JP2017532404A - ホットメルト接着剤組成物およびその使用 - Google Patents
ホットメルト接着剤組成物およびその使用 Download PDFInfo
- Publication number
- JP2017532404A JP2017532404A JP2017512689A JP2017512689A JP2017532404A JP 2017532404 A JP2017532404 A JP 2017532404A JP 2017512689 A JP2017512689 A JP 2017512689A JP 2017512689 A JP2017512689 A JP 2017512689A JP 2017532404 A JP2017532404 A JP 2017532404A
- Authority
- JP
- Japan
- Prior art keywords
- hot melt
- melt adhesive
- acid
- adhesive composition
- functional
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 239000000853 adhesive Substances 0.000 claims description 83
- 230000001070 adhesive effect Effects 0.000 claims description 83
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- 239000004626 polylactic acid Substances 0.000 claims description 26
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- -1 terpene phenols Chemical class 0.000 claims description 21
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- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 12
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 12
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
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- NQZRDXDTNFGVMK-UHFFFAOYSA-N 1,6-dioxecane-2,5-dione;terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1.O=C1CCC(=O)OCCCCO1 NQZRDXDTNFGVMK-UHFFFAOYSA-N 0.000 claims description 2
- MZWUAKOSFJGPFZ-UHFFFAOYSA-N 2-hydroxybutanoic acid;2-hydroxypentanoic acid Chemical compound CCC(O)C(O)=O.CCCC(O)C(O)=O MZWUAKOSFJGPFZ-UHFFFAOYSA-N 0.000 claims description 2
- JRHWHSJDIILJAT-UHFFFAOYSA-N 2-hydroxypentanoic acid Chemical compound CCCC(O)C(O)=O JRHWHSJDIILJAT-UHFFFAOYSA-N 0.000 claims description 2
- DJIHQRBJGCGSIR-UHFFFAOYSA-N 2-methylidene-1,3-dioxepane-4,7-dione Chemical compound C1(CCC(=O)OC(=C)O1)=O DJIHQRBJGCGSIR-UHFFFAOYSA-N 0.000 claims description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 2
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- 239000002318 adhesion promoter Substances 0.000 claims description 2
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- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- SAYGGTSIMQXXIT-UHFFFAOYSA-N carbonic acid;1,6-dioxecane-2,5-dione Chemical compound OC(O)=O.O=C1CCC(=O)OCCCCO1 SAYGGTSIMQXXIT-UHFFFAOYSA-N 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000012943 hotmelt Substances 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
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- 239000002667 nucleating agent Substances 0.000 claims description 2
- 239000011087 paperboard Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
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- 239000003381 stabilizer Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims 2
- 150000008064 anhydrides Chemical class 0.000 claims 1
- OZSVFZAVFRWFAY-UHFFFAOYSA-N butanoic acid;hexanoic acid Chemical compound CCCC(O)=O.CCCCCC(O)=O OZSVFZAVFRWFAY-UHFFFAOYSA-N 0.000 claims 1
- 239000013530 defoamer Substances 0.000 claims 1
- 230000003472 neutralizing effect Effects 0.000 claims 1
- 230000002335 preservative effect Effects 0.000 claims 1
- 239000000080 wetting agent Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 11
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- 229920000573 polyethylene Polymers 0.000 description 9
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Abstract
Description
(2)約275°F〜約400°Fで基材上に接着剤を塗布する工程、および
(3)第2の基材を塗布された接着剤に適用する工程を含む、物品を製造する方法を目的とする。基材は、紙、板紙、プラスチックフィルム、金属箔、剥離紙、綿、または不織布である。ホットメルト接着剤の粘度(v最終−v初期)/v初期は、安定したままであり、ホットメルト接着剤が、320°Fで少なくとも72時間エージング後、30%未満の変化である。
本発明は、経時的な熱安定性を提供する再生可能な原材料から製造されたホットメルト接着剤組成物を提供する。
安定化された粒子のために、極性の低い物質、例えば粘着付与剤、ポリオレフィン、ワックスを、相分離した非相溶系を形成することなく接着剤にさらに含めることができる。さらに、ポリエステル系樹脂の脆性はミセル構造から改質され、接着剤はより柔軟である。
接着剤試料は、ブラベンダー(Brabender)中で成分を一緒に合わせることによって形成し、160℃で約1時間加熱した。相分離または接着剤の均一性が観察され、記された。
非官能性ポリオレフィンは、エチレンコポリマーである。
官能性ポリオレフィンは無水マレイン酸グラフトポリエチレンコポリマーである。
粘着付与剤は、ロジンエステル、テルペンフェノール、スチレン化テルペンの混合物である。
ワックスは、約97℃の凝固点を有するフィッシャー・トロプシュワックスおよび/またはAOCS Cc 18−80に従って測定されたメトラー滴点が158°Fである水素化大豆油グリセリドである。
可塑剤はVertellusのCITRIFLEX A4である。
酸化防止剤は、BASFのIrganox 1010またはIrgafos 168の混合物である。
Claims (20)
- (a)ポリエステル系樹脂、(b)官能性ポリオレフィンまたは官能性ワックスおよび(c)粘着付与剤を含むホットメルト接着剤組成物。
- ホットメルト接着剤が、320°Fで少なくとも72時間エージングした後、ホットメルト接着剤の(v最終−v初期)/v初期が30%未満である、請求項1に記載のホットメルト接着剤組成物。
- ポリエステル系樹脂の酸および/または無水物を有する官能性ポリオレフィンに対する比が、約20:1〜約1:20の範囲である、請求項1に記載のホットメルト接着剤組成物。
- ポリエステル系樹脂が、乳酸、ブチレンサクシネート、ブチレンサクシネート−アジペート、ブチレンサクシネート−テレフタレート、エチレンサクシネート、ブチレンサクシネート−カーボネート、グリコール酸、カプロラクトン、ヒドロキシ酪酸、ヒドロキシ吉草酸、ヘキサノエートブチラート、ヒドロキシ酪酸−ヒドロキシ吉草酸およびこれらの混合物のホモポリマーまたはコポリマーからなる群から選択される、請求項1に記載のホットメルト接着剤。
- ポリエステル系樹脂が、乳酸、ブチレンサクシネート、ヒドロキシ酪酸またはそれらの混合物のホモポリマーまたはコポリマーである、請求項4に記載のホットメルト接着剤組成物。
- 官能性ポリオレフィンが、C2〜C20モノマーから選択されるホモポリマーまたはコポリマーである、請求項1に記載のホットメルト接着剤組成物。
- 官能性ポリオレフィンが、C2、C3、C4およびC8モノマーから選択されるホモポリマーまたはコポリマーである、請求項6に記載のホットメルト接着剤組成物。
- 官能性ワックスが、C2〜C20から選択されるモノマーまたはコモノマーを有する、請求項1に記載のホットメルト接着剤組成物。
- 官能性ワックスが、C2、C3、C4およびC8から選択されるモノマーまたはコモノマーを有する、請求項8に記載のホットメルト接着剤組成物。
- 官能性ポリオレフィンが、カルボン酸基、酸無水物基、アミノ基、イミノ基、ヒドロキシル基またはエポキシ基から選択される極性官能基を含む、請求項1に記載のホットメルト接着剤組成物。
- 極性官能基が、無水マレイン酸、カルボン酸、アクリル酸、マレイン酸、アクリル酸エチル、酢酸ビニル、エチレン−グリシジルメタクリレート、およびこれらの混合物からなる群から選択される、請求項10に記載のホットメルト接着剤組成物。
- 粘着付与剤が、ロジンエステル、テルペンフェノール、スチレン化テルペン、ポリテルペン、炭化水素、芳香族炭化水素、およびこれらの混合物からなる群から選択される、請求項1に記載のホットメルト接着剤組成物。
- C2〜C20モノマーホモポリマーまたはC2〜C20コポリマーを有する非官能性ポリオレフィンをさらに含む、請求項1に記載のホットメルト接着剤組成物。
- 非官能性ワックス、酸化防止剤、安定剤、可塑剤、充填剤、添加剤、顔料、染料、ポリマー添加剤、消泡剤、防腐剤、増粘剤、レオロジー調整剤、湿潤剤、核形成剤、ブロッキング防止剤、加工助剤、UV安定剤、中和剤、滑剤、界面活性剤および接着促進剤をさらに含む、請求項1に記載のホットメルト接着剤組成物。
- (a)約5〜約80重量%のポリ乳酸、(b)約0.1〜約25重量%の官能性ポリオレフィンまたは官能性ワックス、(c)粘着付与剤および(d)約50重量%までのC2〜C20モノマーを有するポリオレフィンを含むホットメルト接着剤組成物であって、ホットメルト接着剤の(v最終−v初期)/v初期が、約320°Fで少なくとも72時間エージングした後、30%未満であり、接着剤は、実質的にゴムエラストマーを含まないホットメルト接着剤組成物。
- 基材と請求項1に記載の接着剤を含む組成物とを含む物品。
- ケース、カートン、トレイ、ラベル、製本、バッグまたは使い捨て物品である、請求項16に記載の物品。
- 基材と請求項15に記載の接着剤を含む組成物とを含む物品。
- ケース、カートン、トレイ、ラベル、製本、バッグまたは使い捨て物品である、請求項18に記載の物品。
- (a)約275°F〜約400°Fで(i)ポリエステル系樹脂、(ii)官能性ポリオレフィンまたは官能性ワックス、(iii)粘着付与剤を含む接着剤を形成する工程、
(b)約275°F〜約400°Fで基材上に接着剤を塗布する工程、および
(c)第2の基材を塗布された接着剤に適用する工程を含む、物品を製造する方法であって、
基材が、紙、板紙、プラスチックフィルム、金属箔、剥離紙、綿、または不織布であり、
接着剤の粘度が、320°Fで少なくとも72時間エージング後、30%未満の変化である方法。
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PCT/US2015/048549 WO2016037062A1 (en) | 2014-09-05 | 2015-09-04 | Hot melt adhesive compositions and use thereof |
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JP2022515781A (ja) * | 2018-12-21 | 2022-02-22 | ヘンケル アイピー アンド ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング | ホットメルト接着剤およびその使用 |
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