyl halide Chemical class 0.000 claims description 13
- 230000000996 additive effect Effects 0.000 claims description 12
- 239000004793 Polystyrene Substances 0.000 claims description 10
- 229920002223 polystyrene Polymers 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 239000004416 thermosoftening plastic Substances 0.000 claims description 9
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 8
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- 230000009477 glass transition Effects 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 238000004132 cross linking Methods 0.000 claims description 2
- 230000033116 oxidation-reduction process Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims 2
- 239000004800 polyvinyl chloride Substances 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 229920000915 polyvinyl chloride Polymers 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 6
- 230000015271 coagulation Effects 0.000 description 6
- 238000005345 coagulation Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- 239000004801 Chlorinated PVC Substances 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 150000004965 peroxy acids Chemical class 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- COCLLEMEIJQBAG-UHFFFAOYSA-N 8-methylnonyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C(C)=C COCLLEMEIJQBAG-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- XWKBMOUUGHARTI-UHFFFAOYSA-N tricalcium;diphosphite Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])[O-].[O-]P([O-])[O-] XWKBMOUUGHARTI-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562269161P | 2015-12-18 | 2015-12-18 | |
| US62/269,161 | 2015-12-18 | ||
| PCT/US2016/065830 WO2017106037A1 (en) | 2015-12-18 | 2016-12-09 | Thermoplastic compositions containing multi-stage copolymers as melt strength process aids with lubrication properties |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018537567A JP2018537567A (ja) | 2018-12-20 |
| JP2018537567A5 true JP2018537567A5 (https=) | 2021-03-25 |
| JP7025330B2 JP7025330B2 (ja) | 2022-02-24 |
Family
ID=57799782
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018528662A Active JP7025330B2 (ja) | 2015-12-18 | 2016-12-09 | 潤滑性を有する溶融強度加工助剤として多段コポリマーを含有する熱可塑性組成物 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10611904B2 (https=) |
| EP (1) | EP3390474B1 (https=) |
| JP (1) | JP7025330B2 (https=) |
| KR (1) | KR102602114B1 (https=) |
| CN (2) | CN108290989A (https=) |
| BR (1) | BR112018010846B1 (https=) |
| ES (1) | ES2837398T3 (https=) |
| WO (1) | WO2017106037A1 (https=) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3521350B1 (en) * | 2016-09-29 | 2024-10-30 | Kuraray Co., Ltd. | Acrylic resin film and production method therefor |
| CN109836532A (zh) * | 2019-03-04 | 2019-06-04 | 浙江华慧塑业有限公司 | 一种超高分子量的pvc熔体增强剂及其制备方法 |
| JP7603405B2 (ja) * | 2020-09-25 | 2024-12-20 | 信越ポリマー株式会社 | アロイ樹脂の製造方法及び成形品の製造方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4086296A (en) | 1970-07-17 | 1978-04-25 | Rohm And Haas Company | Blends of thermoplastic polymer with a multi-phase acrylic composite polymers |
| FR2105362A5 (fr) * | 1970-09-02 | 1972-04-28 | Solvay | Compositions de matieres plastiques a base de polychlorure de vinyle et recipients fabriques a partir de ces compositions |
| JPS5946534B2 (ja) * | 1979-05-31 | 1984-11-13 | 鐘淵化学工業株式会社 | 塩化ビニル系樹脂用加工性改良剤組成物 |
| US4325856A (en) | 1980-01-02 | 1982-04-20 | The Dow Chemical Company | Sequential emulsion polymerization process |
| DE3443964A1 (de) | 1984-12-01 | 1986-06-12 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von polymer-dispersionen, die blockfeste filme bilden |
| US4814373A (en) | 1984-12-20 | 1989-03-21 | Rohm And Haas Company | Modified latex polymer composition |
| TW486502B (en) * | 1998-08-28 | 2002-05-11 | Kanegafuchi Chemical Ind | Processing aid for vinyl chloride resin and vinyl chloride resin composition |
| JP3504215B2 (ja) * | 1999-05-19 | 2004-03-08 | 三菱レイヨン株式会社 | 加工助剤、それを用いた塩化ビニル系樹脂組成物およびそれを用いた成形品の製造法 |
| CN102414264B (zh) | 2009-06-01 | 2014-06-11 | 株式会社钟化 | 发泡成形用加工性改进剂及含有其的氯乙烯系树脂组合物 |
| KR20130074427A (ko) * | 2011-12-26 | 2013-07-04 | 제일모직주식회사 | 유동성, 투명성 및 내충격성이 우수한 열가소성 수지 조성물 |
| FR3019549B1 (fr) * | 2014-04-07 | 2020-10-02 | Arkema France | Composition de poudre de polymere a etapes multiples, son procede de preparation et son utilisation |
| FR3019550B1 (fr) * | 2014-04-07 | 2020-11-20 | Arkema France | Composition de poudre de polymere et son procede de preparation |
-
2016
- 2016-12-09 KR KR1020187018304A patent/KR102602114B1/ko active Active
- 2016-12-09 CN CN201680070865.2A patent/CN108290989A/zh active Pending
- 2016-12-09 BR BR112018010846-4A patent/BR112018010846B1/pt not_active IP Right Cessation
- 2016-12-09 JP JP2018528662A patent/JP7025330B2/ja active Active
- 2016-12-09 CN CN202110522584.9A patent/CN113185788A/zh active Pending
- 2016-12-09 EP EP16826503.1A patent/EP3390474B1/en active Active
- 2016-12-09 US US15/781,879 patent/US10611904B2/en active Active
- 2016-12-09 WO PCT/US2016/065830 patent/WO2017106037A1/en not_active Ceased
- 2016-12-09 ES ES16826503T patent/ES2837398T3/es active Active
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