CN105585396B - 一种由含氧化合物制取低碳烯烃的方法 - Google Patents
一种由含氧化合物制取低碳烯烃的方法 Download PDFInfo
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- CN105585396B CN105585396B CN201410559920.7A CN201410559920A CN105585396B CN 105585396 B CN105585396 B CN 105585396B CN 201410559920 A CN201410559920 A CN 201410559920A CN 105585396 B CN105585396 B CN 105585396B
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- 238000000034 method Methods 0.000 title claims abstract description 88
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 79
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000001301 oxygen Substances 0.000 claims abstract description 63
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 63
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- 238000011069 regeneration method Methods 0.000 claims abstract description 35
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- 150000001336 alkenes Chemical class 0.000 claims description 72
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 54
- 239000002994 raw material Substances 0.000 claims description 46
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical group [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 25
- 238000010791 quenching Methods 0.000 claims description 21
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 230000018044 dehydration Effects 0.000 claims description 15
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 8
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- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
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- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
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- 229910052684 Cerium Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
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- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
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- 229910052804 chromium Inorganic materials 0.000 description 1
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- 239000012065 filter cake Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
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- 238000004230 steam cracking Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
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- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
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- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
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- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1872—Details of the fluidised bed reactor
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0022—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for chemical reactors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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- Y02P20/50—Improvements relating to the production of bulk chemicals
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410559920.7A CN105585396B (zh) | 2014-10-20 | 2014-10-20 | 一种由含氧化合物制取低碳烯烃的方法 |
| US15/520,729 US10737991B2 (en) | 2014-10-20 | 2015-10-20 | Process for producing light olefins |
| RU2017115709A RU2698107C2 (ru) | 2014-10-20 | 2015-10-20 | Способ получения легких олефинов |
| JP2017521188A JP6782233B2 (ja) | 2014-10-20 | 2015-10-20 | 軽オレフィンの製造方法 |
| PCT/CN2015/000705 WO2016061906A1 (zh) | 2014-10-20 | 2015-10-20 | 一种低碳烯烃的制造方法 |
| CN201580011656.6A CN106687428B (zh) | 2014-10-20 | 2015-10-20 | 一种低碳烯烃的制造方法 |
| AU2015336835A AU2015336835B2 (en) | 2014-10-20 | 2015-10-20 | Method for preparing low-carbon alkene |
| SG11201703273SA SG11201703273SA (en) | 2014-10-20 | 2015-10-20 | Process for producing light olefins |
| EP15852702.8A EP3210960B1 (en) | 2014-10-20 | 2015-10-20 | Method for preparing low-carbon alkenes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410559920.7A CN105585396B (zh) | 2014-10-20 | 2014-10-20 | 一种由含氧化合物制取低碳烯烃的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105585396A CN105585396A (zh) | 2016-05-18 |
| CN105585396B true CN105585396B (zh) | 2018-03-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410559920.7A Active CN105585396B (zh) | 2014-10-20 | 2014-10-20 | 一种由含氧化合物制取低碳烯烃的方法 |
| CN201580011656.6A Active CN106687428B (zh) | 2014-10-20 | 2015-10-20 | 一种低碳烯烃的制造方法 |
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| CN107266279B (zh) * | 2016-04-06 | 2020-05-19 | 中国石油化工股份有限公司 | 一种由含氧化合物制取低碳烯烃的方法 |
| CN107469798B (zh) * | 2016-06-07 | 2020-12-04 | 中国石油化工股份有限公司 | 一种硫吸附剂的再生方法 |
| WO2018111456A1 (en) * | 2016-12-14 | 2018-06-21 | Exxonmobil Research And Engineering Company | Method for oxygenate conversion in a fluid catalytic cracker |
| CN107400532A (zh) * | 2017-06-13 | 2017-11-28 | 神华集团有限责任公司 | 甲醇制低碳烯烃装置 |
| CN107982967A (zh) * | 2017-12-29 | 2018-05-04 | 逸盛大化石化有限公司 | 一种降低产品pt酸的压力过滤机反吹气系统 |
| CN110951501B (zh) * | 2018-09-27 | 2022-04-12 | 中国石油化工股份有限公司 | 一种低生焦原料的催化转化方法 |
| CN111659322A (zh) * | 2019-03-06 | 2020-09-15 | 浙江佳汇新材料有限公司 | 一种制备1,1,1,3-四氯丙烷的装置及工艺 |
| WO2020226747A1 (en) * | 2019-05-08 | 2020-11-12 | Exxonmobil Research And Engineering Company | Removal of catalyst fines from fluidized bed effluent in the conversion of oxygenate feedstock |
| US11975315B2 (en) * | 2019-05-10 | 2024-05-07 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | Method for partially regenerating catalyst for methanol and/or dimethyl ether-to-olefin and method for methanol and/or dimethyl ether-to-olefin |
| CN110437023A (zh) * | 2019-07-12 | 2019-11-12 | 中国神华煤制油化工有限公司 | 制备烯烃的方法和烯烃生产系统 |
| CN112745895B (zh) * | 2019-10-31 | 2022-10-21 | 中国石油化工股份有限公司 | 临氢催化裂解fcc循环油连续生产芳烃的方法和装置 |
| CN112774735A (zh) * | 2019-11-09 | 2021-05-11 | 洛阳维达石化工程有限公司 | 一种催化剂预烃池化的方法及其设备 |
| CN111330517B (zh) * | 2020-03-18 | 2022-04-29 | 山东凯泰科技股份有限公司 | 一种催化剂添加及过滤的自动控制系统 |
| CN113087584A (zh) * | 2021-03-15 | 2021-07-09 | 中石化洛阳工程有限公司 | 一种含氧化合物生产低碳烯烃的方法 |
| WO2025045193A1 (zh) * | 2023-08-31 | 2025-03-06 | 中国石油化工股份有限公司 | 烃类原料生产低碳烯烃的方法和系统 |
| CN119819690A (zh) * | 2024-12-26 | 2025-04-15 | 中国华能集团清洁能源技术研究院有限公司 | 催化剂回收再生系统和方法、烯烃的制备方法 |
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| AU2015336835A1 (en) | 2017-05-25 |
| EP3210960B1 (en) | 2020-02-12 |
| EP3210960A1 (en) | 2017-08-30 |
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