JP2016511510A - 架橋ポリマー電解質 - Google Patents
架橋ポリマー電解質 Download PDFInfo
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- JP2016511510A JP2016511510A JP2015557979A JP2015557979A JP2016511510A JP 2016511510 A JP2016511510 A JP 2016511510A JP 2015557979 A JP2015557979 A JP 2015557979A JP 2015557979 A JP2015557979 A JP 2015557979A JP 2016511510 A JP2016511510 A JP 2016511510A
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- 229920006037 cross link polymer Polymers 0.000 title claims abstract description 24
- 239000005518 polymer electrolyte Substances 0.000 title claims description 10
- 239000003792 electrolyte Substances 0.000 claims abstract description 70
- 229920000642 polymer Polymers 0.000 claims abstract description 46
- 239000002131 composite material Substances 0.000 claims abstract description 31
- 150000003839 salts Chemical class 0.000 claims abstract description 28
- 239000002243 precursor Substances 0.000 claims abstract description 24
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 21
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 15
- 125000000524 functional group Chemical group 0.000 claims abstract description 9
- 239000002608 ionic liquid Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 24
- 229920006250 telechelic polymer Polymers 0.000 claims description 24
- 238000004132 cross linking Methods 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 18
- 239000002105 nanoparticle Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 6
- 238000006552 photochemical reaction Methods 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 4
- IVRMZWNICZWHMI-UHFFFAOYSA-N azide group Chemical group [N-]=[N+]=[N-] IVRMZWNICZWHMI-UHFFFAOYSA-N 0.000 claims 4
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 210000004027 cell Anatomy 0.000 description 34
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 30
- 238000006243 chemical reaction Methods 0.000 description 9
- 229910004298 SiO 2 Inorganic materials 0.000 description 8
- 229910001416 lithium ion Inorganic materials 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 229910003002 lithium salt Inorganic materials 0.000 description 7
- 159000000002 lithium salts Chemical class 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 6
- -1 lithium cations Chemical class 0.000 description 6
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 229910010707 LiFePO 4 Inorganic materials 0.000 description 4
- 230000001351 cycling effect Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- HLNRRPIYRBBHSQ-UHFFFAOYSA-N 1-propylpyrrolidine Chemical compound CCCN1CCCC1 HLNRRPIYRBBHSQ-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- 238000002411 thermogravimetry Methods 0.000 description 3
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- LRESCJAINPKJTO-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-ethyl-3-methylimidazol-3-ium Chemical compound CCN1C=C[N+](C)=C1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F LRESCJAINPKJTO-UHFFFAOYSA-N 0.000 description 2
- 238000007385 chemical modification Methods 0.000 description 2
- 210000001787 dendrite Anatomy 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 230000037427 ion transport Effects 0.000 description 2
- VDVLPSWVDYJFRW-UHFFFAOYSA-N lithium;bis(fluorosulfonyl)azanide Chemical compound [Li+].FS(=O)(=O)[N-]S(F)(=O)=O VDVLPSWVDYJFRW-UHFFFAOYSA-N 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000006303 photolysis reaction Methods 0.000 description 2
- 230000015843 photosynthesis, light reaction Effects 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- VTDIWMPYBAVEDY-UHFFFAOYSA-N 1-propylpiperidine Chemical compound CCCN1CCCCC1 VTDIWMPYBAVEDY-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- YXHKONLOYHBTNS-UHFFFAOYSA-N Diazomethane Chemical group C=[N+]=[N-] YXHKONLOYHBTNS-UHFFFAOYSA-N 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 229910010238 LiAlCl 4 Inorganic materials 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910013188 LiBOB Inorganic materials 0.000 description 1
- 229910010941 LiFSI Inorganic materials 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- 229910012305 LiPON Inorganic materials 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000011243 crosslinked material Substances 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- 229920001746 electroactive polymer Polymers 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 230000000155 isotopic effect Effects 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 1
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 1
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 1
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
- 229910001537 lithium tetrachloroaluminate Inorganic materials 0.000 description 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
- 208000020960 lithium transport Diseases 0.000 description 1
- NBVMCMSJGNOOCF-UHFFFAOYSA-N lithium;2,2,2-trifluoroacetic acid Chemical compound [Li].OC(=O)C(F)(F)F NBVMCMSJGNOOCF-UHFFFAOYSA-N 0.000 description 1
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- MPDOUGUGIVBSGZ-UHFFFAOYSA-N n-(cyclobutylmethyl)-3-(trifluoromethyl)aniline Chemical compound FC(F)(F)C1=CC=CC(NCC2CCC2)=C1 MPDOUGUGIVBSGZ-UHFFFAOYSA-N 0.000 description 1
- KTQDYGVEEFGIIL-UHFFFAOYSA-N n-fluorosulfonylsulfamoyl fluoride Chemical compound FS(=O)(=O)NS(F)(=O)=O KTQDYGVEEFGIIL-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000002186 photoactivation Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- JFZKOODUSFUFIZ-UHFFFAOYSA-N trifluoro phosphate Chemical compound FOP(=O)(OF)OF JFZKOODUSFUFIZ-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Conductive Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Primary Cells (AREA)
Abstract
Description
(1)「ワンステップ」プロセスにおける光化学反応による架橋ポリマー複合電解質の調製
Claims (20)
- 少なくとも二つの光活性化することができる端部官能基および約1,000と1,000,000ダルトン(Da)との間の架橋前分子量を有するテレケリック前駆体ポリマーから形成される架橋ポリマー;およびリチウム(Li)塩を含む、複合電解質。
- さらに、イオン液体溶媒が含まれる、請求項1の複合電解質。
- テレケリック前駆体ポリマーは実質同じ分子量および組成をもつ、請求項1の複合電解質。
- テレケリック前駆体ポリマーは約1,000および50,000Daの間の分子量をもつ、請求項1の複合電解質。
- 架橋ポリマーは比較的一定のナノ細孔構造を形成する、請求項1の複合電解質。
- テレケリック前駆体ポリマーはアジド官能基をもつ、請求項1の複合電解質。
- 架橋前混合物は室温でペーストを形成する、請求項1の複合電解質。
- さらに、少なくとも一次元が<1μmであるようなサイズの酸化物ナノ粒子が含まれる、請求項1の複合電解質。
- 電解質を作成するにあたり、次のステップ:
リチウム(Li)塩およびイオン液体の溶液を、少なくとも二つの光活性化することができる端部官能基をもつテレケリック前駆体ポリマーが含まれる混合物に導入すること;および
光化学反応によって前駆体テレケリックポリマーから架橋ポリマーを形成すること
を含む、方法。 - 前駆体テレケリックポリマーはアジド官能基をもつ、請求項9の方法。
- 導入ステップに次いでペーストを形成するために加熱および均質化ステップが続けられる、請求項9の方法。
- 架橋ポリマー電解質を形成するステップには、さらに、光化学反応によって架橋ポリマーを形成するのに先立ち電極または導電性構造に前駆体混合物を配置することが含まれる、請求項9の方法。
- 導入ステップは光化学反応ステップ後に行われる、請求項9の方法。
- リチウム(Li)に適応する(accommodate)ことができるアノード;
カソード;および
約1,000および1,000,000ダルトンの間の分子量を有する少なくとも二つの光活性化することができる端部基を伴う前駆体テレケリックポリマーから形成される架橋ポリマーをもつ複合電解質
を備える、電気化学セル。 - 前駆体テレケリックポリマーにはさらに、末端部に少なくとも一つのアジド官能基が含まれる、請求項14の電気化学セル。
- 一以上の電気化学セルを囲むように形成されるハウジングを含み、ここで、
各電気化学セルは、リチウム(Li)が含まれるアノード;
カソード;および
約1,000および1,000,000ダルトンの間の分子量を有する少なくとも二つの光活性化することができる端部基を伴う前駆体テレケリックポリマーから形成される架橋ポリマーをもつ複合電解質
を含む、バッテリ。 - 電解質を作成するにあたり、次のステップ:
少なくとも二つの光活性化することができる端部基を有する前駆体テレケリックポリマーを用意すること;および
前駆体テレケリックポリマーをリチウム(Li)塩、イオン液体、および固形粒子の存在下で光化学的に反応させることによって架橋ポリマーを形成すること
を含む、方法。 - 前駆体テレケリックポリマーはアジド官能基をもつ、請求項17の方法。
- 前駆体テレケリックポリマーは別個の分子量をもつポリマー物質からブレンドされる、請求項17の方法。
- 固形粒子は、1ミクロン(μm)未満の少なくとも一次元をもつように寸法決めされる、請求項17の方法。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2013/026158 WO2014126570A2 (en) | 2013-02-14 | 2013-02-14 | Crosslinked polymer electrolyte |
Publications (2)
Publication Number | Publication Date |
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JP2016511510A true JP2016511510A (ja) | 2016-04-14 |
JP6290264B2 JP6290264B2 (ja) | 2018-03-07 |
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JP2015557979A Active JP6290264B2 (ja) | 2013-02-14 | 2013-02-14 | 架橋ポリマー電解質 |
Country Status (9)
Country | Link |
---|---|
US (1) | US10547082B2 (ja) |
EP (1) | EP2956978B1 (ja) |
JP (1) | JP6290264B2 (ja) |
KR (1) | KR102047388B1 (ja) |
CN (1) | CN104981930A (ja) |
BR (1) | BR112015019389A2 (ja) |
CA (1) | CA2900369C (ja) |
MX (1) | MX2015010155A (ja) |
WO (1) | WO2014126570A2 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022182011A1 (ko) * | 2021-02-26 | 2022-09-01 | 울산과학기술원 | 가교성 화합물, 이를 포함한 고체 전해질 형성용 조성물, 이를 이용한 고체 전해질 제조 방법, 고체 전해질 및 상기 고체 전해질을 포함한 전자 소자 |
KR20220122482A (ko) * | 2021-02-26 | 2022-09-02 | 울산과학기술원 | 가교성 화합물, 이를 포함한 고체 전해질 형성용 조성물, 이를 이용한 고체 전해질 제조 방법, 고체 전해질 및 상기 고체 전해질을 포함한 전자 소자 |
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US9331360B2 (en) | 2009-12-11 | 2016-05-03 | California Institute Of Technology | Fluoride ion battery electrolyte compositions |
US10615457B2 (en) * | 2015-02-25 | 2020-04-07 | Ses Holdings Pte. Ltd. | Electrolyte system for high voltage lithium ion battery |
KR101879503B1 (ko) | 2016-09-21 | 2018-07-18 | 주식회사 세븐킹에너지 | 이차 전지용 복합 고체 전해질 및 이의 제조방법 |
CN109037774B (zh) * | 2018-07-30 | 2020-10-09 | 哈尔滨工业大学无锡新材料研究院 | 一种适用于锂二次电池的交联聚合物电解质及其制备方法 |
KR20210039056A (ko) * | 2019-10-01 | 2021-04-09 | 현대자동차주식회사 | 이온 전도성 및 기계적 강도가 우수한 고분자 전해질 및 이의 제조방법 |
US11728547B2 (en) * | 2020-09-22 | 2023-08-15 | Apple Inc. | Polymer electrolyte lamination layer for lithium metal battery |
EP4303961A1 (fr) | 2022-07-04 | 2024-01-10 | The Swatch Group Research and Development Ltd | Composition polymerisable pour electrolyte polymere solide |
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WO2022182011A1 (ko) * | 2021-02-26 | 2022-09-01 | 울산과학기술원 | 가교성 화합물, 이를 포함한 고체 전해질 형성용 조성물, 이를 이용한 고체 전해질 제조 방법, 고체 전해질 및 상기 고체 전해질을 포함한 전자 소자 |
KR20220122482A (ko) * | 2021-02-26 | 2022-09-02 | 울산과학기술원 | 가교성 화합물, 이를 포함한 고체 전해질 형성용 조성물, 이를 이용한 고체 전해질 제조 방법, 고체 전해질 및 상기 고체 전해질을 포함한 전자 소자 |
KR102598254B1 (ko) | 2021-02-26 | 2023-11-06 | 울산과학기술원 | 가교성 화합물, 이를 포함한 고체 전해질 형성용 조성물, 이를 이용한 고체 전해질 제조 방법, 고체 전해질 및 상기 고체 전해질을 포함한 전자 소자 |
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JP6290264B2 (ja) | 2018-03-07 |
KR102047388B1 (ko) | 2019-11-21 |
EP2956978B1 (en) | 2021-08-25 |
MX2015010155A (es) | 2016-01-12 |
EP2956978A2 (en) | 2015-12-23 |
US10547082B2 (en) | 2020-01-28 |
CA2900369C (en) | 2020-04-14 |
CN104981930A (zh) | 2015-10-14 |
KR20150119885A (ko) | 2015-10-26 |
BR112015019389A2 (pt) | 2017-07-18 |
EP2956978A4 (en) | 2016-12-21 |
US20150380767A1 (en) | 2015-12-31 |
CA2900369A1 (en) | 2014-08-21 |
WO2014126570A2 (en) | 2014-08-21 |
WO2014126570A3 (en) | 2015-07-30 |
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