JP2015525268A5 - - Google Patents
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- JP2015525268A5 JP2015525268A5 JP2015515416A JP2015515416A JP2015525268A5 JP 2015525268 A5 JP2015525268 A5 JP 2015525268A5 JP 2015515416 A JP2015515416 A JP 2015515416A JP 2015515416 A JP2015515416 A JP 2015515416A JP 2015525268 A5 JP2015525268 A5 JP 2015525268A5
- Authority
- JP
- Japan
- Prior art keywords
- independently
- heteroatom
- hydrocarbon moiety
- appendix
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 21
- 125000005842 heteroatom Chemical group 0.000 claims description 19
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 229910052719 titanium Inorganic materials 0.000 claims description 13
- 239000010936 titanium Substances 0.000 claims description 13
- 229910052726 zirconium Inorganic materials 0.000 claims description 13
- 229910052735 hafnium Inorganic materials 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 125000004429 atom Chemical group 0.000 claims description 10
- 150000004696 coordination complex Chemical class 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Chemical group 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000003446 ligand Substances 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052710 silicon Chemical group 0.000 claims description 4
- 239000010703 silicon Chemical group 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 150000004703 alkoxides Chemical class 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 150000004678 hydrides Chemical class 0.000 claims description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 3
- 239000003426 co-catalyst Substances 0.000 claims description 2
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000011701 zinc Substances 0.000 description 7
- 150000001336 alkenes Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- -1 aluminum compound Chemical class 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 1
- OJJVPGJEBAZOIF-UHFFFAOYSA-N (2,3,4,5-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=CC(F)=C(F)C(F)=C1F OJJVPGJEBAZOIF-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- NPHLURKGGOFSPO-UHFFFAOYSA-N tris(2,3,4,5-tetrafluorophenyl)borane Chemical compound FC1=C(F)C(F)=CC(B(C=2C(=C(F)C(F)=C(F)C=2)F)C=2C(=C(F)C(F)=C(F)C=2)F)=C1F NPHLURKGGOFSPO-UHFFFAOYSA-N 0.000 description 1
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12004263.5A EP2671639B1 (en) | 2012-06-04 | 2012-06-04 | Guanidinate complexes and their use as chain transfer polymerization catalysts |
| EP12004263.5 | 2012-06-04 | ||
| PCT/EP2013/001614 WO2013182290A1 (en) | 2012-06-04 | 2013-06-03 | Amidinate and guanidinate complexes, their use as chain transfer polymerization catalysts and long chain alcohols obtained by such process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015525268A JP2015525268A (ja) | 2015-09-03 |
| JP2015525268A5 true JP2015525268A5 (enExample) | 2016-08-12 |
Family
ID=48570057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015515416A Pending JP2015525268A (ja) | 2012-06-04 | 2013-06-03 | アミジナートおよびグアニジナート錯体、連鎖移動重合触媒としてのそれらの使用、ならびに当該方法により得られる長鎖アルコール |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9579640B2 (enExample) |
| EP (2) | EP2671639B1 (enExample) |
| JP (1) | JP2015525268A (enExample) |
| CN (1) | CN104349840A (enExample) |
| BR (1) | BR112014030113A2 (enExample) |
| CA (1) | CA2874682A1 (enExample) |
| ES (1) | ES2620287T3 (enExample) |
| PL (1) | PL2671639T3 (enExample) |
| RU (1) | RU2014149897A (enExample) |
| WO (1) | WO2013182290A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2857423B1 (en) * | 2013-10-07 | 2020-09-16 | Arlanxeo Netherlands B.V. | Catalyst system |
| CN105813742B (zh) * | 2013-12-19 | 2020-05-15 | 陶氏环球技术有限责任公司 | 金属-配位体络合物、由其衍生的烯烃聚合催化剂以及利用所述催化剂的烯烃聚合方法 |
| EP3037437A1 (en) * | 2014-12-23 | 2016-06-29 | SABIC Global Technologies B.V. | Process for the preparation of a polyolefin having one or multiple end-functionalized branches. |
| EP3093280A1 (en) | 2015-05-13 | 2016-11-16 | Sasol Performance Chemicals GmbH | Process for the oligomerisation of olefins by coordinative chain transfer polymerisation and catalyst synthesis |
| EP3294692A1 (en) * | 2015-05-13 | 2018-03-21 | Sasol Performance Chemicals GmbH | Process for the oligomerisation of olefins by coordinative chain transfer polymerisation |
| CN104857989B (zh) * | 2015-05-27 | 2017-03-01 | 山西大学 | 一种双胍基铝金属催化剂及其制备方法和应用 |
| JP6916808B2 (ja) * | 2016-03-31 | 2021-08-11 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合触媒 |
| JP7259026B2 (ja) | 2018-11-30 | 2023-04-17 | ダウ グローバル テクノロジーズ エルエルシー | 注出ポンプを備える可撓性容器 |
| KR20220016111A (ko) | 2019-05-31 | 2022-02-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 모노-두자리 리간드, 비스-두자리 리간드 및 테트라-두자리 리간드 구아니딘 4족 전이 금속 올레핀 공중합 촉매 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3419352A (en) | 1964-12-02 | 1968-12-31 | Continental Oil Co | Process for producing alpha alumina monohydrate |
| US3641085A (en) | 1969-05-01 | 1972-02-08 | Continental Oil Co | Oxidation of aluminum alkyls |
| US3660447A (en) | 1969-07-18 | 1972-05-02 | Ethyl Corp | Process of oxidizing aluminum alkyls |
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| EP0329891A2 (en) | 1988-02-23 | 1989-08-30 | Petrolite Corporation | End-functionalized low molecular weight polymers of ethylene |
| US5043515A (en) * | 1989-08-08 | 1991-08-27 | Shell Oil Company | Ethylene oligomerization catalyst and process |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5502128A (en) | 1994-12-12 | 1996-03-26 | University Of Massachusetts | Group 4 metal amidinate catalysts and addition polymerization process using same |
| FI102476B1 (fi) | 1996-05-31 | 1998-12-15 | Borealis As | Uudet siirtymämetallikompleksit ja menetelmä niiden valmistamiseksi |
| JP3588665B2 (ja) * | 1996-06-04 | 2004-11-17 | 東ソー株式会社 | 遷移金属錯体を用いたオレフィン重合触媒およびそれを用いたポリオレフィンの製造法 |
| US5777120A (en) | 1997-03-14 | 1998-07-07 | University Of Iowa Research Foundation | Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts |
| WO2002060965A2 (en) * | 2000-12-12 | 2002-08-08 | Baker Hughes Incorporated | Low molecular weight isotactic polypropylene polymers, copolymers and derivatives and materials prepared therewith |
| DE102004030080A1 (de) * | 2004-06-22 | 2006-01-12 | Sasol Germany Gmbh | Verfahren zur Herstellung primärer langkettiger Alkohole |
| US20100209610A1 (en) * | 2007-07-16 | 2010-08-19 | Advanced Technology Materials, Inc. | Group iv complexes as cvd and ald precursors for forming metal-containing thin films |
| CN102432700A (zh) * | 2011-09-01 | 2012-05-02 | 山西大学 | 桥联双脒基钛金属催化剂及其制备方法和应用 |
| US20130131294A1 (en) * | 2011-11-21 | 2013-05-23 | John R. Hagadorn | Amidinate Catalyst Compounds, Process for Their Use and Polymers Produced Therefrom |
-
2012
- 2012-06-04 EP EP12004263.5A patent/EP2671639B1/en not_active Not-in-force
- 2012-06-04 PL PL12004263T patent/PL2671639T3/pl unknown
- 2012-06-04 ES ES12004263.5T patent/ES2620287T3/es active Active
-
2013
- 2013-06-03 RU RU2014149897A patent/RU2014149897A/ru not_active Application Discontinuation
- 2013-06-03 JP JP2015515416A patent/JP2015525268A/ja active Pending
- 2013-06-03 BR BR112014030113A patent/BR112014030113A2/pt not_active IP Right Cessation
- 2013-06-03 WO PCT/EP2013/001614 patent/WO2013182290A1/en not_active Ceased
- 2013-06-03 EP EP13726429.7A patent/EP2855015A1/en not_active Withdrawn
- 2013-06-03 CA CA2874682A patent/CA2874682A1/en not_active Abandoned
- 2013-06-03 US US14/405,505 patent/US9579640B2/en not_active Expired - Fee Related
- 2013-06-03 CN CN201380029386.2A patent/CN104349840A/zh active Pending
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