JP2017514531A - 疎水性高分子フォームに含浸された化粧料組成物を含む化粧品 - Google Patents
疎水性高分子フォームに含浸された化粧料組成物を含む化粧品 Download PDFInfo
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 53
- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 239000006260 foam Substances 0.000 title claims abstract description 35
- 229920001600 hydrophobic polymer Polymers 0.000 title claims abstract description 26
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 62
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 62
- 229920001194 natural rubber Polymers 0.000 claims abstract description 62
- 239000000463 material Substances 0.000 claims abstract description 37
- 230000000903 blocking effect Effects 0.000 claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 229920000459 Nitrile rubber Polymers 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 12
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 9
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 8
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical group CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 claims description 8
- 229940068171 ethyl hexyl salicylate Drugs 0.000 claims description 8
- 229960001679 octinoxate Drugs 0.000 claims description 8
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 claims description 8
- 229960000601 octocrylene Drugs 0.000 claims description 8
- -1 polyethylene Polymers 0.000 claims description 8
- 239000005062 Polybutadiene Substances 0.000 claims description 7
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 4
- 229920002857 polybutadiene Polymers 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 3
- 239000002552 dosage form Substances 0.000 claims description 3
- HEOCBCNFKCOKBX-RELGSGGGSA-N (1s,2e,4r)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-3-one Chemical compound C1=CC(C)=CC=C1\C=C/1C(=O)[C@]2(C)CC[C@H]\1C2(C)C HEOCBCNFKCOKBX-RELGSGGGSA-N 0.000 claims description 2
- WHQOKFZWSDOTQP-UHFFFAOYSA-N 2,3-dihydroxypropyl 4-aminobenzoate Chemical compound NC1=CC=C(C(=O)OCC(O)CO)C=C1 WHQOKFZWSDOTQP-UHFFFAOYSA-N 0.000 claims description 2
- JGUMTYWKIBJSTN-UHFFFAOYSA-N 2-ethylhexyl 4-[[4,6-bis[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 JGUMTYWKIBJSTN-UHFFFAOYSA-N 0.000 claims description 2
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 2
- WYWZRNAHINYAEF-UHFFFAOYSA-N Padimate O Chemical compound CCCCC(CC)COC(=O)C1=CC=C(N(C)C)C=C1 WYWZRNAHINYAEF-UHFFFAOYSA-N 0.000 claims description 2
- UBNYRXMKIIGMKK-RMKNXTFCSA-N amiloxate Chemical compound COC1=CC=C(\C=C\C(=O)OCCC(C)C)C=C1 UBNYRXMKIIGMKK-RMKNXTFCSA-N 0.000 claims description 2
- XVAMCHGMPYWHNL-UHFFFAOYSA-N bemotrizinol Chemical compound OC1=CC(OCC(CC)CCCC)=CC=C1C1=NC(C=2C=CC(OC)=CC=2)=NC(C=2C(=CC(OCC(CC)CCCC)=CC=2)O)=N1 XVAMCHGMPYWHNL-UHFFFAOYSA-N 0.000 claims description 2
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 229960004697 enzacamene Drugs 0.000 claims description 2
- 229960004881 homosalate Drugs 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- GYEGPPIVVUYWAC-UHFFFAOYSA-N (7-oxo-7-phenylheptyl) benzoate Chemical compound C=1C=CC=CC=1C(=O)CCCCCCOC(=O)C1=CC=CC=C1 GYEGPPIVVUYWAC-UHFFFAOYSA-N 0.000 claims 1
- TYYHDKOVFSVWON-UHFFFAOYSA-N 2-butyl-2-methoxy-1,3-diphenylpropane-1,3-dione Chemical compound C=1C=CC=CC=1C(=O)C(OC)(CCCC)C(=O)C1=CC=CC=C1 TYYHDKOVFSVWON-UHFFFAOYSA-N 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- 229960005193 avobenzone Drugs 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
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- 238000000034 method Methods 0.000 description 7
- 239000002174 Styrene-butadiene Substances 0.000 description 6
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- 239000011148 porous material Substances 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 description 3
- 239000006210 lotion Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 230000000274 adsorptive effect Effects 0.000 description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KNUPSOXBESCJLY-UHFFFAOYSA-N 2-methoxy-1-phenylhexan-1-one Chemical compound CCCCC(OC)C(=O)C1=CC=CC=C1 KNUPSOXBESCJLY-UHFFFAOYSA-N 0.000 description 1
- 241001237961 Amanita rubescens Species 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 244000001591 balata Species 0.000 description 1
- 235000016302 balata Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- FDATWRLUYRHCJE-UHFFFAOYSA-N diethylamino hydroxybenzoyl hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)C1=CC=C(N(CC)CC)C=C1O FDATWRLUYRHCJE-UHFFFAOYSA-N 0.000 description 1
- 229960001630 diethylamino hydroxybenzoyl hexyl benzoate Drugs 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 230000037072 sun protection Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229920003212 trans-1,4-polyisoprene Polymers 0.000 description 1
Classifications
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8194—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
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- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/046—Aerosols; Foams
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- A61K8/37—Esters of carboxylic acids
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Abstract
Description
本明細書において、「含浸」という用語は、化粧料組成物を製造する業界で通常用いられる意味で解釈され、具体的には、スポンジのように内部にポアが形成されている材質に、内容物を担持させることを意味する。
組成例1、2及び3の油中水型ファンデーションは、以下のように製作した。
油相槽に油相成分と増粘剤を入れ、80℃に熱を加えて均一にした後、顔料を入れて分散させた。水相槽には水相成分を入れ、80℃に熱を加えて原料を完全に溶解させた後、顔料が分散している油相槽に添加してホモミキサーで乳化させ、低粘度の紫外線遮断油化物を製造した。40mlの安定性容器に内容物を充填した後、25℃のチャンバに一日以上保管した後、ブルックフィールドLVII粘度計にスピンドル4番を用いて30rpmで1分間作動させた後、25℃で粘度を測定した結果、3,000〜5,000cpsであった。下記の表1は、含浸用ファンデーションの製造のための組成を示した表である。
NR、NBR及びSBRの比率別発泡フォームは、S&G CO.,Ltdから受給され(LG−latex #1001−1014)、直径50mm、高さ10mmの円筒状に裁断して化粧料組成物を含浸させた。常温で24時間保管した後、スポンジの表面から含浸されていないファンデーションを除去した後、スポンジを指で押し付けてファンデーションを採った。採られたファンデーション溶液は、同時に確保して以下の方式で測定した。
(1)エチルヘキシルメトキシシンナメートの量(mg)=AT/As×エチルヘキシルメトキシシンナメート標準品の量(mg)
(2)エチルヘキシルサリチレートの量(mg)=AT/As×エチルヘキシルサリチレート標準品の量(mg)
(3)オクトクリレン(mg)=AT/As×オクトクリレンの量(mg)
その結果は表2及び表3のようであった。
特に、NRの比率が20重量%を超過するとき、有機紫外線の吸着度が高いことが分かった。
その結果は表5のようであった。
Claims (7)
- 発泡フォームの製造のための高分子基材として天然ゴム(NR)及び疎水性高分子を含む化粧料組成物含浸用フォームと、
有機紫外線遮断成分を含み、前記発泡フォームに含浸された化粧料組成物と、を含む、化粧品。 - 前記疎水性高分子は、スチレン、ブタジエン、クロロプレン、アクリロニトリル、イソプレン、イソブチレン、エチレン及びプロピレンからなる群より選択されたいずれか一種以上の重合体または共重合体であることを特徴とする請求項1に記載の化粧品。
- 前記疎水性高分子は、スチレン−ブタジエンゴム(SBR)、ブタジエンゴム(BR)、アクリロニトリル−ブタジエンゴム(NBR)、アクリロニトリル−ブタジエン−スチレン(ABS)、ポリエチレン(PE)、ポリビニルアルコール(PVA)及びエチレンビニルアセテート(EVA)からなる群より選択されたいずれか一種以上であることを特徴とする請求項1に記載の化粧品。
- 前記天然ゴム(NR)及び疎水性高分子を含むフォームの製造のための高分子基材が、天然ゴムを高分子基材の全体重量に対し20重量%以下で含むことを特徴とする請求項1に記載の化粧品。
- 前記有機紫外線遮断成分は、エチルヘキシルメトキシシンナメート、エチルヘキシルサリチレート、オクトクリレン、イソアミル−p−メトキシシンナメート、ブチルメトキシジベンゾイルメタン、ホモサレート、ビス−エチルヘキシルオキシフェノールメトキシフェニルトリアジン、エチルヘキシルトリアゾン、ジエチルアミノヒドロキシベンゾイルヘキシルベンゾエート、ポリシリコン−15及びPABA(パラアミノ安息香酸)、シノキセート、4−メチルベンジリデンカンファー、グリセリルパラアミノベンゾエート、及びエチルヘキシルジメチルPABAからなる群より選択されたいずれか一種以上であることを特徴とする請求項1に記載の化粧品。
- 前記有機紫外線遮断成分が、エチルヘキシルメトキシシンナメート、エチルヘキシルサリチレート、オクトクリレンまたはこれらの混合物であることを特徴とする請求項5に記載の化粧品。
- 前記化粧料組成物が、油中水型剤形であることを特徴とする請求項1に記載の化粧品。
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PCT/KR2015/012132 WO2016137087A1 (ko) | 2015-02-27 | 2015-11-11 | 소수성 고분자 폼에 함침된 화장료 조성물을 포함하는 화장품 |
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US9744117B2 (en) | 2017-08-29 |
WO2016137087A1 (ko) | 2016-09-01 |
JP6270879B2 (ja) | 2018-01-31 |
EP3100713A1 (en) | 2016-12-07 |
CN106061464B (zh) | 2017-09-01 |
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