JP2016500715A5 - - Google Patents

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Publication number
JP2016500715A5
JP2016500715A5 JP2015534792A JP2015534792A JP2016500715A5 JP 2016500715 A5 JP2016500715 A5 JP 2016500715A5 JP 2015534792 A JP2015534792 A JP 2015534792A JP 2015534792 A JP2015534792 A JP 2015534792A JP 2016500715 A5 JP2016500715 A5 JP 2016500715A5
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Japan
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complex
complex according
ethylenically unsaturated
unsaturated hydrocarbon
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JP2015534792A
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JP6185070B2 (ja
JP2016500715A (ja
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Priority claimed from PCT/US2013/062611 external-priority patent/WO2014052957A1/en
Publication of JP2016500715A publication Critical patent/JP2016500715A/ja
Publication of JP2016500715A5 publication Critical patent/JP2016500715A5/ja
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Claims (10)

  1. 一般式

    の錯体であって、式中、
    Mは第3族金属原子を表し、Lは中性ルイス塩基を表し、
    zは包括的に0〜2の整数であり、RはH又は一価の有機基であり、
    各Rは、H、ハロゲン原子、又は一価の有機基であり、
    各Rは独立して、H、ハロゲン原子、ヒドロカルビル基、ヒドロカルビルオキシ基、ヒドロカルビルチオ基、ジヒドロカルビルアミノ基、ジシリルアミノ基、又はジヒドロカルビルホスフィノ基であり、
    Qは−N(CH基であり、
    は二価の有機基であり、
    但し、次の:(1)2つのR基は結合して置換又は未置換ヒドロカルビレン基をもたらすことができる、並びに(2)RはRと結合して置換又は未置換ヒドロカルビレン基をもたらすことができる、のいずれか又は両方が真である、錯体。
  2. Lがテトラヒドロフランである、請求項1に記載の錯体。
  3. 各RがClである、請求項1に記載の錯体。
  4. MがNd又はGdである、請求項1に記載の錯体。
  5. がエチレン基である、請求項に記載の錯体。
  6. ポリマーを提供するプロセスであって、前記プロセスが、1種以上のエチレン性不飽和炭化水素モノマーを、請求項1〜5のいずれか1項に記載の錯体を含む触媒組成物と接触させることを含み、前記ポリマーが、前記モノマーの重合生成物を構成する、プロセス。
  7. 前記1種以上のエチレン性不飽和炭化水素モノマーが少なくとも1種のポリエンを含む、請求項に記載のプロセス。
  8. 前記1種以上のエチレン性不飽和炭化水素モノマーが、少なくとも1種のα−オレフィンを更に含む、請求項に記載のプロセス。
  9. 前記触媒組成物が、触媒活性化剤を更に含む、請求項6に記載のプロセス。
  10. 前記触媒活性化剤が、(1)アルキル化剤又は(2)非配位アニオンもしくは非配位アニオン前駆体を含む、請求項9に記載のプロセス。
JP2015534792A 2012-09-30 2013-09-30 有機金属触媒錯体及びこれを使用する重合方法 Active JP6185070B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261708027P 2012-09-30 2012-09-30
US61/708,027 2012-09-30
PCT/US2013/062611 WO2014052957A1 (en) 2012-09-30 2013-09-30 Organometallic catalyst complex and polymerization method employing same

Related Child Applications (1)

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JP2017144183A Division JP6445629B2 (ja) 2012-09-30 2017-07-26 有機金属触媒錯体及びこれを使用する重合方法

Publications (3)

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JP2016500715A JP2016500715A (ja) 2016-01-14
JP2016500715A5 true JP2016500715A5 (ja) 2016-09-08
JP6185070B2 JP6185070B2 (ja) 2017-08-23

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JP2017144183A Expired - Fee Related JP6445629B2 (ja) 2012-09-30 2017-07-26 有機金属触媒錯体及びこれを使用する重合方法

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US (1) US9403848B2 (ja)
EP (1) EP2900702B1 (ja)
JP (2) JP6185070B2 (ja)
CN (1) CN104903358B (ja)
WO (1) WO2014052957A1 (ja)

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