JP2016511208A - 副生成ガス、付随ガス、及び/又は生物ガスを利用する方法 - Google Patents
副生成ガス、付随ガス、及び/又は生物ガスを利用する方法 Download PDFInfo
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Abstract
Description
特許文献1(JP−56−8408)には、コークス炉ガス及びコンバーターガス(変換器ガス)をH2OとCOが3の割合で混合し、そしてメタン化することが開示されている。このメタンリッチなガスは、更なる処理の後、酸素を加えることによって、CrO−触媒使用下にメタノールに部分的に酸化される。
高炉ガスは、典型的には、40〜70体積%の窒素、好ましくは45〜60体積%の窒素、20〜30体積%の一酸化炭素、20〜25体積%の二酸化炭素、及び2〜4体積%の水素から構成される。
標準条件下におけるガス滞留時間に対する固体物質滞留時間が有利なことには、200〜5000の範囲、好ましくは300〜3000の範囲、特に400〜2000の範囲である。
Claims (15)
- 炭化水素を含む、及び/又は二酸化炭素を含む副生成ガス、付随ガス、及び/又は生物ガスを利用するための方法であって、
炭化水素を含む、及び/又は二酸化炭素を含む副生成ガス、付随ガス、及び/又は生物ガスを反応空間に導入し、及び副生成ガス、付随ガス、及び/又は生物ガスに含まれる複成分混合物が、高温領域で、1000℃を超える温度で、及び担体の存在下で、95体積%を超える量がCO、CO2、H2、H2O、CH4、及びN2から成る生成物ガス混合物に変換され、及び場合により、炭素含有固体物に変換され、
該炭素含有固体物は、炭素含有固体物の合計量に対して少なくとも75質量%が担体上に堆積し、及び
副生成ガス、付随ガス、及び/又は生物ガスのガス混合物の反応領域における流速が、20m/s未満であることを特徴とする方法。 - 前記流速が、10m/s未満であることを特徴とする請求項1に記載の方法。
- 生成物ガス混合物中の水素及び一酸化炭素の濃度が増加されることを特徴とする請求項1又は2に記載の方法。
- 生成物ガス混合物中の硫黄含有化合物の含有量が0.1体積%未満であることを特徴とする請求項1〜3の何れか1項に記載の方法。
- 副生成ガス、付随ガス、及び/又は生物ガスによって工程に導入された固体物質含有量の内、生成物ガス混合物に残留する固体物質部分が、2mg/標準m3未満であることを特徴とする請求項1〜4の何れか1項に記載の方法。
- 標準条件下における、単位ガス滞留時間に対する固体物質滞留時間が、200〜5000の範囲であることを特徴とする請求項1〜5の何れか1項に記載の方法。
- メタンの反応に必要とされる二酸化炭素が、少なくとも部分的に、二酸化炭素を含む副生成ガスを介して供給されることを特徴とする請求項1〜6の何れか1項に記載の方法。
- ガス状の出発材料の炭素/酸素モル割合が、1よりも大きく設定されていることを特徴とする請求項1〜7の何れか1項に記載の方法。
- ガス状の出発材料の炭素/酸素モル割合が、1よりも小さく設定されていることを特徴とする請求項1〜7の何れか1項に記載の方法。
- 前記担体として、炭素含有粒状物質が使用され、及び該炭素含有粒状物質が、移動床、又は流動床として、反応空間を通して連続的に輸送されることを特徴とする請求項1〜9の何れか1項に記載の方法。
- 高温領域で形成された合成ガスが、向流で移動床を通して輸送され、及び移動床との直接的な熱交換で冷却されることを特徴とする請求項1〜10の何れか1項に記載の方法。
- 前記高温領域で形成された合成ガスが、>200K/sで冷却されることを特徴とする請求項10又は11に記載の方法。
- 冷却領域におけるCOとH2の、最大温度における収率に対する収率損失が、10%未満であることを特徴とする請求項11又は12に記載の方法。
- コークスを製造するための方法であって、メタンを含む副生成ガスを反応空間に導入し、及び高温領域で、1000℃を超える温度で、及び炭素含有粒状物質の存在下に、メタンを水素と炭素に分解し、及び反応領域における前記副生成ガスの流速が20m/s未満であることを特徴とする方法。
- 請求項14に記載の方法に従い製造されたコークスを高炉で使用する方法。
Applications Claiming Priority (3)
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EP12197657 | 2012-12-18 | ||
EP12197657.5 | 2012-12-18 | ||
PCT/EP2013/076598 WO2014095661A1 (de) | 2012-12-18 | 2013-12-13 | Verfahren zur verwertung von kuppelgasen, begleitgasen und/oder biogasen |
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JP2016511208A true JP2016511208A (ja) | 2016-04-14 |
JP2016511208A5 JP2016511208A5 (ja) | 2017-01-19 |
JP6348120B2 JP6348120B2 (ja) | 2018-06-27 |
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US (1) | US10233078B2 (ja) |
EP (1) | EP2935517B1 (ja) |
JP (1) | JP6348120B2 (ja) |
KR (1) | KR102189389B1 (ja) |
CN (1) | CN105073952B (ja) |
AR (1) | AR094726A1 (ja) |
BR (1) | BR112015014205B1 (ja) |
ES (1) | ES2672331T3 (ja) |
PL (1) | PL2935517T3 (ja) |
RU (1) | RU2652720C2 (ja) |
TW (1) | TWI632111B (ja) |
UA (1) | UA115346C2 (ja) |
WO (1) | WO2014095661A1 (ja) |
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DE102015015531A1 (de) * | 2015-12-01 | 2017-06-01 | Basf Se | Verfahren zur Erzeugung von Synthesegas |
KR101758521B1 (ko) * | 2015-12-23 | 2017-07-17 | 주식회사 포스코 | 열풍로를 이용한 이산화탄소 분해 및 재활용 방법 |
DE112017002937A5 (de) | 2016-07-06 | 2019-08-08 | Hans-Jürgen Maaß | Verfahren zur parallelen Erzeugung von Synthesegas, Kohlenstoff und schadstoffarmer Restkohle aus Braunkohle |
DE112017005572A5 (de) | 2016-11-04 | 2019-08-22 | Basf Se | Verfahren und Vorrichtung zur Durchführung endothermer Gas-Feststoff-Reaktionen |
CN108593700B (zh) * | 2018-05-11 | 2020-12-11 | 武汉钢铁有限公司 | 一种模拟焦炭在高炉软熔带劣化过程的试验方法及模拟装置 |
DE102018209042A1 (de) * | 2018-06-07 | 2019-12-12 | Thyssenkrupp Ag | Anlagenverbund zur Stahlerzeugung sowie ein Verfahren zum Betreiben des Anlagenverbundes. |
CA3142493A1 (en) | 2019-06-05 | 2020-12-10 | Basf Se | Method and system for using the carbon oxide arising in the production of aluminium |
EP3981054A1 (de) | 2019-06-05 | 2022-04-13 | Basf Se | Elektrisch beheizte, hybride hochtemperaturverfahren |
KR102322712B1 (ko) * | 2019-11-20 | 2021-11-04 | 주식회사 포스코 | 일산화탄소 제조방법 및 그 활용 |
DE102020002088A1 (de) | 2020-04-01 | 2021-10-07 | Hans-Jürgen Maaß | Verfahren zur Herstellung von Strom, Synthesegas und Steinkohlesubstitut aus der Restkohle einer Kohleverschwelung |
CN111690423B (zh) * | 2020-06-11 | 2021-12-14 | 陕西东鑫垣化工有限责任公司 | 一种煤炭的分质清洁利用工艺 |
CN114317855A (zh) * | 2022-02-15 | 2022-04-12 | 华东理工大学 | 一种高炉炼铁的方法 |
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JPS4832104A (ja) * | 1971-09-01 | 1973-04-27 | ||
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JPS61186202A (ja) * | 1985-02-13 | 1986-08-19 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 炭化水素およびスチームおよび/またはco↓2からの水素含有ガスの製造方法 |
JP2005511467A (ja) * | 2000-05-08 | 2005-04-28 | ミッドウエスト リサーチ インスティチュート | 太陽熱によるエアゾール流反応処理方法 |
JP2005281609A (ja) * | 2004-03-30 | 2005-10-13 | Japan Oil Gas & Metals National Corp | フィッシャートロプシュ合成用合成ガスの製造方法および製造装置 |
JP2008536682A (ja) * | 2005-04-19 | 2008-09-11 | クネーベル、ケント・エス | 温度スイング吸着システム |
JP2010082611A (ja) * | 2008-10-03 | 2010-04-15 | Jfe Steel Corp | 炭酸ガスの分解方法 |
WO2010144544A1 (en) * | 2009-06-09 | 2010-12-16 | Sundrop Fuels, Inc. | Systems and methods for quenching, gas clean up, and ash removal |
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RU2015129289A (ru) | 2017-01-25 |
US10233078B2 (en) | 2019-03-19 |
US20160068390A1 (en) | 2016-03-10 |
TWI632111B (zh) | 2018-08-11 |
TW201438988A (zh) | 2014-10-16 |
WO2014095661A1 (de) | 2014-06-26 |
BR112015014205B1 (pt) | 2019-12-03 |
PL2935517T3 (pl) | 2018-12-31 |
CN105073952A (zh) | 2015-11-18 |
RU2652720C2 (ru) | 2018-04-28 |
EP2935517A1 (de) | 2015-10-28 |
BR112015014205A2 (pt) | 2018-06-26 |
JP6348120B2 (ja) | 2018-06-27 |
EP2935517B1 (de) | 2018-03-21 |
AR094726A1 (es) | 2015-08-26 |
KR102189389B1 (ko) | 2020-12-14 |
CN105073952B (zh) | 2017-05-24 |
KR20150096758A (ko) | 2015-08-25 |
ES2672331T3 (es) | 2018-06-13 |
UA115346C2 (uk) | 2017-10-25 |
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