JP2016500715A5 - - Google Patents

Download PDF

Info

Publication number
JP2016500715A5
JP2016500715A5 JP2015534792A JP2015534792A JP2016500715A5 JP 2016500715 A5 JP2016500715 A5 JP 2016500715A5 JP 2015534792 A JP2015534792 A JP 2015534792A JP 2015534792 A JP2015534792 A JP 2015534792A JP 2016500715 A5 JP2016500715 A5 JP 2016500715A5
Authority
JP
Japan
Prior art keywords
group
complex
complex according
ethylenically unsaturated
unsaturated hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2015534792A
Other languages
English (en)
Other versions
JP2016500715A (ja
JP6185070B2 (ja
Filing date
Publication date
Application filed filed Critical
Priority claimed from PCT/US2013/062611 external-priority patent/WO2014052957A1/en
Publication of JP2016500715A publication Critical patent/JP2016500715A/ja
Publication of JP2016500715A5 publication Critical patent/JP2016500715A5/ja
Application granted granted Critical
Publication of JP6185070B2 publication Critical patent/JP6185070B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Claims (10)

  1. 一般式

    の錯体であって、式中、
    Mは第3族金属原子を表し、Lは中性ルイス塩基を表し、
    zは包括的に0〜2の整数であり、RはH又は一価の有機基であり、
    各Rは、H、ハロゲン原子、又は一価の有機基であり、
    各Rは独立して、H、ハロゲン原子、ヒドロカルビル基、ヒドロカルビルオキシ基、ヒドロカルビルチオ基、ジヒドロカルビルアミノ基、ジシリルアミノ基、又はジヒドロカルビルホスフィノ基であり、
    Qは−N(CH基であり、
    は二価の有機基であり、
    但し、次の:(1)2つのR基は結合して置換又は未置換ヒドロカルビレン基をもたらすことができる、並びに(2)RはRと結合して置換又は未置換ヒドロカルビレン基をもたらすことができる、のいずれか又は両方が真である、錯体。
  2. Lがテトラヒドロフランである、請求項1に記載の錯体。
  3. 各RがClである、請求項1に記載の錯体。
  4. MがNd又はGdである、請求項1に記載の錯体。
  5. がエチレン基である、請求項に記載の錯体。
  6. ポリマーを提供するプロセスであって、前記プロセスが、1種以上のエチレン性不飽和炭化水素モノマーを、請求項1〜5のいずれか1項に記載の錯体を含む触媒組成物と接触させることを含み、前記ポリマーが、前記モノマーの重合生成物を構成する、プロセス。
  7. 前記1種以上のエチレン性不飽和炭化水素モノマーが少なくとも1種のポリエンを含む、請求項に記載のプロセス。
  8. 前記1種以上のエチレン性不飽和炭化水素モノマーが、少なくとも1種のα−オレフィンを更に含む、請求項に記載のプロセス。
  9. 前記触媒組成物が、触媒活性化剤を更に含む、請求項6に記載のプロセス。
  10. 前記触媒活性化剤が、(1)アルキル化剤又は(2)非配位アニオンもしくは非配位アニオン前駆体を含む、請求項9に記載のプロセス。
JP2015534792A 2012-09-30 2013-09-30 有機金属触媒錯体及びこれを使用する重合方法 Active JP6185070B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261708027P 2012-09-30 2012-09-30
US61/708,027 2012-09-30
PCT/US2013/062611 WO2014052957A1 (en) 2012-09-30 2013-09-30 Organometallic catalyst complex and polymerization method employing same

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2017144183A Division JP6445629B2 (ja) 2012-09-30 2017-07-26 有機金属触媒錯体及びこれを使用する重合方法

Publications (3)

Publication Number Publication Date
JP2016500715A JP2016500715A (ja) 2016-01-14
JP2016500715A5 true JP2016500715A5 (ja) 2016-09-08
JP6185070B2 JP6185070B2 (ja) 2017-08-23

Family

ID=50389050

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2015534792A Active JP6185070B2 (ja) 2012-09-30 2013-09-30 有機金属触媒錯体及びこれを使用する重合方法
JP2017144183A Expired - Fee Related JP6445629B2 (ja) 2012-09-30 2017-07-26 有機金属触媒錯体及びこれを使用する重合方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2017144183A Expired - Fee Related JP6445629B2 (ja) 2012-09-30 2017-07-26 有機金属触媒錯体及びこれを使用する重合方法

Country Status (5)

Country Link
US (1) US9403848B2 (ja)
EP (1) EP2900702B1 (ja)
JP (2) JP6185070B2 (ja)
CN (1) CN104903358B (ja)
WO (1) WO2014052957A1 (ja)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112013019812B1 (pt) 2011-02-05 2021-06-15 Bridgestone Corporation Catalisadores de complexo metálico e métodos de polimerização aplicando o mesmo
EP2670760B1 (en) 2011-02-05 2018-03-21 Bridgestone Corporation Lanthanide complex catalyst and polymerization method employing same
KR101946659B1 (ko) 2011-02-05 2019-02-11 가부시키가이샤 브리지스톤 란타나이드 복합체 촉매 및 이를 이용한 중합 방법
US9879104B2 (en) 2015-04-28 2018-01-30 Exxonmobil Chemical Patents Inc. Process to produce ethylene conjugated diene copolymers and copolymers therefrom
WO2016175963A1 (en) * 2015-04-28 2016-11-03 Exxonmobil Chemical Patents Inc. Process to produce ethylene conjugated diene copolymers and copolymers therefrom
JP7416428B2 (ja) * 2017-12-01 2024-01-17 ユニバーシティ オブ フロリダ リサーチ ファンデーション インコーポレーティッド 立体規則性環拡大メタセシス重合のための組成物および方法

Family Cites Families (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3978103A (en) 1971-08-17 1976-08-31 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Sulfur containing organosilicon compounds
US3873489A (en) 1971-08-17 1975-03-25 Degussa Rubber compositions containing silica and an organosilane
SU580840A3 (ru) 1974-02-07 1977-11-15 Дегусса (Фирма) Способ получени серосодержащих кремнийорганических соединений
US4015061A (en) 1975-02-14 1977-03-29 The Firestone Tire & Rubber Company Protected amino-functional initiators and amino-terminated polymers and their production
US4002594A (en) 1975-07-08 1977-01-11 Ppg Industries, Inc. Scorch retardants for rubber reinforced with siliceous pigment and mercapto-type coupling agent
US4616069A (en) 1984-10-26 1986-10-07 Nippon Zeon Co., Ltd. Process for making diene polymer rubbers
US4906706A (en) 1986-09-05 1990-03-06 Japan Synthetic Rubber Co., Ltd. Modified conjugated diene polymer and process for production thereof
US5064910A (en) 1986-09-05 1991-11-12 Japan Synthetic Rubber Co., Ltd. Preparation of conjugated diene polymers modified with an organo-tin or germanium halide
US4935471A (en) 1987-10-15 1990-06-19 The Goodyear Tire & Rubber Company Capped polydienes
IT1230756B (it) 1989-02-17 1991-10-29 Enichem Elastomers Metodo per la preparazione di polibutadiene a lavorabilita' migliorata.
US5149457A (en) 1989-06-30 1992-09-22 Cyprus Foote Mineral Company Stable mixed lithium amide reagent compositions
US5196138A (en) 1989-06-30 1993-03-23 Cyprus Foote Mineral Company Preparation of mixed lithium amide reagents
US5153159A (en) 1990-04-09 1992-10-06 Bridgestone/Firestone, Inc. Elastomers and products having reduced hysteresis
US5329005A (en) 1992-10-02 1994-07-12 Bridgestone Corporation Soluble anionic polymerization initiators and preparation thereof
DE69410470T2 (de) 1993-07-30 1998-09-17 Nippon Zeon Co Modifiziertes konjugiertes diencopolymer, verfahren zu dessen herstellung und zusammensetzung daraus
US5567815A (en) 1994-07-18 1996-10-22 Bridgestone Corporation Teritary amine containing antonic initiators used in preparing polymers and process for the preparation thereof
DE4436059A1 (de) 1994-10-10 1996-04-11 Bayer Ag Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch
US5521309A (en) 1994-12-23 1996-05-28 Bridgestone Corporation Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same
US5496940A (en) 1995-02-01 1996-03-05 Bridgestone Corporation Alkyllithium compounds containing cyclic amines and their use in polymerization
US5580919A (en) 1995-03-14 1996-12-03 The Goodyear Tire & Rubber Company Silica reinforced rubber composition and use in tires
US5610227A (en) 1995-06-07 1997-03-11 Bridgestone/Firestone, Inc. Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis
US5583245A (en) 1996-03-06 1996-12-10 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5663398A (en) 1996-05-17 1997-09-02 Fmc Corporation Processes for preparing functionalized alkyllithium compounds
US5696197A (en) 1996-06-21 1997-12-09 The Goodyear Tire & Rubber Company Heterogeneous silica carbon black-filled rubber compound
US5663396A (en) 1996-10-31 1997-09-02 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5786441A (en) 1996-12-31 1998-07-28 Bridgestone Corporation Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties
US5684172A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
US5684171A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
ES2198651T3 (es) 1997-03-05 2004-02-01 Jsr Corporation Metodo para producir polimeros dieno conjugados.
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
US6525118B2 (en) 1997-07-11 2003-02-25 Bridgestone Corporation Processability of silica-filled rubber stocks with reduced hysteresis
FR2799468B1 (fr) 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
CA2424815C (en) 1999-11-12 2009-12-29 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
US6977281B1 (en) 1999-11-12 2005-12-20 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
EP1099711B1 (en) 1999-11-12 2006-03-29 JSR Corporation Modified conjugated diene polymer, method of producing it and rubber composition comprising the same
US6531424B2 (en) * 1999-12-17 2003-03-11 E. I. Du Pont De Nemours And Company Polymerization of olefins
JP2004504420A (ja) 2000-07-17 2004-02-12 ユニベーション・テクノロジーズ・エルエルシー 触媒系及びその重合方法への使用
EP1332162B1 (en) 2000-11-10 2013-05-01 Bridgestone Corporation Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents
WO2002060958A2 (en) 2001-02-01 2002-08-08 Fmc Corporation Functionalized initiators for anionic polymerization, protected funtionalized polymers, deprotected analogues thereof, and methods of making the same
WO2003010207A1 (fr) * 2001-07-23 2003-02-06 Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences Catalyseurs de polymerisation ou de copolymerisation d'olefines, leur procede de preparation et leur utilisation
US6699813B2 (en) 2001-11-07 2004-03-02 Bridgestone Corporation Lanthanide-based catalyst composition for the manufacture of polydienes
CN100523023C (zh) 2002-10-16 2009-08-05 米其林技术公司 乙烯/丁二烯共聚物,用于合成其的催化体系和方法
US7153919B2 (en) 2002-10-30 2006-12-26 Bridgestone Corporation Use of sulfur containing initiators for anionic polymerization of monomers
WO2004044018A2 (en) 2002-11-07 2004-05-27 Dow Global Technologies, Inc. Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby
FR2858817B1 (fr) 2003-08-13 2006-02-03 Michelin Soc Tech Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
ES2588177T3 (es) 2004-03-02 2016-10-31 Bridgestone Corporation Proceso de polimerización en masa
ES2533455T3 (es) 2004-10-26 2015-04-10 Bridgestone Corporation Polímero funcionalizado con grupo enlazante
US7816483B2 (en) 2005-08-11 2010-10-19 Bridgestone Corporation Amine functionalized polymer
JP5079294B2 (ja) 2005-10-04 2012-11-21 株式会社ブリヂストン アミンで官能化されたポリマー
US7879952B2 (en) 2005-12-28 2011-02-01 Bridgestone Corporation Functionalized polymers
US7671138B2 (en) 2006-05-26 2010-03-02 Bridgestone Corporation Polymers functionized with hydrobenzamides
US7732534B2 (en) 2006-08-28 2010-06-08 Bridgestone Corporation Polymers functionalized with nitro compounds
US8088868B2 (en) 2006-12-19 2012-01-03 Bridgestone Corporation Polymers functionalized with protected oxime compounds
ZA200711158B (en) 2006-12-28 2009-03-25 Bridgestone Corp A method for producing functionalized cis-1,4-polydienes having high cis-1,4-linkage content and high functionality
MY152879A (en) * 2007-07-04 2014-11-28 Mitsui Chemicals Inc Transition metal complex compounds, olefin oligomerization catalysts including the compounds, and processes for producing olefin oligomers using the catalysts
US7879958B2 (en) 2007-08-07 2011-02-01 Bridgestone Corporation Polyhydroxy compounds as polymerization quenching agents
US8324329B2 (en) 2007-08-07 2012-12-04 Bridgestone Corporation Process for producing functionalized polymers
EP2202247B1 (en) * 2007-10-16 2012-12-12 Sinopec Yangzi Petrochemical Company Ltd. Supported non-metallocene catalyst and its preparation method
EP2202246B1 (en) * 2007-10-16 2016-06-15 Sinopec Yangzi Petrochemical Company Ltd. Non-metallocene catalyst supported on magnesium compound and its preparation method
CN101965420B (zh) 2008-07-16 2013-07-17 日本爱克兰工业株式会社 抗静电丙烯腈系纤维及其制造方法
CN101402694B (zh) * 2008-11-17 2010-10-27 中国科学院长春应用化学研究所 三齿水杨醛亚胺钒烯烃聚合催化剂及制备方法和应用
KR101727342B1 (ko) 2009-06-30 2017-04-14 가부시키가이샤 브리지스톤 히드록시아릴 관능화 중합체
KR101946659B1 (ko) 2011-02-05 2019-02-11 가부시키가이샤 브리지스톤 란타나이드 복합체 촉매 및 이를 이용한 중합 방법
EP2670760B1 (en) 2011-02-05 2018-03-21 Bridgestone Corporation Lanthanide complex catalyst and polymerization method employing same

Similar Documents

Publication Publication Date Title
JP2016500715A5 (ja)
JP2015516399A5 (ja)
JP2011231337A5 (ja)
JP2015518463A5 (ja)
JP2017519849A5 (ja)
JP2015511650A5 (ja)
JP2016520672A5 (ja)
JP2016537478A5 (ja)
JP2015503671A5 (ja)
JP2015536376A5 (ja)
RU2011135031A (ru) Полимеры, функционализированные полицианосоединениями
RU2013140837A (ru) Металлические комплексные катализаторы и способы полимеризации с их применением
JP2015503643A5 (ja)
JP2016125056A5 (ja)
JP2011508037A5 (ja)
JP2016510835A5 (ja)
JP2017516911A5 (ja)
JP2014529350A5 (ja)
JP2018507289A5 (ja)
RU2013140838A (ru) Лантаноидный комплексный катализатор и способ полимеризации с его применением
JP2016504446A5 (ja)
RU2013140836A (ru) Лантаноидный комплексный катализатор и способ полимеризации с его применением
JP2013535519A5 (ja)
JP2016539199A5 (ja)
JP2015227469A5 (ja)