JP2017075998A - 粘着シート、粘着剤層付き偏光板、および画像表示装置 - Google Patents
粘着シート、粘着剤層付き偏光板、および画像表示装置 Download PDFInfo
- Publication number
- JP2017075998A JP2017075998A JP2015202187A JP2015202187A JP2017075998A JP 2017075998 A JP2017075998 A JP 2017075998A JP 2015202187 A JP2015202187 A JP 2015202187A JP 2015202187 A JP2015202187 A JP 2015202187A JP 2017075998 A JP2017075998 A JP 2017075998A
- Authority
- JP
- Japan
- Prior art keywords
- adhesive sheet
- sensitive adhesive
- pressure
- polarizing plate
- image display
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 189
- 239000010410 layer Substances 0.000 title description 15
- 230000001070 adhesive effect Effects 0.000 claims abstract description 91
- 239000000853 adhesive Substances 0.000 claims abstract description 89
- 230000035699 permeability Effects 0.000 claims abstract description 46
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 20
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 20
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 13
- 239000011630 iodine Substances 0.000 claims abstract description 13
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000178 monomer Substances 0.000 claims description 62
- 229920005601 base polymer Polymers 0.000 claims description 37
- 230000001681 protective effect Effects 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 32
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 18
- 239000012790 adhesive layer Substances 0.000 claims description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 13
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 10
- 150000007524 organic acids Chemical class 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 1
- 230000000007 visual effect Effects 0.000 claims 1
- 230000008859 change Effects 0.000 abstract description 9
- 230000003287 optical effect Effects 0.000 abstract description 9
- 238000010030 laminating Methods 0.000 abstract description 2
- 238000002834 transmittance Methods 0.000 description 47
- 239000010408 film Substances 0.000 description 35
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 33
- 229940048053 acrylate Drugs 0.000 description 33
- 238000000034 method Methods 0.000 description 24
- 238000010438 heat treatment Methods 0.000 description 23
- 230000007423 decrease Effects 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 238000012360 testing method Methods 0.000 description 17
- 210000004027 cell Anatomy 0.000 description 16
- -1 iodine ions Chemical class 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 13
- 239000003431 cross linking reagent Substances 0.000 description 13
- 239000011229 interlayer Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 11
- 238000001035 drying Methods 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 229920000058 polyacrylate Polymers 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
- 238000001723 curing Methods 0.000 description 7
- 238000011049 filling Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 229920002284 Cellulose triacetate Polymers 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 6
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000003505 polymerization initiator Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000006087 Silane Coupling Agent Substances 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 239000004973 liquid crystal related substance Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 4
- 229940114077 acrylic acid Drugs 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- 150000004291 polyenes Polymers 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 244000043261 Hevea brasiliensis Species 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000012461 cellulose resin Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 210000002858 crystal cell Anatomy 0.000 description 3
- 238000010227 cup method (microbiological evaluation) Methods 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920003052 natural elastomer Polymers 0.000 description 3
- 229920001194 natural rubber Polymers 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000002093 peripheral effect Effects 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 229920001289 polyvinyl ether Polymers 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 229920005573 silicon-containing polymer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 2
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 2
- KANZWHBYRHQMKZ-UHFFFAOYSA-N 2-ethenylpyrazine Chemical compound C=CC1=CN=CC=N1 KANZWHBYRHQMKZ-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical class NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 238000000016 photochemical curing Methods 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229920005668 polycarbonate resin Polymers 0.000 description 2
- 239000004431 polycarbonate resin Substances 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 239000005061 synthetic rubber Substances 0.000 description 2
- 238000012719 thermal polymerization Methods 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical compound C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- DCRYNQTXGUTACA-UHFFFAOYSA-N 1-ethenylpiperazine Chemical compound C=CN1CCNCC1 DCRYNQTXGUTACA-UHFFFAOYSA-N 0.000 description 1
- PBGPBHYPCGDFEZ-UHFFFAOYSA-N 1-ethenylpiperidin-2-one Chemical compound C=CN1CCCCC1=O PBGPBHYPCGDFEZ-UHFFFAOYSA-N 0.000 description 1
- BFYSJBXFEVRVII-UHFFFAOYSA-N 1-prop-1-enylpyrrolidin-2-one Chemical compound CC=CN1CCCC1=O BFYSJBXFEVRVII-UHFFFAOYSA-N 0.000 description 1
- WLRIOEJDMDJFIK-UHFFFAOYSA-N 12-methyltridecyl prop-2-enoate Chemical compound CC(C)CCCCCCCCCCCOC(=O)C=C WLRIOEJDMDJFIK-UHFFFAOYSA-N 0.000 description 1
- STFXXRRQKFUYEU-UHFFFAOYSA-N 16-methylheptadecyl prop-2-enoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)C=C STFXXRRQKFUYEU-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- TXTIIWDWHSZBRK-UHFFFAOYSA-N 2,4-diisocyanato-1-methylbenzene;2-ethyl-2-(hydroxymethyl)propane-1,3-diol Chemical compound CCC(CO)(CO)CO.CC1=CC=C(N=C=O)C=C1N=C=O TXTIIWDWHSZBRK-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- PGMMQIGGQSIEGH-UHFFFAOYSA-N 2-ethenyl-1,3-oxazole Chemical compound C=CC1=NC=CO1 PGMMQIGGQSIEGH-UHFFFAOYSA-N 0.000 description 1
- MZNSQRLUUXWLSB-UHFFFAOYSA-N 2-ethenyl-1h-pyrrole Chemical compound C=CC1=CC=CN1 MZNSQRLUUXWLSB-UHFFFAOYSA-N 0.000 description 1
- ZDHWTWWXCXEGIC-UHFFFAOYSA-N 2-ethenylpyrimidine Chemical compound C=CC1=NC=CC=N1 ZDHWTWWXCXEGIC-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- CFZDMXAOSDDDRT-UHFFFAOYSA-N 4-ethenylmorpholine Chemical compound C=CN1CCOCC1 CFZDMXAOSDDDRT-UHFFFAOYSA-N 0.000 description 1
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 1
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- JSCDRVVVGGYHSN-UHFFFAOYSA-N 8-hydroxyoctyl prop-2-enoate Chemical compound OCCCCCCCCOC(=O)C=C JSCDRVVVGGYHSN-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- URLYGBGJPQYXBN-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methyl prop-2-enoate Chemical compound OCC1CCC(COC(=O)C=C)CC1 URLYGBGJPQYXBN-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920001727 cellulose butyrate Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005443 coulometric titration Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 229920005994 diacetyl cellulose Polymers 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000004255 ion exchange chromatography Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012788 optical film Substances 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/0073—Optical laminates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
- G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
- G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
- G02B5/3041—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/26—Optical coupling means
- G02B6/32—Optical coupling means having lens focusing means positioned between opposed fibre ends
- G02B6/325—Optical coupling means having lens focusing means positioned between opposed fibre ends comprising a transparent member, e.g. window, protective plate
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/13363—Birefringent elements, e.g. for optical compensation
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/50—OLEDs integrated with light modulating elements, e.g. with electrochromic elements, photochromic elements or liquid crystal elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00634—Production of filters
- B29D11/00644—Production of filters polarizing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
- B32B2457/202—LCD, i.e. liquid crystal displays
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1812—C12-(meth)acrylate, e.g. lauryl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
- C09J133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/414—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of a copolymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2429/00—Presence of polyvinyl alcohol
- C09J2429/006—Presence of polyvinyl alcohol in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/03—Viewing layer characterised by chemical composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/03—Viewing layer characterised by chemical composition
- C09K2323/031—Polarizer or dye
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/03—Viewing layer characterised by chemical composition
- C09K2323/035—Ester polymer, e.g. polycarbonate, polyacrylate or polyester
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
- C09K2323/057—Ester polymer, e.g. polycarbonate, polyacrylate or polyester
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
- C09K2323/059—Unsaturated aliphatic polymer, e.g. vinyl
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/133308—Support structures for LCD panels, e.g. frames or bezels
- G02F1/133311—Environmental protection, e.g. against dust or humidity
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/133308—Support structures for LCD panels, e.g. frames or bezels
- G02F1/133331—Cover glasses
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133528—Polarisers
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2201/00—Constructional arrangements not provided for in groups G02F1/00 - G02F7/00
- G02F2201/50—Protective arrangements
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2202/00—Materials and properties
- G02F2202/28—Adhesive materials or arrangements
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Engineering & Computer Science (AREA)
- Mathematical Physics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Ophthalmology & Optometry (AREA)
- Manufacturing & Machinery (AREA)
- Polarising Elements (AREA)
- Liquid Crystal (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
本発明の粘着シート20は、粘着剤がシート状に形成されたものである。粘着シート20の厚みDは、50μm以上が好ましく、80μm以上がより好ましく、100μm以上がさらに好ましい。層間充填剤として用いられる粘着シートの厚みを大きくすることにより、粘着シートに段差吸収性を持たせ、前面透明部材70が印刷段差72を有する場合でも、印刷段差付近での気泡混入や、応力歪による表示ムラの発生を抑制できる。また、後に詳述するように、粘着シートの厚みが大きい場合は、粘着シートの側面から水分が散逸しやすく、画像表示装置を高温環境に曝した場合の表示特性の低下を抑制できる。粘着シートの厚みの上限は特に限定されないが、生産性等の観点から、500μm以下が好ましく、400μm以下がより好ましく、300μm以下がさらに好ましい。
本発明の粘着シートは、透明性が高いことが好ましい。粘着シートのヘイズは1%以下が好ましく、全光線透過率は90%以上が好ましい。ヘイズおよび全光線透過率は、ヘイズメータを用いて、JIS K7136に準じて測定される。
本発明の粘着シート20は、透湿度Xと厚みDの2乗との積XD2(g/24h)が、2.7×10−6以上であることが好ましく、3.2×10−6以上であることがより好ましく、3.9×10−6以上であることがさらに好ましい。XD2が大きいほど、画像表示装置が高温環境に曝された場合における、偏光板の面内中央部での単体透過率の低下が抑制される傾向がある。透湿度は、JIS Z0208の透湿度試験(カップ法)に準じて測定される値であり、40℃、90%の相対湿度差で、面積1m2の試料を24時間で透過する水蒸気の重量である。
本発明の粘着シート20は、水分率Yを、厚みDで割った値Y/D(m−1)が、47以下であることが好ましく、44以下であることがより好ましく、40以下であることがさらに好ましい。Y/Dが小さいほど、画像表示装置が高温環境に曝された場合における、偏光板の面内中央部での直交透過率の上昇が抑制される傾向がある。水分率Yは、粘着剤の単位質量あたりの水分の量であり、温度23℃湿度55%の雰囲気下で3日間静置して状態調整を行った試料を用いて、カールフィッシャー法により測定した値である。
粘着シート20を構成する粘着剤としては、アクリル系ポリマー、シリコーン系ポリマー、ポリエステル、ポリウレタン、ポリアミド、ポリビニルエーテル、酢酸ビニル/塩化ビニルコポリマー、変性ポリオレフィン、エポキシ系、フッ素系、天然ゴム、合成ゴム等のゴム系等のポリマーをベースポリマーとするものを適宜に選択して用いることができる。特に、光学的透明性に優れ、適度な濡れ性、凝集性および接着性等の粘着特性を示し、耐候性や耐熱性等にも優れるという点から、ベースポリマーとしてアクリル系ポリマーを含有するアクリル系粘着剤が好ましく用いられる。
上記の粘着剤組成物溶液を適宜の支持体上に塗布・乾燥することにより、粘着シートが得られる。粘着シートの形成方法としては、各種方法が用いられる。具体的には、例えば、ロールコート、キスロールコート、グラビアコート、リバースコート、ロールブラッシュ、スプレーコート、ディップロールコート、バーコート、ナイフコート、エアーナイフコート、カーテンコート、リップコート、ダイコーター等による押出しコート法等の方法が挙げられる。これらの中でも、ダイコーターを使用することが好ましく、特にファウンテンダイ、スロットダイを用いるダイコーターを使用することがより好ましい。
本発明の粘着シートは、画像表示装置における、偏光板と前面透明部材との貼り合わせに好適に用いられる。図3に示す画像表示装置110は、液晶セルや有機ELセル等の画像表示セル90の視認側に偏光板10を備え、さらにその視認側に、前面透明部材70を備える。画像表示セル90の視認側と反対側には、偏光板等の光学フィルムやバックライト等の光学素子(不図示)が設けられていてもよい。前面透明部材70は、本発明の粘着シート20を介して、偏光板10と貼り合せられている。
偏光板10は、偏光子11を含む。偏光子11は、ヨウ素を含有するポリビニルアルコール系フィルムである。偏光子に適用されるポリビニルアルコール系フィルムの材料としては、ポリビニルアルコールまたはその誘導体が用いられる。ポリビニルアルコールの誘導体としては、ポリビニルホルマール、ポリビニルアセタール等が挙げられる他、エチレン、プロピレン等のオレフィン、アクリル酸、メタクリル酸、クロトン酸等の不飽和カルボン酸そのアルキルエステル、アクリルアミド等で変性したものが挙げられる。ポリビニルアルコールは、重合度が1000〜10000程度、ケン化度が80〜100モル%程度のものが一般に用いられる。
前面透明部材70としては、前面透明板(ウインドウ層)やタッチパネル等が挙げられる。前面透明板としては、適宜の機械強度および厚みを有する透明板が用いられる。このような透明板としては、例えばアクリル系樹脂やポリカーボネート系樹脂のような透明樹脂板、あるいはガラス板等が用いられる。タッチパネルとしては、抵抗膜方式、静電容量方式、光学方式、超音波方式等、任意の方式のタッチパネルが用いられる。
偏光板10と画像表示セル90との貼り合わせに用いられるセル側粘着シート30は特に限定されない。粘着シート30の粘着剤としては、アクリル系ポリマー、シリコーン系ポリマー、ポリエステル、ポリウレタン、ポリアミド、ポリビニルエーテル、酢酸ビニル/塩化ビニルコポリマー、変性ポリオレフィン、エポキシ系、フッ素系、天然ゴム、合成ゴム等のゴム系等のポリマーをベースポリマーとするものを適宜に選択して用いることができる。特に、光学的透明性に優れ、適度な濡れ性、凝集性および接着性等の粘着特性を示し、耐候性や耐熱性等にも優れるという点からは、アクリル系粘着剤が好ましく用いられる。
画像表示装置の形成における光学部材の貼り合せの順序は特に限定されない。例えば、画像表示セル90と、偏光板10とを、セル側粘着シート30を介して貼り合わせて画像表示パネルを形成した後、視認側粘着シート20(本発明の粘着シート)を介して、画像表示パネル表面の偏光板10と前面透明部材70とを貼り合わせが行われる。画像表示セル90と偏光板10との貼り合わせの前に、前面透明部材70と偏光板10との貼り合わせを先に行ってもよい。また、両者の貼り合せを同時に行うこともできる。
本発明の粘着シートを用いて画像表示装置を形成する場合、粘着シートと偏光板とが積層した粘着剤層付き偏光板を準備しておき、粘着剤層付き偏光板の粘着シートと前面透明部材とを貼り合わせてもよい。図2は、偏光板10の一方の面に視認側粘着シート20を備え、偏光板10の他方の面にセル側粘着シート30を備える両面粘着剤層付き偏光板の一形態を模式的に表す断面図である。粘着シート20,30の表面には、保護シート45,46が剥離可能に貼着されている。両面粘着剤層付き偏光板100は、視認側粘着シート20が視認側の前面透明板との貼り合わせに用いられ、セル側粘着剤シート30が液晶セル等との貼り合わせに用いられる。
偏光板10上に粘着シート20,30を付設する方法としては、例えば、粘着剤組成物を剥離処理した基材等に塗布して、必要に応じて乾燥や硬化処理を行って粘着シートを形成した後に、偏光板10上に転写する方法;または偏光板10に粘着剤組成物を塗布し、必要に応じて偏光板上で乾燥や硬化処理を行って、粘着剤層を偏光板上に形成する方法、等が挙げられる。
(偏光板の水分量)
偏光板を温度23℃湿度55%の雰囲気下で3日間静置して状態調整を行った後、10cm角のサイズに切り出して、初期重量m0を測定し、120℃で2時間乾燥後の乾燥重量m1を求めた。下記式により、単位面積当たりの水分量(g/cm2)を算出した。
水分量=(m1−m0)/試料面積
JIS Z0208の透湿度試験(カップ法)に準拠して、温度40℃、湿度90%の雰囲気中で測定した。
両面にセパレータが付設された粘着シートを、温度23℃湿度55%の雰囲気下で3日間静置して状態調整を行ったものを試料として用いた。状態調整後の試料を10cm2(1cm×5cmのサイズの試料2枚)に切り出し、粘着シートからセパレータを剥離し、アルミニウム箔に貼り合せて秤量した後、加熱気化装置(三菱化学アナリテック VA−200型)を備える水分計(三菱化学アナリテック CA−200型)を用い、カールフィッシャー電量滴定法により、下記の条件で、水分率を測定した。
陽極液:アクアミクロンAKX(三菱化学製)
陰極液:アクアミクロンCXU(三菱化学製)
加熱気化温度:150℃
水分率の測定と同様に状態調整を行った粘着シートを試料として用いた。粘着シートの一方の面のセパレータを剥離して、厚み25μmのトリアセチルセルロースフィルム(透湿度:1070g/m2・24h)に貼り合せた後、他方の面のセパレータを剥離し、JIS Z0208の透湿度試験(カップ法)に準拠して、温度40℃、湿度90%の雰囲気中で測定した。なお、ここで得られた透湿度は、トリアセチルセルロースフィルムと粘着シートとの積層体の透湿度であるが、トリアセチルセルロースフィルムの透湿度が粘着シートの透湿度よりも十分に大きいため、積層体の透湿度=粘着シートの透湿度とみなした。
<粘着シートA〜G>
(プレポリマーの重合)
温度計、攪拌機、還流冷却管および窒素ガス導入管を備えたセパラブルフラスコに、表1に示す組成のモノマー(合計100重量部)、および光重合開始剤として0.1重量部の2,2−ジメトキシ−1,2−ジフェニルエタン−1−オン(BASF製、商品名「イルガキュア651」)を投入した後、窒素ガスを流し、攪拌しながら約1時間窒素置換を行った。その後、窒素雰囲気下で、5mW/cm2のUVAを照射して重合を行い、プレポリマー組成物を調製した。重合時間は、プレポリマーの重合率が5〜15%になるように調整した。なお、表1において、各成分は以下の略称により記載されている。
2EHA: 2−エチルヘキシルアクリレート
ISA: イソステアリルアクリレート
LA: ラウリルアクリレート
HEA: ヒドロキシエチルアクリレート
NVP: N−ビニルピロリドン
AA: アクリル酸
上記で得られたアクリル系プレポリマー組成物(全量を100重量部とする)に、多官能モノマーとして1,6‐ヘキサンジオールジアクリレート(新中村工業化学製、商品名「NKエステル A−HD−N」)0.1重量部、シランカップリング剤として3−グリシドキシプロピルトリメトキシシラン(信越シリコーン製、商品名「KBM−403」)0.3重量部、および光重合開始剤として0.1重量部のイルガキュア651を加えて、光重合性の粘着剤組成物を調製した。
離型処理されたPETフィルム(軽剥離セパレータ)上に、厚みが200μmとなるように上記の粘着剤組成物を塗布し、塗布層上に別のPETフィルム(重剥離セパレータ)を積層貼着した。その後、セパレータ上から、5mW/cm2のUVA(積算光量3000mJ/cm2)を照射して重合を進行させ、両面にセパレータが付設された粘着シートを得た。
粘着シート作製時の塗布厚みを、それぞれ100μmおよび500μmに変更したこと以外は、粘着シートBの作製と同様にして、粘着シートを得た。
(ベースポリマーの重合)
温度計、攪拌機、還流冷却管および窒素ガス導入管を備えたセパラブルフラスコに、ブチルアクリレートを97重量部、アクリル酸を3重量部、重合開始剤としてAIBN0.2重量部、および酢酸エチル233部を投入した後、窒素ガスを流し、攪拌しながら約1時間窒素置換を行った。その後、60℃にフラスコを加熱し、7時間反応させて、重量平均分子量110万のアクリル系ポリマーを得た。
上記で得られたアクリル系ポリマー溶液に、ポリマーの固形分100重量部に対して、下記の化合物を配合して、粘接着剤組成物溶液を調製した。
イソシアネート系架橋剤:トリメチロールプロパントリレンジイソシアネート(日本ポリウレタン工業(株)製「コロネートL」)0.8重量部
シランカップリング剤:3−グリシドキシプロピルトリメトキシシラン(信越シリコーン製、商品名「KBM−403」)0.1重量部
ヨウ素が含浸された厚み25μmの延伸ポリビニルアルコールフィルムからなる偏光子の両面に、透明保護フィルムが貼り合せられた偏光板(偏光度:99.995%、水分量:5.1g/m2)を用いた。偏光子の一方の面(セル側)の透明保護フィルムは、厚み30μmのアクリル系フィルム(透湿度:120g/m2・24h)であり、他方の面(視認側)の透明保護フィルムは厚み40μmのトリアセチルセルロースフィルム(透湿度:984g/m2・24h)であった。
上記偏光板のセル側の面にセル側粘着シートを貼り合せ、視認側の面に上記粘着シートA〜Iのそれぞれを貼り合せ、両面粘着剤層付き偏光板A〜Iを得た。偏光板と粘着シートの貼り合せに際しては、粘着シートの表面から軽剥離セパレータを剥離して、粘着シートの露出面に偏光板を貼り合わせた。
上記の両面粘着剤層付き偏光板A〜Iのそれぞれを200mm×140mmのサイズにカットし、セル側粘着シート上のセパレータを剥離した後、ハンドローラを用いて、粘着シートの露出面をガラス板(280mm×180mm×0.7mm)上に貼り合わせた。その後、視認側粘着シート上のセパレータを剥離し、粘着シートの露出面にガラス板(280mm×180mm×0.7mm)を載置して、真空圧着装置で圧着して貼り合せを行った(装置内圧力:30Pa、貼り合わせ面圧:0.3MPa、貼り合わせ時間:5秒)。その後、オートクレーブ処理(温度:50℃、圧力:0.5MPa、時間:15分)を行った。このようにして、偏光板の両面に、粘着シートを介してガラス板が貼り合せられた評価用パネルを得た。
評価用パネルの面内中心部の単体透過率を測定した。透過率は、JlS Z8701の2度視野(C光源)により視感度補正を行ったY値である。単体透過率を測定後の評価用パネルを、温度95℃の熱風オーブン内に投入して加熱試験を実施し、300時間後の直交透過率および500時間後の単体透過率を測定した。直交透過率は、評価用パネルに、別の偏光板(偏光度:99.995%)を配置して測定した。
各粘着シートのベースポリマー組成、粘着シートの厚み、ならびに評価用パネルの加熱試験後の単体透過率変化および直交透過率の評価結果を表1に示す。単体透過率は、500時間の加熱試験後の透過率の低下率が2%未満のものを○、2%以上5%未満のものを△、5%以上のものを×とした。直交透過率は、300時間の加熱試験後の値が0.03%未満のものを○、0.03%以上0.08%未満のものを△、0.08%以上のものを×とした。
11 :偏光子
12,13:透明保護フィルム
20,30:粘着シート
41,42,45,46:保護シート
70 :前面透明部材
71 :透明板
72 :印刷段差
90 :画像表示セル
100 :粘着剤層付き偏光板
110 :画像表示装置
Claims (8)
- 画像表示装置の視認側に配置される透明部材と偏光板との貼り合せに用いられる粘着シートであって、
厚みがD、透湿度がX、水分率がYであり、
XD2が2.7×10−6g/24h以上、Y/Dが47m−1以下であり、
粘着シートを構成する粘着剤組成物のベースポリマーが、モノマーユニットとして、有機酸モノマー成分を実質的に含有しない、粘着シート。 - 厚みDが、50〜500μmである、請求項1に記載の粘着シート。
- 粘着シートを構成する粘着剤組成物が、アクリル系ベースポリマーを50重量%以上含有する、請求項1または2に記載の粘着シート。
- 前記アクリル系ベースポリマーが、モノマーユニットとしてヒドロキシ基含有モノマーおよび窒素含有モノマーを含有し、
構成モノマー成分全量に対する前記ヒドロキシ基含有モノマーと前記窒素含有モノマーの含有量の合計が、10〜45重量%である、請求項3に記載の粘着シート。 - ヨウ素を含有するポリビニルアルコール系フィルムからなる偏光子を含む偏光板の一方の主面に、請求項1〜4のいずれか1項に記載の粘着シートを備える、粘着剤層付き偏光板。
- 前記偏光板は、前記偏光子の前記粘着シートの付設面側に透明保護フィルムを備え、
前記透明保護フィルムの透湿度が、300g/m2・24h以上である、請求項5に記載の粘着剤層付き偏光板。 - 前記偏光板の他方の主面に、厚みが35μm以下の粘着シートを備える、請求項5または6に記載の粘着剤層付き偏光板。
- 画像表示セルの視認側表面に、ヨウ素を含有するポリビニルアルコール系フィルムからなる偏光子を含む偏光板を備え、
前記偏光板の視認側に、請求項1〜4のいずれか1項に記載の粘着シートを介して前面透明部材が貼り合わせられている、画像表示装置。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015202187A JP6944759B2 (ja) | 2015-10-13 | 2015-10-13 | 粘着剤層付き偏光板 |
KR1020160129686A KR102197870B1 (ko) | 2015-10-13 | 2016-10-07 | 점착 시트, 점착제층을 갖는 편광판 및 화상 표시 장치 |
US15/287,921 US20170101553A1 (en) | 2015-10-13 | 2016-10-07 | Pressure sensitive adhesive sheet, polarizing plate with pressure sensitive adhesive, and image display device |
CN201610885224.4A CN106867418B (zh) | 2015-10-13 | 2016-10-10 | 粘合片、带有粘合剂层的偏振板和图像显示装置 |
TW105132702A TWI725061B (zh) | 2015-10-13 | 2016-10-11 | 黏著片材、附有黏著劑層之偏光板、及圖像顯示裝置 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015202187A JP6944759B2 (ja) | 2015-10-13 | 2015-10-13 | 粘着剤層付き偏光板 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017075998A true JP2017075998A (ja) | 2017-04-20 |
JP6944759B2 JP6944759B2 (ja) | 2021-10-06 |
Family
ID=58499623
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015202187A Active JP6944759B2 (ja) | 2015-10-13 | 2015-10-13 | 粘着剤層付き偏光板 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20170101553A1 (ja) |
JP (1) | JP6944759B2 (ja) |
KR (1) | KR102197870B1 (ja) |
CN (1) | CN106867418B (ja) |
TW (1) | TWI725061B (ja) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018221320A1 (ja) * | 2017-06-02 | 2018-12-06 | 日東電工株式会社 | 偏光フィルムおよび画像表示装置 |
WO2018221323A1 (ja) * | 2017-06-02 | 2018-12-06 | 日東電工株式会社 | 偏光フィルムおよび画像表示装置 |
JP2018202621A (ja) * | 2017-05-30 | 2018-12-27 | バンドー化学株式会社 | 積層体、光学透明粘着シート、及び、積層体の製造方法 |
JP2019035061A (ja) * | 2017-08-21 | 2019-03-07 | リンテック株式会社 | 粘着シートおよび表示体 |
JP2019101429A (ja) * | 2018-11-21 | 2019-06-24 | 住友化学株式会社 | 光学積層体及びその製造方法 |
JP2019139007A (ja) * | 2018-02-08 | 2019-08-22 | 日東電工株式会社 | 粘着剤付き偏光板および画像表示装置 |
JP2020067612A (ja) * | 2018-10-26 | 2020-04-30 | 住友化学株式会社 | 偏光板および表示装置 |
WO2020116074A1 (ja) * | 2018-12-07 | 2020-06-11 | 住友化学株式会社 | 偏光板および表示装置 |
JP2020128470A (ja) * | 2019-02-07 | 2020-08-27 | 日東電工株式会社 | 粘着シート、光学積層体、および画像表示装置 |
JP2021033159A (ja) * | 2019-08-28 | 2021-03-01 | 日東電工株式会社 | 粘着剤層付偏光フィルム積層体、及び、該粘着剤層付偏光フィルム積層体が使用される光学表示パネル |
JP2021033164A (ja) * | 2019-08-28 | 2021-03-01 | 日東電工株式会社 | 粘着剤層付偏光フィルム積層体、及び、該粘着剤層付偏光フィルム積層体が使用される光学表示パネル |
WO2021166659A1 (ja) | 2020-02-17 | 2021-08-26 | 日東電工株式会社 | 粘着剤層付き偏光フィルム、および画像表示装置 |
WO2022149585A1 (ja) * | 2021-01-08 | 2022-07-14 | コニカミノルタ株式会社 | 積層フィルム、積層体、偏光板、偏光板ロールの製造方法及び表示装置 |
WO2022210375A1 (ja) * | 2021-03-29 | 2022-10-06 | 住友化学株式会社 | 基材レス両面粘着シートの製造方法 |
WO2022239508A1 (ja) * | 2021-05-10 | 2022-11-17 | 住友化学株式会社 | 光学積層体 |
KR20230055942A (ko) | 2021-10-19 | 2023-04-26 | 닛토덴코 가부시키가이샤 | 이접착 필름, 편광판, 점착제가 부착된 편광판, 및 화상 표시 장치 |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105974635A (zh) * | 2016-07-18 | 2016-09-28 | 京东方科技集团股份有限公司 | 遮光胶带、应用该遮光胶带的显示装置及其制备方法 |
JP6860666B2 (ja) * | 2017-06-28 | 2021-04-21 | 日東電工株式会社 | 偏光板 |
WO2019103002A1 (ja) * | 2017-11-24 | 2019-05-31 | 日東電工株式会社 | 偏光子および偏光板 |
KR102126057B1 (ko) * | 2017-12-28 | 2020-06-23 | 삼성에스디아이 주식회사 | 편광판 및 이를 포함하는 광학표시장치 |
KR20200111741A (ko) | 2018-02-28 | 2020-09-29 | 후지필름 가부시키가이샤 | 적층체, 유기 전계 발광 장치, 액정 표시 장치 |
GB2574793B (en) * | 2018-05-01 | 2022-09-28 | Flexenable Ltd | Organic liquid crystal display device with one or more oxygen permeable films |
CN114966935A (zh) * | 2018-11-12 | 2022-08-30 | 日东电工株式会社 | 偏振膜、层叠偏振膜、图像显示面板、以及图像显示装置 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100086705A1 (en) * | 2008-10-03 | 2010-04-08 | 3M Innovative Properties Company | Cloud point-resistant adhesives and laminates |
WO2011111575A1 (ja) * | 2010-03-10 | 2011-09-15 | 日東電工株式会社 | 光学用粘着シート |
JP2014102353A (ja) * | 2012-11-19 | 2014-06-05 | Nitto Denko Corp | 偏光板および画像表示装置、ならびにそれらの製造方法 |
JP2015101720A (ja) * | 2013-11-28 | 2015-06-04 | 日東電工株式会社 | 板の剥離方法 |
WO2015084960A1 (en) * | 2013-12-04 | 2015-06-11 | 3M Innovative Properties Company | Optically clear adhesives for durable plastic bonding |
CN107216819A (zh) * | 2017-06-01 | 2017-09-29 | 京东方科技集团股份有限公司 | 一种胶膜及其制备方法、柔性显示模组 |
US20180157350A1 (en) * | 2015-05-18 | 2018-06-07 | Dongwoo Fine-Chem Co., Ltd. | Display device |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5119920B2 (ja) * | 2005-06-29 | 2013-01-16 | コニカミノルタアドバンストレイヤー株式会社 | セルロースエステルフィルム、それを用いた横電界駆動式表示装置用偏光板及び横電界駆動式表示装置 |
JP5010994B2 (ja) * | 2006-06-28 | 2012-08-29 | 日東電工株式会社 | 粘着型光学フィルムおよび画像表示装置 |
JP2009157361A (ja) * | 2007-12-06 | 2009-07-16 | Nitto Denko Corp | 偏光板及び画像表示装置 |
JP4938632B2 (ja) * | 2007-12-07 | 2012-05-23 | 日東電工株式会社 | 液晶パネル及び液晶表示装置 |
JP4870115B2 (ja) * | 2008-05-09 | 2012-02-08 | 日東電工株式会社 | 液晶パネルのガラス基板貼着用の粘着型光学フィルム、液晶表示装置 |
JP5518436B2 (ja) * | 2009-11-09 | 2014-06-11 | 日東電工株式会社 | 光学用粘着シート |
JP5758647B2 (ja) * | 2011-02-17 | 2015-08-05 | 日東電工株式会社 | 光学用粘着シート |
JP2012237965A (ja) | 2011-04-27 | 2012-12-06 | Nitto Denko Corp | 粘着剤層、光学フィルムおよび画像表示装置 |
JP5851166B2 (ja) * | 2011-09-20 | 2016-02-03 | 藤森工業株式会社 | 粘着剤組成物及び粘着フィルム |
JP5426715B2 (ja) * | 2011-09-30 | 2014-02-26 | 日東電工株式会社 | 粘着剤、粘着剤層、および粘着シート |
JP6093624B2 (ja) * | 2012-05-24 | 2017-03-08 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着剤層付光学フィルム、及び、画像表示装置 |
JP6073173B2 (ja) * | 2013-03-29 | 2017-02-01 | 日東電工株式会社 | 粘着剤およびそれを用いた画像表示装置 |
JP6002701B2 (ja) * | 2014-01-27 | 2016-10-05 | 藤森工業株式会社 | 粘着剤層、及び粘着フィルム |
-
2015
- 2015-10-13 JP JP2015202187A patent/JP6944759B2/ja active Active
-
2016
- 2016-10-07 US US15/287,921 patent/US20170101553A1/en not_active Abandoned
- 2016-10-07 KR KR1020160129686A patent/KR102197870B1/ko active IP Right Grant
- 2016-10-10 CN CN201610885224.4A patent/CN106867418B/zh active Active
- 2016-10-11 TW TW105132702A patent/TWI725061B/zh active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100086705A1 (en) * | 2008-10-03 | 2010-04-08 | 3M Innovative Properties Company | Cloud point-resistant adhesives and laminates |
WO2011111575A1 (ja) * | 2010-03-10 | 2011-09-15 | 日東電工株式会社 | 光学用粘着シート |
JP2014102353A (ja) * | 2012-11-19 | 2014-06-05 | Nitto Denko Corp | 偏光板および画像表示装置、ならびにそれらの製造方法 |
JP2015101720A (ja) * | 2013-11-28 | 2015-06-04 | 日東電工株式会社 | 板の剥離方法 |
WO2015084960A1 (en) * | 2013-12-04 | 2015-06-11 | 3M Innovative Properties Company | Optically clear adhesives for durable plastic bonding |
JP2017507193A (ja) * | 2013-12-04 | 2017-03-16 | スリーエム イノベイティブ プロパティズ カンパニー | 耐久性プラスチック接合用の光学的に透明な接着剤 |
US20180157350A1 (en) * | 2015-05-18 | 2018-06-07 | Dongwoo Fine-Chem Co., Ltd. | Display device |
CN107216819A (zh) * | 2017-06-01 | 2017-09-29 | 京东方科技集团股份有限公司 | 一种胶膜及其制备方法、柔性显示模组 |
Cited By (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018202621A (ja) * | 2017-05-30 | 2018-12-27 | バンドー化学株式会社 | 積層体、光学透明粘着シート、及び、積層体の製造方法 |
CN110730916A (zh) * | 2017-06-02 | 2020-01-24 | 日东电工株式会社 | 偏振膜及图像显示装置 |
WO2018221323A1 (ja) * | 2017-06-02 | 2018-12-06 | 日東電工株式会社 | 偏光フィルムおよび画像表示装置 |
JP2018205490A (ja) * | 2017-06-02 | 2018-12-27 | 日東電工株式会社 | 偏光フィルムおよび画像表示装置 |
JP2018205498A (ja) * | 2017-06-02 | 2018-12-27 | 日東電工株式会社 | 偏光フィルムおよび画像表示装置 |
WO2018221320A1 (ja) * | 2017-06-02 | 2018-12-06 | 日東電工株式会社 | 偏光フィルムおよび画像表示装置 |
CN110730916B (zh) * | 2017-06-02 | 2022-07-26 | 日东电工株式会社 | 偏振膜及图像显示装置 |
TWI709490B (zh) * | 2017-06-02 | 2020-11-11 | 日商日東電工股份有限公司 | 偏光薄膜及影像顯示裝置 |
TWI671556B (zh) * | 2017-06-02 | 2019-09-11 | 日商日東電工股份有限公司 | 偏光薄膜及影像顯示裝置 |
JP7170387B2 (ja) | 2017-08-21 | 2022-11-14 | リンテック株式会社 | 粘着シートおよび表示体 |
JP2019035061A (ja) * | 2017-08-21 | 2019-03-07 | リンテック株式会社 | 粘着シートおよび表示体 |
JP2019139007A (ja) * | 2018-02-08 | 2019-08-22 | 日東電工株式会社 | 粘着剤付き偏光板および画像表示装置 |
JP7236217B2 (ja) | 2018-02-08 | 2023-03-09 | 日東電工株式会社 | 粘着剤付き偏光板 |
JP2022189836A (ja) * | 2018-02-08 | 2022-12-22 | 日東電工株式会社 | 粘着剤付き偏光板および画像表示装置 |
JP7331347B2 (ja) | 2018-10-26 | 2023-08-23 | 住友化学株式会社 | 偏光板および表示装置 |
JP2020067612A (ja) * | 2018-10-26 | 2020-04-30 | 住友化学株式会社 | 偏光板および表示装置 |
JP2019101429A (ja) * | 2018-11-21 | 2019-06-24 | 住友化学株式会社 | 光学積層体及びその製造方法 |
WO2020116074A1 (ja) * | 2018-12-07 | 2020-06-11 | 住友化学株式会社 | 偏光板および表示装置 |
CN113167960A (zh) * | 2018-12-07 | 2021-07-23 | 住友化学株式会社 | 偏振板及显示装置 |
JP2020128470A (ja) * | 2019-02-07 | 2020-08-27 | 日東電工株式会社 | 粘着シート、光学積層体、および画像表示装置 |
JP7365772B2 (ja) | 2019-02-07 | 2023-10-20 | 日東電工株式会社 | 粘着シート、光学積層体、および画像表示装置 |
JP2021033159A (ja) * | 2019-08-28 | 2021-03-01 | 日東電工株式会社 | 粘着剤層付偏光フィルム積層体、及び、該粘着剤層付偏光フィルム積層体が使用される光学表示パネル |
WO2021039583A1 (ja) * | 2019-08-28 | 2021-03-04 | 日東電工株式会社 | 粘着剤層付偏光フィルム積層体、及び、該粘着剤層付偏光フィルム積層体が使用される光学表示パネル |
WO2021039585A1 (ja) * | 2019-08-28 | 2021-03-04 | 日東電工株式会社 | 粘着剤層付偏光フィルム積層体、及び、該粘着剤層付偏光フィルム積層体が使用される光学表示パネル |
JP2021033164A (ja) * | 2019-08-28 | 2021-03-01 | 日東電工株式会社 | 粘着剤層付偏光フィルム積層体、及び、該粘着剤層付偏光フィルム積層体が使用される光学表示パネル |
JP7309521B2 (ja) | 2019-08-28 | 2023-07-18 | 日東電工株式会社 | 粘着剤層付偏光フィルム積層体、及び、該粘着剤層付偏光フィルム積層体が使用される光学表示パネル |
JP7309522B2 (ja) | 2019-08-28 | 2023-07-18 | 日東電工株式会社 | 粘着剤層付偏光フィルム積層体、及び、該粘着剤層付偏光フィルム積層体が使用される光学表示パネル |
KR20220130806A (ko) | 2020-02-17 | 2022-09-27 | 닛토덴코 가부시키가이샤 | 점착제층을 구비한 편광 필름, 및 화상 표시 장치 |
WO2021166659A1 (ja) | 2020-02-17 | 2021-08-26 | 日東電工株式会社 | 粘着剤層付き偏光フィルム、および画像表示装置 |
WO2022149585A1 (ja) * | 2021-01-08 | 2022-07-14 | コニカミノルタ株式会社 | 積層フィルム、積層体、偏光板、偏光板ロールの製造方法及び表示装置 |
WO2022210375A1 (ja) * | 2021-03-29 | 2022-10-06 | 住友化学株式会社 | 基材レス両面粘着シートの製造方法 |
WO2022239508A1 (ja) * | 2021-05-10 | 2022-11-17 | 住友化学株式会社 | 光学積層体 |
KR20230055942A (ko) | 2021-10-19 | 2023-04-26 | 닛토덴코 가부시키가이샤 | 이접착 필름, 편광판, 점착제가 부착된 편광판, 및 화상 표시 장치 |
Also Published As
Publication number | Publication date |
---|---|
CN106867418A (zh) | 2017-06-20 |
US20170101553A1 (en) | 2017-04-13 |
CN106867418B (zh) | 2021-07-20 |
TW201726850A (zh) | 2017-08-01 |
JP6944759B2 (ja) | 2021-10-06 |
KR20170043450A (ko) | 2017-04-21 |
KR102197870B1 (ko) | 2021-01-05 |
TWI725061B (zh) | 2021-04-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI725061B (zh) | 黏著片材、附有黏著劑層之偏光板、及圖像顯示裝置 | |
KR102309118B1 (ko) | 양면 점착제 부착 광학 필름 및 그것을 사용한 화상 표시 장치의 제조 방법, 그리고 양면 점착제 부착 광학 필름의 컬 억제 방법 | |
JP6104706B2 (ja) | 粘着シートおよび積層体 | |
KR102084282B1 (ko) | 점착제 부착 광학 필름 및 그 제조 방법, 그리고 화상 표시 장치의 제조 방법 | |
US20160237319A1 (en) | Optical film with pressure sensitive adhesive and image display device | |
KR102444565B1 (ko) | 점착 시트, 점착제를 갖는 광학 필름, 및 화상 표시 장치의 제조 방법 | |
US20150346408A1 (en) | Optical film with pressure sensitive adhesive on both sides and method for producing image display device using same | |
KR101488274B1 (ko) | 적층체의 제조 방법 및 적층체 | |
JP7236217B2 (ja) | 粘着剤付き偏光板 | |
EP2910616A1 (en) | Transparent double-sided adhesive sheet and image display device using same | |
JP6073173B2 (ja) | 粘着剤およびそれを用いた画像表示装置 | |
KR20090048363A (ko) | 점착제 조성물 및 광학필름 | |
JP6803951B2 (ja) | 両面粘着剤付き光学フィルム、およびそれを用いた画像表示装置の製造方法、ならびに両面粘着剤付き光学フィルムのカール抑制方法 | |
KR20220130806A (ko) | 점착제층을 구비한 편광 필름, 및 화상 표시 장치 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20180824 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20190614 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190618 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190813 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190820 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20200204 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200401 |
|
RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20200731 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20200923 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20201124 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210511 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20210817 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20210913 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6944759 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |