JP2017533199A5 - - Google Patents
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- JP2017533199A5 JP2017533199A5 JP2017521188A JP2017521188A JP2017533199A5 JP 2017533199 A5 JP2017533199 A5 JP 2017533199A5 JP 2017521188 A JP2017521188 A JP 2017521188A JP 2017521188 A JP2017521188 A JP 2017521188A JP 2017533199 A5 JP2017533199 A5 JP 2017533199A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- reaction
- reactor
- pipeline
- spent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003054 catalyst Substances 0.000 claims description 587
- 150000001336 alkenes Chemical class 0.000 claims description 195
- 238000006243 chemical reaction Methods 0.000 claims description 184
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 116
- 229930195733 hydrocarbon Natural products 0.000 claims description 114
- 150000002430 hydrocarbons Chemical class 0.000 claims description 114
- 238000004519 manufacturing process Methods 0.000 claims description 108
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 87
- 239000001301 oxygen Substances 0.000 claims description 87
- 229910052760 oxygen Inorganic materials 0.000 claims description 87
- 239000004215 Carbon black (E152) Substances 0.000 claims description 73
- 238000000034 method Methods 0.000 claims description 70
- 150000001875 compounds Chemical class 0.000 claims description 67
- 238000006297 dehydration reaction Methods 0.000 claims description 56
- 238000000926 separation method Methods 0.000 claims description 41
- 238000011084 recovery Methods 0.000 claims description 27
- 230000008929 regeneration Effects 0.000 claims description 27
- 238000011069 regeneration method Methods 0.000 claims description 27
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 24
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 11
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 238000007620 mathematical function Methods 0.000 claims description 4
- 239000002808 molecular sieve Substances 0.000 claims description 4
- 230000001172 regenerating effect Effects 0.000 claims description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 4
- ZVYSYCLZXICWLH-UHFFFAOYSA-N 1,3-dioxetan-2-one Chemical compound O=C1OCO1 ZVYSYCLZXICWLH-UHFFFAOYSA-N 0.000 claims description 3
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 2
- 239000000047 product Substances 0.000 description 45
- 230000000052 comparative effect Effects 0.000 description 39
- 230000008569 process Effects 0.000 description 30
- 239000010457 zeolite Substances 0.000 description 24
- 239000007789 gas Substances 0.000 description 21
- 239000000843 powder Substances 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 15
- 239000003546 flue gas Substances 0.000 description 14
- 238000010791 quenching Methods 0.000 description 14
- 229910021536 Zeolite Inorganic materials 0.000 description 12
- -1 reaction conditions Substances 0.000 description 10
- 239000000571 coke Substances 0.000 description 9
- 238000001914 filtration Methods 0.000 description 9
- 239000007795 chemical reaction product Substances 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 238000010926 purge Methods 0.000 description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- 238000000746 purification Methods 0.000 description 7
- 239000003085 diluting agent Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 229910052746 lanthanum Inorganic materials 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000269350 Anura Species 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000007233 catalytic pyrolysis Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410559920.7 | 2014-10-20 | ||
| CN201410559920.7A CN105585396B (zh) | 2014-10-20 | 2014-10-20 | 一种由含氧化合物制取低碳烯烃的方法 |
| PCT/CN2015/000705 WO2016061906A1 (zh) | 2014-10-20 | 2015-10-20 | 一种低碳烯烃的制造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017533199A JP2017533199A (ja) | 2017-11-09 |
| JP2017533199A5 true JP2017533199A5 (enExample) | 2020-03-05 |
| JP6782233B2 JP6782233B2 (ja) | 2020-11-11 |
Family
ID=55760118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017521188A Active JP6782233B2 (ja) | 2014-10-20 | 2015-10-20 | 軽オレフィンの製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10737991B2 (enExample) |
| EP (1) | EP3210960B1 (enExample) |
| JP (1) | JP6782233B2 (enExample) |
| CN (2) | CN105585396B (enExample) |
| AU (1) | AU2015336835B2 (enExample) |
| RU (1) | RU2698107C2 (enExample) |
| SG (1) | SG11201703273SA (enExample) |
| WO (1) | WO2016061906A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107266279B (zh) * | 2016-04-06 | 2020-05-19 | 中国石油化工股份有限公司 | 一种由含氧化合物制取低碳烯烃的方法 |
| CN107469798B (zh) * | 2016-06-07 | 2020-12-04 | 中国石油化工股份有限公司 | 一种硫吸附剂的再生方法 |
| WO2018111456A1 (en) * | 2016-12-14 | 2018-06-21 | Exxonmobil Research And Engineering Company | Method for oxygenate conversion in a fluid catalytic cracker |
| CN107400532A (zh) * | 2017-06-13 | 2017-11-28 | 神华集团有限责任公司 | 甲醇制低碳烯烃装置 |
| CN107982967A (zh) * | 2017-12-29 | 2018-05-04 | 逸盛大化石化有限公司 | 一种降低产品pt酸的压力过滤机反吹气系统 |
| CN110951501B (zh) * | 2018-09-27 | 2022-04-12 | 中国石油化工股份有限公司 | 一种低生焦原料的催化转化方法 |
| CN111659322A (zh) * | 2019-03-06 | 2020-09-15 | 浙江佳汇新材料有限公司 | 一种制备1,1,1,3-四氯丙烷的装置及工艺 |
| WO2020226747A1 (en) * | 2019-05-08 | 2020-11-12 | Exxonmobil Research And Engineering Company | Removal of catalyst fines from fluidized bed effluent in the conversion of oxygenate feedstock |
| US11975315B2 (en) * | 2019-05-10 | 2024-05-07 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | Method for partially regenerating catalyst for methanol and/or dimethyl ether-to-olefin and method for methanol and/or dimethyl ether-to-olefin |
| CN110437023A (zh) * | 2019-07-12 | 2019-11-12 | 中国神华煤制油化工有限公司 | 制备烯烃的方法和烯烃生产系统 |
| CN112745895B (zh) * | 2019-10-31 | 2022-10-21 | 中国石油化工股份有限公司 | 临氢催化裂解fcc循环油连续生产芳烃的方法和装置 |
| CN112774735A (zh) * | 2019-11-09 | 2021-05-11 | 洛阳维达石化工程有限公司 | 一种催化剂预烃池化的方法及其设备 |
| CN111330517B (zh) * | 2020-03-18 | 2022-04-29 | 山东凯泰科技股份有限公司 | 一种催化剂添加及过滤的自动控制系统 |
| CN113087584A (zh) * | 2021-03-15 | 2021-07-09 | 中石化洛阳工程有限公司 | 一种含氧化合物生产低碳烯烃的方法 |
| WO2025045193A1 (zh) * | 2023-08-31 | 2025-03-06 | 中国石油化工股份有限公司 | 烃类原料生产低碳烯烃的方法和系统 |
| CN119819690A (zh) * | 2024-12-26 | 2025-04-15 | 中国华能集团清洁能源技术研究院有限公司 | 催化剂回收再生系统和方法、烯烃的制备方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6124526A (ja) | 1984-07-14 | 1986-02-03 | Agency Of Ind Science & Technol | 低級オレフインの製造法 |
| FI97595C (fi) * | 1994-01-04 | 1997-01-10 | Nokia Telecommunications Oy | Matkaviestinjärjestelmä ja matkaviestinjärjestelmän tukiasema |
| KR100338991B1 (ko) * | 1994-04-01 | 2002-12-26 | 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 | 재귀반사성아플리케를가진의류 |
| US6531639B1 (en) * | 2000-02-18 | 2003-03-11 | Exxonmobil Chemical Patents, Inc. | Catalytic production of olefins at high methanol partial pressures |
| US7038102B2 (en) * | 2003-07-30 | 2006-05-02 | Exxonmobil Chemical Patents Inc. | Liquid contacting of post-quench effluent vapor streams from oxygenate to olefins conversion to capture catalyst fines |
| US7138558B2 (en) * | 2004-11-01 | 2006-11-21 | Uop Llc | Direct return of oxygenate recycle stream in olefin production process |
| US20050203326A1 (en) * | 2004-12-16 | 2005-09-15 | Miller Lawrence W. | Process for containment of catalyst particles in a oxygenate-to-olefin process |
| CN100430349C (zh) * | 2005-08-15 | 2008-11-05 | 中国石油化工股份有限公司 | 由甲醇或二甲醚生产丙烯的方法 |
| US7439414B2 (en) * | 2005-10-13 | 2008-10-21 | Uop Llc | Oxygenate conversion catalyst processing |
| CN101274872B (zh) * | 2007-03-30 | 2012-06-27 | 中国石油化工股份有限公司 | 一种乙醇脱水制乙烯的流化装置和工艺方法 |
| CN101279877B (zh) * | 2007-04-04 | 2011-07-20 | 中国石油化工股份有限公司 | 含氧化合物转化过程中提高乙烯、丙烯收率的方法 |
| CN101348404B (zh) * | 2007-07-18 | 2011-11-30 | 中国石油化工股份有限公司 | 甲醇或二甲醚转化过程中提高乙烯、丙烯收率的方法 |
| CA2713169C (en) | 2008-02-07 | 2014-07-08 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| CN101260013B (zh) * | 2008-04-24 | 2011-07-20 | 中国石油化工股份有限公司 | 含氧化合物制备低碳烯烃的方法 |
| EA025806B1 (ru) | 2010-03-15 | 2017-01-30 | Тотал Ресерч Энд Текнолоджи Фелюи | Одновременная дегидратация и скелетная изомеризация изобутанола на кислотных катализаторах |
| CN102814151B (zh) | 2011-06-08 | 2014-02-26 | 富德（北京）能源化工有限公司 | 由含氧化合物制烯烃的流化床反应器和方法 |
| KR101622496B1 (ko) | 2011-12-19 | 2016-05-18 | 달리안 인스티튜트 오브 케미컬 피직스, 차이니즈 아카데미 오브 사이언시즈 | 메탄올 및/또는 디메틸에테르로부터 에틸렌 및 프로필렌을 제조하는 촉매, 그 제조방법 및 응용 |
| WO2014207134A1 (en) * | 2013-06-27 | 2014-12-31 | Shell Internationale Research Maatschappij B.V. | An olefin cracking catalyst |
-
2014
- 2014-10-20 CN CN201410559920.7A patent/CN105585396B/zh active Active
-
2015
- 2015-10-20 WO PCT/CN2015/000705 patent/WO2016061906A1/zh not_active Ceased
- 2015-10-20 SG SG11201703273SA patent/SG11201703273SA/en unknown
- 2015-10-20 JP JP2017521188A patent/JP6782233B2/ja active Active
- 2015-10-20 US US15/520,729 patent/US10737991B2/en active Active
- 2015-10-20 CN CN201580011656.6A patent/CN106687428B/zh active Active
- 2015-10-20 AU AU2015336835A patent/AU2015336835B2/en active Active
- 2015-10-20 RU RU2017115709A patent/RU2698107C2/ru active
- 2015-10-20 EP EP15852702.8A patent/EP3210960B1/en active Active
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