JP2018530104A - 酸化還元活性遷移金属配位化合物を生成するための水熱処理方法 - Google Patents
酸化還元活性遷移金属配位化合物を生成するための水熱処理方法 Download PDFInfo
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- JP2018530104A JP2018530104A JP2018503635A JP2018503635A JP2018530104A JP 2018530104 A JP2018530104 A JP 2018530104A JP 2018503635 A JP2018503635 A JP 2018503635A JP 2018503635 A JP2018503635 A JP 2018503635A JP 2018530104 A JP2018530104 A JP 2018530104A
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- transition metal
- titanium
- chelating agent
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 26
- 229910052723 transition metal Inorganic materials 0.000 title claims abstract description 15
- 150000003624 transition metals Chemical class 0.000 title claims abstract description 15
- 238000001027 hydrothermal synthesis Methods 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 33
- 239000003792 electrolyte Substances 0.000 claims abstract description 19
- 239000002738 chelating agent Substances 0.000 claims abstract description 16
- 239000012431 aqueous reaction media Substances 0.000 claims abstract description 6
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 36
- 239000010936 titanium Substances 0.000 claims description 28
- 229910052719 titanium Inorganic materials 0.000 claims description 17
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 12
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims description 12
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 8
- 229910052684 Cerium Inorganic materials 0.000 claims description 7
- 229910052770 Uranium Inorganic materials 0.000 claims description 7
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 7
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 229940079877 pyrogallol Drugs 0.000 claims description 6
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 5
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 5
- 229960005070 ascorbic acid Drugs 0.000 claims description 5
- 235000010323 ascorbic acid Nutrition 0.000 claims description 5
- 239000011668 ascorbic acid Substances 0.000 claims description 5
- 229950006191 gluconic acid Drugs 0.000 claims description 5
- JRNGUTKWMSBIBF-UHFFFAOYSA-N naphthalene-2,3-diol Chemical compound C1=CC=C2C=C(O)C(O)=CC2=C1 JRNGUTKWMSBIBF-UHFFFAOYSA-N 0.000 claims description 5
- -1 aromatic 1,2-diols Chemical class 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 239000000376 reactant Substances 0.000 claims description 3
- 150000002009 diols Chemical class 0.000 claims description 2
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 4
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 2
- 150000004706 metal oxides Chemical class 0.000 abstract description 2
- 230000007704 transition Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 7
- 150000003863 ammonium salts Chemical class 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 4
- 238000012983 electrochemical energy storage Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000010335 hydrothermal treatment Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000012047 saturated solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 238000007738 vacuum evaporation Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- NVEBAFPMSFQEPP-UHFFFAOYSA-J benzene-1,2-diolate titanium(4+) Chemical compound [O-]C=1C(=CC=CC1)[O-].[Ti+4].[O-]C=1C(=CC=CC1)[O-] NVEBAFPMSFQEPP-UHFFFAOYSA-J 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- LUWLVFVKEACFEB-UHFFFAOYSA-L disodium;benzene-1,2-diolate Chemical compound [Na+].[Na+].[O-]C1=CC=CC=C1[O-] LUWLVFVKEACFEB-UHFFFAOYSA-L 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/005—Compounds of elements of Group 5 of the Periodic Table without metal-carbon linkages
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/20—Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/64—Preparation of O-metal compounds with O-metal group bound to a carbon atom belonging to a six-membered aromatic ring
- C07C37/66—Preparation of O-metal compounds with O-metal group bound to a carbon atom belonging to a six-membered aromatic ring by conversion of hydroxy groups to O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/08—Fuel cells with aqueous electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
- Compounds Of Iron (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inert Electrodes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fuel Cell (AREA)
Abstract
Description
本件説明および特許請求に係る発明は、電気化学的エネルギー貯蔵システムのための電解質を生成する方法に関し、より具体的には、フロー電池システムにおける電解質としての使用のための酸化還元活性Ti(IV)配位化合物を水溶液中で生成する方法に関する。
[実施例1‐チタンカテコール錯体、ナトリウム塩の調製]
[実施例2‐チタンカテコール錯体、アンモニウム塩の調製]
[実施例3‐チタンピロガール錯体、アンモニウム塩の調製]
[実施例4‐バナジウムカテコール錯体、カリウム塩の調製]
[項目1]
遷移金属の酸化還元活性配位化合物を含有する水性電解質を生成する方法であって、水熱反応ゾーンにおいて、100℃〜160℃の範囲の温度にて、4〜48時間にわたる時間、対応する前記遷移金属の酸化物を水性反応媒体中で、キレート剤または複数のキレート剤の組み合わせと反応させる段階を備える、方法。
[項目2]
結晶性固体を形成すべく、反応物を冷却し、前記結晶性固体を回収する段階を追加で備える、項目1に記載の方法。
[項目3]
前記遷移金属は、チタン、アルミニウム、クロム、鉄、バナジウム、マンガン、セリウムおよびウランから成る群から選択され、前記キレート剤は、1種以上の芳香族1,2‐ジオールおよびこれらのジオールの組み合わせから実質的に成る群から選択される、項目1または2に記載の方法。
[項目4]
前記遷移金属は、チタンであり、前記キレート剤は、カテコール、ピロガロール、2,3−ナフタレンジオール、アスコルビン酸、グリコン酸、およびこれらの組み合わせから実質的に成る群から選択される、項目1または2に記載の方法。
[項目5]
酸化還元活性Ti(IV)配位化合物を含有する水性電解質を生成する方法であって、水熱反応ゾーンにおいて、100℃〜160℃の範囲の温度にて、4〜48時間にわたる時間、TiO 2 を水性反応媒体中で、カテコール、ピロガロール、2,3−ナフタレンジオール、アスコルビン酸、グリコン酸およびこれらの組み合わせから実質的に成る群から選択されるキレート剤と反応させる段階を備える、方法。
Claims (5)
- 遷移金属の酸化還元活性配位化合物を含有する水性電解質を生成する方法であって、水熱反応ゾーンにおいて、100℃〜160℃の範囲の温度にて、4〜48時間にわたる時間、対応する前記遷移金属の酸化物を水性反応媒体中で、キレート剤または複数のキレート剤の組み合わせと反応させる段階を備える、方法。
- 結晶性固体を形成すべく、反応物を冷却し、前記結晶性固体を回収する段階を追加で備える、請求項1に記載の方法。
- 前記遷移金属は、チタン、アルミニウム、クロム、鉄、バナジウム、マンガン、セリウムおよびウランから成る群から選択され、前記キレート剤は、1種以上の芳香族1,2‐ジオールおよびこれらのジオールの組み合わせから実質的に成る群から選択される、請求項1または2に記載の方法。
- 前記遷移金属は、チタンであり、前記キレート剤は、カテコール、ピロガロール、2,3−ナフタレンジオール、アスコルビン酸、グリコン酸、およびこれらの組み合わせから実質的に成る群から選択される、請求項1または2に記載の方法。
- 酸化還元活性Ti(IV)配位化合物を含有する水性電解質を生成する方法であって、水熱反応ゾーンにおいて、100℃〜160℃の範囲の温度にて、4〜48時間にわたる時間、TiO2を水性反応媒体中で、カテコール、ピロガロール、2,3−ナフタレンジオール、アスコルビン酸、グリコン酸およびこれらの組み合わせから実質的に成る群から選択されるキレート剤と反応させる段階を備える、方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/813,372 | 2015-07-30 | ||
US14/813,372 US9666893B2 (en) | 2015-07-30 | 2015-07-30 | Hydrothermal treatment method for producing redox-active transition metal coordination compounds |
PCT/IB2016/001223 WO2017017529A1 (en) | 2015-07-30 | 2016-07-18 | Hydrothermal treatment method for producing redox-active transition metal coordination compounds |
Publications (2)
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JP6381064B1 JP6381064B1 (ja) | 2018-08-29 |
JP2018530104A true JP2018530104A (ja) | 2018-10-11 |
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US (1) | US9666893B2 (ja) |
EP (1) | EP3243238B1 (ja) |
JP (1) | JP6381064B1 (ja) |
KR (1) | KR101942693B1 (ja) |
CN (1) | CN108140863A (ja) |
ES (1) | ES2673147T3 (ja) |
IL (1) | IL257191B (ja) |
TW (1) | TW201722970A (ja) |
WO (1) | WO2017017529A1 (ja) |
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CN111573725B (zh) * | 2020-05-22 | 2021-06-25 | 四川君和环保股份有限公司 | 从含钛高炉渣中提取二氧化钛制作钛白粉的方法 |
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JPS579072A (en) * | 1980-06-17 | 1982-01-18 | Agency Of Ind Science & Technol | Redox battery |
JPH0864223A (ja) * | 1994-08-22 | 1996-03-08 | Sumitomo Electric Ind Ltd | バナジウム系レドックスフロー型電池の電解液 |
WO2008007451A1 (fr) * | 2006-07-13 | 2008-01-17 | Central Japan Railway Company | Solution de revêtement, couche mince d'oxyde de titane formée en utilisant la solution de revêtement et procédé de formation de la couche mince |
JP2015529941A (ja) * | 2012-07-27 | 2015-10-08 | ロッキード・マーティン・アドバンスト・エナジー・ストレージ・エルエルシーLockheed Martin Advanced EnergyStorage, LLC | 金属リガンド配位化合物を含む水性レドックスフロー電池 |
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JP3502904B2 (ja) * | 2000-05-11 | 2004-03-02 | 岐阜大学長 | チタン含有水溶液の製造方法 |
US7435503B2 (en) * | 2004-06-10 | 2008-10-14 | Cornell Research Foundation, Inc. | Planar membraneless microchannel fuel cell |
CN101651221B (zh) * | 2009-09-27 | 2011-11-09 | 湖南维邦新能源有限公司 | 一种制备钒电池用电解液的方法 |
CN102254688B (zh) * | 2011-04-13 | 2012-12-26 | 清华大学 | 一种吡啶离子液体电解质及其制备方法和应用 |
US8691413B2 (en) | 2012-07-27 | 2014-04-08 | Sun Catalytix Corporation | Aqueous redox flow batteries featuring improved cell design characteristics |
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2015
- 2015-07-30 US US14/813,372 patent/US9666893B2/en active Active
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2016
- 2016-07-18 WO PCT/IB2016/001223 patent/WO2017017529A1/en active Application Filing
- 2016-07-18 EP EP16766352.5A patent/EP3243238B1/en active Active
- 2016-07-18 CN CN201680044800.0A patent/CN108140863A/zh active Pending
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- 2016-07-18 ES ES16766352.5T patent/ES2673147T3/es active Active
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JPS579072A (en) * | 1980-06-17 | 1982-01-18 | Agency Of Ind Science & Technol | Redox battery |
JPH0864223A (ja) * | 1994-08-22 | 1996-03-08 | Sumitomo Electric Ind Ltd | バナジウム系レドックスフロー型電池の電解液 |
WO2008007451A1 (fr) * | 2006-07-13 | 2008-01-17 | Central Japan Railway Company | Solution de revêtement, couche mince d'oxyde de titane formée en utilisant la solution de revêtement et procédé de formation de la couche mince |
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CN108140863A (zh) | 2018-06-08 |
KR20180029256A (ko) | 2018-03-20 |
TW201722970A (zh) | 2017-07-01 |
IL257191B (en) | 2019-09-26 |
US9666893B2 (en) | 2017-05-30 |
EP3243238A1 (en) | 2017-11-15 |
US20170033388A1 (en) | 2017-02-02 |
IL257191A (en) | 2018-03-29 |
ES2673147T3 (es) | 2018-06-20 |
WO2017017529A1 (en) | 2017-02-02 |
JP6381064B1 (ja) | 2018-08-29 |
KR101942693B1 (ko) | 2019-01-25 |
EP3243238B1 (en) | 2018-06-06 |
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