JP2015506908A - ホルムアルデヒドの水含有供給源の脱水、およびエチレン性不飽和カルボン酸エステルを生成するための方法 - Google Patents

ホルムアルデヒドの水含有供給源の脱水、およびエチレン性不飽和カルボン酸エステルを生成するための方法 Download PDF

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Publication number
JP2015506908A
JP2015506908A JP2014540247A JP2014540247A JP2015506908A JP 2015506908 A JP2015506908 A JP 2015506908A JP 2014540247 A JP2014540247 A JP 2014540247A JP 2014540247 A JP2014540247 A JP 2014540247A JP 2015506908 A JP2015506908 A JP 2015506908A
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Prior art keywords
water
formaldehyde
source
containing source
zeolite membrane
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Pending
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JP2014540247A
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English (en)
Japanese (ja)
Inventor
嘉之 姫野
嘉之 姫野
大谷内　健
健 大谷内
近藤　正英
正英 近藤
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Mitsubishi Chemical UK Ltd
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Mitsubishi Chemical UK Ltd
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Priority to JP2014540247A priority Critical patent/JP2015506908A/ja
Publication of JP2015506908A publication Critical patent/JP2015506908A/ja
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
    • B01D61/362—Pervaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/028—Molecular sieves
    • B01D71/0281—Zeolites
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/448—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by pervaporation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/786—Separation; Purification; Stabilisation; Use of additives by membrane separation process, e.g. pervaporation, perstraction, reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/56—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/34—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/79—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2014540247A 2012-02-17 2013-02-18 ホルムアルデヒドの水含有供給源の脱水、およびエチレン性不飽和カルボン酸エステルを生成するための方法 Pending JP2015506908A (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2014540247A JP2015506908A (ja) 2012-02-17 2013-02-18 ホルムアルデヒドの水含有供給源の脱水、およびエチレン性不飽和カルボン酸エステルを生成するための方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
PCT/JP2012/054498 WO2013121594A1 (en) 2012-02-17 2012-02-17 Dehydration of water containing source of formaldehyde, and a method for producing an ethylenically unsaturated carboxylic ester
JPPCT/JP2012/054498 2012-02-17
JP2014540247A JP2015506908A (ja) 2012-02-17 2013-02-18 ホルムアルデヒドの水含有供給源の脱水、およびエチレン性不飽和カルボン酸エステルを生成するための方法
PCT/JP2013/054639 WO2013122268A1 (en) 2012-02-17 2013-02-18 Dehydration of water containing source of formaldehyde, and a method for producing an ethylenically unsaturated carboxylic ester

Related Child Applications (1)

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JP2017054078A Division JP6391744B2 (ja) 2012-02-17 2017-03-21 ホルムアルデヒドの水含有供給源の脱水、およびエチレン性不飽和カルボン酸エステルを生成するための方法

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JP2015506908A true JP2015506908A (ja) 2015-03-05

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JP2014540247A Pending JP2015506908A (ja) 2012-02-17 2013-02-18 ホルムアルデヒドの水含有供給源の脱水、およびエチレン性不飽和カルボン酸エステルを生成するための方法
JP2017054078A Expired - Fee Related JP6391744B2 (ja) 2012-02-17 2017-03-21 ホルムアルデヒドの水含有供給源の脱水、およびエチレン性不飽和カルボン酸エステルを生成するための方法

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Country Status (16)

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US (2) US10093559B2 (enExample)
EP (2) EP4029593A1 (enExample)
JP (2) JP2015506908A (enExample)
KR (1) KR102058178B1 (enExample)
CN (1) CN104254389B (enExample)
AU (1) AU2013221193B2 (enExample)
BR (1) BR112014020319B1 (enExample)
CA (1) CA2864701C (enExample)
ES (1) ES2913076T3 (enExample)
IN (1) IN2014MN01685A (enExample)
MX (1) MX367141B (enExample)
MY (1) MY173232A (enExample)
RU (1) RU2632869C2 (enExample)
SG (1) SG11201404923SA (enExample)
TW (1) TWI582071B (enExample)
WO (2) WO2013121594A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017124371A (ja) * 2016-01-14 2017-07-20 株式会社東芝 ガス分離体とそれを用いたガス分離装置
CN117482988A (zh) * 2023-06-19 2024-02-02 中国科学院过程工程研究所 一种用于合成丙烯酸甲酯的催化剂制备方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014112021A1 (de) 2014-08-22 2016-02-25 Karlsruher Institut für Technologie Verfahren zur Herstellung von Oxymethylendialkylethern und deren Verwendung
DE102016222657A1 (de) 2016-11-17 2018-05-17 OME Technologies GmbH Verfahren zur Herstellung von Polyoxymethylendimethylethern aus Formaldehyd und Methanol in wässrigen Lösungen
US10377689B2 (en) 2016-11-17 2019-08-13 OME Technologies GmbH Process for preparing polyoxymethylene dimethyl ethers from formaldehyde and methanol in aqueous solutions
CN106831380B (zh) * 2017-01-19 2020-05-22 中国科学院成都有机化学有限公司 甲醛溶液脱水浓缩的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5289570A (en) * 1976-01-22 1977-07-27 Asahi Chem Ind Co Ltd Gaseous phase separation
JPH07185275A (ja) * 1993-12-27 1995-07-25 Mitsui Eng & Shipbuild Co Ltd 液体混合物分離膜
DE10004562A1 (de) * 2000-02-02 2001-08-09 Basf Ag Verfahren zur Herstellung von alkoholischen Formaldehydlösungen mittels Membrantrennverfahren
JP2002517477A (ja) * 1998-06-05 2002-06-18 イネオス アクリリックス ユーケー リミティド 脱水方法

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SU141148A1 (ru) * 1960-12-14 1961-11-30 В.Б. Коган Метод концентрировани водных растворов формальдегида
GB1107234A (en) * 1965-10-22 1968-03-27 Air Reduction Production of acrylate and methacrylate esters
US4035291A (en) * 1970-06-16 1977-07-12 Monsanto Company Process for separating aqueous formaldehyde mixtures
US5387269A (en) 1993-09-03 1995-02-07 At&T Bell Laboratories Methods for making planar waveguides with removal of a sacrifical member which surrounds the core
DE4337231A1 (de) * 1993-10-30 1995-05-04 Basf Ag Verfahren zur Gewinnung konzentrierter wäßriger Formaldehydlösungen durch Pervaporation
US5554286A (en) * 1993-12-27 1996-09-10 Mitsui Engineering & Shipbuilding Co., Ltd. Membrane for liquid mixture separation
DE19732291A1 (de) * 1997-07-26 1999-01-28 Basf Ag Verfahren zur Abtrennung von Trioxan
JP3686262B2 (ja) 1998-07-27 2005-08-24 三井造船株式会社 混合物分離膜
US20030134662A1 (en) 2001-12-28 2003-07-17 Samsung Electronics Co., Ltd. Clear reject message for call clearing and mobile resource assignment with holding call
US6755975B2 (en) * 2002-06-12 2004-06-29 Membrane Technology And Research, Inc. Separation process using pervaporation and dephlegmation
JP2006265123A (ja) 2005-03-22 2006-10-05 Toray Ind Inc 高濃度ホルムアルデヒド水溶液の連続製造方法
JP5135671B2 (ja) 2005-09-28 2013-02-06 三菱化学株式会社 ゼオライト分離膜の製造方法
GB0710265D0 (en) * 2007-05-30 2007-07-11 Phoenix Ipr Ltd Membrane structures and their production and use
GB0809332D0 (en) 2008-05-22 2008-07-02 Lucite Int Uk Ltd Production of ethylenically unsaturated acids or esters thereof
CN101721920A (zh) 2009-12-11 2010-06-09 大连理工大学 一种NaA沸石分子筛膜渗透蒸发脱除糠醛中水的方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5289570A (en) * 1976-01-22 1977-07-27 Asahi Chem Ind Co Ltd Gaseous phase separation
JPH07185275A (ja) * 1993-12-27 1995-07-25 Mitsui Eng & Shipbuild Co Ltd 液体混合物分離膜
JP2002517477A (ja) * 1998-06-05 2002-06-18 イネオス アクリリックス ユーケー リミティド 脱水方法
DE10004562A1 (de) * 2000-02-02 2001-08-09 Basf Ag Verfahren zur Herstellung von alkoholischen Formaldehydlösungen mittels Membrantrennverfahren

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017124371A (ja) * 2016-01-14 2017-07-20 株式会社東芝 ガス分離体とそれを用いたガス分離装置
CN117482988A (zh) * 2023-06-19 2024-02-02 中国科学院过程工程研究所 一种用于合成丙烯酸甲酯的催化剂制备方法

Also Published As

Publication number Publication date
BR112014020319B1 (pt) 2021-05-04
WO2013121594A1 (en) 2013-08-22
MX367141B (es) 2019-08-07
JP6391744B2 (ja) 2018-09-19
US10793448B2 (en) 2020-10-06
AU2013221193A1 (en) 2014-09-11
TWI582071B (zh) 2017-05-11
EP4029593A1 (en) 2022-07-20
MY173232A (en) 2020-01-07
RU2632869C2 (ru) 2017-10-11
RU2014137472A (ru) 2016-04-10
US20150053616A1 (en) 2015-02-26
WO2013122268A1 (en) 2013-08-22
EP2814596B1 (en) 2022-04-06
KR20140129199A (ko) 2014-11-06
KR102058178B1 (ko) 2019-12-20
MX2014009868A (es) 2015-06-05
SG11201404923SA (en) 2014-09-26
IN2014MN01685A (enExample) 2015-05-29
TW201336821A (zh) 2013-09-16
AU2013221193B2 (en) 2017-11-23
EP2814596A1 (en) 2014-12-24
CA2864701A1 (en) 2013-08-22
ES2913076T3 (es) 2022-05-31
CA2864701C (en) 2022-04-26
US20190062181A1 (en) 2019-02-28
JP2017137335A (ja) 2017-08-10
CN104254389A (zh) 2014-12-31
CN104254389B (zh) 2017-05-31
US10093559B2 (en) 2018-10-09

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